US 200701341 82A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2007/0134.182 A1 Shimizu et al. (43) Pub. Date: Jun. 14, 2007

(54) COSMETC COMPOSITION COMPRISING (30) Foreign Application Priority Data AN ESTER OF DIMERDLINOLEC ACID AND OF POLYOLCS) AND A SILICONE Dec. 8, 2005 (FR)...... O5 53,797 SURFACTANT

(75) Inventors: Momoko Shimizu, Tokyo (JP); Emiko Publication Classification Tokunaga, Kanagawa (JP) (51) Int. Cl. Correspondence Address: A6IR 8/37 (2006.01) OLIFF & BERRIDGE, PLC P.O. BOX 19928 (52) U.S. Cl...... 424/64; 424/70.31 ALEXANDRIA, VA 22320 (US) (73) Assignee: L'OREAL PARIS (FR) (57) ABSTRACT (21) Appl. No.: 11/635,006 The present invention relates to an anhydrous cosmetic (22) Filed: Dec. 7, 2006 composition for caring for and/or making up the skin and/or the lips, comprising at least one ester of dimerdilinoleic acid Related U.S. Application Data and of polyol(s) or an ester thereof, the viscosity of which, (60) Provisional application No. 60/754,189, filed on Dec. measured at about 25°C., is greater than or equal to about 28, 2005. 20 000 mPa.s, and at least one silicone surfactant. US 2007/01341.82 A1 Jun. 14, 2007

COSMETC COMPOSITION COMPRISING AN 0012 For example, the cosmetic composition according ESTER OF DIMERDLINOLEIC ACID AND OF to the invention has a gloss and/or a gloss staying power that POLYOLCS) AND A SILICONE SURFACTANT is/are not affected, or that is/are even improved. 0001. This non provisional application claims the benefit 0013 Thus, according to one of these aspects, one subject of French Application No. 05 53797 filed on Dec. 8, 2005 of the present invention is an anhydrous cosmetic compo and U.S. Provisional Application No. 60/754,189 filed on sition for caring for and/or making up the skin and/or the Dec. 28, 2005. lips, comprising at least one ester of dimerdilinoleic acid and of polyol(s) or an ester thereof, the viscosity of which, 0002 The present invention relates to cosmetic compo measured at about 25°C., is greater than or equal to about sitions for caring for and/or making up the skin and/or the 20 000 mPa.s, and at least one silicone surfactant. lips, comprising an ester of dimerdilinoleic acid and of polyol(s) and a silicone surfactant. 0014 For the purposes of the invention, the term “anhy drous composition” means a composition containing less 0003. The compositions according to the invention may than 5% by weight, less than 3% by weight, less than 2% by show improved gloss and/or colour staying power. weight, less than 1% by weight of water relative to the total weight of the composition. 0004 The present invention also relates to a process for making up the human face and/or body using a composition 00.15 According to another of its aspects, a subject of the according to the invention. present invention is a cosmetic composition for caring for and/or making up the skin and/or the lips, comprising at least 0005. A composition according to the invention may, for one ester of general formula (I) below: example, be a makeup and/or care product intended to be R–OCO-R(-COO R—OCO-R), COO applied to the body, for example the face, and/or the lips, and R (I) may be a lipstick, a lip balm, a lip pencil, a liquid or Solid foundation, for example cast as a stick or a dish, a concealer in which: product, a skin colouring product, an eye makeup product, 0016 CORCO represents a dimerdilinoleate residue, for instance an eyeliner, for example in pencil form, a mascara for example in cake form, or alternatively an 0017 ORO represents a fatty alcohol dimer residue, eyeshadow or a lip gloss. 0018 OR represents a hydrocarbon-based monoalcohol 0006. Many cosmetic compositions exist for which gloss residue, and properties and colour effect properties of the deposited film, after application to the skin and/or the lips, are desired. 0019 n is an integer ranging from 1 to 15, These properties generally contribute towards the desired and at least one silicone surfactant. aesthetic effect. 0020. According to another aspect, a subject of the 0007 Moreover, it is also required that this aesthetic present invention is a cosmetic composition for caring for effect be maintained over time, for example in the face of the and/or making up the skin and/or the lips comprising at least various external factors liable to affect its gloss and/or colour one ester of general formula (II) below: properties.

