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Tech Manual Excerpt

Water Chemistry and Pretreatment Colloidal and Particulate

Other Methods Methods to prevent colloidal are discussed in the following documents: l Colloidal and Particulate (Form No. 45-D01559-en)

l Media (Form No. 45-D01560-en)

l Oxidation–Filtration (Form No. 45-D01561-en)

l In-Line Filtration (Form No. 45-D01562-en)

l / (Form No. 45-D01563-en)

l Cartridge Microfiltration (Form No. 45-D01564-en)

In addition, the following methods are available:

Lime softening has already been described as a method for silica removal (Scale Control-Lime Softening (Form No. 45-D01549-en) ). Removal of iron and colloidal matter are further benefits.

Strong acid cation exchange resin softening not only removes hardness, but it also removes low concentrations of iron and aluminum that otherwise could foul the . Softened water is also known to exhibit a lower fouling tendency than unsoftened (hard) water because multivalent cations promote the adhesion of naturally occurring , which are usually negatively charged. The ability to minimize iron depends on the Fe species present. Fe2+ and Fe3+ are substantially removed by the SAC resin and, if in excess of 0.05 ppm, have a tendency to foul the membrane and catalyze its degradation. Colloidal or organo-Fe-complexes are usually not removed at all and will pass through into the product water. Insoluble iron-oxides are, depending on their size, filtered out depending on the flowrate and bed-depth used.

When dealing with higher concentration of ferrous iron, one needs special care to avoid ferric iron fouling. It was reported that addition of SMBS was able to prevent membrane fouling

Antifoulants: certain scaling inhibitors, also called antifoulants, can handle iron. This pretreatment process can be used for relatively low concentrations of iron.

Page 1 of 2 Form No. 45-D01565-en, Rev. 4 April 2020 Excerpt from FilmTec™ Technical Manual (Form No. 45-D01504-en), Chapter 2, "Water Chemistry and Pretreatment."

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Page 2 of 2 Form No. 45-D01565-en, Rev. 4 April 2020