Hazard Symbols and Their Meanings Pdf

Total Page:16

File Type:pdf, Size:1020Kb

Hazard Symbols and Their Meanings Pdf Hazard symbols and their meanings pdf Continue The symbols of danger came far from the rudimentary drawings used to refer to the poison in the early 1800s. As a result of the updated requirements for chemical labeling, OSHA 2016 marks the first full year of the adoption of the Globally Agreed Chemical Classification and Labeling System (GHS) in the United States. The GHS system, which includes the OSHA (HCS) OSHA Threat Communication Standard, consists of nine characters, or pictograms, that recognize the hazards associated with certain substances. The use of eight out of nine are mandatory in the U.S., with the exception of an environmental pictogram (see below). Each pictogram covers a certain type of hazard and is designed to be immediately recognizable to anyone who processes hazardous materials. In addition to pictograms, labels should include a signal word (danger or warning), a brief statement of danger, and a statement outlining ways to prevent exposure. Pictograms and health hazard descriptions: a cancer- causing agent (carcinogen) or a substance with respiratory, reproductive or organ toxicity that over time causes damage (chronic or long-term health hazard). Flames: flammable materials or substances to self-ignite when exposed to water or air (pyrophor), or which emit flammable gas. exclamation point: Immediate skin, eyes or respiratory tract irritant, or narcotic. Gas cylinder: Gas stored under pressure, such as ammonia or liquid nitrogen. Corrosion: Materials that cause skin corrosion/burns or eye damage on contact, or are corrosive to metals. Exploding bomb: Explosives, including organic peroxides and highly unstable material, run the risk of exploding even without exposure to air (self-activity). Flame over the circle: identifies oxidizer. Oxidizers are chemicals that facilitate burning or make fires burn hotter and last longer. Skull and crossed bones: substances such as poisons and highly concentrated acids that have an immediate and severe toxic effect (acute toxicity). Environmental hazard: Chemicals toxic to aquatic wildlife. The danger of death redirects here. For other purposes, see Skull and Crossed Bones, a common symbol of venom and other sources of deadly danger (GHS hazard pictograms) Hazard symbols or warning symbols are recognizable symbols designed to warn of hazardous or hazardous materials, locations or objects, including electrical currents, poisons and radioactivity. The use of hazard symbols is often regulated by law and regulated by standards organizations. Hazard symbols can be displayed with different colors, backgrounds, boundaries, and additional to indicate the type of danger and threat level (e.g. toxicity classes). Warning symbols are used in many places instead of written warnings or in addition to them because they are quickly recognized (faster than warning) and is more commonly understood (the same symbol can be recognized as having the same value for speakers of different languages). List of Common Danger Type Unicode Type Unicode Image caption General caution ⚠ U-26A0 Poison ☠ U-2620 Ionizing Radiation ☢ U-2622 Radiation - a high-level source of Non-ionizing Radiation Biological Hazard ☣ U-2623 Carcinogen High Voltage ⚡ ⛌ U-26CC Wheelchair ⛍ U'26CD Ice Road ⛐ U'26D0 More hazard symbols can be found in the list of GHS hazard pictograms and the list of DIN 4844-2 warning symbols Common warning symbol Additional information: Warning sign German road warning symbol On roadside warning signs, exclamation marks are often used, to draw attention to the general warning of danger, danger, and unexpected. In Europe, this type of sign is used unless there are more specific signs to indicate a specific danger. When used for road signs, it is accompanied by an additional sign describing the danger, usually placed under the exclamation point. This symbol has also been more widely accepted for general use in many other non-traffic contexts. It often appears on dangerous equipment or in instructions to draw attention to precautions when a more specific warning symbol is not available. Poisonous Symbol Home article: Skull and Crossed Bones (Poison) ☠Hazard symbolIn UnicodeU-2620 ☠ SKULL AND CROSSBONES (HTML #9760 No.3;) The skull and crossed bones symbol, consisting of a human skull and two bones crossed together behind a skull, is now commonly used as a warning of the dangers of death, especially against poisonous substances. The symbol, or some of its variations, particularly with bones (or swords) under the skull, was also featured on Jolly Roger, the traditional flag of European and American sea pirates. It is also part of the Canadian WHMIS home symbols placed on containers to warn that the contents are poisonous. In the United States, because of fears that the link between the skull symbol and crossed bones with pirates may encourage children to play with toxic materials, Mr. Yuk's symbol is also used to refer to poison. Symbol