Portland State University PDXScholar Dissertations and Theses Dissertations and Theses 1982 An investigation of cadmium and sulfur reactions in dimethylsulfoxide Howard W. Hogle Portland State University Follow this and additional works at: https://pdxscholar.library.pdx.edu/open_access_etds Part of the Inorganic Chemistry Commons Let us know how access to this document benefits ou.y Recommended Citation Hogle, Howard W., "An investigation of cadmium and sulfur reactions in dimethylsulfoxide" (1982). Dissertations and Theses. Paper 3213. https://doi.org/10.15760/etd.3204 This Thesis is brought to you for free and open access. It has been accepted for inclusion in Dissertations and Theses by an authorized administrator of PDXScholar. Please contact us if we can make this document more accessible:
[email protected]. AN ABSTRACT OF THE THESIS OF Howard W. Hogle for the Master of Science in Chemistry presented July 23, 1982. Title: An Investigation of Cadmium and Sulfur Reactions in Dimethylsulfoxide. APPROVED BY MEMBERS OF THE THESIS COMMITTEE: David K. Roe, Chairman Dennis W. Barnum The study of the reaction of cadmium and sulfur in dimethyl- sulfoxide (DMSO) is presented. Specifically, the reaction of dissolved molecular sulfur in DMSO at temperatures greater than 90°C with freshly precipitated metallic cadmium is followed by UV-visible spectrometry, atomic absorption spectrometry, and Raman spectrometry. Evidence for the formation of a new cadmium-sulfur species and S3- is discussed. In a second reaction, an equilibrium sodium polysulfide solution in DMSO is titrated with a solution of cadmium ion at room 2 temperature and the reaction progress is followed by means of UV visible spectrometry.