Appendices Accompanying Report Toxics Across America

Total Page:16

File Type:pdf, Size:1020Kb

Appendices Accompanying Report Toxics Across America ©2014 Environmental Defense Fund Appendices accompanying report Toxics Across America Appendices accompanying report Toxics Across America Important notes: The Toxic Substances Control Act (TSCA) allows a company to claim most information it submits to EPA as confidential business information (CBI), which EPA by law cannot publicly disclose. Such claims can be made for the identity of a chemical a company produces or imports, the company’s own identity, whether the company produces or imports the chemical, the location of sites at which a company produces or imports a chemical, chemical production or import volume, and chemical processing and use information. Hence the public version of EPA’s Chemical Data Reporting (CDR) database does not include any information claimed CBI, although it does include an indicator wherever specific information was claimed CBI. For this reason, these appendices may not contain all “Mind the Store” (MTS) list chemicals that were reported to EPA or all companies that reported producing or importing MTS list chemicals in the U.S. Nor do they contain any other information about these chemicals claimed as CBI by a reporting company. Wherever possible, we have sought to include information on the extent to which specific items or categories of information have been claimed as CBI. In addition, while we used the most recent public data on U.S. chemical production and import, they were collected by EPA in 2012 for activity during the calendar years 2011 and 2010. Given the dynamic nature of the chemical market, some of the data we report here may have changed. This document contains the following data appendices referred to in Toxics Across America: Appendix 1. Status of MTS List Chemicals in the U.S. in 2011: Production and Use Appendix 2. Companies that Reported Producing or Importing MTS List Chemicals in 2011 A. Listed by company B. Listed by CAS number Appendix 3. Number of MTS List Chemicals Produced or Imported and Number of Sites Reporting MTS List Chemicals in 2011, by State Appendix 4. MTS List Chemicals Produced or Imported in 2011, by State Appendix 5. MTS List Chemicals with Consumer or Commercial Uses Reported in 2011 ©2014 Environmental Defense Fund Appendices accompanying report Toxics Across America Appendix 1. Status of MTS List Chemicals in the U.S. in 2011: Production and Use (see pages 1 - 10 to 1 - 12 for table notes) In U.S. commerce # of # of reporting Reported to be Basis for inclusion on On TSCA at >25k National Production # of site public # of CBI companies # of reporting present in products Chemical Name(s) CAS # MTS list Primary Category inventory? lbs/year/site? Volume (lb) records sites sites public companies CBI intended for children Reported product categories Hazardous 100 List 2-Aminotoluene (o-Toluidine) 95-53-4 Cancer Dyes & Pigments Y Y 60,105,332 4 4 0 4 0 Not reported None reported 2-Naphthylamine 91-59-8 Cancer Dyes & Pigments N N - - - - - - - - 3,3'-Dimethylbenzidine (o-Tolidine) 119-93-7 Cancer Dyes & Pigments Y N - - - - - - - - 4,4'-Bis(dimethylamino)benzophenone 90-94-8 Cancer Dyes & Pigments Y N - - - - - - - - (Michler's ketone) 4,4'-Methylenedi-o-toluidine 838-88-0 Cancer Dyes & Pigments Y N - - - - - - - - 4-Aminoazobenzene (Aniline yellow) 60-09-3 Cancer Dyes & Pigments Y N - - - - - - - - 6-Methoxy-m-toluidine (p-Cresidine) 120-71-8 Cancer Dyes & Pigments Y Y CBI 2 1 1 1 1 Not reported None reported Benzenamine (Aniline) 62-53-3 Cancer Dyes & Pigments Y Y 1,955,882,344 9 9 0 6 0 Not reported None reported Benzidine and its salts 92-87-5 Cancer Dyes & Pigments Y N - - - - - - - - 1 C.I. Direct Blue 218 28407-37-6 Cancer* Dyes & Pigments Y Y CBI 1 1 0 1 0 Not reported None reported C.I. Solvent Yellow 14 (Sudan I) 842-07-9 Cancer Dyes & Pigments Y N - - - - - - - - C.I. Solvent