of ionizing radiation See also: Warning signs of radiation danger ☢Dimoactive signIn UnicodeU-2622 ☢ RADIOACTIVE SIGN (HTML No #9762;) The international symbol of radiation (also known as shamrock) first appeared in 1946 at the University of California at the Berkeley Radiation Laboratory. At the time it was presented as magenta, and was set against a blue background. The original version used in the United States is magenta on a yellow background, and it is drawn with a central R radius, an internal radius of 1.5R and an external 5R radius for blades, separated from each other by 60 degrees. The shamrock is black in the international version, which is also United States. The sign is commonly referred to as a warning sign of radioactivity, but it is actually a warning sign of ionizing radiation. Ionizing radiation is a much broader category than radioactivity alone, as many non-radioactive sources also emit potentially dangerous levels of ionizing radiation. This includes an X-ray machine, radiotherapy of linear accelerators and particle accelerators. Non-ionizing radiation can also reach potentially dangerous levels, but this warning sign differs from the ionizing radiation warning symbol of the shamrock. On 15 February 2007, two groups, the International Atomic Energy Agency (IAEA) and the International Organization for Standardization (ISO), jointly announced the adoption of a new symbol of ionizing radiation warning in addition to the traditional shamrock symbol. The new symbol, which will be used on airtight radiation sources, aims to warn anyone, anywhere, of the danger of being near a strong source of ionizing radiation. The red background depicts a black shamrock with waves of radiation streaming from it, as well as a black skull and crossed bones, and a running figure with an arrow pointing away from the stage. The radiant wormifier indicates the presence of radiation, while the red background and skull and crossed bones warn of danger. The figure, running away from the stage, is designed to offer to take measures to avoid the marked material. The new symbol is not intended to be generally visible, but rather to appear on the internal components of devices that contain radiation sources, so if someone tries to disassemble such devices, they will see a clear warning not to go any further. The international ionizing symbol of the radiation shamrock Yellow and magenta ionizing radiation shamrock, used in the symbol of early ionizing radiation of the USA (1946) ISO 21482 high-level sealed sources of the ionizing radiation symbol Biohazard symbol Main article: Biological danger ☣Hazard symbolIn UnicodeU-2623 ☣ BIOH'ARD SIGN (HTML #9763 No0 q1;0 qgt;;) The bio- hazard symbol is used in the labeling of biological materials that pose a significant health risk, including viral and bacteriological samples, including contaminated bandages and used subcutaneous needles (see sharpness waste). The History symbol of bio-dangerous danger was developed by the chemical company Dow in 1966 for their containment products. According to Charles Baldwin, an environmental engineer who contributed to its development: We wanted something memorable but meaningless so that we could educate people about what it means. In a paper published in the journal Science in 1967, the symbol was presented as a new standard for all dangers (bio-risks). The article explains that more than 40 characters were composed by Dow artists, and all the characters studied had to meet a number of criteria: (i) striking in form in order to attract immediate attention; Attention Unique and unambiguous, not to be confused with symbols used for other purposes; (iii) A quick recognizable and easily recognisable; (iv) Easily stencil; (v) Symmetrical in order to appear identical on all sides of the approach; and (vi) acceptable to groups of different ethnic backgrounds. Selected scored the best in the nationwide memory test. The symbol of biological danger is sometimes used as a tattoo indicating that the owner is HIV-positive. Geometry All parts of the bio-dangerous sign can be drawn by a compass and straight. The main outline of the symbol is a simple shamrock, which three circles overlap with each other equally, as in the triple diagram of the Venn with overlapping parts erased. The diameter of the overlapping part is half a radius of three circles. Then the three inner circles are drawn into a 2⁄3 radius from the original circles so that it is tangential for the outer three overlapping circles. The tiny circle in the center has a diameter of 1⁄2 radius of three inner circles, and the arcs are erased at 90 degrees, 210 and 330 degrees. The arcs of the inner circles and the tiny circle are connected by a line. Finally, the ring is drawn from a distance to the perimeter of the equilateral triangle, which is formed between the centers of three intersecting circles. The outer circle of the ring is under drawn and finally enclosed with arcs from the center of the inner circles with a shorter radius from the inner circles.