0008. In order to give cosmetic compositions good gloss (II) properties and for example good gloss staying power, it has HO-R-C-O-C-R-C-O-R)-OH been proposed to use "glossy oils such as oily polymers, for instance high-viscosity polybutenes, esters of fatty acids or O O of fatty alcohols with a high carbon number (typically greater than 16), or alternatively certain plant oils. in which: 0009. However, these compounds may under certain cir 0021 n is an integer ranging from 1 to 15, cumstances be tacky on application and/or over time, which may result in considerable unpleasant sensations and a 0022 COR'CO represents a dimerdilinoleate residue, feeling of discomfort for the user. 0023 ORO represents a diglyceryl residue of general 0010. The inventors have been able to observe, surpris formula (III) below: ingly, that the use of certain esters of dimerdilinoleic acid and of polyol(s), or an ester thereof, in combination with a silicone Surfactant, for instance polyglyceryl-3 polymethyl (III) siloxyethyl dimethicone, for preparing a cosmetic compo O-(-CH-CH-CH-O-CH-CH-CH-)-O sition, makes it possible to give these compositions O O improved colour staying power without affecting their com bination of aesthetic properties, such as the gloss effect and R's R" the gloss staying power, while at the same time affording a comfortable sensation on application. in which: 0011 For example, a cosmetic composition according to the invention may have the advantageous property of not 0024 R', reprepresents H or OR", reprepresents a fatty acid causing any tacky sensation after application. residue, and comprising at least one silicone surfactant. US 2007/01341.82 A1 Jun. 14, 2007

0025. According to another of its aspects, a subject of the 0037 As examples of alcohol residues that are suitable present invention is the use of at least one ester of dimer for use in the invention, mention may be made of hydro dilinoleic acid and of polyol(s) or an ester thereof, according carbon-based compounds comprising a hydroxyl function to the invention, in combination with at least one silicone and containing from 4 to 40 carbon atoms, from 6 to 36 Surfactant, for the preparation of a cosmetic care and/or carbon atoms, from 8 to 32 carbon atoms, f from 16 to 28 make-up composition with improved colour staying power. carbon atoms and from 18 to 24 carbon atoms. 0026. According to yet another of its aspects, a subject of 0038. As examples of monoalcohols that are suitable for the present invention is a process for making up and/or the invention, mention may be made, in a non-limiting caring for the skin and/or the lips, comprising at least one manner, of butanol, pentanol, propanol, hexanol, heptanol, step that consists in applying a composition in accordance octanol, decanol, dodecanol, hexadecanol, octadecanol, with the invention to at least part of a Support. eicosadecanol, phytosterol, isoStearol, Stearol, cetol, 0027. For example, the present invention makes it pos behenol, etc. sible to provide cosmetic compositions whose gloss staying power and/or gloss is not affected, or is even improved, Polvols while at the same time showing improved colour staying 0.039 The term “polyol is intended to denote any hydro power. carbon-based compound comprising at least two hydroxyl 0028. For instance, the present invention makes it pos functions and containing from 4 to 40 carbon atoms, from 6 sible to provide compositions whose colour staying power is to 36 carbon atoms, from 8 to 32 carbon atoms, from 16 to improved over time, for example with regard to various 28 carbon atoms and or from 18 to 24 carbon atoms. external attacking factors, such as meals or contact with 0040. The hydrocarbon-based chains may be interrupted, fabrics. where appropriate, by the presence of at least one heteroa 0029. For example, the present invention makes it pos tom, for example an oxygen atom. sible to provide cosmetic compositions that do not cause any 0041 A polyol or a polyol ester that is suitable for use in sensation of tack or discomfort when applied. the present invention may comprise, for example, from 2 to 12 hydroxyl functions, from 2 to 8 hydroxyl functions, or Ester of Dimerdilinoleic Acid and of Pollol(s) from 4 to 6 hydroxyl functions. 