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Annual Report of Institute of Nuclear Chemistry and Technology 1996

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Annual Report of Institute of Nuclear Chemistry and Technology 1996 PL9702079 ISSN 1425-ZU4A IN/&~PL- 003 INSTITUTE OF NUCLEAR CHEMISTRY AND TECHNOLOGY m DO /? WMEM\ 1996 OF NUCLEI AND TECHNOLOGY 1996 EDITORIAL BOARD Wiktor Smuiek, Ph.D. Ewa Godlewska Sylwester Wojtas © Copyright by the Institute of Nuclear Chemistry and Technology, Warszawa 1997 All rights reserved CONTENTS GENERAL INFORMATION 7 MANAGEMENT OF THE INSTITUTE 9 MANAGING STAFF OF THE INSTITUTE 9 HEADS OF THE INCT DEPARTMENTS 9 PROFESSORS AND SCIENTIFIC COUNCIL 10 PROFESSORS 10 ASSOCIATE PROFESSORS 10 ASSISTANT PROFESSORS (Ph.D.) 11 SCIENTIFIC COUNCIL (1995-1999) 13 HONORARY MEMBERS OF THE INCT SCIENTIFIC COUNCIL (1995-1999) 14 RADIATION CHEMISTRY AND PHYSICS 15 ONE-ELECTRON OXIDATION OF METALLOPORPHYCENES AS STUDIED BY RADIOLYTIC METHODS D M. Guldi, J. Field, J. Grodkowski, P. Neta, E. Vogel 17 IRON-PORPHYRIN CATALYZED REDUCTION OF CO& PHOTOCHEMICAL AND RADIATION CHEMICAL STUDIES J. Grodkowski, D. Behar, P. Neta, P. Hambright 17 RATE CONSTANTS FOR REACTIONS OF ALIPHATIC CARBON-CENTERED RADICALS IN AQUEOUS SOLUTION P. Neta, J. Grodkowski, A.B. Ross 19 TETRABENZOPORPHYRINS: METAL INCORPORATION AND EXCHANGE KINETICS, LIGATIONAL EQUILIBRIA AND PULSE RADIOLYSIS STUDY S. Cromer, P. Hambright, J. Grodkowski, P. Neta 19 REDUCTION AND ALKYLATION OF RHODIUM PORPHYRINS IN ALCOHOL SOLUTIONS. RADIATION CHEMICAL AND PHOTOCHEMICAL STUDIES J. Grodkowski, P. Neta, Y. Abdallach, P. Hambright 20 •OH RADICAL INDUCED OXIDATION OF S-METHYLCYSTEINE AND ITS DERIVATIVES FRAGMENTATION OF a-AMINOALKYL RADICALS D. Pogocki, K. Bobrowski, K.-D. Asmus 21 Trp ' -* iyrO RADICAL TRANSFOMATION IN HEN-EGG WHITE LYSOZYME K. Bobrowski, J. Holcman, J. Poznafiski, K.L. Wierzchowski 24 SENSITIZED PHOTOOXIDATION OF METHIONINE-CONTAINING PEPTIDES IN AQUEOUS SOLUTION K. Bobrowski, B. Marciniak, G.L. Hug 25 GENERATION OF SULFUR RADICALS IN ZEOLITES BY MEANS OF IONIZING RADIATION S. Kowalak, Z. Stuglik, M. Strtiiyk, AB. Wiqckowski 28 ESR STUDY OF RADIATION INDUCED RADICALS IN POLYCRYSTALLINE METHIONINE AND ITS HOMOPEPTIDES G. Strzelczak-Burlitiska, K. Bobrowski, D. Pogocki, J. Michalik 28 ENDOR OF HUMAN TOOTH ENAMEL HEATED AT 400°C J. Sadto, F. Callens, J. Michalik, W. Stachowicz, P. Mattys, E. Boesman 30 DAMAGE BUILDUP AND