Yellow 3 (o-Aminoazotoluene) 97-56-3 Cancer Dyes & Pigments Y N - - - - - - - - N,N,N',N'-tetramethyl-4,4'- 101-61-1 Cancer Dyes & Pigments Y N - - - - - - - - methylenedianiline (Michler's base) 2 Hexabromocyclododecane (HBCD) 25637-99-4 PBT Halogenated Flame Y Y CBI 3 1 2 1 2 No Building/Construction Materials not covered elsewhere; Retardants Plastic and Rubber Products not covered elsewhere 3 1,2,5,6,9,10-Hexabromocyclododecane 3194-55-6 PBT* Halogenated Flame Y Y CBI 2 2 0 2 0 No Building/Construction Materials not covered elsewhere 4 Retardants c-DecaBDE 1163-19-5 PBT; vPvB* Halogenated Flame Y Y 18,110,827 5 4 1 4 1 Yes/ No Adhesives and Sealants; Building/Construction Materials - Retardants Wood and Engineered Wood Products; Electrical and Electronic Products; Fabric, Textile, and Leather Products not covered elsewhere; Floor Coverings; Plastic and Rubber Products not covered elsewhere 5 c-PentaBDE 32534-81-9 PBT; vPvB* Halogenated Flame Y N - - - - - - - - Retardants 6 c-OctaBDE 32536-52-0 PBT; vPvB* Halogenated Flame Y N - - - - - - - - Retardants Tetrabromobisphenol A (TBBPA) 79-94-7 PBT Halogenated Flame Y Y 119,837,559 5 4 1 4 1 No/ NKRA Electrical and Electronic Products; Not Known or Retardants Reasonably Ascertainable; Plastic and Rubber Products not covered elsewhere Tris(2-chloroethyl) phosphate (TCEP) 115-96-8 Cancer Halogenated Flame Y Y CBI 1 1 0 1 0 NKRA Paints and Coatings Retardants 1,1,2,2-Tetrachloroethane 79-34-5 Cancer Halogenated Y Y Withheld (>390,676) 3 1 2 1 2 Not reported None reported Solvents 1-Bromopropane (n-Propyl bromide)(nPB) 106-94-5 Developmental Halogenated Y Y 15,348,727 5 4 1 4 1 No Cleaning and Furnishing Care Products; Electrical and Solvents Electronic Products Methylene chloride 75-09-2 Cancer Halogenated Y Y 261,469,894 12 8 4 6 4 No/ NKRA Adhesives and Sealants; Automotive Care Products; Metal Solvents Products not covered elsewhere; Not Known or Reasonably Ascertainable; Paints and Coatings Perchloroethylene (PCE or Perc) 127-18-4 Cancer Halogenated Y Y 420,694,838 11 7 4 6 3 No Automotive Care Products; Metal Products not covered Solvents elsewhere Trichloroethylene (TCE) 79-01-6 Cancer Halogenated Y Y 224,674,308 9 7 2 7 2 No/ NKRA Adhesives and Sealants; Not Known or Reasonably Solvents Ascertainable Furan 110-00-9 Cancer Various Uses Y Y CBI 1 1 0 1 0 Not reported None reported Antimony trioxide 1309-64-4 Cancer Metals Y Y 5,389,792 14 13 1 12 1 No/ NKRA Automotive Care Products; Building/Construction Materials not covered elsewhere; Electrical and Electronic Products; Not Known or Reasonably Ascertainable; Plastic and Rubber Products not covered elsewhere 1 - 1 ©2014 Environmental Defense Fund Appendices accompanying report Toxics Across America In U.S. commerce # of # of reporting Reported to be Basis for inclusion on On TSCA at >25k National Production # of site public # of CBI companies # of reporting present in products Chemical Name(s) CAS # MTS list Primary Category inventory? lbs/year/site? Volume (lb) records sites sites public companies CBI intended for children Reported product categories Antimony 7440-36-0 Cancer* Metals Y Y 10,000,000 - 50,000,000 16 16 0 10 0 No/ NKRA Batteries; Explosive Materials; Metal Products not covered elsewhere; Not Known or Reasonably Ascertainable; Other (specify) Arsenic 7440-38-2 Cancer Metals Y Y 500,000 - 1,000,000 9 9 0 6 0 No/ NKRA Batteries; Metal Products not covered elsewhere Arsenic trioxide 1327-53-3 Cancer* Metals Y Y 3,946,374 4 4 0 4 0 No Building/Construction Materials - Wood and Engineered Wood Products Dimethyl arsenic 75-60-5 Cancer* Metals Y N - - - - - - - - Arsenic acid 7778-39-4 Cancer* Metals Y Y 538,673 1 1 0 1 0 Not reported None reported Diarsenic pentaoxide 1303-28-2 Cancer* Metals Y N - - - - - - - - Calcium arsenate 7778-44-1 Cancer* Metals Y N - - - - - - - - Trilead diarsenate 3687-31-8 Cancer** Metals N N - - - - - - - - Lead hydrogen arsenate 7784-40-9 