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Explosion of Lithium-Thionyl-Chloride Battery Due to Presence of Lithium Nitride
Downloaded from orbit.dtu.dk on: Sep 25, 2021 Explosion of lithium-thionyl-chloride battery due to presence of lithium nitride Hennesø, E.; Hedlund, Frank Huess Published in: Journal of Failure Analysis and Prevention Link to article, DOI: 10.1007/s11668-015-0004-y Publication date: 2015 Document Version Early version, also known as pre-print Link back to DTU Orbit Citation (APA): Hennesø, E., & Hedlund, F. H. (2015). Explosion of lithium-thionyl-chloride battery due to presence of lithium nitride. Journal of Failure Analysis and Prevention, 15(5), 600-603. https://doi.org/10.1007/s11668-015-0004-y General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. Users may download and print one copy of any publication from the public portal for the purpose of private study or research. You may not further distribute the material or use it for any profit-making activity or commercial gain You may freely distribute the URL identifying the publication in the public portal If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim. This article appeared in Journal of Failure Analysis and Prevention, ISSN 1547-7029 http://dx.doi.org/10.1007/s11668-015-0004-y Explosion of lithium-thionyl- chloride battery due to presence of lithium nitride Document no. -
(12) United States Patent (10) Patent No.: US 7.449,161 B2 Boryta Et Al
USOO74491.61B2 (12) United States Patent (10) Patent No.: US 7.449,161 B2 Boryta et al. (45) Date of Patent: Nov. 11, 2008 (54) PRODUCTION OF LITHIUM COMPOUNDS 4,207,297 A * 6/1980 Brown et al. ............. 423,179.5 DIRECTLY FROM LITHIUM CONTAINING 4,243,641 A * 1/1981 Ishimori et al. .......... 423/179.5 BRINES 4.261,960 A * 4/1981 Boryta ............. ... 423,179.5 4,271,131. A * 6/1981 Brown et al. ...... ... 423,179.5 4,274,834. A 6/1981 Brown et al. .............. 23,302 R (75) Inventors: Daniel Alfred Boryta, Cherryville, NC 4,463,209 A * 7/1984 Kursewicz et al. .......... 585/467 (US); Teresita Frianeza Kullberg, 4,465,659 A * 8/1984 Cambridge et al. ......... 423,495 Gastonia, NC (US); Anthony Michael 4,588,565 A * 5/1986 Schultze et al. .......... 423,179.5 Thurston, Edmond, OK (US) 4,747.917 A * 5/1988 Reynolds et al. ............ 205,512 4,859,343 A * 8/1989 Frianeza-Kullberg (73) Assignee: Chemetall Foote Corporation, Kings et al. .......................... 210,679 Mountain, NC (US) 4,980,136 A * 12/1990 Brown et al. ... 423,179.5 5,049,233 A 9, 1991 Davis .......................... 216.93 (*) Notice: Subject to any disclaimer, the term of this 5,219,550 A * 6/1993 Brown et al. ............. 423 (419.1 patent is extended or adjusted under 35 5,599,516 A * 2/1997 Bauman et al. .......... 423/179.5 U.S.C. 154(b) by 0 days. 5,939,038 A * 8/1999 Wilkomirsky ............... 423,276 5.993,759 A * 1 1/1999 Wilkomirsky ........... -
Reactions of Lithium Nitride with Some Unsaturated Organic Compounds. Perry S
Louisiana State University LSU Digital Commons LSU Historical Dissertations and Theses Graduate School 1963 Reactions of Lithium Nitride With Some Unsaturated Organic Compounds. Perry S. Mason Jr Louisiana State University and Agricultural & Mechanical College Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_disstheses Recommended Citation Mason, Perry S. Jr, "Reactions of Lithium Nitride With Some Unsaturated Organic Compounds." (1963). LSU Historical Dissertations and Theses. 