Recommended publications
  • (Eastwood)\WPD Files\MSDS Easthill E6271CT Chassis B
    EW #11176ZP - Extreme Chassis Black Satin Quart Page 1 of 6 MATERIAL SAFETY Chassis Black High Gloss Part No. E6175CT11176ZP Liquid DATA SHEET Revision 1 ˜ February 6, 2006 EMERGENCY OVERVIEW FLAMMABLE LIQUID. AVOID CONTACT WITH SKIN AND EYES. VAPOR HARMFUL. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. INGESTION MAY BE HARMFUL OR FATAL. SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MANUFACTURER:MANUFACTURED FOR: Chem-Pak,The Easthill Inc.Group SUPPLIER: The Easthill Group, Inc. dba/ The Eastwood Company 242263 CorningShoemaker Way Road 263 Shoemaker Road Martinsburg,Pottstown, PA WV 19464 25401 USA Pottstown PA 19464 USA USA & Canada: 800-345-1178 INFORMATION: 800-336-9828Outside USA: (610) 323-2200 INFORMATION: 610-323-2200 EMERGENCY: 800-255-3924Chem-Trec 800-424-9300 (24 hr) Chem-Tel EMERGENCY: 1-800-424-9300 PRODUCT IDENTIFIER: 11176ZPE6175CT, Gallon SUPPLIER NUMBER: 11177ZP 11177ZPE6176CT, Quart 11176ZP PRODUCT DESCRIPTION: Extreme Chassis Black PRODUCT TYPE: Liquid REVISION NUMBER: 1 CAS NUMBER: Mixture REVISION DATE: January 30, 2006 EMAIL: [email protected] PRINT DATE: February 6, 2006 WEBSITE: http://www.chem-pak.com SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENT CAS NUMBER OSHA PEL NIOSH REL ACGIH PEL IDLH % WT Xylene 001330-20-7 100 ppm 100 ppm 100 ppm 900 ppm 20-30 n-Hexane 000110-54-2 500 ppm 50 ppm 50 ppm 1100 ppm 20-30 Toluene 000108-88-3 200 ppm 100 ppm 50 ppm 500 ppm < 10 Ethyl Benzene 000100-41-4 100 ppm 100 ppm 100 ppm 800 ppm < 10 Butyl Acetate 000123-86-4 150 ppm 150 ppm 150 ppm 1700 ppm < 10 Proprietary Resin Trade Secret N/E N/E N/E N/E < 10 Carbon Black 001333-86-4 3.5 mg/m3 3.5 mg/m3 3.5 mg/m3 1750 mg/m3 < 10 Methyl Alcohol 000067-56-1 200 ppm 200 ppm 200 ppm 6000 ppm < 10 See Section 11 for LD50 and LC50 Species/Route Information.
    [Show full text]
  • Microplastics in Shore Sediments – Development of a Suitable Extraction and Purification Technique for Citizen Science Projects
    Christian Pacher, BSc Microplastics in shore sediments – Development of a suitable extraction and purification technique for citizen science projects Masterarbeit zur Erlangung des akademischen Grades eines Master of Science der Studienrichtung Ökologie und Evolutionsbiologie an der Karl-Franzens-Universität Graz Betreuer: Priv.-Doz. Mag. Dr.rer.nat. Stephan Koblmüller Institut für Biologie Abstract ..................................................................................................................................... 4 Introduction .............................................................................................................................. 5 Plastic – Our omnipresent companion .................................................................................... 5 Dangers of microplastics ........................................................................................................ 6 Plastic distribution in the Mediterranean Sea ......................................................................... 8 Microplastics in shore sediments ............................................................................................ 9 Citizen science ...................................................................................................................... 10 Location of the sampling spot .............................................................................................. 11 Material and methods ...........................................................................................................