Cancer** Metals Y N - - - - - - - - Triethyl arsenate 15606-95-8 Cancer* Metals N N - - - - - - - - Beryllium 7440-41-7 Cancer Metals Y N - - - - - - - - Cadmium 7440-43-9 Cancer Metals Y Y 1,000,000 - 10,000,000 3 3 0 3 0 No Metal Products not covered elsewhere Chromium 7440-47-3 Cancer, Metals Y Y 3,713,384,499 68 61 7 40 7 Yes/ No/ NKRA Building/Construction Materials not covered elsewhere; developmental CBI; Electrical and Electronic Products; Floor Coverings; toxicity Metal Products not covered elsewhere; Not Known or Reasonably Ascertainable; Other (specify) Chromium trioxide 1333-82-0 Cancer, Metals Y Y 50,000,000 - 100,000,000 4 4 0 4 0 No/ NKRA Metal Products not covered elsewhere; Not Known or developmental Reasonably Ascertainable toxicity* Acids generated from chromium trioxide and 7738-94-5 Cancer, Metals Y N - - - - - - - - their oligomers. Names of the acids and their developmental oligomers: Chromic acid, Dichromic acid, toxicity* Oligomers of chromic acid and dichromic 7 acid Dichromium tris(chromate) 24613-89-6 Cancer, Metals Y Y CBI 1 0 1 0 1 Not reported None reported developmental toxicity* Pentazine chromate octahydroxide 49663-84-5 Cancer, Metals N N - - - - - - - - developmental toxicity* Potassium 11103-86-9 Cancer, Metals Y N - - - - - - - - hydroxyoctaoxodizincatedichromate developmental toxicity* Strontium chromate 7789-06-2 Cancer, Metals Y Y 6,498,000 2 2 0 2 0 No Paints and Coatings developmental toxicity* Ammonium dichromate 7789-09-5 Cancer, Metals Y N - - - - - - - - developmental toxicity* Potassium dichromate 7778-50-9 Cancer, Metals Y N - - - - - - - - developmental toxicity* Sodium chromate 7775-11-3 Cancer, Metals Y N - - - - - - - - developmental toxicity* Potassium chromate 7789-00-6 Cancer, Metals Y N - - - - - - - - developmental toxicity* Lead sulfochromate yellow (C.I. Pigment 1344-37-2 Cancer, Metals Y Y 1,000,000 - 10,000,000 3 3 0 3 0 No Paints and Coatings; Plastic and Rubber Products not Yellow 34) developmental covered elsewhere toxicity** Lead chromate molybdate sulphate red (C.I.
Recommended publications
  • Acute Tetraethyllead Poisoning
    Arch. Toxikol. 24, 283--291 (1969) Acute Tetraethyllead Poisoning M. STASIK, Z. BYCZKOWSKA, S. SZENDZIKOWSKI,and Z. FIEDOttCZUK Clinical and Pathomorphological Department, Institute of Occupational Medicine, L6@, Poland, Department of Forensic Medicine, Medical Academy, L6dA l%eceived September 16, 1968 Summary. Four cases of accidental poisoning with tetraethyllead are described. Three out of four of the patients died. In the first case, pure ethyl fluid was accidentally ingested. Dominating the clinical picture of this patient were signs of greatly elevated intracranial pressure. Three other persons were poisoned as a group. They unknowingly inhaled tetra- ethyllead contained in a paint solvent they used. In these three cases, the intoxication manifested itself predominantly as a mental disorder suggestive of schizophrenia. Gross and microscopic changes observed in the fatal cases gave evidence of a capillary vascular lesion, particularly involving the vessels of the CNS. Liver damage and less severe damage to the heart muscle and kidney parenchyma were also noted. The distribution as well as the extent of the above mentioned lesions correlate approximately with the distribution and concentration of triethyllead in the various internal organs. Key- Words: Tetraethyllead -- Mental Disorder -- Damage to Parenchymatous Organs. Zusammen/assung. Die Verfasser berichten fiber 4 F/ille, yon denen 3 tSdlich waren, zuf~lliger Vergiftungen durch das sog. Ethylfluid, das Bleitetra~thyl enthElt. Im ersten Fall trat die t6dliche Vergiftung infolge irrtfimlich getrunkenem Ethylfluid auf. Als klinisches Symptom entstand erh6hter intrakranieller Druck. In den drei n~ehsten F~llen besa6 die Vergiftung einen kollektiven Charakter und war durch den Respirationstrakt zustande gekommen; zwei von den Vergifteten sind gestorben.