898. https://digitalcommons.lsu.edu/gradschool_disstheses/898 This Dissertation is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Historical Dissertations and Theses by an authorized administrator of LSU Digital Commons. For more information, please contact [email protected]. This dissertation has been 64—5058 microfilmed exactly as received MASON, Jr., Perry S., 1938- REACTIONS OF LITHIUM NITRIDE WITH SOME UNSATURATED ORGANIC COMPOUNDS. Louisiana State University, Ph.D., 1963 Chemistry, organic University Microfilms, Inc., Ann Arbor, Michigan Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. REACTIONS OF LITHIUM NITRIDE WITH SOME UNSATURATED ORGANIC COMPOUNDS A Dissertation Submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College in partial fulfillment of the requireiaents for the degree of Doctor of Philosophy in The Department of Chemistry by Perry S. Mason, Jr. B. S., Harding College, 1959 August, 1963 Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. -
1 Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction Nikifar Lazouski,1 Zachary J Schiffer,1 Kindle Wi
© 2019 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ doi: 10.1016/j.joule.2019.02.003 Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction Nikifar Lazouski,1 Zachary J Schiffer,1 Kindle Williams,1 and Karthish Manthiram1* 1Department of Chemical Engineering; Massachusetts Institute of Technology; Cambridge, MA 02139, USA *Corresponding Author: [email protected] 1 © 2019 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ doi: 10.1016/j.joule.2019.02.003 Summary Ammonia is a large-scale commodity chemical that is crucial for producing nitrogen- containing fertilizers. Electrochemical methods have been proposed as renewable and distributed alternatives to the incumbent Haber-Bosch process, which utilizes fossils for ammonia production. Herein, we report a mechanistic study of lithium-mediated electrochemical nitrogen reduction to ammonia in a non-aqueous system. The rate laws of the main reactions in the system were determined. At high current densities, nitrogen transport limitations begin to affect the nitrogen reduction process. Based on these observations, we developed a coupled kinetic-transport model of the process, which we used to optimize operating conditions for ammonia production. The highest Faradaic efficiency observed was 18.5 ± 2.9%, while the highest production rate obtained was (7.9 ± 1.6) × 10-9 mol cm-2 s-1. Our understanding of the reaction network and the influence of transport provides foundational knowledge for future improvements in continuous lithium- mediated ammonia synthesis. -
Lithium Nitride
TECHNICAL DATA SHEET Date of Issue: 2016/12/12 Lithium Nitride CAS-No. 26134-62-3 EC-No. 247-475-2 Molecular Formula Li3N Product Number 401121 SPECIFICATION Lithium Nitride: min. 94% METHOD OF ANALYSIS Assay by determination of nitrogen by the method of Kjeldahl. A detailed laboratory instruction is available on request. PHYSICAL PROPERTIES Appearance fine powder Color red brown Melting point/ range ca. 840 - 845 °C Density ca. 1.38 g/cm3 at 20 °C Water solubility (Not applicable) Molecular weight 34.82 g/mol Additional Physical Theoretical lithium weight: 59.8 % Properties The information presented herein is believed to be accurate and reliable, but is presented without guarantee or responsibility on the part of Albemarle Corporation and its subsidiaries and affiliates. It is the responsibility of the user to comply with all applicable laws and regulations and to provide for a safe workplace. The user should consider any health or safety hazards or information contained herein only as a guide, and should take those precautions which are necessary or prudent to instruct employees and to develop work practice procedures in order to promote a safe work environment. Further, nothing contained herein shall be taken as an inducement or recommendation to manufacture or use any of the herein materials or processes in violation of existing or future patent. Technical data sheets may change frequently. You can download the latest version from our website www.albemarle-lithium.com. Please contact us at www.albemarle-lithium.com/contact with questions. Lithium Nitride Page 2 / 3 Product Number: 401121 Date of Issue: 2016/12/12 HANDLING & STORAGE Handling Lithium Nitride should be handled under inert gas atmosphere. -
