Safety Data Sheet Oramide Dl 215

Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) SAFETY DATA SHEET ORAMIDE DL 215

SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Product trade name : ORAMIDE DL 215 Product code : 37140V REACH Product name : Amides, C8-18 (even-numbered) and C18-unsatd., N, N-bis(hydroxyethyl) REACH Registration number Registration number 01-2119490100-53-0021

1.2 Relevant identified uses of the substance or mixture and uses advised against Material uses : Non ionic surfactant. Identified uses 1 - Manufacture of substance Amides, C8-18 (even-numbered) and C18(unsatd.), N,N-bis(hydroxyethyl) ; CE 931-329-6 2 - Formulation, Distribution of substance Amides, C8-18 (even-numbered) and C18-unsatd., N, N-bis(hydroxyethyl) ; CE 931-329-6. Manufacture of personal care products. 3- Professional use of the substance Amides, C8-18 (even-numbered) and C18-unsatd., N, N-bis(hydroxyethyl) ; CE 931-329-6 See Annex to the Safety data sheet for additional information in the Exposure Scenario(s).

1.3 Details of the supplier of the safety data sheet Supplier : SEPPIC S.A. 22 Terrasse Bellini - Paris La Défense 92806 Puteaux CEDEX - France Phone: +33(0)1 42 91 40 00 Fax: +33 (0)01 42 91 41 41 e-mail address of person : [email protected] responsible for this SDS

1.4 Emergency telephone number National advisory body/Poison Centre Emergency telephone : UNITED KINGDOM : number (with hours of 999 operation) Supplier Emergency telephone : SEPIPROD. number (with hours of Tél.: +33 (0)5 63 72 69 69 operation)

SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 2, H411 Classification according to Directive 67/548/EEC [DSD] Xi; R41, R38 See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms.

Date of issue/Date of revision : 10/04/2015. 1/20

Signal word : Danger Hazard statements : Causes serious eye damage. Causes skin irritation. Toxic to aquatic life with long lasting effects. Precautionary statements Prevention : Wear suitable gloves. Wear eye or face protection. Avoid release to the environment. Wash hands thoroughly after handling. Response : IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. Contains : Amides, C8-18 (even-numbered) and C18-unsatd., N, N-bis(hydroxyethyl)

2.3 Other hazards Substance meets the : No. criteria for PBT according P: Not available. B: No. T: No. to Regulation (EC) No. 1907/2006, Annex XIII Substance meets the : No. criteria for vPvB vP: Not available. vB: No. according to Regulation (EC) No. 1907/2006, Annex XIII Other hazards which do : None known. not result in classification

SECTION 3: Composition/information on ingredients 3.1 Substances : UVCB INCI Name: : COCAMIDE DEA Classification Product/ingredient Identifiers % 67/548/EEC Regulation (EC) No. Type name 1272/2008 [CLP] Amides, C8-18 (even- REACH #: 80 - Xi; R41, R38 Skin Irrit. 2, H315 [*] numbered) and 01-2119490100-53 100 Eye Dam. 1, H318 C18-unsatd., N, N-bis EC: 931-329-6 Aquatic Chronic 2, (hydroxyethyl) H411 See Section 16 for See Section 16 for the the full text of the R- full text of the H phrases declared statements declared above. above. There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section. Type [*] Substance [A] Constituent [B] Impurity [C] Stabilising additive Occupational exposure limits, if available, are listed in Section 8.

Date of issue/Date of revision : 10/04/2015. 2/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) ORAMIDE DL 215 SECTION 4: First aid measures 4.1 Description of first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth- to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact : Get medical attention immediately. Call a poison center or physician. Wash contaminated skin with soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Inhalation : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Skin contact : Causes skin irritation. Ingestion : May cause burns to mouth, throat and stomach. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain watering redness Inhalation : No specific data. Skin contact : Adverse symptoms may include the following: pain or irritation redness blistering may occur Ingestion : Adverse symptoms may include the following: stomach pains

4.3 Indication of any immediate medical attention and special treatment needed

Date of issue/Date of revision : 10/04/2015. 3/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) ORAMIDE DL 215 SECTION 4: First aid measures Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment.

SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing : None known. media

5.2 Special hazards arising from the substance or mixture Hazards from the : In a fire or if heated, a pressure increase will occur and the container may burst. substance or mixture This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide nitrogen oxides

5.3 Advice for firefighters Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident for fire-fighters if there is a fire. No action shall be taken involving any personal risk or without suitable training. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains precautions and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

6.3 Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Date of issue/Date of revision : 10/04/2015. 4/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) ORAMIDE DL 215 SECTION 6: Accidental release measures Large spill : Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product.

6.4 Reference to other : See Section 1 for emergency contact information. sections See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage 7.1 Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

7.2 Conditions for safe : Store in accordance with local regulations. Store in original container protected storage, including any from direct sunlight in a dry, cool and well-ventilated area, away from incompatible incompatibilities materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

7.3 Specific end use(s) Recommendations : Not available. Industrial sector specific : Not available. solutions

SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational exposure limits No exposure limit value known. Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace procedures atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required. DNELs/DMELs

Date of issue/Date of revision : 10/04/2015. 5/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) ORAMIDE DL 215 SECTION 8: Exposure controls/personal protection Product/ingredient name Type Exposure Value Population Effects Amides, C8-18 (even-numbered) DNEL Long term Dermal 4,16 mg/ Workers Systemic and C18-unsatd., N, N-bis kg bw/day (hydroxyethyl) DNEL Long term 73,4 mg/m³ Workers Systemic Inhalation DNEL Long term Dermal 0,09 mg/ Workers Local cm² PNECs Product/ingredient name Type Compartment Detail Value Method Detail Amides, C8-18 (even-numbered) - Fresh water 7 μg/l Assessment Factors and C18-unsatd., N, N-bis (hydroxyethyl) - Marine water 0,7 μg/l Assessment Factors - Sewage Treatment 830 mg/l Assessment Factors Plant

8.2 Exposure controls Appropriate engineering : If user operations generate dust, fumes, gas, vapour or mist, use process controls enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Individual protection measures Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended : butyl rubber, fluor rubber, nitrile rubber. Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure : Emissions from ventilation or work process equipment should be checked to controls ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Date of issue/Date of revision : 10/04/2015. 6/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) ORAMIDE DL 215 SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state : Liquid. Colour : Yellow. Brown. pH : 10 to 11,5 [Conc. (% w/w): 10%] Melting point/freezing point : -10 to -7°C Initial boiling point and boiling : Decomposes. range Flash point : Closed cup: 188°C [Not determined.] Flammability of the product : Non-flammable. Density : 0,9819 g/cm³ to 20 °C Solubility : Very slightly soluble in the following materials: cold water. Dispersible in the following materials: cold water. Water solubility (g/l) : 0,015 to 0,03 g/l Partition coefficient: n-octanol/ : 3,75 water Viscosity : Dynamic: 1357 mPa·s Temperature of viscosity : 20 °C measurement:

9.2 Other information The information presented in this section does not serve as specifications.

SECTION 10: Stability and reactivity 10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable. Conditions of instability : Keep away from oxidizing agents.

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur. hazardous reactions

10.4 Conditions to avoid : No specific data.

10.5 Incompatible materials : No specific data.

10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products decomposition products should not be produced.

SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Conclusion/Summary : Not classified as dangerous. (Oral , Dermal) Irritation/Corrosion Conclusion/Summary : Skin : Causes skin irritation. Eyes : Causes serious eye damage. Sensitisation Conclusion/Summary : Skin : Non-sensitiser to skin. Mutagenicity Date of issue/Date of revision : 10/04/2015. 7/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) ORAMIDE DL 215 SECTION 11: Toxicological information Conclusion/Summary : Not mutagenic in a standard battery of genetic toxicological tests. Carcinogenicity Conclusion/Summary : Not classified as dangerous. Reproductive toxicity Conclusion/Summary : NOAEL, Oral (OCDE 414, Rat, Maternal toxicity ) :1000 mg/kg bw/day NOAEL, Oral (OCDE 414, Rat, Embryotoxicity ) :1000 mg/kg bw/day Teratogenicity Conclusion/Summary : Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available.

Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Long term exposure Potential chronic health effects Chronic toxicity Conclusion/Summary : Not classified as dangerous. General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards.

Other information : Not available.