    [Show full text]
  • 2,4,6- Or 2,6-Alkoxyphenyl Dialkylphosphine, Tetrafluoroborate, Preparation Method and Use Thereof
    (19) & (11) EP 2 492 274 A1 (12) EUROPEAN PATENT APPLICATION published in accordance with Art. 153(4) EPC (43) Date of publication: (51) Int Cl.: 29.08.2012 Bulletin 2012/35 C07F 9/50 (2006.01) B01J 31/24 (2006.01) C07C 43/215 (2006.01) C07C 41/30 (2006.01) (2006.01) (21) Application number: 09850497.0 C07D 307/58 (22) Date of filing: 21.12.2009 (86) International application number: PCT/CN2009/001527 (87) International publication number: WO 2011/047501 (28.04.2011 Gazette 2011/17) (84) Designated Contracting States: •LV,Bo AT BE BG CH CY CZ DE DK EE ES FI FR GB GR Zhejiang 310027 (CN) HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL • FU, Chunling PT RO SE SI SK SM TR Zhejiang 310027 (CN) (30) Priority: 22.10.2009 CN 200910154029 (74) Representative: Meyer-Dulheuer, Karl-Hermann Dr. Meyer- Dulheuer & Partner (71) Applicant: Zhejiang University Patentanwaltskanzlei Hangzhou, Zhejiang 310027 (CN) Mainzer-Landstrasse 69-71 60329 Frankfurt am Main (DE) (72) Inventors: • MA, Shengming Zhejiang 310027 (CN) (54) 2,4,6- OR 2,6-ALKOXYPHENYL DIALKYLPHOSPHINE, TETRAFLUOROBORATE, PREPARATION METHOD AND USE THEREOF (57) The current invention relates to the structure, current invention uses only one step to synthesize dialkyl synthesis of dialkyl(2,4,6- or 2,6-alkoxyphenyl)phos- (2,4,6- or 2,6-alkoxyphenyl)phosphine and its tetrafluor- phine or its tetrafluoroborate, as well as its applications oborate is stable in the air. Compared with known syn- in the palladium catalyzed carbon-chlorine bond activa- thetic routes of ligands used in activating carbon- chlorine tion for Suzuki coupling reactions and carbon-nitrogen bonds, the method of current invention is short, easy to bond formation reactions.
    [Show full text]
  • Technical Note TN-106 a Guideline for PID Instriment Response
    Technical Note TN-106 05/15/VK A GUIDELINE FOR PID INSTRUMENT RESPONSE CORRECTION FACTORS AND IONIZATION ENERGIES* Example 1: RAE Systems PIDs can be used for the detection of a wide variety of With the unit calibrated to read isobutylene equivalents, the reading gases that exhibit different responses. In general, any compound with is 10 ppm with a 10.6 eV lamp. The gas being measured is butyl ionization energy (IE) lower than that of the lamp photons can acetate, which has a correction factor of 2.6. Multiplying 10 by 2.6 be measured.* The best way to calibrate a PID to different compounds gives an adjusted butyl acetate value of 26 ppm. Similarly, if the is to use a standard of the gas of interest. However, correction factors gas being measured were trichloroethylene (CF = 0.54), the adjusted have been determined that enable the user to quantify a large number value with a 10 ppm reading would be 5.4 ppm. of chemicals using only a single calibration gas, typically isobutylene. In our PIDs, correction factors can be used in one of three ways: Example 2: With the unit calibrated to read isobutylene equivalents, the reading 1. Calibrate the monitor with isobutylene in the usual fashion to is 100 ppm with a 10.6 eV lamp. The gas measured is m-xylene read in isobutylene equivalents. Manually multiply the reading (CF = 0.43). After downloading this factor, the unit should read about by the correction factor (CF) to obtain the concentration of 43 ppm when exposed to the same gas, and thus read directly in the gas being measured.