    [Show full text]
  • (Eastwood)\WPD Files\MSDS Easthill E6271CT Chassis B
    EW #10043 ZP - EW Chassis Black Satin Quarts Page 1 of 6 MATERIAL SAFETY Chassis Black Satin Part No. E6271CT10043ZP Liquid DATA SHEET Revision 1 ˜ February 6, 2006 EMERGENCY OVERVIEW FLAMMABLE LIQUID. AVOID CONTACT WITH SKIN AND EYES. VAPOR HARMFUL. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. INGESTION MAY BE HARMFUL OR FATAL. SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION The Easthill Group MANUFACTUREDMANUFACTURER: FOR: dba/Chem-Pak, The Eastwood Inc. Co. SUPPLIER: The Easthill Group, Inc. 242263 CorningShoemaker Way Rd. 263 Shoemaker Road Martinsburg,Pottstown, PA WV 19464 25401 USA Pottstown PA 19464 USA USA and Canada: 1-800-345-1178 INFORMATION: 800-336-9828Outside USA: (610) 323-2200 INFORMATION: 610-323-2200 EMERGENCY: 800-255-3924Chem-Trec 1-800-424-9300 (24 hr) Chem-Tel EMERGENCY: 1-800-424-9300 PRODUCT IDENTIFIER: E6271CT,10043ZP Quart SUPPLIER NUMBER: 10043ZP PRODUCT DESCRIPTION: Chassis Black Satin PRODUCT TYPE: Liquid REVISION NUMBER: 1 CAS NUMBER: Mixture REVISION DATE: February 6, 2006 EMAIL: [email protected] PRINT DATE: February 6, 2006 WEBSITE: http://www.chem-pak.com SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENT CAS NUMBER OSHA PEL NIOSH REL ACGIH PEL IDLH % WT Toluene 000108-88-3 200 ppm 100 ppm 50 ppm 500 ppm 20-30 Xylene 001330-20-7 100 ppm 100 ppm 100 ppm 900 ppm 20-30 Acetone 000067-64-1 1000 ppm 250 ppm 500 ppm 750 ppm < 10 Stoddard Solvent 008052-41-3 500 ppm 350 mg/m3 100 ppm 20 g/m3 < 10 Methyl Alcohol 000067-56-1 200 ppm 200 ppm 200 ppm 6000 ppm < 10 Ethyl Benzene 000100-41-4 100 ppm 100 ppm 100 ppm 800 ppm < 10 Carbon Black 001333-86-4 3.5 mg/m3 3.5 mg/m3 3.5 mg/m3 1750 mg/m3 < 10 See Section 11 for LD50 and LC50 Species/Route Information.
    [Show full text]
  • TS Lab Safety Rules for Chemistry Labs (Version December 2020)
    20201106-tslab-chemistry-lab-safety-rules-instruction-short TS Lab Safety Rules for Chemistry Labs (version December 2020) This is just a compendium of some essential issues concerning the safety in a chemistry lab. For detailed information and issues that are not listed you are legally bound to inform yourself about “Working Safely in Laboratories - Basic Principles and Guidelines” DGUV Information 213-851 (https://www.sicherheitswesen.verwaltung.uni-muenchen.de/arbeitssicherheit/infos/index.html). You are also required to read and approve our lab's online safety webpage at https://thornseshold.cup.uni-muenchen.de/resources/safety/ General Rules • Smoking in the lab is prohibited. • Eating and drinking in the lab is prohibited. Food and drink must not be brought into the lab! • Chemicals must not be stored in containers that lead to confusion with food or beverages! • All containers have to be labelled according to CLP regulation (DGUV Information 213-851). • You have to wear protective eye in the lab! • You have to wear adequate protective clothes such as lab coats and slip-resistant footwear in the lab! Contaminated lab coats have to be changed. Wear lab coats only in lab-like workspaces! Whenever you enter libraries, lecture halls, seminar rooms, dining halls, or social rooms put them off! • If you wear protective gloves remove them when leaving the lab! Do not touch any device that will lead to contamination of your colleagues! • Do not work in labs with a red light display! Do not work in a hood with a red lit flow indicator! • All actions with hazards (e.g.
