Metamorphic History and Geodynamic Significance of the Early Cretaceous
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A Single-Crystal Epr Study of Radiation-Induced Defects
A SINGLE-CRYSTAL EPR STUDY OF RADIATION-INDUCED DEFECTS IN SELECTED SILICATES A Thesis Submitted to the College of Graduate Studies and Research In Partial Fulfillment of the Requirements For the Degree of Doctor of Philosophy In the Department of Geological Sciences University of Saskatchewan Saskatoon By Mao Mao Copyright Mao Mao, October, 2012. All rights reserved. Permission to Use In presenting this thesis in partial fulfilment of the requirements for a Doctor of Philosophy degree from the University of Saskatchewan, I agree that the Libraries of this University may make it freely available for inspection. I further agree that permission for copying of this thesis in any manner, in whole or in part, for scholarly purposes may be granted by the professor or professors who supervised my thesis work or, in their absence, by the Head of the Department or the Dean of the College in which my thesis work was done. It is understood that any copying or publication or use of this thesis or parts thereof for financial gain shall not be allowed without my written permission. It is also understood that due recognition shall be given to me and to the University of Saskatchewan in any scholarly use which may be made of any material in my thesis. Requests for permission to copy or to make other use of material in this thesis in whole or part should be addressed to: Head of the Department of Geological Sciences 114 Science Place University of Saskatchewan Saskatoon, Saskatchewan S7N5E2, Canada i Abstract This thesis presents a series of single-crystal electron paramagnetic resonance (EPR) studies on radiation-induced defects in selected silicate minerals, including apophyllites, prehnite, and hemimorphite, not only providing new insights to mechanisms of radiation-induced damage in minerals but also having direct relevance to remediation of heavy metalloid contamination and nuclear waste disposal. -
Polyphase Deformation in San Miguel Las Minas, Northern
POLYPHASE DEFORMATION IN SAN MIGUEL LAS MINAS, NORTHERN ACATLAN COMPLEX, SOUTHERN MEXICO A thesis presented to the faculty of the Arts and Sciences of Ohio University In partial fulfillment of the requirements for the degree Master of Sciences Brent J. Barley August 2006 This thesis entitled POLYPHASE DEFORMATION IN SAN MIGUEL LAS MINAS, NORTHERN ACATLAN COMPLEX, SOUTHERN MEXICO by BRENT J. BARLEY has been approved for the Department of Geological Sciences and the College of Arts and Sciences by R. Damian Nance Professor of Geological Sciences Benjamin M. Ogles Dean, College of Arts and Sciences Abstract BARLEY, BRENT J., M.S., August 2006, Geological Sciences POLYPHASE DEFORMATION IN SAN MIGUEL LAS MINAS, NORTHERN ACATLAN COMPLEX, SOUTHERN MEXICO (58 pages) Director of Thesis: R. Damian Nance Mapping in the northern part of the Acatlán Complex (southern Mexico) has distinguished two lithological units: a high-grade unit assigned to the Piaxtla Suite, and a low-grade unit assigned to the Cosoltepec Formation. Two major Paleozoic tectonothermal events have been identified in these rocks. The first event produced a penetrative deformational fabric (SPS1) parallel to a compositional banding during blueschist and amphibolite facies metamorphism, which has recently been dated as ~346 Ma in a neighboring area, and a greenschist overprint during exhumation. The second event, which is recorded in both the Piaxtla Suite and Cosoltepec Formation, produced two penetrative deformational fabrics under subgreenschist metamorphic conditions. The first, high-grade tectonothermal event accompanied closure of the Rheic Ocean and tectonic juxtapositioning of the two units during exhumation of the high-grade unit in the Devono-Carboniferous. -
Facies and Mafic
