U–Pb and Re–Os Isotopic Systematics and Zircon Ce4+/Ce3+ Ratios in the Shiyaogou Mo Deposit in Eastern Qinling, Central Chin

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U–Pb and Re–Os Isotopic Systematics and Zircon Ce4+/Ce3+ Ratios in the Shiyaogou Mo Deposit in Eastern Qinling, Central Chin Ore Geology Reviews 55 (2013) 29–47 Contents lists available at SciVerse ScienceDirect Ore Geology Reviews journal homepage: www.elsevier.com/locate/oregeorev U–Pb and Re–Os isotopic systematics and zircon Ce4+/Ce3+ ratios in the Shiyaogou Mo deposit in eastern Qinling, central China: Insights into the oxidation state of granitoids and Mo (Au) mineralization Yigui Han a,b,⁎, Shihong Zhang a, Franco Pirajno c, Xuewu Zhou d, Guochun Zhao b, Wenjun Qü e, Shihua Liu f, Jiangming Zhang f, Haibin Liang f, Ke Yang a,f a State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China b Department of Earth Sciences, The University of Hong Kong, Pokfulam Road, Hong Kong c Centre for Exploration Targeting, School of Earth and Environment, University of Western Australia, 35 Stirling Highway, Crawley WA 6009, Australia d Faculty of Resources, China University of Geosciences, Wuhan 430074, China e National Research Center of Geoanalysis, Chinese Academy of Geological Sciences, Beijing 100037, China f The Sixth Gold Exploration Branch of Armed Police, Sanmenxia 472000, China article info abstract Article history: The newly-discovered Shiyaogou molybdenum deposit is located in the eastern Qinling metallogenic belt in Received 5 November 2012 central China. The deposit contains at least 152,000 t of Mo metal and bears typical porphyry-type features in Received in revised form 23 April 2013 terms of its concentric alteration zonation, quartz vein-hosted Mo mineralization, veining sequence and the Accepted 23 April 2013 spatial association with concealed granite porphyries. Re–Os isotope analyses of molybdenite from the de- Available online 29 April 2013 posit yield an ore-forming age of 132.3 ± 2.8 Ma. LA-ICP-MS U–Pb zircon dating of ore-related porphyries yields crystallization ages from 135 Ma to 132 Ma, indicating a temporal link between granitic magmatism Keywords: Eastern Qinling and Mo mineralization. A population of captured magmatic zircons indicates another pulse of magmatism Shiyaogou at ~143 Ma. A barren granite intrusion near the deposit gives a zircon U–Pb age of 148.1 ± 1.1 Ma. These Porphyry molybdenum deposit magmatic activities were concurrent with the emplacement of the nearby Heyu granitic batholith, a largely U–Pb dating ore-barren intrusive complex formed from ~148 Ma to ~127 Ma. Zircon Ce4+/Ce3+ ratios of ore-related por- Re–Os dating phyries are obviously higher than those of contemporaneous barren granitoids, implying an affinity between Ce anomaly Mo mineralization and highly oxidized magmas. Moreover, zircons from these granitoids overall have de- creasing Ce4+/Ce3+ ratios from 148 Ma to 132 Ma, reflecting decreasing oxygen fugacities during magma evolution. Available geological, radiometric and stable isotopic evidence suggests that the decrease of magma oxygen fugacity was probably associated with an increase of mantle contribution to granitic magmatism and metallogenesis, which probably gave rise to successive mineralization of Mo and Au in the eastern Qinling. The intense magmatic–metallogenic events in the eastern Qinling during Late Jurassic to Early Cretaceous times are interpreted as a response to the large-scale lithosphere thinning and subsequent asthenosphere upwelling beneath the eastern part of the North China Craton. © 2013 Elsevier B.V. All rights reserved. 1. Introduction (2011b), along the Mianlue suture in the Jurassic. The region of eastern Qinling, referred to here, comprises the southern margin of the NCC The ~2000 km long Qinling–Dabie orogenic belt, extending east– and northeastern part of the Qinling belt (Fig. 1) since both units have westward in central China, was assembled by the collision between the been involved into an intracontinental tectonism since the Late Mesozoic North China craton (NCC) and the Yangtze craton (YZC) (Fig. 1). The (Dong et al., 2011b; Meng and Zhang, 1999; Zhang et al., 2001). This re- final stage of the collision probably took place along the Shangdan suture gion has been recognized as a world-class molybdenum (Mo) ore district intheLateTriassic(Ames et al., 1993; Hacker et al., 1998; Kröner et al., and one of the most important gold (Au) and polymetallic ore districts in 1993; Mattauer et al., 1985; Meng and Zhang, 2000; Ratschbacher et China (Mao et al., 2011b). These ore deposits were dominantly formed in al., 2003; Zhang et al., 2001) or, as recently documented by Dong et al. an interval from ~235 Ma to ~110 Ma and have been received much in- vestigation in the last decade (Chen and Wang, 2011; Chen et al., 2008a, 2009a; Fan et al., 2011; Han et al., 2007a; C.Y. Li et al., 2011; N. Li et al., 2011; J.W. Li et al., 2012b; N. Li et al., 2012c; Mao et al., 2002, 2008, ⁎ Corresponding author at: Department of Earth Sciences, The University of Hong Kong, Pokfulam Road, Hong Kong. Tel.: +852 28578913. 