23Rd MEETING
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INTERNATIONAL SOCIETY OF ELECTROCHEMISTRY (I.S.E.) w (formerly C.I.T.C.E.) SOClÉTÉ INTERNATIONALE D'ELECTROCHIMIE (S.I.E.) -i (anciennement C.I.T.C.E.) f G lMlS-r>v^f- 6?2 OJ IB f (ö -I 0 ö I o- l 23rd MEETING $ m, Ds n< Z ; c ; »i' EXTENDED ABSTRACTS STOCKHOLM, SWEDEN August 27th-September 2nd, 1972 We regret that some of the pages in the microfiche copy of this report may not be up to the proper legibility standards, even though the best possible copy was used for preparing the master fiche. INTERNATIONAL SOCIETY OF ELECTROCHEMISTRY (I.S.E.) SOCIETE INTERNATIONALE D"ELECTROCHIMIE (S.I.E.) 23rd MEETING including SYMPOSIUM ON ELECTROCHEMICAL ENGINEERING (114th EVENT OF THE EUROPEAN FEDERATION OF CHEMICAL ENGINEERING) and SYMPOSIUM ON ACCELERATED CORROSION TESTING WITH ELECTROCHEMICAL METHODS (66th EVENT OF THE EUROPEAN FEDERATION OF CORROSION) EXTENDED ABSTRACTS STOCKHOLM, SWEDEN AUGUST 27th - SEPTEMBER 2nd, 1972 This volume has been produced by off-set printing from originals as received from the authors» Technical Editor: Mr. Jaak Berendson, Met.Eng., The Royal Institute of Technology, Stockholm, Sweden. Printing Office: AB Realtryck, Stockholm, Sweden. Edition: 600 copies. CONTENTS SYMPOSIA ELECTROCHEMICAL ENGINEERING Optimization of Electrolytic Processes (Plenary Lecture) N. Ibl Design and Materials of Construction for Electrolytic Cells (Plenary Lecture") Robert B. MacMullin Some Fundamencal Aspects of Industrial Electro lytic Processes (Plenary Lecture) Charles W. Tobias Dimensionally Stable Anodes in Chlorate Electrolysis R.T. Atanasoski, A.O. Filip, B.Z. Nikolic, M.M. JakSic and A.R. Despic Cells for Electro-Organic Synthesis Fritz Beck Basic Problems of the Electrochemical Production of Chlorine Giuseppe Bjanchi and Giuseppe Faita Experimental Realisation of a Clamped Ionic Concentration Gradient Michel Delmotte. and Jacques Chanu Pulsating Potential Electrolysis in Deposition of Copper Aleksandar Despic and Gordana Savic Maglic Electroneutrality and Steady State during the Transfer of Electric Current through Graded Electrolyte Solutions Chaim Forgacs II New Concepts in the Scaleup of Chlorine-Caustic Mercury Cells P. Gallone 25 Performance Studies of a Bipolar Packed Bed Cell for the Production of Propylene Oxide Francis Goodridge and Ola Osifade 28 Some Performance Characteristics of Three- Dimensional Electrodes Martin Fleischmann and Francis Goodridge 30 A Model for Membrane Fouling in Electrodialysis G. Grossman and A.A. Sonin 33 Mass Transfer Determined Reactions in Flui- dised Bed Cells Ewald Heitz and Siegfried Pionteck 36 Some Surface Studies of Electrochemically Machined High-Temperature Alloys James P. Hoare, Armand J. Chartrand and Mitchell A. LaBoda 38 The Influence of Foreign Atoms on the Proper ties of Electrolytic Zinc Powder I.N. Justinijanovie, J.N. Jovicevic and A.R. Despic 41 On the Anodic Dissolution of Metals at High Current Densities V.D. Kashcheey, B.N. Kabanov and A.D. Davydov 42 Sulphate Electrolysis Based on Anionic Proton Migration Joseph Kerti 43 Some Features of a Novel Bi-Polar Electrolytic Flow Cell Christopher J.H. King 46 Electrochemical Investigations