(12) United States Patent (10) Patent No.: US 8,871,843 B2 Lee (45) Date of Patent: Oct
USOO887 1843B2 (12) United States Patent (10) Patent No.: US 8,871,843 B2 Lee (45) Date of Patent: Oct. 28, 2014 (54) HALOGEN-FREE FLAME RETARDANT 5,456,984 A 10/1995 Bishop et al. MATERAL 5,484,830 A 1/1996 Staendeke 5,648.436 A 7/1997 Janowitz et al. 5,925,700 A 7/1999 Imahashi (75) Inventor: Jean L. Lee, San Jose, CA (US) 5,955, 184 A 9, 1999 Honda et al. 5,994,429 A 11/1999 Honda et al. (73) Assignee: Apple Inc., Cupertino, CA (US) 6,140,411 A 10/2000 Schwanborn et al. 6,355,767 B1 * 3/2002 Takagi .......................... 528,196 (*) Notice: Subject to any disclaimer, the term of this 6,440,567 B1 8, 2002 Choate et al. 6,495,244 B1 12/2002 Andresakis et al. patent is extended or adjusted under 35 6,518,336 B1 2/2003 Yabuhara et al. U.S.C. 154(b) by 190 days. 6,642,288 B1 1 1/2003 Hulskotte 6,755,995 B1 6/2004 Hasegawa et al. (21) Appl. No.: 12/638,489 6,767,941 B2 7/2004 Van Der Speket al. 6,809,130 B2 10/2004 Chiou et al. 6,894, 101 B2 5, 2005 Paul et al. (22) Filed: Dec. 15, 2009 6,916,539 B2 7/2005 Cooray et al. 6,998,536 B2 2/2006 Barusseau et al. (65) Prior Publication Data 7,053,145 B1 5/2006 Tasaka et al. US 2011/O144244A1 Jun. 16, 2011 7,115,678 B2 10/2006 Ihara et al. -
Safety Data Sheet
SAFETY DATA SHEET SECTION 1: CHEMICAL PRODUCT and COMPANY IDENTIFICATION Product Name: Lithium nitride 99.5% Li -60 Mesh Product Code: L04310 Supplier: Pfaltz & Bauer, Inc. 172 E. Aurora Street Waterbury, CT 06708 USA Phone: 203-574-0075 FAX: 203-574-3181 Emergency Phone: INFOTRAC, US: 1-800-535-5053 INFOTRAC, INTERNATIONAL: +1-352-323-3500 SECTION 2: HAZARDS IDENTIFICATION Statement of Hazard: Corrosive, Dangerous when wet, Irritant, Reacts violently with water, Respiratory irritant Acute Health Hazard: Irritant to eyes, skin, mucous membranes and respiratory system. May be harmful by ingestion, skin absorption and inhalation. Chronic Health Hazard: Not Available HMIS Rating: H: 3 F: 3 P: 2 NFPA Rating: H: 3 F: 0 R: 2 To the best of our knowledge, the toxicological properties of this chemical have not been thoroughly investigated. Use appropriate procedures and precautions to prevent or minimize exposure. GHS Classification in accordance with 29 CFR 1910 (OSHA HCS): Page 1 of 7 Acute toxicity, dermal (Category 4), H312 Acute toxicity, inhalation (Category 4), H332 Acute toxicity, oral (Category 4), H302 Serious eye damage/eye irritation (Category 2A), H319 Skin corrosion/irritation (Category 1A), H314 Specific target organ toxicity, single exposure; Respiratory tract irritation (Category 3), H335 Substances and mixtures which, in contact with water, emit flammable gases (Category 1), H260 Pictogram: Signal Word: Danger Hazard Statement(s): H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. -
Pfs Update Confirms Potential of Low-Cost Lithium Hydroxide Production
For immediate release 17 June 2019 EUROPEAN METALS HOLDINGS LIMITED PFS UPDATE CONFIRMS POTENTIAL OF LOW-COST LITHIUM HYDROXIDE PRODUCTION European Metals Holdings Limited (“European Metals” or “the Company”) is pleased to announce the results from the successful update of the process flowsheet previously developed to enable the production of lithium hydroxide (LiOH.H2O). This work has been completed in conjunction with test-work confirming the production of battery grade lithium hydroxide from Cinovec ore. These results significantly enhance the forecast economics of the Cinovec Project. HIGHLIGHTS (all $ figures in this release are US Dollars and increases refer to the 2017 PFS Lithium Carbonate study): • Net estimated overall cost of production post credits: $3,435 / tonne LiOH.H2O • Project Net Present Value (“NPV”) increases 