    [Show full text]
  • United States Patent Office Patented Aug
    2,849,302 United States Patent Office Patented Aug. 26, 1953 thasaraywarrasants, 2. east one hydrogen atom attached thereto. That is, each of the tertiary halogens is capable of forming hydro 2,849,392 gen halide with a hydrogen atom attached to a different ANTIKNoCK COMPOSITIONS carbon atom which is in a position alpha to the halogen 5 bearing carbon. In this description the term tertiary car Raymond G. Lyben, Detroit, Mich., assigner to Ethy bon atom is defined as a carbon atom which has three Corporation, New York, N. Y., a corporation of Dear other carbon atoms attached thereto by single bonds. Ware Thus, the novel scavenging agents of this invention are No Drawing. Application May 31, 955 certain chlorohydrocarbons, bromohydrocarbons and Seria Rio. 52,284 chlorobromohydrocarbons. The halohydrocarbon scav enging agents of this invention can be derived from al 7 Clains. (C. 44-69) kanes, cycloalkanes, alkenes, cycloalkenes, and hydrocar bon-substituted derivatives thereof. The smallest hydro carbon radical which can provide a scavenger of this in This invention relates to improved antiknock composi s vention contains five carbon atoms; e. g., 1,2-dihalo-1,2- tions. These compositicins encompass antiknock fluids dimethylcyclopropane. In order to provide scavengers and leaded fuels. In particular, this invention relates to having the desirable volatility characteristics with respect a class of hydrocarbons having a particular molecular to the lead antiknock agent, I prefer to employ uniform structure for use as a scavenger with lead antiknock con ly stable scavengers having up to 20 carbon atoms. pounds. Thus, it will be seen that the carbon content of my scav With the discovery of the antiknock effectiveness of or engers ranges from 5 to 20 carbons per molecule.
    [Show full text]
  • List of Extremely Hazardous Substances
    Emergency Planning and Community Right-to-Know Facility Reporting Compliance Manual List of Extremely Hazardous Substances Threshold Threshold Quantity (TQ) Reportable Planning (pounds) Quantity Quantity (Industry Use (pounds) (pounds) CAS # Chemical Name Only) (Spill/Release) (LEPC Use Only) 75-86-5 Acetone Cyanohydrin 500 10 1,000 1752-30-3 Acetone Thiosemicarbazide 500/500 1,000 1,000/10,000 107-02-8 Acrolein 500 1 500 79-06-1 Acrylamide 500/500 5,000 1,000/10,000 107-13-1 Acrylonitrile 500 100 10,000 814-68-6 Acrylyl Chloride 100 100 100 111-69-3 Adiponitrile 500 1,000 1,000 116-06-3 Aldicarb 100/500 1 100/10,000 309-00-2 Aldrin 500/500 1 500/10,000 107-18-6 Allyl Alcohol 500 100 1,000 107-11-9 Allylamine 500 500 500 20859-73-8 Aluminum Phosphide 500 100 500 54-62-6 Aminopterin 500/500 500 500/10,000 78-53-5 Amiton 500 500 500 3734-97-2 Amiton Oxalate 100/500 100 100/10,000 7664-41-7 Ammonia 500 100 500 300-62-9 Amphetamine 500 1,000 1,000 62-53-3 Aniline 500 5,000 1,000 88-05-1 Aniline, 2,4,6-trimethyl- 500 500 500 7783-70-2 Antimony pentafluoride 500 500 500 1397-94-0 Antimycin A 500/500 1,000 1,000/10,000 86-88-4 ANTU 500/500 100 500/10,000 1303-28-2 Arsenic pentoxide 100/500 1 100/10,000 1327-53-3 Arsenous oxide 100/500 1 100/10,000 7784-34-1 Arsenous trichloride 500 1 500 7784-42-1 Arsine 100 100 100 2642-71-9 Azinphos-Ethyl 100/500 100 100/10,000 86-50-0 Azinphos-Methyl 10/500 1 10/10,000 98-87-3 Benzal Chloride 500 5,000 500 98-16-8 Benzenamine, 3-(trifluoromethyl)- 500 500 500 100-14-1 Benzene, 1-(chloromethyl)-4-nitro- 500/500
    [Show full text]
  • Crystal Structure of the 1M-Modification of Caesium Gallium(III) Monohy- Drogen Triphosphate, 1M-Csgahp3o10
    Z. Kristallogr. NCS 218 (2003) 169–170 169 © by Oldenbourg Wissenschaftsverlag, München Crystal structure of the 1M-modification of caesium gallium(III) monohy- drogen triphosphate, 1M-CsGaHP3O10 J.-X. MiI, H. BorrmannII, Y.-X. HuangII, J.