AMORPHIZATION IN ION - IMPLANTED GaAsi-xPx S. Warchol, J. Krynicki, H. Rzewuski, R. Groetzschel 31 DOSIMETRIC RESPONSE OF MICROCRYSTALLINE L-a- ALANINE AND STANDARD BONE POWDER TO HIGH-LET RADIATIONS Z. Stuglik, J. Sadto 33 DOSIMETRIC PROPERTIES OF CDP-F2 FOILS Z. Stuglik, T. Bryl-Sandelewska 34 THE FORMATION OFdCMP RADICALS FOLLOWING RADIOLYSIS, THE EFFECT OF CYSTEAMINE G. Przybytniak, J, Hiittermann, H. Ambroz, B. Weiland 35 UV-Vis ABSORPTION SPECTRUM OF THE RADICAL ANION DERIVED FROM e-ALANINE BY DEAMINATION ZP. Zagdrski, G.K, Przybytniak 36 EXAFS STUDY OF SILVER CLUSTERS IN ZEOLITE H. Grigoriew, J. Michalik 38 RADIOCHEMISTRY, STABLE ISOTOPES, NUCLEAR ANALYTICAL METHODS, CHEMISTRY IN GENERAL 41 SOLVENT EXTRACTION OF GROUP 4 AND 14 METAL CHELATE COMPLEXES. MODEL EXPERIMENTS FOR CHEMICAL STUDIES ON COORDINATION NUMBER OF ELEMENT 104 A Bilewicz 43 FRACTIONATION OF EUROPIUM ISOTOPES IN THE EXTRACTION SYSTEMS. Eu(HI), HDEHPZEu(IlI), H+ (Cl-, NOJ, SO* -). LIGAND ISOTOPE EFFECT W. Dembitiski, R. Fiedler, Z. Janiszewski 43 FRACTIONATION OF YTTERBIUM ISOTOPES IN Yb(III)-ACETATE/Yb-AMALGAM SYSTEM. EVEN-ODD EFFECT W. Dembitiski, M. Poniliski, R. Fiedler 45 SEPARATION OF PROTIUM/DEUTERIUM AND OXYGEN-16/OXYGEN-18 BY MEMBRANE DISTILLATION G. Zakrzewska-Trznadcl, A.G. Chmielewski 46 PRECONCENTRATION OF RADIUM FROM SALINE COAL-MINE WATER ON SELECTIVE ION EXCHANGER - a-CRYSTALLINE MANGANIC ACID J. Narbutt, A Bilewicz, B. Bart06, R. Postek 47 SYNTHESIS AND ION EXCHANGE PROPERTIES OF VARIOUS FORMS OF MANGANESE DIOXIDE FOR CATIONS OF I AND II GROUPS B. BartoA, A Bilewicz, R. Delmas, C. Loos-Neskovid 48 HYDRATION AND COVALENCE OF THE Ln2+ AND An2+ IONS vs. ALKALINE EARTH IONS AS REFLECTED IN SOLUBILITY AND COCRYSTALLIZATION OF THEIR SULFATES T. Mioduski SO LIQUID-LIQUID PARTITION AND HYDRATION OF STRAIGHT-CHAIN OXAALKANES E. Gniazdowska, J. Narbutt 51 BEHAVIOUR OF THE SYSTEM: ARSENIC-PALLADIUM-MAGNESIUM DURING ATOMIZATION IN GRAPHITE FURNACE ATOMIC ABSORPTION SPECTROMETRY L. Pszonicki, J. Dudek 53 DETERMINATION AND SPECIATION OF MERCURY IN NATURAL WATERS J. Chwastowska, W. Skwara, E. Sterlirtska, J. Dudek, L. Pszonicki 54 PREPARATION OF GEL PRECURSORS FOR SYNTHESIS OF MERCURY - BASED SUPERCONDUCTING CUPRATES FROM ACIDIC ACETATE-AMMONIA SYSTEMS A Deptuta, T. Olczak, W. Lada, A Di Bartolomeo 54 A STUDY OF SUITABILITY OF THE ION CHORMATOGRAPHY EQUIPMENT OF DIONEX 2000i/SP FOR THE DETERMINATION OF ALKALI METALS AND OTHER INORGANIC CATIONS IN AQUEOUS