Glencore Technology August Newsletter

Total Page:16

File Type:pdf, Size:1020Kb

Glencore Technology August Newsletter Copper Refinery Modernisation in Zambia Glencore Technology is currently commissioning one of its largest copper refinery conversion projects to date, the modernisation of Glencore’s Mufulira Copper Refinery, in Zambia. The refinery, having a capacity of 220 KTPa of copper, was a copper starter sheet operation, and has been modernised using ISAKIDD™ proprietary technology. As part of the modernisation Glencore Technology has supplied electrode handling equipment including 3 Cathode Stripping Machines, Operator conducting cell inspections an Anode Scrap Washing machine, and an Anode Preparation Machine. The cathode plates used at Mufulira are manufactured using Glencore Technology proprietary Duplex stainless steel. Glencore Technology personnel also assisted with the detailed design, planning, commissioning and training. Brendan O’Rourke, Glencore Technology Senior Project Manager, said that Mufulira is now producing LME Grade A Copper. Mufulira is now the single largest user of Duplex cathode plates, which have High grade copper cathode become the benchmark in electro refining and production electrowinning due to their superior mechanical strength and corrosion resistance properties. This results in better flexing performance in the cathode stripping operation, reducing the chance of permanent deformation of the cathode plate blade, resulting in longer cathode plate life New Feed Port design – for better IsaSmelt™ pressure control The Mount Isa Copper Smelter, in conjunction with Glencore Technology, has been working towards improving the system that controls the Mount Isa IsaSmelt™ furnace pressure at the port where the feed is added to the furnace. Together they have developed and installed a new Induced Draught IsaSmelt™ feed port which will be offered to all IsaSmelt™ customers. Previously the Mount Isa IsaSmelt™ furnace was charged with fluxed concentrates which were delivered via conveyor into an open chute at the feed Induced Draft feed port prior to port. This feed port was open to atmosphere, and installation difficulties in fine control of the furnace internal gas pressures in this region, made it hard to avoid pressure fluctuations during operation, which resulted in poor workplace hygiene. The inductively sealed feed port makes the internal furnace pressure much easier to control and significantly improve the workplace hygiene in this area. In addition, the inductively sealed feed port lessens the build-up of unburnt concentrate on the vessel wall. ZipaTanks™ under Construction in the Arctic Circle Glencore Technology’s unique slurry tank design, the ZipaTank™, is under construction at TMAC’s Hope Bay gold project, located in the article circle, Nunavut, Canada. The plant consists of grinding and flotation circuits, with the concentrate undergoing leaching to produce gold bullion. The ZipaTanks™ will be part of the leaching circuit. Paul Voigt Hydrometallurgy Manager at Glencore Technology, said the ZipaTanks™ were well suited to remote and harsh conditions such as Hope Bay, as they were easy to containerise, with the shell, base and associated auxiliary equipment being able to fit in a standard shipping container. The rubber lined tanks were manufactured, constructed and water tested in Australia under controlled conditions, before being disassembled and Completed ZipaTank™ prior to packed for shipment. Paul said the volume of the tanks containerisation to site were just over 90m3, and said the tanks were to be used in leach residue storage and detox duties at the site, where cyanide underwent chemical reactions to render it harmless. Each tank is complete with baffles, nozzles, overflows and agitator platforms as well as other equipment suited to each duty. The ZipaTank™ is designed as a modular slurry storage and agitation system, for rapid site installation with only the tank base requiring welding at site. The rest of the tank and auxiliaries are bolted in place, no specialist skills are required, nor is there any scaffolding required during installation. Lining is applied in controlled conditions out of the elements, ensuring a longer service life than lining applied at site. Glencore Technology After Market and Specialist Services Glencore Technology prides itself on being able to supply its clients with a full selection of wear and replacement parts for its current and older technology models. With warehouses around the world, clients are guaranteed on being able to have critical parts delivered to them in the quickest possible lead times. Glencore Technology also offers a range of specialist services to improve the productivity, availability or maintenance in your plant, ranging from mineral processing to smelting and refining. Backed by first hand operational experience in real plants, Glencore Technology’s specialist and experts can assist in getting the most out of your plants. Whether it is operational services, specialist engineering components or designs for items or functions that might be deemed “too hard” by others, Glencore Technology has the experience that can provide you with solutions that work. For ordering parts, services or general enquiries on what we can provide contact us on: Email: [email protected] Tel +61 7 3833 8500 Fax +61 7 3833 8555 .