Metamorphic Facies and Metamorphosed Mafic Rocks l V.M. Goldschmidt (1911, 1912a), contact Metamorphic Facies and metamorphosed pelitic, calcareous, and Metamorphosed Mafic Rocks psammitic hornfelses in the Oslo region l Relatively simple mineral assemblages Reading: Winter Chapter 25. (< 6 major minerals) in the inner zones of the aureoles around granitoid intrusives l Equilibrium mineral assemblage related to Xbulk Metamorphic Facies Metamorphic Facies l Pentii Eskola (1914, 1915) Orijärvi, S. l Certain mineral pairs (e.g. anorthite + hypersthene) Finland were consistently present in rocks of appropriate l Rocks with K-feldspar + cordierite at Oslo composition, whereas the compositionally contained the compositionally equivalent pair equivalent pair (diopside + andalusite) was not biotite + muscovite at Orijärvi l If two alternative assemblages are X-equivalent, l Eskola: difference must reflect differing we must be able to relate them by a reaction physical conditions l In this case the reaction is simple: l Finnish rocks (more hydrous and lower MgSiO3 + CaAl2Si2O8 = CaMgSi2O6 + Al2SiO5 volume assemblage) equilibrated at lower En An Di Als temperatures and higher pressures than the Norwegian ones Metamorphic Facies Metamorphic Facies Oslo: Ksp + Cord l Eskola (1915) developed the concept of Orijärvi: Bi + Mu metamorphic facies: Reaction: “In any rock or metamorphic formation which has 2 KMg3AlSi 3O10(OH)2 + 6 KAl2AlSi 3O10(OH)2 + 15 SiO2 arrived at a chemical equilibrium through Bt Ms Qtz metamorphism at constant temperature and = -
Geology the Geotrail Follows Rocks Exposed on the Beaches South of Port Macquarie
Geology The Geotrail follows rocks exposed on the beaches south of Port Macquarie. These rocks record a fascinating story involving the migration of an oceanic plate away from a mid-ocean ridge (oceanic spreading ridge) to a subduction zone about 500 million years ago (Figures 1, 2). Back then, our continent was part of a supercontinent called Gondwana which was located near the Equator (Figure 3). Since then, this supercontinent has migrated and broken up, with the Australian continent eventually reaching its current position (Figure 2S). To imagine this process of breaking up and migration, think of the way ice sheets in Antarctica crack and float across the ocean carried by ocean currents. Figure 1 shows the migration of oceanic crust away from a mid-ocean ridge exuding basalt (mid ocean ridge basalt - MORB; Shelly Beach) and down the subduction zone (Rocky Beach). Figure 2 Geological Time Scale Walking the geotrail allows you to track the migration of tectonic plates, observe how the rocks change, and learn about the setting in which they formed. At Shelly Beach (Stop 1), are dark rocks called basalt that are thought to have formed close to a spreading ridge (the boundary between two divergent tectonic plates; Figures 1S, 4) because their chemical composition is similar to mid-oceanic ridge basalts (Och 2007). The Mid-Atlantic Ridge that divides the North American plate from the African plate is an example of this type of plate border (Figure 4). Figure 3 shows the supercontinent Gondwana and the Australian continent as part of Gondwana. The Australian continent was at the Equator at this time. -
Finding of Prehnite-Pumpellyite Facies Metabasites from the Kurosegawa Belt in Yatsushiro Area, Kyushu, Japan
Journal ofPrehnite Mineralogical-pumpellyite and Petrological facies metabasites Sciences, in Yatsushiro Volume 107, area, page Kyushu 99─ 104, 2012 99 LETTER Finding of prehnite-pumpellyite facies metabasites from the Kurosegawa belt in Yatsushiro area, Kyushu, Japan * * ** Kenichiro KAMIMURA , Takao HIRAJIMA and Yoshiyuki FUJIMOTO *Department of Geology and Mineralogy, Graduate School of Science, Kyoto University, Kitashirakawa Oiwakecho, Kyoto 606-8502, Japan ** Nittetsu-Kogyo Co., Ltd, 2-3-2 Marunouchi, Chiyoda, Tokyo 100-8377, Japan. Common occurrence of prehnite and pumpellyite is newly identified from metabasites of Tobiishi sub-unit in the Kurosegawa belt, Yatsushiro area, Kyushu, where Ueta (1961) had mapped as a greenschist facies area. Prehnite and pumpellyite are closely associated with chlorite, calcite and quartz, and they mainly occur in white colored veins or in amygdules in metabasites of the relevant area, but actinolite and epidote are rare in them. Pumpellyite is characterized by iron-rich composition (7.2-20.0 wt% as total iron as FeO) and its range almost overlaps with those in prehnite-pumpellyite facies metabasites of Ishizuka (1991). These facts suggest that the metabasites of the Tobiishi sub-unit suffered the prehnite-pumpellyite facies metamorphism, instead of the greenschist facies. Keywords: Prehnite-pumpellyite facies, Lawsonite-blueschist facies, Kurosegawa belt INTRODUCTION 1961; Kato et al., 1984; Maruyama et al., 1984; Tsujimori and Itaya, 1999; Tomiyoshi and Takasu, 2009). Until now, The subduction zone has an essential role for the global there is neither clear geological nor petrological evidence circulation of solid, fluid and volatile materials between suggesting what type of metamorphic rocks occupied the the surface and inside of the Earth at present. -