SOLUTIONS K. Kulisa, R. Dybczyliski, H. Polkowska-Motrenko 55 IINS SPECTROSCOPY OF AMINOACIDS. PART IV. SULFOGLYCINE A Pawlukojd, J. Tomkinson, S.F. Parker 58 IINS SPECTROSCOPY OF AMINOACIDS. PART V. L-SERINE A Pawlukojd, S.F. Parker 58 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLIC ACIDS. PART XV. THE CRYSTAL AND MOLECULAR STRUCTURES OF DIAQUABIS (3-AMIN0PYRAZINE-2-CARB0XYLAT0-N,0)MAGNESIUM(II) MONOHYDRATE AND 3-AMINOPYRAZINE-2-CARBOXYLIC ACID DIHYDRATE H. Ptasiewicz-Bqk, J. Leciejewicz 59 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLIC ACIDS. PART XVI. THE CRYSTAL AND MOLECULAR STRUCTURE OF CALCIUM AMINOPYRAZINATE J. Leciejewicz, H. Ptasiewicz-Bqk, B. Paluchowska 60 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLIC ACIDS. PART XVII. THE CRYSTAL AND MOLECULAR STRUCTURES OF PYRAZINE-2.5-DICARBOXYLIC ACID DIHYDRATE AND ITS MAGNESIUM COMPOUND H. Ptasiewicz-Bqk, J. Leciejewicz 61 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLIC ACIDS. PART XVIII. THE CRYSTAL STRUCTURE OF DIAQUABIS(THIOPHENE-2-CARBOXYLATE)ZINC(II) B. Paluchowska, IK. Maurin, J. Leciejewicz 62 MAGNETIC ORDERING IN LANTHANIDE INTERMETALLIC PHASES J. Leciejewicz, A Szytula 62 X-RAY STUDY OF WATER INFLUENCE ON CELLULOSE MEMBRANE STRUCTURE H. Grigoriew, AG. Chmielewski 64 RADIOBIOLOGY 67 OXIDATIVE BASE DAMAGE IN DNA FROM L5178Y SUBLINES M. Kruszewski, T. Zastawny, T. Wrortska, R. Oliliski 69 EFFECT OF COPPER CHELATOR, NEOCUPREINE, ON L5178Y CELLS E. BouZyk, T. Iwancliko, M. Kruszewski 70 ION CHELATOR, DESFERAL, DIFFERENTIALLY AFFECTS NULEOID DNA IN TWO SUBLINES OF L5178Y MURINE LYMPHOMA E. Bouiyk, T. Iwaneliko, M. Kruszewski 70 DETERMINATION OF DNA DAMAGE REPAIR IN CAMPTOTHECIN - TREATED MURINE LYMPHOMA CELLS BY THREE METHODS I. Grqdzka, I. Szumiel 71 INDUCTION OF DNA-PROTEIN CROSS LINKS BY GAMMA RAYS IN CELLS OF THREE MURINE LYMPHOMAS N. Jarocewicz, I. Szumiel 72 LACK OF CORRELATION BETWEEN DNA REPAIR KINETICS, RESIDUAL DAMAGE AND MICRONUCLEI FREQUENCY IN RADIOADAPTBD HUMAN LYMPHOCYTES M. Wojew6dzka, M Kruszewski, I. Szumiel 73 APPLICATION OF THE COMET ASSAY FOR DETECTION OF DNA DAMAGE IN LYMPHOCYTES OF WORKERS EXPOSED TO LOW-DOSES OF IONIZING RADIATION M. Wojewddzka, T. Iwaneliko. M. Kruszewski 73 LOVASTATIN TREATMENT DIFFERENTIALLY ALTERS ACTIVATION OF TRANSCRIPTION FACTOR, NF*B AND SENSITIVITY TO HYDROGEN PEROXIDE B. Sochanowicz, I. Szumiel 74 INITIAL DNA DAMAGE AND LETHALITY IN BLEOMYCIN - TREATED L5178Y CELLS J. Zaim, I. Szumiel 