0030. In the expression “ester of dimerdilinoleic acid and of polyol(s) or an ester thereof, the term “or an ester 0042. Where appropriate, the hydroxyl functions, other thereof is intended to denote one of the derivatives of these than those already employed in an ester bond with the esters of dimerdilinoleic acid and of polyol(s) obtained dimerdilinoleic acid, may also be employed, wholly or either by reaction of alcohol function(s) of the polyol, which partly with other ester bonds via reactivity with acid mol are not employed in bonds of ester type with acid functions ecules other than the dimerdilinoleic acid. of the dilinoleic acid, with one or more carboxylic functions 0043. The polyol or an ester thereof that is suitable for of acid molecules other than dilinoleic acid or alternatively use in the present invention may, for example, be chosen by reaction of acid function(s) of the dilinoleic dimer, which from linear, branched, cyclic or polycyclic, Saturated or are not employed in bonds of ester type with alcohol unsaturated alcohols. functions of the polyol, with alcohol functions of alcohol molecules other than the polyol. 0044) Thus, the polyol may be chosen, for example, from a diol, a triol, a tetraol, or a pentaol, or an ester thereof. Dimerdilinoleic Acid 0045. The polyol may be a diol, or an ester thereof, 0031. The dimerdilinoleic acid that is suitable for use in chosen for example from a fatty alcohol dimer, a monoglyc the present invention may be obtained by polymerization erol or polyglycerol, a C monoalkylene or polyalkylene reaction, for example by intermolecular dimerization of at glycol, 1,4-butanediol and pentaerytiritol. least one linoleic acid. 0046. As examples of diols that are also suitable for use 0032. The oxidation stability of the compound may be in the invention, mention may be made, in a non-exhaustive improved by hydrogenating the double bonds remaining manner, of butanediol, pentanediol, propanediol, hex after the dimerization reaction. anediol, hexylene glycol, heptanediol, octanediol. nonanediol, decanediol, undecanediol, dodecanediol, tride 0033. The dimerdilinoleic acid may also be obtained by canediol, tetradecanediol, pentadecanediol, hexadecanediol. dimerization of the hydrogenated form of linoleic acid. nonadecanediol, octadecenediol, cyclohexanediol, diglyc 0034. The hydrogenated form of the acid or of the diacid erol, erythritol, pentaerythritol, xylitol, sorbitol, ethylene may be partial or total, and may correspond, for example, to glycol and Xylene glycol, and isomers thereof. the saturated form, which is more oxidation-stable. 0047 A fatty alcohol dimer may also be the product of 0035. As indicated previously, the carboxylic functions hydrogenation, for example catalytic hydrogenation, of a of the dimerdilinoleic acid residue not engaged in the ester fatty acid dimer, which is itself obtained by dimerization of bond with the polyol residue(s) may be engaged in other at least one Cs to C4, C12 to C22, C16 to C20, or C1s ester bonds with other alcohol functions of alcohol mol unsaturated fatty acid. ecules other than the polyol(s). 0048. A fatty alcohol dimer may range from C to Ces, 0036) These alcohol molecules or residues may be for example from C to C, from C to Cao, or may be of monoalcohols or polyols. C36. US 2007/01341.82 A1 Jun. 14, 2007