Recommended publications
  • From Base Metals and Back – Isamills and Their Advantages in African Base Metal Operations
    The Southern African Institute of Mining and Metallurgy Base Metals Conference 2013 H. de Waal, K. Barns, and J. Monama From base metals and back – IsaMills and their advantages in African base metal operations H. de Waal, K. Barns, and J. Monama Xstrata IsaMill™ technology was developed from Netzsch Feinmahltechnik GmbH stirred milling technology in the early 1990s to bring about a step change in grinding efficiency that was required to make Xstrata’s fine-grained lead/zinc orebodies economic to process. From small-scale machines suited to ultrafine grinding, the IsaMill™ has developed into technology that is able to treat much larger tonnages, in coarser applications, while still achieving high energy efficiency, suited for coarser more standard regrind and mainstream grinding applications. The unique design of the IsaMillTM, combining high power intensity and effective internal classification, achieves high energy efficiency and tight product distribution which can be effectively scaled from laboratory scale to full-sized models. The use of fine ceramic media also leads to significant benefits in downstream flotation and leaching operations. These benefits are key drivers for the adoption of the technology into processing a diverse range of minerals worldwide, and offer major opportunities for power reduction and improved metallurgy for the African base metal operations. Keywords: IsaMill, regrind, energy efficiency, inert grinding. Introduction The development of the IsaMillTM, by MIM (now GlencoreXstrata) and Netzsch Feinmahltechnik GmbH, was initiated to enable the development of the fine-grained ore deposits at Mt Isa and McArthur River in Northern Australia. To liberate the valuable minerals and so produce a saleable concentrate this ultrafine-grained ore needed to be ground to a P80 of 7 μm.
    [Show full text]
  • Significance of Mineralogy in the Development of Flowsheets for Processing Uranium Ores
    JfipwK LEACHING TIME REAGENTS TEMPERATURE FLOCCULANT CLARITY AREA COUNTER CURRENT DECANTATION It 21 21 J^^LJt TECHNICAL REPORTS SERIES No.19 6 Significance of Mineralogy in the Development of Flowsheets for Processing Uranium Ores \W# INTERNATIONAL ATOMIC ENERGY AGENCY, VIENNA, 1980 SIGNIFICANCE OF MINERALOGY IN THE DEVELOPMENT OF FLOWSHEETS FOR PROCESSING URANIUM ORES The following States are Members of the International Atomic Energy Agency: AFGHANISTAN HOLY SEE PHILIPPINES ALBANIA HUNGARY POLAND ALGERIA ICELAND PORTUGAL ARGENTINA INDIA QATAR AUSTRALIA INDONESIA ROMANIA AUSTRIA IRAN SAUDI ARABIA BANGLADESH IRAQ SENEGAL BELGIUM IRELAND SIERRA LEONE BOLIVIA ISRAEL SINGAPORE BRAZIL ITALY SOUTH AFRICA BULGARIA IVORY COAST SPAIN BURMA JAMAICA SRI LANKA BYELORUSSIAN SOVIET JAPAN SUDAN SOCIALIST REPUBLIC JORDAN SWEDEN CANADA KENYA SWITZERLAND CHILE KOREA, REPUBLIC OF SYRIAN ARAB REPUBLIC COLOMBIA KUWAIT THAILAND COSTA RICA LEBANON TUNISIA CUBA LIBERIA TURKEY CYPRUS LIBYAN ARAB JAMAHIRIYA UGANDA CZECHOSLOVAKIA LIECHTENSTEIN UKRAINIAN SOVIET SOCIALIST DEMOCRATIC KAMPUCHEA LUXEMBOURG REPUBLIC DEMOCRATIC PEOPLE'S MADAGASCAR UNION OF SOVIET SOCIALIST REPUBLIC OF KOREA MALAYSIA REPUBLICS DENMARK MALI UNITED ARAB EMIRATES DOMINICAN REPUBLIC MAURITIUS UNITED KINGDOM OF GREAT ECUADOR MEXICO BRITAIN AND NORTHERN EGYPT MONACO IRELAND EL SALVADOR MONGOLIA UNITED REPUBLIC OF ETHIOPIA MOROCCO CAMEROON FINLAND NETHERLANDS UNITED REPUBLIC OF FRANCE NEW ZEALAND TANZANIA GABON NICARAGUA UNITED STATES OF AMERICA GERMAN DEMOCRATIC REPUBLIC NIGER URUGUAY GERMANY, FEDERAL REPUBLIC OF NIGERIA VENEZUELA GHANA NORWAY VIET NAM GREECE PAKISTAN YUGOSLAVIA GUATEMALA PANAMA ZAIRE HAITI PARAGUAY ZAMBIA PERU The Agency's Statute was approved on 23 October 1956 by the Conference on the Statute of the IAEA held at United Nations Headquarters, New York; it entered into force on 29 July 1957.