75 NUCLEAR TECHNOLOGIES AND METHODS 77 PROCESS ENGINEERING 79 CONCEPTUAL DESIGN OF THE DEMO-INDUSTRIAL INSTALLATION FOR ELECTRON-BEAM FLUE GAS TREATMENT AG. Chmielewski, E. Iller, B. Tymiliski, Z Zimek 79 FILTRATION OF AEROSOLS FORMED IN EB FLUE GAS TREATMENT PROCESS AG. Chmielewski, B. Tymiliski, G. Zakrzewska-Trznadel, O. Tokunaga, S. Machi 82 RADIOTRACERS IN ROTARY KILNS INVESTIGATION J. Palige, A Owczarczyk 83 TRACER INVESTIGATION OF THE SEDIMENT AND SEWAGE FLOW DYNAMICS THROUGH AERATION TANK A Owczarczyk, J. Palige, M. Strzelecki, AG. Chmielewski 84 MEMBRANE DISTILLATION EMPLOYED FOR CONCENTRATION OF LIQUID RADIOACTIVE WASTE AG. Chmielewski, M. Harasimowicz, G. Zakrzewska-Trznadel 86 METAL RECOVERY FROM DILUTE STREAMS M. Harasimowicz, J. Palige 86 APPLICATION OF PARTICLE TRACK MEMBRANES IN A DYNAMIC FILTRATION DEVICE W. Starosta, M. Buczkowski, S. Wroliski, A Adach 87 MATERIAL ENGINEERING, STRUCTURAL STUDIES, DIAGNOSTICS 89 NEW APPARATUS FOR PREPARATION OF GASEOUS METHYL BROMIDE AND RECORDING LEAKS IN UNDERGROUND PIPELINES J. KraS, S. Myczkowski 89 INTENSE PLASMA PULSES; TWO MODES OF THE USE FOR SURFACE PROCESSING PURPOSES J. Piekoszewski, J. Langner, L. WaliS, Z. Werner 89 USE OF HIGH INTENSITY PULSED PLASMA BEAMS IN FORMATION CERAMIC/MBTAL JOINTS J. Piekoszewski, J. Langner, A Krajewski, L. WaliS, W. Wiosiliski 90 THE PLASMA DISCHARGE DEVICE FOR MODIFICATION OF SURFACE PROPERTIES OF PARTICLE TRACK MEMBRANES W. Starosta, M. Buczkowski, D. Wawszczak, T. Z6ttowski 91 PREPARATION OF HIGH PURITY BORON ON A LARGE LABORATORY SCALE A. Nowicki 92 ORGANIC FIBRES IMPREGNATED WITH POLYMERIC COMPLEXES OF AMINOTRIAZOLE WITH METALS AS NEW FILTERS AND SORBENTS A. Lukasiewicz, L. WaliS 93 PREPARATION OF CALCIUM PHOSPHATE SPHERICAL POWDERS AND COATINGS BY COMPLEX SOL-GEL PROCESS (CSGP) A Deptula, W. Lada, T. Olczak, R Z LeGeros, J.P. LeGeros 94 DETERMINATION OF TRACE ELEMENTS IN LEAD WHITE FROM LANCKORONA PAINTING COLLECTION BY INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS E. Paliczyk, P. Rudniewski, L. WaliS 96 APPLICATION OF X-RAY FLUORESCENCE ANALYSIS FOR EXAMINATION OF THE AUTHENTICITY OF THAI CERAMICS A. Kalicki, E. Paliczyk, L. WaliS 100 STUDIES OF MILLINGABILITY OF COAL COMBUSTED IN HEAT POWER STATIONS P J. Bukowski 101 TOTAL-REFLECTION X-RAY FLUORESCENCE ANALYSIS FOR EFFECTIVENESS OF MICROFILTRATION MEASUREMENTS M Buczkowski, J. Kierzek, D. Wawszczak,
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