-T. Zhao*,III and R. KniepII I Xiamen University, College of Chemistry and Chemical Engineering, Xiamen 361005, P. R. China II Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Straße 40, D-01187 Dresden, Germany III Shanghai Institute of Ceramics, Chinese Academy of Sciences, State Key Laboratory of High Performance Ceramics, and Superfine Microstructure, 1295 Dingxi Road, Shanghai 200050, P. R. China Received February 24, 2003, accepted and available on-line June 10, 2003; CSD-No. 409693 (2.525 g) and an excess of 37% HCl (molar ratio Ga : Cs =1:1). The mixture was heated to the boiling point. The resulting reac- tion product (CsGaCl4 [1]) was used as reactant for the next step, which was made with a mixture of CsGaCl4 (3.444 g), Cs(OH) · H2O (1.679 g) and 5 ml 85% H3PO4 (molar ratio 1:1:7). The start- ing materials were all of analytical grade. The mixture was heated (open system) to the boiling point and kept heating for three days to evaporate the solvent. Three modifications of CsGaHP3O10 crystals were obtained in the reaction product. The one with a shape of thin plate corresponds to the title compound and was used for the structure determination. Experimental details The positions of the H atom was determined from a difference Fourier map. Discussion In 1987, Chudinova et al.
    [Show full text]
  • Cumulative Cross Index to Iarc Monographs
    RADIATION volume 100 D A review of humAn cArcinogens This publication represents the views and expert opinions of an IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, which met in Lyon, 2-9 June 2009 LYON, FRANCE - 2012 iArc monogrAphs on the evAluAtion of cArcinogenic risks to humAns CUMULATIVE CROSS INDEX TO IARC MONOGRAPHS The volume, page and year of publication are given. References to corrigenda are given in parentheses. A A-α-C .............................................................40, 245 (1986); Suppl. 7, 56 (1987) Acenaphthene ........................................................................92, 35 (2010) Acepyrene ............................................................................92, 35 (2010) Acetaldehyde ........................36, 101 (1985) (corr. 42, 263); Suppl. 7, 77 (1987); 71, 319 (1999) Acetaldehyde associated with the consumption of alcoholic beverages ..............100E, 377 (2012) Acetaldehyde formylmethylhydrazone (see Gyromitrin) Acetamide .................................... 7, 197 (1974); Suppl. 7, 56, 389 (1987); 71, 1211 (1999) Acetaminophen (see Paracetamol) Aciclovir ..............................................................................76, 47 (2000) Acid mists (see Sulfuric acid and other strong inorganic acids, occupational exposures to mists and vapours from) Acridine orange ...................................................16, 145 (1978); Suppl. 7, 56 (1987) Acriflavinium chloride ..............................................13, 31 (1977); Suppl. 7,
    [Show full text]
  • Tetraethyllead Is a Deadly Toxic Chemical Substance Giving Rise to Severe Psychotic Manifestations. for Its Excellent Properties
    Industrial Health, 1986, 24, 139-150. Determination of Triethyllead, Diethyllead and Inorganic Lead in Urine by Atomic Absorption Spectrometry Fumio ARAI Department of Public Health St. Marianna University School of Medicine 2095 Sugao, Miyamae-ku, Kawasaki 213, Japan (Received March 10, 1986 and in revised form May 21, 1986) Abstract : A method was developed for the sequential extraction of tetraethyllead (Et4Pb), triethyllead (Et3Pb+), diethyllead (Et2Pb2+) and inorganic lead (Pb2+) from one urine sample with methyl isobutyl ketone and the subsequent sequential determination of the respective species of lead by flame and flameless atomic ab- sorption spectrometry. When 40 ml of a urine sample to which 2 ƒÊg of Pb of each of Et4Pb, Et3Pb+, Et2Pb2+ or Pb2+ had been experimentally added was assayed for the respective species of lead by flame atomic absorption spectrometry, ten repetitions of the assay gave a mean recovery rate of 98% for each of Et4Pb, Et3Pb+, and Et2Pb2+, and 99% for Pb2+, with a coefficient of variation of 2.0% for Et4Pb, 0.7% for Et3Pb+ and Pb2+, 2.6% for Et2Pb2+, and a detection limit of 4 ƒÊg of Pb/L for Et4Pb, 3 ƒÊg of Pb/L for Et3Pb+, and 5 ƒÊg of Pb/L for each of Et2Pb2+ and Pb2+. Examination of urine samples from a patient with tetraethyllead poisoning 22 days after exposure to the lead revealed that the total lead output was made up of about 51% Pb2+, about 43% Et2Pb2+, and about 6% Et3Pb+ but no Et4Pb. Ad- ministration of calcium ethylenediaminetetraacetic acid (Ca-EDTA) was followed by no increased urinary excretion of Et3Pb+ or Et2Pb2+.