0049 According to one embodiment, a fatty alcohol 0063 Thus, in such a configuration, each of the two ends dimer may be a diol dimer which may be the product of of the said sequence may bear, respectively, a unit OR and hydrogenation of dilinoleic diacid. It may be in a saturated OR" with R' and R" representing, independently of each form. other, a hydrogen atom or OR" and OR" representing, 0050. A fatty alcohol dimer may be, for example, a independently of each other, a C to C. Cs to C. C to dilinoleol dimer. Co or C to Cs hydrocarbon-based monoalcohol residue. 0051. As an example of a diol that may be suitable for use 0064. According to one embodiment, R' and R" may both in the invention, mention may be made of diglycerol. represent a hydrogen atom. 0.052 This compound is a glycerol dimer resulting from 0065 According to one embodiment, OR" and OR" may the condensation of two molecules of glycerol, with the loss both represent an identical or different hydrocarbon-based of a water molecule. monoalcohol residue. 0053. The term “diglycerol' denotes any isomer combi nation that can result from Such a condensation, for instance 0066. As examples of hydrocarbon-based monoalcohol linear isomers, branched isomers and, where appropriate, residues OR" and OR" that may be suitable for the invention, cyclic isomers resulting from an intramolecular dehydration mention may be made of fatty alcohol residues. of a diglycerol molecule. 0067. According to one embodiment, an ester of dimer 0054 The diglycerol may be obtained via any process dilinoleic acid and of polyol(s) or an ester thereof that may known to those skilled in the art and for example via those be suitable for use in the present invention may have the described in patent EP 0750848. general formula (I) below: 0.055 As examples of acid molecules that can interact R—OCO-R(-COO-R-OCO-R), COO with one or more hydroxyl functions of the polyol, not R (I) employed in the ester bond with the dimerdilinoleic acid, mention may be made, in a non-limiting manner, of mol in which: ecules derived from isostearic acid, behenic acid, phytosteric 0068 CORCO represents a dimerdilinoleate residue, acid, Stearic acid or cetylic acid. 0056 An ester that is suitable for use in the present 0069 ORO represents a fatty alcohol dimer residue that invention may be obtained by reacting a polyol or an ester may range from C to Ces, from C to C. from C to thereof with a dimerdilinoleic acid, in a molar ratio of about Cao, or may be of Cs. 10:0.2-1.O. 0070) OR represents a monoalcohol residue that may 0057. An ester that may be suitable for use in the present range from 4 to 40 carbon atoms, for example from 6 to invention may for example, be obtained by reacting a 36 carbon atoms, for example from 8 to 32, for example dimerdilinoleic acid with a dilinoleol and, where appropri from 16 to 28, or for example from 18 to 24 carbonatoms, ate, at least one additional monoalcohol for example chosen and from behenol, isostearol, phytosterol, Stearol and cetol, and mixtures thereof 0071 n is an integer ranging from 1 to 15, from 2 to 10 or from 5 to 7. 0.058 Thus, an ester used in the context of the present invention may be used in the form of a mixture of various 0072 According to one embodiment, ORO may repre esters, for example. sent a dimerdilinoleyl residue. 0059 An ester that is suitable for the invention may be 0073 Moreover, OR may represent a hydrocarbon obtained, for example, by reacting a glycerol, an isostearic based monoalcohol residue chosen, for example, from behe acid and a dimerdilinoleic acid, for example, in a molar ratio nyl, isostearyl and phytosteryl residues, and mixtures of 1.0:0.2-1.0:0.5-0.9. thereof. 0060. As examples of esters of dimerdilinoleic acid and 0074 According to another embodiment, the ester of of polyol(s) or an ester thereof suitable for the invention, dimerdilinoleic acid and of polyol(s) or an ester thereof that mention may be made of the esters described in patent may be suitable for use in the invention may, have the applications JP 2004-256515 and JP 2005-179377. general formula (II) below: 0061 An ester of dilinoleic acid and of polyol(s) or an ester thereof suitable for use in the present invention may have a molecular weight ranging from about 2000 to about (II) 25 000 g/mol, from about 4000 to about 20 000 g/mol, from HO-R-C-O-C-R-C-O-R)-OH about 5000 to about 20 000 g/mol, from about 7000 to about O O 15 000 g/mol or from about 8000 to about 10 000 g/mol. 0062 According to one embodiment, an ester in accor dance with the invention may comprise an alternating in which: sequence of dimerdilinoleate residue(s) and of residue(s) 0075 n is an integer ranging from 1 to 15, from 2 to 10 related to the said polyol(s), and for example to the said or from 5 to 7, diol(s), the said polyol(s) or diol(s) being, for example, as defined above. 0.076 OCR'CO represents a dimerdilinoleate residue, US 2007/01341.82 A1 Jun. 14, 2007