SECTION 12: Ecological information 12.1 Toxicity Product/ingredient Result Test Species Exposure name ORAMIDE DL 215 Acute EC50 3,9 mg/l Fresh water OCDE 201 Algae - Desmodesmus 72 hours subspicatus (Scenedesmus subspicatus) Acute EC50 3,2 mg/l Fresh water OCDE 202 Daphnia - Daphnia 48 hours magna Acute LC50 2,4 mg/l Fresh water OCDE 203 Fish - Oncorhynchus 96 hours mykiss Chronic EC10 0,3 mg/l Fresh water OCDE 201 Algae - Desmodesmus 72 hours subspicatus (Scenedesmus subspicatus) Chronic NOEC 0,07 mg/l Fresh OCDE 211 Daphnia - Daphnia 21 days water magna Chronic NOEC 0,32 mg/l Fresh OCDE 204 Fish - Oncorhynchus 28 days water mykiss Conclusion/Summary : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Date of issue/Date of revision : 10/04/2015. 8/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) ORAMIDE DL 215 SECTION 12: Ecological information 12.2 Persistence and degradability Product/ingredient name Test Result Dose Inoculum ORAMIDE DL 215 OCDE 301B 92,5 % - Readily - 28 days - Activated sludge Conclusion/Summary : This product is readily biodegradable. This product shows a low bioaccumulation potential. Product/ingredient name Aquatic half-life Photolysis Biodegradability Amides, C8-18 (even- - - Readily numbered) and C18-unsatd., N, N-bis(hydroxyethyl)

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential Amides, C8-18 (even- 3,75 65 low numbered) and C18-unsatd., N, N-bis(hydroxyethyl)

12.4 Mobility in soil Soil/water partition : 243 coefficient (KOC)

12.5 Results of PBT and vPvB assessment PBT : No. P: Not available. B: No. T: No. vPvB : No. vP: Not available. vB: No.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations 13.1 Waste treatment methods Product Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non- recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Hazardous waste : Within the present knowledge of the supplier, this product is not regarded as hazardous waste, as defined by EU Directive 91/689/EEC. Packaging Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. Special precautions : This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Date of issue/Date of revision : 10/04/2015. 9/20

ADR/RID ADN IMDG IATA 14.1 UN number UN3082 UN3082 UN3082 UN3082

14.2 UN proper ENVIRONMENTALLY ENVIRONMENTALLY ENVIRONMENTALLY Environmentally shipping name HAZARDOUS HAZARDOUS HAZARDOUS hazardous substance, SUBSTANCE, SUBSTANCE, SUBSTANCE, liquid, n.o.s. LIQUID, N.O.S. LIQUID, N.O.S. LIQUID, N.O.S. (COCAMIDE DEA) (COCAMIDE DEA) (COCAMIDE DEA) (COCAMIDE DEA). Marine pollutant 14.3 Transport 9 9 9 9 hazard class(es)

14.4 Packing III III III III group 14.5 Yes. Yes. Yes. Yes. Environmental hazards 14.6 Special Transport within user’s premises: always transport in closed containers that are upright and precautions for secure. Ensure that persons transporting the product know what to do in the event of an user accident or spillage. Additional The environmentally The environmentally The marine pollutant The environmentally information hazardous substance hazardous substance mark is not required hazardous substance mark is not required mark is not required when transported in mark is not required when transported in when transported in sizes of ≤5 L or ≤5 kg. when transported in sizes of ≤5 L or ≤5 kg. sizes of ≤5 L or ≤5 kg. sizes of ≤5 L or ≤5 kg. Emergency Passenger and Hazard identification Special provisions schedules (EmS) Cargo Aircraft number 274, 601, 335 F-A, S-F Quantity limitation: 90 450 L Special provisions Packaging Limited quantity 274, 335 instructions: 964 5 L Cargo Aircraft Only IMDG Code Quantity limitation: Special provisions Segregation group 450 L 274, 335, 601 None. Packaging instructions: 964 Tunnel code Limited Quantities - (E) Passenger Aircraft Quantity limitation: 30 kg Packaging instructions: Y964

Special provisions A97, A158

14.7 Transport in bulk : Not available. according to Annex II of MARPOL 73/78 and the IBC Code

Date of issue/Date of revision : 10/04/2015. 10/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) ORAMIDE DL 215 SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation Annex XIV None of the components are listed. Substances of very high concern None of the components are listed. Annex XVII - Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Other EU regulations Europe inventory : Not determined. EC number : 931-329-6