    [Show full text]
  • Leaded Avgas Safety Data Sheet According to Federal Register / Vol
    Leaded Avgas Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision Date : 01/22/2014 Version : 1.0 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY 1.1. Product Identifier Product Form: Mixture Product Name: Leaded Avgas Synonyms: Avgas; Avgas100LL; Aviation Gasoline; Avgas 100LL; DOT - Gasoline, 3, II Product Group: Commercial product 1.2. Intended Use of the Product Use of the Substance/Mixture: Aviation fuel. For professional use only. 1.3. Name, Address, and Telephone of the Responsible Party Customer EPIC Aviation, LLC P.O. Box 12249 Salem, OR 97309 T 866-501-3742 www.EPICaviationllc.com 1.4. Emergency Telephone Number Emergency Number : Within USA and Canada: 800-424-9300 Outside USA and Canada: +1 703-527-3887 (Collect Calls Accepted) For Chemical Emergency, Spill, Leak, Fire, Exposure, or Accident, call CHEMTREC – Day or Night SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification (GHS-US) Flam. Liq. 1 H224 Skin Irrit. 2 H315 Eye Irrit. 2A H319 Muta. 1B H340 Carc. 1A H350 Repr. 1A H360 STOT SE 3 H336 STOT RE 1 H372 Asp. Tox. 1 H304 Aquatic Acute 2 H401 Aquatic Chronic 2 H411 2.2. Label Elements GHS-US Labeling Hazard Pictograms (GHS-US) : GHS02 GHS07 GHS08 GHS09 Signal Word (GHS-US) : Danger Hazard Statements (GHS-US) : H224 - Extremely flammable liquid and vapor H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H340 - May cause genetic defects H350 - May cause cancer H360 - May damage fertility or the unborn child 01/22/2014 EN (English US) 1/21 Leaded Avgas Safety Data Sheet according to Federal Register / Vol.
    [Show full text]
  • Synthesis of Organofluorine Compounds and Allenylboronic Acids - Applications Including Fluorine-18 Labelling Denise N
    Denise N. Meyer Synthesis of Organofluorine Compounds and Allenylboronic Synthesis of Organofluorine Compounds and Allenylboronic Acids - Applications Including Fluorine-18 Labelling Applications Acids - Allenylboronic Synthesis of Organofluorine Compounds and Acids - Applications Including Fluorine-18 Labelling Denise N. Meyer Denise N. Meyer Raised in Lauterecken, South-West Germany, Denise studied chemistry at Johannes Gutenberg University Mainz where she obtained her Bachelor's and Master's degree. In 2017, she moved to Stockholm where she pursued her doctoral studies with Prof. Kálmán J. Szabó. ISBN 978-91-7911-490-9 Department of Organic Chemistry Doctoral Thesis in Organic Chemistry at Stockholm University, Sweden 2021 Synthesis of Organofluorine Compounds and Allenylboronic Acids - Applications Including Fluorine-18 Labelling Denise N. Meyer Academic dissertation for the Degree of Doctor of Philosophy in Organic Chemistry at Stockholm University to be publicly defended on Friday 4 June 2021 at 10.00 in Magnélisalen, Kemiska övningslaboratoriet, Svante Arrhenius väg 16 B. Abstract This work is focused on two areas: the chemistry of organofluorine and organoboron compounds. In the first chapter, a copper-catalysed synthesis of tri- and tetrasubstituted allenylboronic acids is presented. Extension of the same method leads to allenylboronic esters. The very reactive and moisture-sensitive allenylboronic acids are further applied to the reaction with aldehydes, ketones and imines to form homopropargyl alcohols and amines. In addition, an enantioselective reaction catalysed by a BINOL organocatalyst was developed to form tertiary alcohols with adjacent quaternary carbon stereocenters. The second chapter specialises in the functionalisation of 2,2-difluoro enol silyl ethers with electrophilic reagents under mild reaction conditions.