    [Show full text]
  • Some Problems and Potentials of the Study of Cupellation
    Some problems and potentials of the study of cupellation remains: the case of post-medieval Montbéliard, France Marcos Martinon-Torres, Nicolas Thomas, Thilo Rehren, Aude Mongiatti To cite this version: Marcos Martinon-Torres, Nicolas Thomas, Thilo Rehren, Aude Mongiatti. Some problems and po- tentials of the study of cupellation remains: the case of post-medieval Montbéliard, France. Archeo- sciences, revue d’Archéométrie, G.M.P.C.A./Presses universitaires de Rennes, 2008, pp.59-70. halshs- 00599974 HAL Id: halshs-00599974 https://halshs.archives-ouvertes.fr/halshs-00599974 Submitted on 19 Jun 2011 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Some problems and potentials of the study of cupellation remains: the case of early modern Montbéliard, France Problèmes et perspectives à partir de l’étude des vestiges archéologiques issus de la coupellation : l’exemple du site de Montbéliard (France) Marcos Martinón-Torres*, Nicolas Thomas**, Thilo Rehren*, and Aude Mongiatti* Abstract: Bone-ash cupels are increasingly identified in medieval and later archaeological contexts related to the refining of noble metals in alchemy, assaying, jewellery or coin minting. These small finds may provide information on metal refining activities, the technical knowledge of different craftspeople, and the versatility of laboratory practices, which often differed from the standard protocols recorded in metallurgical treatises.
    [Show full text]
  • Effects of Varied Process Parameters on Froth Flotation Efficiency: a Case Study of Itakpe Iron Ore
    Nigerian Journal of Technology (NIJOTECH) Vol. 39, No. 3, July 2020, pp. 807 – 815 Copyright© Faculty of Engineering, University of Nigeria, Nsukka, Print ISSN: 0331-8443, Electronic ISSN: 2467-8821 www.nijotech.com http://dx.doi.org/10.4314/njt.v39i3.21 EFFECTS OF VARIED PROCESS PARAMETERS ON FROTH FLOTATION EFFICIENCY: A CASE STUDY OF ITAKPE IRON ORE S. Akande1, E. O. Ajaka2, O. O. Alabi3 and T. A. Olatunji4,* 1, 2, DEPARTMENT OF MINING ENGINEERING, FEDERAL UNIV. OF TECHNOLOGY, AKURE, ONDO STATE, NIGERIA 3, 4, DEPT. OF MET. & MATERIALS ENGINEERING, FEDERAL UNIV. OF TECHNOLOGY, AKURE, ONDO STATE, NIGERIA Email addresses: 1 [email protected], 2 [email protected], 3 [email protected], 4 [email protected] ABSTRACT The dire need for Itakpe iron ore concentrates of appreciable iron content meets for smelting operation necessitated this study. Core samples of the iron ore sourced from Itakpe, Kogi State, Nigeria were prepared for petrological analysis followed by chemical and particle size analyses. Froth flotation was done using different collectors at varying particle sizes and pH values. Characterization studies carried out revealed that Itakpe iron ore is a lean ore assaying 36.18% Fe2O3 and contains predominantly quartz, sillimanite, and haematite. Its liberation size lies favourably at 75 µm. Processing the ore by froth flotation yielded appreciable enrichment. Optimal recovery (~92%) was achieved using potassium amyl xanthate (PAX) at pH 11 for fine feed sizes (<125 µm) yielding iron concentrate assaying 67.66% Fe2O3. Thus, processing at this set-of- conditions is recommended for the industrial production of more enriched Itakpe iron ore concentrates.