15.2 Chemical Safety : Complete. Assessment

SECTION 16: Other information Indicates information that has changed from previously issued version. Abbreviations and : ATE = Acute Toxicity Estimate acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Classification Justification Skin Irrit. 2, H315 On basis of test data Eye Dam. 1, H318 On basis of test data Aquatic Chronic 2, H411 On basis of test data Full text of abbreviated H : H315 Causes skin irritation. statements H318 Causes serious eye damage. H411 Toxic to aquatic life with long lasting effects. Full text of classifications : Aquatic Chronic 2, H411 LONG-TERM AQUATIC HAZARD - Category 2 [CLP/GHS] Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2 Full text of abbreviated R : R41- Risk of serious damage to eyes. phrases R38- Irritating to skin. Full text of classifications : Xi - Irritant [DSD/DPD] History Date of printing : 10/04/2015. Date of issue/ Date of : 10/04/2015. revision Date of previous issue : 02/10/2013. Version : 3 Notice to reader

Date of issue/Date of revision : 10/04/2015. 11/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Complying with 1907/2006/EC, 1272/2008/EC and 453/2010/EC regulations - United Kingdom (UK) ORAMIDE DL 215 SECTION 16: Other information The information contained in this document is provided as a guideline; it is based on the extent of SEPPIC’s knowledge regarding the product on the date indicated above. It applies to the product as is, in conformity with the specifications provided by SEPPIC*. Should the product undergo chemical transformation or be combined or mixed with other substances, it is the sole responsibility of the user to ensure that no new danger appear. Given that the use of this information is beyond the control of SEPPIC*, SEPPIC* provides no warranty, whether express or implied, and assumes no responsibility, regarding the use of this information and of the user’s product. SEPPIC* being SEPPIC SA and its subsidiaries (addresses available on www.seppic.com )

Date of issue/Date of revision : 10/04/2015. 12/20

Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Annex to the extended Safety Data Sheet (eSDS) Industrial Identification of the substance or mixture Product definition : UVCB

Section 1: - Title Number of the ES : 1 For substance : Amides, C8-18 (even-numbered) and C18-unsatd., N, N- bis(hydroxyethyl)

List of use descriptors : Identified use name: 1 - Manufacture of substance Amides, C8-18 (even- numbered) and C18(unsatd.), N,N-bis(hydroxyethyl) ; CE 931-329-6 Process Category: PROC03, PROC09, PROC15 Substance supplied to that use in form of: As such Sector of end use: SU03, SU09 Subsequent service life relevant for that use: No. Environmental Release Category: ERC01 Market sector by type of chemical product: PC39 Article category related to subsequent service life: Not applicable. Health Contributing : General exposures (PROC 3) Scenarios Bulk transfers (PROC 9) Laboratory activities (PROC 15) Clean-down and maintenance of equipment Storage

Section 2: - Exposure controls

Contributing scenario : ( Environment ) Product characteristics : Liquid. Concentration of : 100 % substance in mixture or article Amounts used : ≤ 200 Tonnes/year Frequency and duration of : Maximum daily site tonnage (kg/day): ≤ 1242 use Emission Days (days/year): 161 Fraction of Regional tonnage used locally: 100 % Environment factors not : Flow rate of receiving surface water (m3/d): 345600 influenced by risk management Other given operational : Release fraction to air from process: not applicable (Vapour pressure : low) conditions affecting Release to waste water from process : 0.928 kg/day (Water used in process or environmental exposure maintenance (cleaning) operation: Yes.) Release fraction to soil from process: Not applicable - no direct release to soil Conditions and measures : Assumed on-site sewage treatment plant flow (m³/d): 400 related to municipal Municipal STP : 20000 m³/day sewage treatment plant pH adjustment prior to discharge to the municipal STP. No application of sludge to soil, Sewage sludge incineration

Contributing scenario : General exposures (PROC 3) ( Workers: ) Concentration of : Covers percentage substance in the product up to 100% (unless stated differently). substance in mixture or article Frequency and duration of : > 4 h (half shift). use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Industrial applications workers exposure Technical conditions and : Avoid splashing. Use a sampling system designed to control exposure. Transfer measures to control via enclosed lines. Provide enhanced general ventilation by mechanical means. Fill dispersion from source containers/cans at dedicated fill points supplied with local extract ventilation. Wear towards the worker suitable gloves (tested to EN374) and eye protection. Wear work clothing with long sleeves.