    [Show full text]
  • Tetrahydrofuran
    TETRAHYDROFURAN PRODUCT IDENTIFICATION CAS NO. 109-99-9 EINECS NO. 203-726-8 FORMULA C4H8O MOL WT. 72.11 H.S. CODE 2932.11 TOXICITY Oral rat LD50: 890 mg/kg SYNONYMS Cyclotetramethylene oxide; THF; Butylene Oxide; Furanidine; Butane ¥á,¥ä-oxide; 1,4-Epoxy-Butane; Oxacyclopentane; Oxolane; Tetrahydrofuran; Tetramethylene oxide; Diethylene oxide; Hydrofuran; Tetrahydrofuraan; Tetrahydrofuranne; Tetraidrofurano; PRICE U$2,450/mt CFR (fcl quantity basis) CLASSIFICATION GENERAL DESCRIPTION OF FURAN AND THF Furan; One of a class of heterocyclic aromatic compounds characterized by five-membered ring structure consisting of four CH 2 groups and one oxygen atom. The simplest furan compound is furan itself; a clear, volatile and mildly toxic liquid; melts at -86 C, boils at 32 C, insoluble in water, soluble in alcohol and ether. In the absence of inhibitors, it may form peroxides and and accumulate peroxides which may explode when subjected to heat or shock. It may discolor on exposure to air. This material is hazardous when peroxide levels are concentrated by distillation or evaporation. It can be stabilized with BHT. It can be obtained from wood oils. It is used as a solvent as well as in the synthesis of furfural and other organic compounds. It is converted to more important solvent, tetrahydrofuran by hydrogenation. Niitro-substituted furan derivatives are used as biocides or fungicides to inhibit bacterial growth. Sulfur-substituted furan derivatives are used as flavouring agents. Furfural (Furfuraldehyde), a derivative of furan, is a viscous, colorless liquid that has a pleasant aromatic odor; upon exposure to air it turns dark brown or black; boils at about 160 C; soluble in ethanol, ether and somewhat in water.
    [Show full text]
  • Download SCOPE Newsletter
    With participation of the European Commission: DG GROW and Joint Research Centre Summary of joint European Commission – ESPP webinar th on P4 (phosphorus) Critical Raw Material, 9 July 2020 This ESPP SCOPE Newsletter summarises discussions at the expert webinar jointly organised by ESPP and the European Commission on 9th July, with participation of Contents the leading companies using phosphorus (P4) or its derivatives in Europe, with additional input from the The EU Critical Raw Materials: “Phosphate Rock” and “Phosphorus”........................................................................... 2 independent industry expert Willem Schipper. The content (Fig. i) Overview numbers: from phosphate rock to P4 / P4-derivatives below has been seen by the participants but does not and applications .................................................................................. 3 represent their position, it represents ESPP’s own How is P4 produced? the phosphorus furnace .............. 4 assessment. Photo: P4 furnace ................................................................................ 4 Schematic: P4 manufacture process (simplified) ................................. 4 This webinar aimed to provide expert input to the European Which chemicals critically depend on P4 / P4 derivatives? . 5 Commission’s MSA (Material System Analysis) of the EU dependency on P4 concerns many industry sectors . 5 specific industrial form of “Phosphorus”, P4, as a Critical (Fig. ii) Production via wet-acid or via P4 / P4 derivatives / ‘thermal’ Raw
    [Show full text]
  • The Elements.Pdf