of the Cylindrical Ro'tating Electrode Dj. Matic, B. Lovrecek and D. Skansi 49 The Glanor Diaphragm Cell: .A New Tool for the Chlorine Industry Vittorio de Nora 51 Theory of Electrochemical Machining S.K^Rangarajan, T.G. Ramesh and S. Ramabhadran 52 Study of Mass Transfer in Flowing Electrolyte with Quasi Porous Electrode Branko LovreSek, Darke Skans i and Djani Matic 53 Electrokinetic Salt Rejection by Porous Materials - Theory and Experiment G. Jacazio, R.F. Probstein, A.A. Sonin and D. Yung 54 Design Approach to the Chlorate Cell M.M. Jaksic, N.M. Jaksic, M.D. Spasojevic and B.Z. Nikolic " " 57 Concentration-Polarization at Ion-Exchange Membrane/Solution Interfaces C. Forgacs, J. Leibovitz, J. Sinkovic and K.S. Spiegler 58 Engineering Aspects of Gold Plating for Electronic Devices Dennis Turner 62 The Effect of Superimposed Alternating and Direct Current on the Internal Stresses in Nickel Deposits Jean Vereecken and René Winand 63 Ionic Mass Transfer by Free Convection with Simultaneous Heat Transfer A.A. Wragg and A.K. Nasiruddin 65 Calculation of Local Current Densities and Terminal Voltage for a Monopolar Sandwich Electro- lyzer; Application to Chlorate Cells I. Rousar, V. Cezner, J, Hostomsky, M.M. Jak'sic, M. Spasojevic and B.Z. Nikolic 68 The Decomposition of Sodium Amalgam in a Horizontal Decomposer J. Hostomsky, I. Rousar and V. Cezner 70 Sodium Amalgam Decomposition in a Vertical Tower S. Rajasekaran4 I. Rousar, J. Hostomsky and V. Cezner 72 ACCELERATED CORROSION TESTING WITH ELECTROCHEMICAL METHODS Controlled Potential Methods of Corrosion Testing (Plenary Lecture) Norbert D. Greene 77 Use of Methods of Electrochemistry and Radio active Indicators for Determining Low Corrosion Rates (Plenary Lecture) Ya.M. Kolotyrkin 79 The Polarization Resistance Method of Corrosion Testing (Plenary Lecture) Milan Prazäk 81 The Radiographical Method of the Examination of Permeability of Paint Coating Modified with Corrosion Inhibitor L. Chromy and A. Zimnoch 84 Pitting Potential Measurements on Stainless Steels, as Compared "with Rest Potentials and the Electrochemical Behaviour of Passive Films J.M. Defranoux 85 Intergranular Corrosion of Austenitic Stainless Steels in the Sensitized or Solution-Annealed Condition André Desestret, Michel Froment and Pierre Guiraldenq 87 Electrochemical Methods for Corrosion Evaluation of Low-Alloy Steels, Copper Alloys and Stainless Steels Lucio Giuliani, Alberto Tamba and Roberto Bruno 90 Accelerated Stress-Corrosion Cracking of Ti-8%A1- l%Mo-l%V in the Presence of a Hydrogen-Recombina tion Poison J..A.S. Green and A.J. Sedriks 93 Accelerated Method for the Investigation of the Susceptibility of Stainless Steels to Intergranular Corrosion by Potentiodynamic Polarization Lajos Hackl, G. Muller, J. Horvåth and F. Märta 96 Basic Principles of Electrochemical Corrosion Testing Michel Keddam 99 v 55 59 • The Application of Fe and Fe * to Corrosion Testing Pance Kirkov and Zarko Radosavljevic 102 The Electrochemical Behaviour of Nimonic and Tita nium Alloys in Molten Salts David G. Lovering 103 An Electrochemical Test for Quality of Conversion Coatings on Al Alloys F. Mansfeld and E.P. Parry 106 On the So-Called Linear Polarization