    [Show full text]
  • Curbing Illicit Mercury and Gold Flows in West Africa: Options for a Regional Approach
    Curbing Illicit Mercury and Gold Flows in West Africa: Options for a Regional Approach i INCLUSIVE AND SUSTAINABLE INDUSTRIAL DEVELOPMENT ii Curbing Illicit Mercury and Gold Flows in West Africa: Options for a Regional Approach iii November 2018 iv © UNIDO 2018. All rights reserved. This document has been produced without formal United Nations editing. The designations employed and the presentation of the material in this document do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations Industrial Development Organization (UNIDO) concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries, or its economic system or degree of development. Designations such as ‘developed’, ‘industrialized’ or ‘developing’ are intended for statistical convenience and do not necessarily express a judgement about the stage reached by a particular country or area in the development process. Mention of firm names or commercial products does not constitute an endorsement by UNIDO. Unless otherwise men- tioned, all references to sums of money are given in United States dollars. References to ‘tons’ are to metric tons, unless otherwise stated. All photos © UNIDO unless otherwise stated. Cover photo by Sadibou Sylla Acknowledgements This report was authored by Marcena Hunter of the Global Initiative Against Transnational Organized Crime. The report is part of the United Nations Industrial Development Organization (UNIDO) project, funded by the Government of Switzerland, to assist the Economic Community of West African States (ECOWAS) in its early implementation of the Minamata Convention. More information about the Minamata Convention and UNIDO’s work can be found on UNIDO’s website <https://www.unido.org/mercury> or by emailing Gabriela Eigenmann at [email protected].
    [Show full text]
  • Softening Behaviour of Lead Sinter and Slag At
    Paper Title: THE ISA-YMG LEAD SMELTING PROCESS Paper Presented at: PbZn 2005 Conference, Kyoto, Japan Authors: Bill Errington & Philip Arthur, Xstrata Technology Jikun Wang & Ying Dong, Yunnan Metallurgical Group, Date of Publication: October, 2005 For further information please contact us at [email protected] www.isasmelt.com THE ISA-YMG LEAD SMELTING PROCESS Bill Errington and Philip Arthur Xstrata Technology, Level 4, 307 Queen Street,, Brisbane, Queensland 4000, Australia [email protected] Jikun Wang and Ying Dong Yunnan Metallurgical Group, Kunming,Yunnan, P. R. China ABSTRACT The Yunnan Metallurgical Group (YMG) has constructed a new lead-zinc smelting/refinery complex at Qujing in Yunnan Province, China. The lead smelting process combines an ISASMELT™ smelting furnace with a YMG designed blast furnace. The ISASMELT furnace produces lead bullion plus a high-lead slag that is cast into lump form and fed to the blast furnace. YMG installed a blast furnace in the 1950's to treat high lead slag produced by earlier silver operations. This furnace later treated sinter. For the present project YMG carried out trials at the pilot and commercial scale before deciding on the final blast furnace design. The ISASMELT furnace design was based on the operation of the Lead ISASMELT Plant at Mount Isa. This paper describes the development and the operation of both the ISASMELT furnace and the YMG blast furnace. This combination of new technology and remodelled traditional technology provides an economical solution to achieving an environmentally acceptable lead smelter. Key words: ISASMELT process, lead smelting, lead slag, lead blast furnace www.isasmelt.com 2 INTRODUCTION The new YMG lead smelter forms one part of a new greenfield lead/zinc smelting and refinery complex located at Qujing in Yunnan Province in China.