105% to: $1.108B (post tax, 8%) • Internal Rate of Return (“IRR”) increased 37% to 28.8% (post tax) • Total Capital Cost: $482.6M • Annual production of Battery Grade Lithium Hydroxide: 25,267 tonnes • Studies are based on only 9.3% of reported Indicated Mineral Resource and a mine life of 21 years processing an average of 1.68 Mtpa ore • The process used to produce lithium hydroxide allows for the staging of lithium carbonate and then lithium hydroxide production to minimize capital and startup risk and enables the production of either battery grade lithium hydroxide or carbonate as markets demand European Metals Managing Director Keith Coughlan said, “I am very pleased to report to shareholders on the completion of this update to our 2017 Preliminary Feasibility Study for the Cinovec project which adds significantly to the already robust forecast economics for the project. -
Low Temperature and Pressure Synthesis of Lithium–Nitride
Materials Transactions, Vol. 54, No. 12 (2013) pp. 2233 to 2237 ©2013 The Japan Institute of Metals and Materials Low Temperature and Pressure Synthesis of LithiumNitride Compound with H2O Addition on Lithium Target for BNCT Shintaro Ishiyama1,+, Yuji Baba1, Ryo Fujii2, Masaru Nakamura2 and Yoshio Imahori2 1Quantum Beam Science Directorate, Japan Atomic Energy Agency, Naka-gun, Ibaraki 319-1195, Japan 2Cancer Intelligence Care Systems, Inc., Tokyo 135-0063, Japan Low temperature synthesis of lithiumnitride compound was conducted on the lithium target for BNCT by N2/H2O mixing gas squirt in the ultra high vacuum chamber, and the following results were derived. (1) Lithiumnitride compound was synthesized on the lithium target ¹8 under 101.3 Pa N2 gas squirt at room temperature and in the ultra high vacuum chamber under the pressure of 1 © 10 Pa. (2) Remarkable contamination by O and C was observed on the lithiumnitride compound synthesized under the squirt pressure of 13.380 Pa/1.334.7 Pa N2/ H2O mixing gas. (3) No contamination and synthesis of LiN compound was observed under the squirt pressure of 0.0130.027 Pa/00.005 Pa N2/H2O mixing gas. (4) Contamination by O and C was enhanced with excessive addition of H2O at the pressure of over 1.33 Pa. [doi:10.2320/matertrans.M2013242] (Received June 26, 2013; Accepted September 25, 2013; Published November 9, 2013) Keywords: boron neutron capture therapy, neutron source, lithium target, lithium nitride, nitrogen gas, contamination, H2O addition 1. Introduction Implemented deployment of accelerator-driven neutron source for Boron Neutron Capture Therapy (BNCT) is scheduled in 2013 in National Cancer Center, Japan. -
Sonora Project)
SONORA LITHIUM PROJECT FS TECHNICAL REPORT TECHNICAL REPORT ON THE FEASIBILITY STUDY FOR THE SONORA LITHIUM PROJECT, MEXICO January 2018 January 2018 Prepared For Bacanora Minerals Ltd Prepared by Ausenco Services Pty Ltd 144 Montague Rd South Brisbane Australia Effective Date: December 12, 2017 Issue Date: January 25, 2018 101304-FS-0004-Tech Report rev 0.docx SONORA LITHIUM PROJECT FS TECHNICAL REPORT CERTIFICATE OF QUALIFIED PERSON I, Joel A. Carrasco, P.E., do hereby certify thhat: 1. I am a Principal Engineer, Solum Consulting Group, 350 S Jackson st. #454 Denver, Colorado 80209 USA. 2. This certificate applies to the technical report titled “Technical Report on the Feasibility Study for the Sonora Lithium Project, Mexico, January 2018” (the “Technical Report”), prepared for Bacanora Minerals Limited; 3. The Effective Date of the Technical Report is 12 December 2017. 4. I am a graduate of Texas Tech Univerrsity, Texas with a Bachelor of Scieence degree in Civil Engineering. I have worked as a Civil Engineer continuously for a total off 15 years since my graduation from University. My relevant experience has been working as Project Manager for multi-national engineering companies on feasibility studies and engineering designs of tailings facilities; 5. I am registered as a Professional Engineer in the State of Arizona (Licence # 52000). 6. I havve read the definition of “Qualified Person” set out in National Instrument 43-101 (NI 43-101) and certify that by reason of my education, affiliation with a professional association (as defined in NI 43-101) and past relevant work experrience, I fulfil the requirements to bee a “Qualified Person” for the purposes of NI 43-101. -