Petrologic and Textural Examination of Blueschist-Facies Micaceous Schists of Syros, Greece
PETROLOGIC AND TEXTURAL EXAMINATION OF BLUESCHIST-FACIES MICACEOUS SCHISTS OF SYROS, GREECE. Joshua W. Otis Dept. Of Geology, Amherst College, Amherst, MA, 01002 Faculty Sponsors: John T. Cheney, Tekla Harms, Amherst College INTRODUCTION The island of Syros lies in the high pressure belt of the Attico -Cycladic crystalline massif. It is composed dominantly of metasedimentary and meta-igneous rocks with local areas of melange and serpentinite zones. These rocks preserve blueschist facies mineral assemblages, although an incomplete greenschist overprint exists locally across the island. This study focuses on the semi-pelitic and calcareous schists of Syros. The schist units are interlayered with marble across the island, and are laterally continuous parallel to the strike of the foliation, with beds generally dipping 25-45° to the NE (Hecht, 1985). The schists from the north end of the island were very consistent, laterally continuous units. Over the rest of the island, the schists tended to be much more locally variable in composition, Ideally, this project aims to integrate structural, petrographic, and compositional data to characterize the nature and timing of deformation relative to mineral growth, and to place constraints on the P/T conditions experienced by semi-pelitic rocks across the island. PETROGRAPHY The north end of the island contains calcareous schists with the relatively uniform mineral assemblages of quartz + phengite ± calcite ± minor amounts of sodic amphibole, garnet, epidote, rutile, titanite, and graphite. These rocks are divisible into two main groups based on the presence or absence of calcite, forming two fairly homogenous, mappable units (~1km scale). A greenschist overprint of albite + chlorite +/- epidote typically occurs in these rocks (Fig. -
Geology of the Prince William Sound and Kenai Peninsula Region, Alaska
Geology of the Prince William Sound and Kenai Peninsula Region, Alaska Including the Kenai, Seldovia, Seward, Blying Sound, Cordova, and Middleton Island 1:250,000-scale quadrangles By Frederic H. Wilson and Chad P. Hults Pamphlet to accompany Scientific Investigations Map 3110 View looking east down Harriman Fiord at Serpentine Glacier and Mount Gilbert. (photograph by M.L. Miller) 2012 U.S. Department of the Interior U.S. Geological Survey Contents Abstract ..........................................................................................................................................................1 Introduction ....................................................................................................................................................1 Geographic, Physiographic, and Geologic Framework ..........................................................................1 Description of Map Units .............................................................................................................................3 Unconsolidated deposits ....................................................................................................................3 Surficial deposits ........................................................................................................................3 Rock Units West of the Border Ranges Fault System ....................................................................5 Bedded rocks ...............................................................................................................................5 -
Blueschist Metamorphism in an Active Subduction Zone Hirokazu Maekawa, Kobe University