    A Periodic Table of the Elements at Los Alamos National Laboratory Los Alamos National Laboratory's Chemistry Division Presents Periodic Table of the Elements A Resource for Elementary, Middle School, and High School Students Click an element for more information: Group** Period 1 18 IA VIIIA 1A 8A 1 2 13 14 15 16 17 2 1 H IIA IIIA IVA VA VIAVIIA He 1.008 2A 3A 4A 5A 6A 7A 4.003 3 4 5 6 7 8 9 10 2 Li Be B C N O F Ne 6.941 9.012 10.81 12.01 14.01 16.00 19.00 20.18 11 12 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 3 Na Mg IIIB IVB VB VIB VIIB ------- VIII IB IIB Al Si P S Cl Ar 22.99 24.31 3B 4B 5B 6B 7B ------- 1B 2B 26.98 28.09 30.97 32.07 35.45 39.95 ------- 8 ------- 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 39.10 40.08 44.96 47.88 50.94 52.00 54.94 55.85 58.47 58.69 63.55 65.39 69.72 72.59 74.92 78.96 79.90 83.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 5 Rb Sr Y Zr NbMo Tc Ru Rh PdAgCd In Sn Sb Te I Xe 85.47 87.62 88.91 91.22 92.91 95.94 (98) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 6 Cs Ba La* Hf Ta W Re Os Ir Pt AuHg Tl Pb Bi Po At Rn 132.9 137.3 138.9 178.5 180.9 183.9 186.2 190.2 190.2 195.1 197.0 200.5 204.4 207.2 209.0 (210) (210) (222) 87 88 89 104 105 106 107 108 109 110 111 112 114 116 118 7 Fr Ra Ac~RfDb Sg Bh Hs Mt --- --- --- --- --- --- (223) (226) (227) (257) (260) (263) (262) (265) (266) () () () () () () http://pearl1.lanl.gov/periodic/ (1 of 3) [5/17/2001 4:06:20 PM] A Periodic Table of the Elements at Los Alamos National Laboratory 58 59 60 61 62 63 64 65 66 67 68 69 70 71 Lanthanide Series* Ce Pr NdPmSm Eu Gd TbDyHo Er TmYbLu 140.1 140.9 144.2 (147) 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.0 175.0 90 91 92 93 94 95 96 97 98 99 100 101 102 103 Actinide Series~ Th Pa U Np Pu AmCmBk Cf Es FmMdNo Lr 232.0 (231) (238) (237) (242) (243) (247) (247) (249) (254) (253) (256) (254) (257) ** Groups are noted by 3 notation conventions.
    [Show full text]
  • Eastwood Inc
    EW #16018Z - Heavy Duty Anti Rust Aerosol Page 1 of 5 MATERIAL SAFETY Heavy-Duty Anti-Rust Part No. E6049CT16018Z Aerosol DATA SHEET Revision 1 ˜ May 8, 2006 EMERGENCY OVERVIEW CONTENTS EXTREMELY FLAMMABLE AND UNDER PRESSURE. STORE BELOW 120/F, OUT OF SUNLIGHT, AND AWAY FROM HEAT SOURCES. DO NOT PUNCTURE OR INCINERATE. AVOID CONTACT WITH SKIN AND EYES. VAPOR HARMFUL. HARMFUL OR FATAL IF SWALLOWED. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION The Easthill Group MANUFACTURER:MANUFACTURED FOR: Chem-Pak,dba/ The Eastwood Inc. Co. SUPPLIER: The Easthill Group, Inc. 242263 Corning Shoemaker Way Rd. 263 Shoemaker Road Martinsburg,Pottstown, PA WV 19464 25401 USA Pottstown PA 19464 USA USA & Canada: 1-800-345-1178 INFORMATION: 800-336-9828Outside USA: (610) 323-2200 INFORMATION: 610-323-2200 EMERGENCY: 800-255-3924Chem-Trec 1-800-424-9300 (24 hr) Chem-Tel EMERGENCY: PRODUCT IDENTIFIER: E6049CT16018Z SUPPLIER NUMBER: 16018Z PRODUCT DESCRIPTION: Heavy Duty Anti-Rust PRODUCT TYPE: Aerosol REVISION NUMBER: 1 CAS NUMBER: Mixture REVISION DATE: May 8, 2006 EMAIL: [email protected] PRINT DATE: May 8, 2006 WEBSITE: http://www.chem-pak.com PREPARED BY: Safety & Environmental Manager SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENT CAS NUMBER OSHA PEL NIOSH REL ACGIH PEL IDLH % WT Liquefied Petroleum Gas 068476-85-7 1000 ppm 1000 ppm 1000 ppm 2000 ppm 30-40 Stoddard Solvent 008052-41-3 500 ppm 350 mg/m3 100 ppm 20 g/m3 20-30 Heptane 000142-82-5 500 ppm 85 ppm 400 ppm 750 ppm 20-30 See Section 11 for LD50 and LC50 Species/Route Information.