Method for Measurement of Corrosion Rates K.B. Oldham and F. Mansfeld 109 Evaluation of the Susceptibility of Austenitic Stainless Steels to Stress C.C. by Chemical or Electrochemical Methods Giuseppe Bianchi, Alessandro Cerquetti, Francesco Mazza and Sandro Torchio 112 Comparison of Corrosion Rates in Sulfuric Acid Obtained Using Resistance-Polarization, Tafel- Extrapolation, and Weight-Loss Techniques James R. Myers 115 Electrochemical Studies of Corrosion-Erosion during Hydraulic Transport of Solids in Pipes J. Postlethwaite and E.B. Tinker 116 Electrochemical Corrosion Testing of Metals in Alkali Sulphate Melts A. Rahmel 119 Electrochemical Investigations on Pitting Giinter Herbsleb and Wilhelm Schwenk 120 Transient Straining Electrodes for Studying Stress Corrosion Cracking R.W. Staehle, J.B. Lumsden and S. Abe 123 Experiments on the Acceleration of the Intergranular Stress Corrosion Cracking of Type AISI 304 Stainless Steel by Means of Potentiostatic Polarization Pee ter Tarkpea, Kjell Lundberg and Walter Hiibner 126 Corrosion Tests with the Aid of Electrochemical Measurements on Nickelbase Alloys under Pressure Water Conditions Norbert Wieling 129 SECTION MEETINGS SECTION 1 -ELECTROCHEMICAL THERMODYNAMICS i • i—t i i i —• —— —• Thermodynamics of Surface Layers. (Invited Paper) Hermann Göhr 133 The Adsorption of Acetone at the Mercury - Solu tion Interface Zofia Borkowska and Barbara Behr 136 Entropies of Silver Halides in Water, Molten Calcium Nitrate Tetrahydrate and Anhydrous Nitrate Melts Brian Burrows and Soefjan Noersjamsi 139 Thermodynamics of Mixed Aqueous Solvents: Transfer Parameters Gerard Douhéret 141 The Transference Numbers in Aqueous Solutions of 1:1 Type Salts as a Function of Temperature and Concentration Nadezda Jakovljevic Halai 144 Polarographic Determination of Hydrogen Ion Activities in Strongly Acidic Media: A New Acidity Function Jiri Janata and Geertje Jansen 147 Stability of Laminar Flow of Liquid Mixture with Temperature Gradient Claude Klapisz and Jacques Chanu 149 Adsorption of Tetrapropyl- and Tetrabutyl- Ammonium Cations and Higher Alkylsulphonate Anions on Mercury J. Kuta and I. Smoler 152 A Method of Estimating the Reaction of Electrodes at the Surface of Sulphide Minerals in Conditions of Flotation Janusz Lekki 156 Determination of the Equilibrium Constant of the Side Reaction Occuring in the Concentration Cell Zbigniew Moser and Krzysztof Fitzner 159 VII Quantum Mechanical Estimation of Heats of Adsorp tion of Atomic Oxygen on some Metal Surfaces Walter Sarholz, Detlef Baresel and Gunter Schuiz-Ekloff 162 Thermodynamics and Kinetics of Metal Ion Adsorption J.W. Schultze 163 EMF of the Cells (Pt)Ho/H Hal, Hg2Halo/Hg in Organic Solvents and their Mixtures with Water Kurt Schwabe 166 Coupled Self and Chemical Diffusion in Electro lyte Solutions. Diffusion Potential and Corre sponding Reciprocal Relations Pierre Turq and Marius Chemla 169 SECTION 2 - ELECTROCHEMICAL KINETICS Kinetics of Thin Oxide Layer Formation on Noble Metals (Invited Paper) K.J. Vetter 175 Kinetics of the Electrochemical Formation of Parathiocyanogen Films A.J. Arvia and A.J. Calandra 178 Activities or Concentrations in Equations of Electrode Kinetics M.M.