2011b; Stein et al., 1997; Xu et al., 2010; Zhang et al., 2007, 2011; Zhu E-mail address: [email protected] (Y. Han). et al., 2009). 0169-1368/$ – see front matter © 2013 Elsevier B.V. All rights reserved. http://dx.doi.org/10.1016/j.oregeorev.2013.04.006 30 Y. Han et al. / Ore Geology Reviews 55 (2013) 29–47 Fig. 1. Generalized geological map of the eastern Qinling area (modified after HBGMR, 1989; Mao et al., 2008), also showing the sampling site of 08LC57-1. Mo deposits: 1—Quanjiayu, 2—Shiyaogou, 3—Shangfanggou, 4—Sandaozhuang, 5—Nannihu, 6—Shapoling, 7—Leimengou, 8—Nangou, 9—Shimengou, 10—Banchang; Au deposits: 11—Hongtuling, 12—Dongchuang, 13—Liushugou, 14—Kangshan, 15—Qiyugou, 16—Qianhe; Granite batholiths: WY—Wenyu, NNS—Niangniangshan, ML—Mangling, HSI—Huashani, WZS—Wuzhangshan, Heyu—Heyu, TSM—Taishanmiao, LJS—Laojunshan, ELP—Erlangping. Molybdenum ore deposits in the eastern Qinling occur primarily as this deposit exceed 152,000 t (Zhang, 2010). The deposit is suggested porphyry and porphyry-skarn types and are spatially and genetically to be porphyry-type and formed at ~133 Ma (Y.L. Gao et al., 2010), associated with small granitic porphyry intrusions (Chen and Wang, which coincides with the nearest granite batholith (Heyu batholith, 2011; N. Li et al., 2012c; Mao et al., 2008; Zhu et al., 2009). By contrast, Fig. 1) that has been well documented recently (X.Y. Gao et al., large volumes of Late Mesozoic granitic plutons/batholiths distributed 2010; Guo et al., 2009; Han et al., 2007b; N. Li et al., 2012b; Mao et in the eastern Qinling are usually barren, such as Wuzhangshan, Heyu, al., 2010). Ore-bearing granitic porphyries have been discovered at Huashani, Laojunshan, Taishanmiao in the Xiong'er–Waifang Moun- depth beneath the deposit, which enables us to study the variation tains, and Huashan, Niangniangshan and Wenyu in the Xiaoqinling of oxidation states of ore-related/barren granitoids by an index of zir- (or lesser Qinling) Mountains (X.Y. Gao et al., 2010; Guo et al., 2009; con Ce4+/Ce3+ ratios (Ballard et al., 2002). In combination with geol- Han et al., 2007b; Mao et al., 2010; N. Li et al., 2012b). The genetic rela- ogy, U–Pb and Re–Os systematics, we discuss the genetic links tionships between the small porphyries and large plutons are still de- between magmatism and metallogenesis in the region and their tec- bated: the ore-related porphyries were evolved from deep-seated tonic implications in the eastern Qinling metallogenic belt. granite plutons (Mao et al., 2008, 2010; N. Li et al., 2012b), or they are essentially the same in origin except that they may represent different 2. Geological background intrusive depths (Chen et al., 2000). This controversy has led to different metallogenic models proposed for the formation of granitoids and Mo– 2.1. Regional geology Au deposits in the eastern Qinling belt (Chen et al., 2009a; J.W. Li et al., 2012a; Mao et al., 2008; Zhu et al., 2009). However, the oxidation states The general geology of the southern margin of the NCC and the of these granitoids and their significance to metallogenesis have not northeastern part of the Qinling belt, which constitute the eastern been fully investigated. Since the oxidation state of melts and fluids is Qinling region, is described separately (Fig. 1). The southern margin of a very important variable that can influence the behavior of Mo, Cu the NCC is generally named the region bounded by the Sanmenxia– andAu(Bali et al., 2012; Ballard et al., 2002; Blevin and Chappell, Lushan fault to the north and Luanchuan fault to the south. The region 1992; Candela and Bouton, 1990; Czamanske and Wones, 1973), in shares the same basement-cover sequence to the NCC, namely an Ar- this study we investigate the oxidation states of ore-bearing and barren chean to Paleoproterozoic basement, covered by Mesoproterozoic to granitoids and their relations to Mo (Au) mineralization by considering Phanerozoic sedimentary rocks. The crystalline basement of the NCC the case of the newly-discovered Shiyaogou Mo deposit in the eastern was affected by two Paleoproterozoic tectonic events: a 1.95–1.92 Ga Qinling. collision between the Yinshan Block and the Ordos Block to form the The Shiyaogou molybdenum deposit is located in the southern Western Block, and a ~1.85 Ga collision between the Western and the Xiong'er Mountains on the southern margin of the NCC (Fig. 1). It Eastern Blocks along the Trans-North China Orogen (Zhao, 2001; Zhao was discovered in recent years by the Sixth Gold Exploration Branch et al., 2005, 2011; G.C. Zhao et al., 2010). Afterwards, the craton proper of Armed Police Army of China. Measured molybdenum resources in maintained a steady state until the Late Mesozoic, when intensive and Y. Han et al. / Ore Geology Reviews 55 (2013) 29–47 31 large-scale magmatic, metallogenic and structural events (commonly basin setting in the Neoproterozoic (Diwu et al., 2010b).
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