0.077 ORO represents a diglyceryl residue of general 0092 An ester of dimerdilinoleic acid and of polyol(s) or formula (III) below: an ester thereof suitable for use in the invention may be present in the cosmetic compositions according to the inven tion in an amount Sufficient to give these compositions (III) improved cosmetic properties, for example in terms of mean -O-(-CH-CH-CH-O-CH-CH-CH-O- gloss staying power. O O 0093. An ester according to the invention may be present in a composition in accordance with the invention in a content ranging from about 5% to about 90%, from about 15% to about 80% or from about 20% to about 50% by weight relative to the total weight of the composition. in which: 0078 R's represents H or OR's represents a fatty acid Surfacants residue that may range from Cs to C, for example 0094. The term “surfactant’ means a compound having at from C to C, for example of C to C20 or for least one hydrophilic portion and at least one hydrophobic example may be of Cs. portion. Hydrophilic groups and hydrophobic groups are 0079 According to one embodiment, the fatty acid resi well known to those skilled in the art. due represented by OR's may be an isostearyl residue. 0095. A cosmetic composition in accordance with the 0080. The viscosity of an ester of dimerdilinoleic acid present invention comprises at least one silicone surfactant. and of polyol(s) or an ester thereof, according to the inven tion, may be measured according to any process known to 0096. For the purposes of the present invention, the term those skilled in the art, and for example according to the 'silicone surfactant’ means a Surfactant comprising at least conventional process described hereinbelow. one silicon atom and for example Si-O groups. 0081. The viscosity may be measured using a cone/plate 0097 As examples of silicone surfactants that may be or parallel plate viscometer of Ares type (TA-Instrument) suitable for the invention, mention may be made of silicone operating in kinetic Sweep mode over a shear range of about Surfactants selected from the group constituted of a polyhy 1-1000 s to induce a flow tension at about 1000 Pa. droxylated silicone surfactant and an emulsifying silicone 0082 The cone/plate or parallel plates may consist of a resin or elastomer, and mixtures thereof. material selected from the group constituted of stainless 0098. A hydroxylated silicone surfactant that may be steel, acrylic resins or polyphenylene sulfide (PPS resin). used in a cosmetic composition according to the present 0083. The cone/plate diameter may be 25 mm (cone invention is, for example, described in detail in patent angle 0.10 radiant). application EP 1213 316. 0084. The measurement is performed at about 25°C. 0099 When introduced in sufficient amount, and in com bination with an ester of dimerdilinoleic acid and of poly 0085. Before any measurement, the stability of the ol(s) or an ester thereof as defined above, it is able for sample is checked by means of the dynamic Sweep period example to improve the gloss staying power, or even also the test, which makes it possible to determine if the sample is colour staying power, of the cosmetic compositions accord stable per se. ing to the invention. 