    [Show full text]
  • Tert-BUTYL ACETATE
    tert-BUTYL ACETATE PRODUCT IDENTIFICATION CAS NO. 540-88-5 EINECS NO. 208-760-7 FORMULA CH 3COOC 4H9 MOL WT. 116.16 H.S. CODE 2915.39 TOXICITY Oral rat LD50: > 10000 mg/kg SYNONYMS Acetic acid, tert-butyl ester; 1,1-Dimethyl ethyl acetate; acetic acid, 1,1-dimethylethyl ester; t-Butyl acetate; DERIVATION CLASSIFICATION PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE clear liquid MELTING POINT BOILING POINT 97 - 98 C SPECIFIC GRAVITY 0.9 SOLUBILITY IN WATER Insoluble (soluble in ethanol, ether) pH VAPOR DENSITY 4 AUTOIGNITION NFPA RATINGS Health: 1; Flammability: 3; Reactivity: 0 REFRACTIVE INDEX 1.3853 FLASH POINT 17 C STABILITY Stable under normal conditions. APPLICATIONS Tert-butyl acetate (TBAc) is an oxygenated solvent used alone or in blends for coatings, industrial cleaning and surface treatment applications. It is a substitute for HAP (Hazardous Air Pollutant) solvents, VOCs (volatile organic compounds: acetaldehyde, benzene, 1,3-butadiene, ethylbenzene, formaldehyde, toluene, xylenes, and particulate organic matter), chlorinated solvents and other ozone depleters as well as esters and ethers in a short supply. It is also used as a process solvent for chemical reactions and polymerization. TBAc is a tert-butyl protecting group for organic synthesis. It undergoes Claisen condensation reaction for C-C bond formation. It is used as a component of aroma. It is used as an intermediate to manufacture pharmaceuticals, synthetic flavorings and other organic compounds. SALES SPECIFICATION APPEARANCE Clear liquid PURITY (GC) 99.0% min WATER 0.2% max COLOR (Pt-Co) 15 max TRANSPORTATION PACKING 170kgs in drum HAZARD CLASS 3 (Packing Group: II) UN NO.
    [Show full text]
  • The General Certificate in Packaging (GCP)
    1 GCP Syllabus (All Containers) The General Certificate in Packaging (GCP) Examination Syllabus (May 2011) This document details the course of study necessary to prepare for the examination for the GCP (Can, Keg, NRB and RB options). The specifications to which the respective examination papers are prepared are also shown. © The Institute of Brewing and Distilling (GCP Syllabus Version 2, May 2011) 2 GCP Syllabus (All Containers) Introduction. The General Certificate in Packaging gives international recognition of a basic, under- pinning knowledge and understanding in the principles of packaging operations. The General Certificate examinations have been designed for candidates who may have little or no formal academic or technical qualification. Typically a candidate will be employed as a senior operator or team leader in a brewery or packaging plant, however the scope of these examinations will enable candidates from smaller brewing and packaging operations to obtain this recognised qualification. This examination is open to anybody with interest in brewing or beer packaging. They are a measure of basic knowledge (theoretical and practical) underpinning brewing, packaging and associated operations. - The General Certificate in Packaging can be an end in itself, or the start of professional development, leading to the Diploma in Packaging (Dipl.Pack) and potentially, the Master Brewer (M.Brew) examinations. - The General Certificate in Packaging has City & Guilds accreditation at Level 3 of the National Qualifications Framework in the UK (or equivalent internationally recognised standards),. - The General Certificate in Packaging takes the form of one multiple choice paper of two hours. Candidates can register to sit the exam on-line instead of using the traditional paper format.