    [Show full text]
  • Cumulative Cross Index to Iarc Monographs
    PERSONAL HABITS AND INDOOR COMBUSTIONS volume 100 e A review of humAn cArcinogens This publication represents the views and expert opinions of an IARC Working Group on the Evaluation of Carcinogenic Risks to Humans, which met in Lyon, 29 September-6 October 2009 LYON, FRANCE - 2012 iArc monogrAphs on the evAluAtion of cArcinogenic risks to humAns CUMULATIVE CROSS INDEX TO IARC MONOGRAPHS The volume, page and year of publication are given. References to corrigenda are given in parentheses. A A-α-C .............................................................40, 245 (1986); Suppl. 7, 56 (1987) Acenaphthene ........................................................................92, 35 (2010) Acepyrene ............................................................................92, 35 (2010) Acetaldehyde ........................36, 101 (1985) (corr. 42, 263); Suppl. 7, 77 (1987); 71, 319 (1999) Acetaldehyde associated with the consumption of alcoholic beverages ..............100E, 377 (2012) Acetaldehyde formylmethylhydrazone (see Gyromitrin) Acetamide .................................... 7, 197 (1974); Suppl. 7, 56, 389 (1987); 71, 1211 (1999) Acetaminophen (see Paracetamol) Aciclovir ..............................................................................76, 47 (2000) Acid mists (see Sulfuric acid and other strong inorganic acids, occupational exposures to mists and vapours from) Acridine orange ...................................................16, 145 (1978); Suppl. 7, 56 (1987) Acriflavinium chloride ..............................................13,
    [Show full text]
  • Degradation and Metabolism of Tetraethyllead in Soils
    Journal of Industrial Microbiology (1995] 14, 312-318 1995 Society for Industrial Microbiology 0169-4146/95/S12,00 Degradation and metabolism of tetraethyllead in soils Li-Tse Ou, Wei Jing and John E. Thomas Soil and Water Science Department, University of Florida, Gainesville, FL 32611, USA (Received 31 March 1994; accepted 19 September 1994) Key words: Tetraethyllead; Antiknock agent; Biological degradation; Chemical degradation; Metabolites; Soils Downloaded from https://academic.oup.com/jimb/article/14/3-4/312/5988466 by guest on 30 September 2021 SUMMARY The objective of this study was to determine the disappearanceof the ieaded gasoline enhancer tetraethyllead (TEL), formation of degradation products, and mass balance in nonsterile and autoclaved Leon and Madison soils. EthyI-1J4C-labeledTEL was used so that mineralizationrates of TEL and mass balance could be determined. ~4C-TELin nonsterile and autoclaved surface and subsurface samples of the two soils disappeared rapidly, and ionic ethyllead products, water soluble nonlead organic products and bound residues were rapidly formed. A small fraction (<7.74%) of 14C-TELin nonsterile soil samples was mineralized to 14CO2 in 28 days. Triethyllead(TREL) was the major ionic ethylleadproduct detected in both nonsterileand autoclaved soils; diethyllead (DEL) was occasionally detected. Recovery of ~4C from mass balance studies for all nonsterile and autoclaved soil samples after 28 days of incubation was poor, less than 50% of the 14C applied. It appears that unknown volatile and/or gaseous organic products were the major degradation products of TEL in soils. Based on the observationsof more rapid initial disappearanceof ~4C-TEL,more rapid formationand more rapid disappearanceof 14C-DEL, and occurrenceof t*COzproduction in nonsterilesoils, it was concluded that both biological and chemical degradation contributedto the degradation of TEL in soils, with chemical degradation being the major factor.
    [Show full text]