    [Show full text]
  • S Ndlovu (PDF)
    Extraction of Gold Then, Now and the Future Prof Sehliselo Ndlovu DST/NRF SARChI: Hydrometallurgy and Sustainable Development University of the Witwatersrand, Johannesburg Building a Robust Minerals Industry 3 – 4 July 2017, Cresta Lodge, Harare University of the Witwatersrand Johannesburg Founded Oct. 1896: School of Mines Approx. 37 000 Students 5 Faculties, 33 Schools, 3610 Courses >160 000 Degrees Conferred since 1922 55% Female Students 10 National Centres of Excellence Home to the Bidvest Football Club( Current PSL league Champions) Evolution in Gold Processing Past Technologies • Amalgamation • Panning Current Technologies • Cyanide leaching • Processing of Emerging and Future refractory ores Technologies • Bio-oxidation • Ionic liquids • Alternative leaching • Ultrasonic leaching reagents • Corn starch?? Past Technologies Used in Ancient Times History of gold extends back at least 6,000 years. Egypt and Mesopotamia around 4000 BC. Gravity Separation: Gold Panning Gold concentrated by washing lighter river sands with water Leaves dense gold particles Alternative- wash gold-bearing sand and gravel over a woollen fleece Traps heavier gold dust that would sink into the wool fibres. Advantages • Simplicity Disadvantages • Labour intensive Gravity Separation: Sluicing • Water is channelled to flow through a sluice-box. • Sluice-box is essentially a man-made channel with riffles (barriers) at the bottom. • Riffles create dead-zones in the water current which allows gold to drop out of suspension. Sluicing and panning results in the direct recovery of small gold nuggets and flakes. Gold Parting: Salt Cementation Process • Invented to remove Ag from Au-Ag mixtures around 6th century BC. Mix: argentiferous gold foil, common salt, brick dust or burnt clay and urine in a sealed container.
    [Show full text]
  • Mineral Processing
    Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19
    [Show full text]
  • Principles of Extractive Metallurgy Lectures Note
    PRINCIPLES OF EXTRACTIVE METALLURGY B.TECH, 3RD SEMESTER LECTURES NOTE BY SAGAR NAYAK DR. KALI CHARAN SABAT DEPARTMENT OF METALLURGICAL AND MATERIALS ENGINEERING PARALA MAHARAJA ENGINEERING COLLEGE, BERHAMPUR DISCLAIMER This document does not claim any originality and cannot be used as a substitute for prescribed textbooks. The information presented here is merely a collection by the author for their respective teaching assignments as an additional tool for the teaching-learning process. Various sources as mentioned at the reference of the document as well as freely available material from internet were consulted for preparing this document. The ownership of the information lies with the respective author or institutions. Further, this document is not intended to be used for commercial purpose and the faculty is not accountable for any issues, legal or otherwise, arising out of use of this document. The committee faculty members make no representations or warranties with respect to the accuracy or completeness of the contents of this document and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. BPUT SYLLABUS PRINCIPLES OF EXTRACTIVE METALLURGY (3-1-0) MODULE I (14 HOURS) Unit processes in Pyro metallurgy: Calcination and roasting, sintering, smelting, converting, reduction, smelting-reduction, Metallothermic and hydrogen reduction; distillation and other physical and chemical refining methods: Fire refining, Zone refining, Liquation and Cupellation. Small problems related to pyro metallurgy. MODULE II (14 HOURS) Unit processes in Hydrometallurgy: Leaching practice: In situ leaching, Dump and heap leaching, Percolation leaching, Agitation leaching, Purification of leach liquor, Kinetics of Leaching; Bio- leaching: Recovery of metals from Leach liquor by Solvent Extraction, Ion exchange , Precipitation and Cementation process.
    [Show full text]
  • Recovery of Gold and Iron from Cyanide Tailings with a Combined Direct Reduction Roasting and Leaching Process
    metals Article Recovery of Gold and Iron from Cyanide Tailings with a Combined Direct Reduction Roasting and Leaching Process Pingfeng Fu 1,2,* ID , Zhenyu Li 1, Jie Feng 1 and Zhenzhong Bian 1 1 School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China; [email protected] (Z.L.); [email protected] (J.F.); [email protected] (Z.B.) 2 Key Laboratory of High-Efficient Mining and Safety of Metal Mines, Ministry of Education, Beijing 100083, China * Correspondence: [email protected]; Tel.: +86-10-6233-2902 Received: 25 June 2018; Accepted: 19 July 2018; Published: 21 July 2018 Abstract: Cyanide tailings are the hazardous waste discharged after gold cyanidation leaching. The recovery of gold and iron from cyanide tailings was investigated with a combined direct reduction roasting and leaching process. The effects of reduction temperature, coal dosage and CaO dosage on gold enrichment into Au-Fe alloy (FexAu1−x) were studied in direct reduction roasting. Gold containing iron powders, i.e., Au-Fe alloy, had the gold grade of 8.23 g/t with a recovery of 97.46%. After separating gold and iron in iron powders with sulfuric acid leaching, ferrous sulfate in the leachate was crystallized to prepare FeSO4·7H2O with a yield of 222.42% to cyanide tailings. Gold enriched in acid-leaching residue with gold grade of 216.58 g/t was extracted into pregnant solution. The total gold recovery of the whole process reached as high as 94.23%. The tailings generated in the magnetic separation of roasted products, with a yield of 51.33% to cyanide tailings, had no toxic cyanide any more.