    [Show full text]
  • M:\Material Safety Data Sheets\Finished Goods MSDS
    EW #10025 Z - EW Chassis Black Satin Aerosol 14 oz Page 1 of 6 MATERIAL SAFETY Chassis Black Satin Part No. E6269CT10025Z Aerosol DATA SHEET Revision 1 January 27, 2006 EMERGENCY OVERVIEW CONTENTS EXTREMELY FLAMMABLE AND UNDER PRESSURE. STORE BELOW 120 F, OUT OF SUNLIGHT, AND AWAY FROM HEAT SOURCES. DO NOT PUNCTURE OR INCINERATE. AVOID CONTACT WITH SKIN AND EYES. VAPOR HARMFUL. HARMFUL OR FATAL IF SWALLOWED. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION The Easthill Group MANUFACTUREDMANUFACTURER: FOR: Chem-Pak, Inc. SUPPLIER: The Easthill Group, Inc. dba/ The Eastwood Co. 242263 CorningShoemaker Way Rd. 263 Shoemaker Road Martinsburg,Pottstown, PA WV 19464 25401 USA Pottstown PA 19464 USA USA & Canada: 1-800-345-1178 INFORMATION: 800-336-9828Outside USA: (610) 323-2200 INFORMATION: 610-323-2200 EMERGENCY: 800-255-3924Chem-Trec 1-800-424-9300 (24 hr) Chem-Tel EMERGENCY: 1-800-424-9300 PRODUCT IDENTIFIER: E6269CT10025Z SUPPLIER NUMBER: 10025Z PRODUCT DESCRIPTION: Chassis Black Satin PRODUCT TYPE: Aerosol REVISION NUMBER: 1 CAS NUMBER: Mixture REVISION DATE: October 31, 2005 EMAIL: [email protected] PRINT DATE: January 27, 2006 WEBSITE: http://www.chem-pak.com PREPARED BY: Safety & Environmental Manager SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENT CAS NUMBER OSHA PEL NIOSH REL ACGIH PEL IDLH % WT Liquefied Petroleum Gas 068476-85-7 1000 ppm 1000 ppm 1000 ppm 2000 ppm 20-30 Toluene 000108-88-3 200 ppm 100 ppm 50 ppm 500 ppm 20-30 Xylene 001330-20-7 100 ppm 100 ppm 100 ppm 900 ppm 10-20 Acetone 000067-64-1 1000 ppm 250 ppm 500 ppm 750 ppm < 10 Methyl Alcohol 000067-56-1 200 ppm 200 ppm 200 ppm 6000 ppm < 10 Stoddard Solvent 008052-41-3 500 ppm 350 mg/m3 100 ppm 20 g/m3 < 10 Ethyl Benzene 000100-41-1 100 ppm 100 ppm 100 ppm 800 ppm < 10 Carbon Black 001333-86-4 3.5 mg/m3 3.5 mg/m3 3.5 mg/m3 1750 mg/m3 < 10 See Section 11 for LD50 and LC50 Species/Route Information.
    [Show full text]
  • European Product Labelling Guide
    European Product Labelling Guide 1 INTRODUCTION Within my role in the Enterprise Europe Network, one of the issues I’m regularly asked about is product labelling, i.e: “What regulations apply to my product?” or “What information has to be displayed on my product?”. European legislation can be complex and consequently sourcing the answers to these questions isn’t necessarily the simplest task, therefore the purpose of this guide is to pull together all the information on European Union product labelling rules so that it is accessible from one source but broken up into a consistent and readable format. The hope is that it will give companies a clearer understanding as to what rules may be applicable to them, so that they can better prepare themselves for trading in the European market. I think you will find this guide useful, but if you require more information please contact your local Enterprise Europe team. Thank you. Ross Thomson European Information Executive Enterprise Europe Network 2 DISCLAIMER All information was sourced from http://europa.eu/, unless stated otherwise. Whilst every effort has been made to ensure that the information and content within this document is accurate, up-to-date and reliable, the Enterprise Europe Network and its partners cannot be held responsible for inaccuracies or errors. Any images used are to be taken as purely hypothetical examples; their accuracy has not been verified and they are not intended to promote any product or labelling style. Use of this guide, or actions taken from the information provided, are solely at the user's own risk.
    [Show full text]