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Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 ORAMIDE DL 215 Respiratory protection : None

Contributing scenario : Bulk transfers (PROC 9) ( Workers: ) Concentration of : Covers percentage substance in the product up to 100% (unless stated differently). substance in mixture or article Frequency and duration of : 1 - 4 hours use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Provide extract ventilation to points workers exposure where emissions occur. Transfer via enclosed lines. Industrial applications Technical conditions and : Wear chemical-resistant gloves (tested to EN374). Wear suitable gloves (tested to measures to control EN374), coverall and eye protection. dispersion from source towards the worker Respiratory protection : None

Contributing scenario : Laboratory activities (PROC 15) ( Workers: ) Concentration of : Covers percentage substance in the product up to 100% (unless stated differently). substance in mixture or article Frequency and duration of : 15 min - 1 hour use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Industrial applications workers exposure Technical conditions and : Avoid splashing. General ventilation. Wear suitable gloves (tested to EN374), measures to control coverall and eye protection. dispersion from source towards the worker Respiratory protection : None

Contributing scenario : Clean-down and maintenance of equipment ( Workers: ) Concentration of : Covers percentage substance in the product up to 100% (unless stated differently). substance in mixture or article Frequency and duration of : > 4 h (half shift). use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Industrial applications Drain down and workers exposure flush system prior to equipment break-in or maintenance. Retain drain-downs in sealed storage pending disposal or for subsequent recycle. Technical conditions and : Wear work clothing with long sleeves. Use suitable eye protection. Wear suitable measures at process level gloves. (source) to prevent release Technical conditions and : Wear work clothing with long sleeves. Wear suitable gloves (tested to EN374) and measures to control eye protection. dispersion from source towards the worker Respiratory protection : None

Contributing scenario : Storage ( Workers: ) Concentration of : Covers percentage substance in the product up to 100% (unless stated differently). substance in mixture or article Frequency and duration of : 1 - 4 h (half shift). use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Industrial applications workers exposure

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Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 ORAMIDE DL 215 Technical conditions and : General ventilation. Use dedicated equipment. (Keep away from heat. Keep in a measures to control well-ventilated place.) dispersion from source towards the worker Respiratory protection : None

Section 3: - Exposure estimation and reference to its source

Contributing scenario : -Exposure estimation and reference to its source -Workers: Exposure estimation : Risk Management Measures are based on qualitative risk characterisation.

Contributing scenario : - Exposure estimation and reference to its source -Environment: Exposure assessment : Used EUSES model. (environment): Exposure estimation : PEC Environment, water, continuous: 2.16 x 10E-4 mg/l (freshwater) 3.18 x 10E-5 mg/l (marine water) 5.76 x 10E-3 mg/l (STP) PEC Environment, soil, continuous: 2.44 x 10E-3 mg/kg wet weight (Fresh water sediment) 3.88 x 10E-4 mg/kg wet weight (Marine water sediment) 2.9 x 10E-3 mg/kg wet weight (soil)

Section 4: - Guidance to DU to evaluate whether he works inside the boundaries set by the ES Environment : Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels. Guidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary to define appropriate site-specific risk management measures. Health : Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.

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Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Annex to the extended Safety Data Sheet (eSDS) Industrial Identification of the substance or mixture Product definition : UVCB

Section 1: - Title Number of the ES : 2 For substance : Amides, C8-18 (even-numbered) and C18-unsatd., N, N- bis(hydroxyethyl)

List of use descriptors : Identified use name: 2 - Formulation, Distribution of substance Amides, C8-18 (even-numbered) and C18-unsatd., N, N-bis(hydroxyethyl) ; CE 931-329-6. Manufacture of personal care products. Process Category: PROC01, PROC02, PROC03, PROC05, PROC08a, PROC08b, PROC09, PROC15 Sector of end use: SU03, SU10 Subsequent service life relevant for that use: No. Environmental Release Category: ERC02 Market sector by type of chemical product: PC39 Article category related to subsequent service life: Not applicable. Health Contributing : General exposures (PROCs 1, 2, 3, 5) Scenarios Bulk transfers (PROCs 8a, 8b, 9) Laboratory activities (PROC 15) Equipment cleaning and maintenance Storage