Blueschist metamorphism in an active subduction zone Hirokazu Maekawa, Kobe University The high-pressure, low-temperature metamorphic rocks known clasts obtained by dredging samples of high pressure rocks as blueschists have long been considered to form in subduc- from the two serpentinite seamounts in the Izu-Ogasawara tion zones, where the descent of a relatively cold slab leads to forearc, that is the Torishima forearc seamount [Maekawa, 1995] the occurrence of unusually low temperatures at mantle and the Hahajima seamount [Hashimoto et al., in prep.]. pressures. Until now, however, the link between blueschist- Blueschist facies rocks are common in forearcs and drilling has facies rocks and subduction zones has been indirect, relying on showed at least one way to get them to the surface by carrying a spatial association of blueschists with old subduction them along in the serpentinite diapirs. Further study of these complexes, and estimates of the geothermal gradients likely to rocks may provide new insight into the tectonics of trench- exist in subduction zones. Here we strengthen this link, by forearc systems, and in particular, the processes by which reporting the discovery of blueschist-facies minerals, lawsonite, blueschist facies clasts come to be associated with forearc aragonite, sodic pyroxene, and blue amphibole (winchite), in sediments in ancient subduction complexes. clasts from a serpentinite seamount in the forearc of the active Mariana subduction zone during ODP Leg 125 [Maekawa et al., References: Maekawa, H., M. Shozui, T. Ishii, P. Fryer, and J.A. Pearce, Blueschist metamor- 1993]. The metamorphic conditions estimated from the mineral phism in an active subduction zone, Nature, 364, 520-523, 1993. -
List of Abbreviations
List of Abbreviations Ab albite Cbz chabazite Fa fayalite Acm acmite Cc chalcocite Fac ferroactinolite Act actinolite Ccl chrysocolla Fcp ferrocarpholite Adr andradite Ccn cancrinite Fed ferroedenite Agt aegirine-augite Ccp chalcopyrite Flt fluorite Ak akermanite Cel celadonite Fo forsterite Alm almandine Cen clinoenstatite Fpa ferropargasite Aln allanite Cfs clinoferrosilite Fs ferrosilite ( ortho) Als aluminosilicate Chl chlorite Fst fassite Am amphibole Chn chondrodite Fts ferrotscher- An anorthite Chr chromite makite And andalusite Chu clinohumite Gbs gibbsite Anh anhydrite Cld chloritoid Ged gedrite Ank ankerite Cls celestite Gh gehlenite Anl analcite Cp carpholite Gln glaucophane Ann annite Cpx Ca clinopyroxene Glt glauconite Ant anatase Crd cordierite Gn galena Ap apatite ern carnegieite Gp gypsum Apo apophyllite Crn corundum Gr graphite Apy arsenopyrite Crs cristroballite Grs grossular Arf arfvedsonite Cs coesite Grt garnet Arg aragonite Cst cassiterite Gru grunerite Atg antigorite Ctl chrysotile Gt goethite Ath anthophyllite Cum cummingtonite Hbl hornblende Aug augite Cv covellite He hercynite Ax axinite Czo clinozoisite Hd hedenbergite Bhm boehmite Dg diginite Hem hematite Bn bornite Di diopside Hl halite Brc brucite Dia diamond Hs hastingsite Brk brookite Dol dolomite Hu humite Brl beryl Drv dravite Hul heulandite Brt barite Dsp diaspore Hyn haiiyne Bst bustamite Eck eckermannite Ill illite Bt biotite Ed edenite Ilm ilmenite Cal calcite Elb elbaite Jd jadeite Cam Ca clinoamphi- En enstatite ( ortho) Jh johannsenite bole Ep epidote -
What We Know About Subduction Zones from the Metamorphic Rock Record
What we know about subduction zones from the metamorphic rock record Sarah Penniston-Dorland University of Maryland Subduction zones are complex We can learn a lot about processes occurring within active subduction zones by analysis of metamorphic rocks exhumed from ancient subduction zones Accreonary prism • Rocks are exhumed from a wide range of different parts of subduction zones. • Exhumed rocks from fossil subduction zones tell us about materials, conditions and processes within subduction zones • They provide complementary information to observations from active subduction systems Tatsumi, 2005 The subduction interface is more complex than we usually draw Mélange (Bebout, and Penniston-Dorland, 2015) Information from exhumed metamorphic rocks 1. Thermal structure The minerals in exhumed rocks of the subducted slab provide information about the thermal structure of subduction zones. 2. Fluids Metamorphism generates fluids. Fossil subduction zones preserve records of fluid-related processes. 3. Rheology and deformation Rocks from fossil subduction zones record deformation histories and provide information about the nature of the interface and the physical properties of rocks at the interface. 4. Geochemical cycling Metamorphism of the subducting slab plays a key role in the cycling of various elements through subduction zones. Thermal structure Equilibrium Thermodynamics provides the basis for estimating P-T conditions using mineral assemblages and compositions Systems act to minimize Gibbs Free Energy (chemical potential energy) Metamorphic facies and tectonic environment SubduconSubducon zone metamorphism zone metamorphism Regional metamorphism during collision Mid-ocean ridge metamorphism Contact metamorphism around plutons Determining P-T conditions from metamorphic rocks Assumption of chemical equilibrium Classic thermobarometry Based on equilibrium reactions for minerals in rocks, uses the compositions of those minerals and their thermodynamic properties e.g. -