Gemological ABSTRACTS 2002
Gemological ABSTRACTS 2002 EDITOR COLORED STONES AND A. A. Levinson ORGANIC MATERIALS University of Calgary Characterization of beryl (aquamarine variety) by Mössbauer Calgary, Alberta, Canada spectroscopy. R. R. Viana, G. M. da Costa, E. De Grave, H. Jordt-Evangelista, and W. B. Stern, Physics and REVIEW BOARD Chemistry of Minerals, Vol. 29, No. 1, 2002, pp. 78–86. Five aquamarine samples were analyzed by Mössbauer spec- Anne M. Blumer troscopy to find a correlation between their dark blue to green- Bloomington, Illinois ish blue colors and the locations of iron atoms in the beryl Jo Ellen Cole structure. An asymmetric Fe2+ doublet was observed in the Vista, California spectra of all samples at room temperature. The asymmetry is D. Darmour related to a relaxation process involving Fe2+ ions and water GIA Gem Trade Laboratory, Carlsbad molecules in structural channels. At higher temperatures, the Vladislav Dombrovskiy spectra indicated at least two Fe2+ components. At very low GIA Gem Trade Laboratory, Carlsbad temperatures, the spectra of a deep blue specimen showed that 2+ 2+ R. A. Howie Fe was in structural channels. Fe also occupied octahedral Royal Holloway, University of London and tetrahedral sites, whereas Fe3+ was only located in the octa- hedral site. The authors conclude that the color of green-to-blue Alethea Inns 3+ GIA Gem Trade Laboratory, Carlsbad beryls is determined by the relative proportions of Fe in the octahedral sites and of Fe2+ in the channels. Thus, deep blue Taijin Lu beryls have little Fe3+, whereas greener beryls have more octahe- GIA Research, Carlsbad dral Fe3+ or less channel Fe2+. -
A New Cubic Phase of Li3n: Stability of the N3− Ion to 200
3¡ A New Cubic Phase of Li3N: Stability of the N Ion to 200 GPa A. Lazicki1;2, B. Maddox1;2, W. J. Evans, C. -S. Yoo and A. K. McMahan 1Lawrence Livermore National Laboratory, Livermore, California 94550 W. E. Pickett and R. T. Scalettar 2Physics Department, University of California, Davis, California 95616 M. Y. Hu and P. Chow HPCAT/APS, Argonne National Laboratory, Argonne, Illinois 60439 Diamond anvil cell experiments augmented by ¯rst principles calculations have found a remarkable 3¡ stability of the N ion in Li3N to a six-fold volume reduction. A new (γ) phase is discovered above 40(§5) GPa, with an 8% volume collapse and a bandgap quadrupling at the transition determined by synchrotron x-ray di®raction and inelastic x-ray scattering. γ-Li3N (Fm3m, Li3Bi-like structure) remains stable up to 200 GPa, and calculations do not predict metallization until »8 TPa. The high structural stability, wide bandgap and simple electronic structure make this N3¡ based system analogous to lower valency compounds (MgO, NaCl, Ne), meriting its use as an internal pressure standard. PACS numbers: 62.50.+p, 61.10.-i, 64.70.Kb, 71.20.Nr Nitrogen can form compounds with elements from al- particular interest. most every column in the periodic table, with chemi- In this paper, we present the ¯rst concrete experimen- cal bonding ranging from covalent to ionic to metallic. tal evidence that ¯-Li3N indeed transforms to a cubic Lithium nitride is the only known thermodynamically structure (γ-Li3N) in the pressure range of 36-45 GPa. stable alkali metal nitride and is one of the most ionic This transformation represents an increase in structural of all known nitrides.