Section 2: - Exposure controls

Contributing scenario : ( Environment ) Product characteristics : Liquid. Amounts used : ≤ 200 Tonnes/year Frequency and duration of : Maximum daily site tonnage (kg/day): 759 use Emission Days (days/year): 120 (Used EUSES model.) Fraction of Regional tonnage used locally: 100 % Environment factors not : Receiving surface water flow (m³/day):≥ 18000 m³/d (Used EUSES model.) influenced by risk management Other given operational : Release to air from process : 0.217 kg/day conditions affecting Release to waste water from process : 0.975 kg/day environmental exposure Conditions and measures : Municipal STP < 2000 m³/day (Used EUSES model.) related to municipal sewage treatment plant

Contributing scenario : General exposures (PROCs 1, 2, 3, 5) ( Workers: ) Concentration of : Covers percentage substance in the product up to 100% (unless stated differently). substance in mixture or article Physical state : Liquid. Frequency and duration of : > 4 h (half shift). - 330 days use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Industrial applications workers exposure Technical conditions and : Avoid splashing. Use a sampling system designed to control exposure. Transfer measures to control via enclosed lines. Provide enhanced general ventilation by mechanical means. Fill dispersion from source containers/cans at dedicated fill points supplied with local extract ventilation. towards the worker Ventilation control : Provide enhanced general ventilation by mechanical means. measures

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Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 ORAMIDE DL 215 Personal protection : Wear suitable gloves (tested to EN374), coverall and eye protection. Wear safety glasses with side protection in accordance with EN 166. Wear work clothing with long sleeves. Respiratory protection : None

Contributing scenario : Bulk transfers (PROCs 8a, 8b, 9) ( Workers: ) Concentration of : Covers percentage substance in the product up to 100% (unless stated differently). substance in mixture or article Physical state : Liquid. Frequency and duration of : 1 - 4 hours, 220 days use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Provide extract ventilation to points workers exposure where emissions occur. Industrial applications. Transfer via enclosed lines. Ventilation control : Provide extract ventilation to points where emissions occur (professional use). measures Personal protection : Wear suitable gloves (tested to EN374), coverall and eye protection. Respiratory protection : None

Contributing scenario : Laboratory activities (PROC 15) ( Workers: ) Concentration of : Covers percentage substance in the product up to 100% (unless stated differently). substance in mixture or article Physical state : Liquid. Frequency and duration of : 15 min. - 1 hour ; 330 days use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Industrial applications. workers exposure Technical conditions and : Avoid splashing. measures at process level (source) to prevent release Ventilation control : General ventilation measures Personal protection : Wear suitable gloves (tested to EN374), coverall and eye protection. Respiratory protection : None

Contributing scenario : Equipment cleaning and maintenance ( Workers: ) Concentration of : Covers percentage substance in the product up to 20% (unless stated differently). substance in mixture or article Physical state : Liquid. Frequency and duration of : > 4 h (half shift). 330 days use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Industrial applications. workers exposure Drain down system prior to equipment break-in or maintenance. Retain drain-downs in sealed storage pending disposal or for subsequent recycle. Personal protection : Wear work clothing with long sleeves. Use suitable eye protection and gloves. Respiratory protection : None

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Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 ORAMIDE DL 215 Contributing scenario : Storage ( Workers: ) Concentration of : Covers percentage substance in the product up to 100% (unless stated differently). substance in mixture or article Physical state : Liquid. Frequency and duration of : 1 - 4 h (half shift). 330 days use Other given operational : Assumes use at not more than 20°C above ambient temperature, unless stated conditions affecting differently. Ensure good industrial hygiene. Industrial applications. workers exposure Technical conditions and : Use dedicated equipment. (Keep away from heat. Keep in a well-ventilated place.) measures to control dispersion from source towards the worker Ventilation control : Natural ventilation. measures Respiratory protection : None

Section 3: - Exposure estimation and reference to its source

Contributing scenario : -Exposure estimation and reference to its source -Workers: Exposure estimation : Risk Management Measures are based on qualitative risk characterisation.