12. Prehnite-Pumpellyite Facies Metamorphism in Oceanic Arc Basement from Site 791 in the Sumisu Rift, Western Pacific1
Taylor, B., Fujioka, K., et al., 1992 Proceedings of the Ocean Drilling Program, Scientific Results, Vol. 126 12. PREHNITE-PUMPELLYITE FACIES METAMORPHISM IN OCEANIC ARC BASEMENT FROM SITE 791 IN THE SUMISU RIFT, WESTERN PACIFIC1 Makoto Yuasa,2 Teruo Watanabe,3 Toshiaki Kuwajima,3 Tadao Hirama,4 and Kantaro Fujioka5 ABSTRACT Prehnite-pumpellyite facies metamorphism is described in the oceanic-arc basement rocks of Ocean Drilling Program Leg 126, Site 791 in the Sumisu Rift, western Pacific. Chemical variations of pumpellyite, epidote, chlorite, and prehnite are examined and paragenetic relations discussed. The metamorphism took place during the pre-rifting stage of an intraoceanic arc. During the backarc rifting stage, the geothermal gradient of the area was not as high as that of a spreading mid-oceanic ridge. INTRODUCTION The drill hole penetrated about 1100 m below the seafloor (mbsf) into basaltic basement (Shipboard Scientific Party, 1990). Studies of the metamorphism of the oceanic crust have advanced since the International Phase of Ocean Drilling (IPOD) project. Forearc "Ohmachi" Seamount According to the summary by Maruyama and Liou (1988), diversity in ocean-floor metamorphism reflects a difference in tectonics. For The Nishinoshima Trough has a rift morphology and obliquely cuts example, the fast-spreading Pacific Ocean has higher geothermal across the Izu-Bonin Arc between the Sofugan and Nishinoshima islands gradients than the slow-spreading Atlantic; and prehnite-pumpellyite (Fig. 1). The distance between the nearest islands is widest at about facies metamorphic rocks have not been collected from the Pacific 290 km here at the Shichito-Iwojima Ridge. There are nine large Ocean floor, but they have been obtained from the Atlantic Ocean and seamounts, some of which have parasitic highs, between the Sofugan and Philippine Sea floors where the geothermal gradient is rather low Nishinoshima islands. -
Synthesis of Analcime from Natural Heulandite and Clinoptilolite
THE AMERICAN MINERALOGIST, VOL. 56, SEPTEIVIBER_OCTOBtrR, 1971 SYNTHESIS OF ANALCIME FROM NATURAL HEULANDITE AND CLINOPTILOLITE Jenos R. Bor.ns, Department of Geology,University of Otago, Dunedin, New Zealand' Als:rnncr Analcime has been synthesized from natural heulandite and clinoptilolite at 100oC with solutions of NaOH (0.1M) and NazCOs (0.lM and 0.01M) in 3-week runs. Both increased pH and Na+ concentration favor the reaction. The Si/Al ratio of the analcime product is largely a function of the Si/Al ratio of the zeoiite reactant. Analogy of the experiments wi'uh saline-alkaline lakes and marine environments is discussed. Inrnooucrrolr Numerous occurrenceswhere analcime and heulandite group minerals co-existin the same suite of sedimentary rocks have been summarized by Hay (1966, p. 21-30). Additional occurrences, both non-n:arine and marine are recorded at Kaka Point, New Zealand (Coombs, 1965); in the Green River Formation, Wyoming (Goodwin and Surdam, 1967); a't PleistoceneLake Tecopa, California (Sheppardand Gude' 1968);in the Barstow Formation, California (Sheppard and Gude, 1969); at Beard- more Glaciet area,Antarctica (Barrett, 1969);in geothermalbore holes, Yellowstone Park, Wyoming (Honda and Muffier, 1970); and in the Wagon Bed Formation, Wyoming (Boles and Surdam, in preparation). At all theselocalities the host rocks show evidencef or the former presence of volcanic glass. Saline or saline-alkaline solutions are inferred to have beenpresent in most cases. Hay (1966) and Iijima and Hay (1968) point out that in lacustrine environments analcime commonly forms in low-temperature reactions from other zeolites including clinoptilolite. These reactions are implied by the distribution of zeolites as a function of age in saline-lakedeposits.