    [Show full text]
  • A History of Tailings1
    A HISTORY OF MINERAL CONCENTRATION: A HISTORY OF TAILINGS1 by Timothy c. Richmond2 Abstract: The extraction of mineral values from the earth for beneficial use has been a human activity- since long before recorded history. Methodologies were little changed until the late 19th century. The nearly simultaneous developments of a method to produce steel of a uniform carbon content and the means to generate electrical power gave man the ability to process huge volumes of ores of ever decreasing purity. The tailings or waste products of mineral processing were traditionally discharged into adjacent streams, lakes, the sea or in piles on dry land. Their confinement apparently began in the early 20th century as a means for possible future mineral recovery, for the recycling of water in arid regions and/or in response to growing concerns for water pollution control. Additional Key Words: Mineral Beneficiation " ... for since Nature usually creates metals in an impure state, mixed with earth, stones, and solidified juices, it is necessary to separate most of these impurities from the ores as far as can be, and therefore I will now describe the methods by which the ores are sorted, broken with hammers, burnt, crushed with stamps, ground into powder, sifted, washed ..•. " Agricola, 1550 Introduction identifying mining wastes. It is frequently used mistakenly The term "tailings" is to identify all mineral wastes often misapplied when including the piles of waste rock located at the mouth of 1Presented at the 1.991. National mine shafts and adi ts, over- American. Society for Surface burden materials removed in Mining and Reclamation Meeting surface mining, wastes from in Durango, co, May 1.4-17, 1.991 concentrating activities and sometimes the wastes from 2Timothy c.
    [Show full text]
  • Hydrometallurgy – the Basis of Radiochemistry
    The Interaction Between Nuclear Chemistry and Hydrometallurgy A Strategy for the Future By Tor Bjørnstad and Dag Øistein Eriksen April 2013 A short history of radiochemistry • 1898: Marie and Pierre Curie discovered Po and Ra by chemical separations of dissolved uranium ore • 1923: de Hevesy uses 212Pb as a tracer to follow the absorption in the roots, stems and leaves of the broad bean • 1929: Ellen Gleditsch appointed professor in inorganic chemistry. Established radiochemistry in Norway in 1916. • 1938: Hahn proves fission of uranium as Ba is separated from irradiated uranium solution • 1940: First transurane produced: Np by McMillan and Abelson • Nuclear power requires separation of fission products Primus.inter.pares AS Nuclear chemistry has contributed to the development of hydrometallurgy The need for safe, remote handling of the laborious separations required in the nuclear sector boosted innovation in: • Solvent extraction: – Continuous, counter current process enabled large quantities to be processed – Contactors like mixer-settlers were developed • Ion exchange to perform difficult purifications Primus.inter.pares AS Hydrometallurgy and nuclear chemistry Nuclear (radio-)chemistry offers special methods useful in hydrometallurgy: • Use of radioactive tracers, i.e. radioactive isotopes of the elements studied – Particularly important in liquid-liquid extraction • Neutron activation can be used on all phases: solid, aqueous-, organic phases (and gas) • AKUFVE-method very efficient in measuring extraction kinetics • Many "hydrometallurgical" elements have suitable isotopes for use as tracers – In addition, e.g. Eu(III) can be used as tracer for Am(III), and 3+ 3+ Nd has equal ionic radius as Am Primus.inter.pares AS Some strategic metals • Lithium for batteries – Scarcity of Li may be a reality.
    [Show full text]