Contributing scenario : - Exposure estimation and reference to its source -Environment: Exposure assessment : Used EUSES model. (environment): Exposure estimation : PEC Environment, water, continuous: 2.06 x 10E-3 mg/l (freshwater) 2.05 x 10E-4 mg/l (marine water) 0.0605 mg/l (STP) PEC Environment, soil, continuous: 0.0371 mg/kg wet weight (Fresh water sediment) 3.71 x 10E-3 mg/kg wet weight (Marine water sediment) 0.029 mg/kg wet weight (soil)

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Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 Annex to the extended Safety Data Sheet (eSDS) Industrial Identification of the substance or mixture Product definition : UVCB

Section 1: - Title Number of the ES : 3 For substance : Amides, C8-18 (even-numbered) and C18-unsatd., N, N- bis(hydroxyethyl) Further information : Processes, tasks, activities covered: Covers the use as a cosmetic and includes activities associated with its transfer, use, equipment maintenance and handling of waste.

List of use descriptors : Identified use name: 3- Professional use of the substance Amides, C8-18 (even- numbered) and C18-unsatd., N, N-bis(hydroxyethyl) ; CE 931-329-6 Process Category: PROC19 Substance supplied to that use in form of: As such Sector of end use: SU21, SU22 Subsequent service life relevant for that use: No. Environmental Release Category: ERC08a Market sector by type of chemical product: PC39 Article category related to subsequent service life: Not applicable.

Section 2: - Exposure controls

Contributing scenario : ( Environment ) Product characteristics : Liquid. Concentration of : Covers percentage substance in the product up to 5%. substance in mixture or article Amounts used : Maximum daily site tonnage (kg/day): 200 Tonnes/year Daily amount for wide dispersive uses : 0.11 kg/day Fraction of EU tonnage used in region: 10% Frequency and duration of : Exposure duration per year: 365 days use Environment factors not : Receiving surface water flow (m³/day): >= 1.8 x 10E4 m³/d influenced by risk management Other given operational : Release to waste water from process : 0.11 kg/day conditions affecting Release to air from process : 0 kg/day environmental exposure Release to soil from process : 0 kg/day Conditions and measures : Municipal STP ≥ 2000 m³/day related to municipal sewage treatment plant

Contributing scenario : ( Workers: ) Concentration of : Covers percentage substance in the product up to 5%. substance in mixture or article Physical state : liquid Frequency and duration of : Use duration (h/d): >4 use 220 days per year. Human factors not : Skin contact : Whole body influenced by risk management

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Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23 ORAMIDE DL 215 Other given operational : Professional use : conditions affecting Outdoor. (Use in room with a volume of minimum [m³]: 20 m3) workers exposure The saturated vapour pressure is far higher the vapour pressure of the substance. Hence, the risk is considered negligible via the inhalation route. Regular training in workplace hygiene practice and proper use of personal protective equipment are required. Consumer use : Not applicable. Technical conditions and : Professional use : measures at process level Wear suitable gloves (tested to EN374) and eye protection. (source) to prevent release Consumer use : Not applicable. Conditions and measures related to personal protection and hygiene Advice on general : Professional use : occupational hygiene Pay attention to good general hygiene and housekeeping. Personal protection : Professional use : Wear suitable working clothes. Wear protective shoes. Respiratory protection : None

Section 3: - Exposure estimation and reference to its source

Contributing scenario : -Exposure estimation and reference to its source -Workers: Exposure estimation : Risk Management Measures are based on qualitative risk characterisation.

Contributing scenario : - Exposure estimation and reference to its source -Environment: Exposure assessment : Used EUSES model. (environment): Exposure estimation : PEC Environment, water, continuous: 7.49 x 10-4 mg/l (freshwater) 5.54 x 10-4mg/l (marine water) 6.8 x 10-3 mg/l (STP) PEC Environment, soil, continuous: 4.54 x 10-3mg/kg wet weight (Fresh water sediment) 3.36 x 10-3 mg/kg wet weight (marine sediment) 3.26 x 10-3 mg/kg wet weight (soil)

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Quick-FDS [18387-50962-25250-016588] - 2018-05-04 - 14:09:23