0.086 The shear viscosity is determined using the ETA 0.100 For instance, a polyhydroxylated silicone surfac value in the plateau region according to the flow. tant that may be used in a cosmetic composition according 0087. The dynamic sweep period is determined at a to the present invention may be represented by the general frequency of 1.0 Hz over a period of 600 seconds. formula (IV) below: 0088. The measurements at constant sweep rate are per R".R.R.SIO4 tea (IV) formed with a rate ranging from 1.0 to 1000 s' and for example from 1.0 to 100 s. in which: 0089. The viscosity of an ester of dimerdilinoleic acid 0101 a) a, b and c may be such that a ranges from 1 to and of polyol or an ester thereof suitable for use in the 2.5; and b and c, independently of each other, range from invention may range from about 20 000 mPa.s to about 150 0.001 to 1.5, 000 mPa.s, from about 40 000 mPa.s to about 100 000 mPa.s 0102) b) R', which may be identical or different, may be or from about 60 000 mPa.S to about 80 000 mPa.s. selected from the group constituted of: 0090 An ester that is suitable for the invention may be chosen for example from the esters having the following 0.103 C to Co alkyl radicals, where appropriate sub INCI nomenclature: polyglyceryl-2 isostearate dimerdili stituted with one or more fluorine atoms and amino noleate copolymer, bis-behenyl/isostearyl/phytosteryl and/or carboxyl groups, dimerdilinoleyl dimerdilinoleate, and mixtures thereof. 0.104) aryl and aralkyl radicals, and 0.091 Such compounds may be obtained, for example, under the reference Hailuscent ISDA (Kokyu Alcohol) and 0105 the radicals of general formula (V): Plandool-G (Nippon Fine Chemical Company Ltd). US 2007/01341.82 A1 Jun. 14, 2007

in which: radical, a C to Cs alkyl radical, a Cs to Co alkyl radical, or a C to Cs alkyl radical. For example, it may 01.06) R' may be a C to Cohydrocarbon-based radical be a methyl, ethyl, n-propyl, isopropyl. n-butyl, isobu or a radical R (CO)— with R being a C to Cso tyl, tert-butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, hydrocarbon-based radical, and undecyl or lauryl radical. It may also be a cycloalkyl 0.107 d e and f may be integers such that d ranges radical Such as a cyclopropyl, a cyclobutyl, a cyclo from 0 to 15, and e and f, independently of each other, pentyl or a cyclohexyl. It may also be a linear or range from 0 to 50, and branched monounsaturated or polyunsaturated alkyl radical. It may also be an alkyl radical substituted with 0.108 combinations thereof, one or more fluorine atoms, such as trifluoropropyl or 0109 c) R2 may be represented by the general formula heptadecafluorodecyl. It may also be an alkyl radical (VI) below: Substituted with one or more amino groups, such as 2-aminoethyl, 3-aminopropyl or 3-(2-aminoethyl)ami -Q-O-X (VI) nopropyl. It may also be an alkyl group Substituted with in which: one or more carboxyl groups, such as 3-carboxypropyl; 0110 Q may be a divalent C to Co. hydrocarbon 0122) R' may also be an aryl or aralkyl radical such as based radical which may include at least one ether bond a phenyl radical, a tolyl radical, a benzyl radical or a and/or at least one ester bond, and phenethyl radical; 0.111 X may be a polyhydroxylated hydrocarbon based radical, 0123 R' may also be an organic group represented by 0112) d) R may be an organosiloxane group of general the general formula (V): formula (VII): 0.124. According to one particular embodiment, R' may be a hydroxylated radical or a radical derived from the (VII) R addition reaction of a saturated or unsaturated, linear or branched alkenyl ether, in which d=0 and thus of formula: -CH2-(SO)-SERs R 0.125. In this case, whene and fare equal to zero, then R is an alkoxy group containing from 4 to 30 carbon atoms, for example a C to Co lower alkoxy radical. Such as butoxy or with: pentoxy, or a C to Co higher alkoxy radical. Such as 0113 each of the radicals R possibly representing, inde oleoxy or Stearoxy, namely, for example, cetyl alcohol, oleyl pendently of each other, a radical selected from the group alcohol and Stearyl alcohol, or a radical derived from an acid constituted of C to Co alkyl radicals, where appropriate or from a fatty acid, such as acetic acid, lactic acid, butyric Substituted with one or more fluorine atoms, and aryland acid, oleic acid, Stearic acid or behenic acid. aralkyl radicals, 0126 When e and f are greater than 1, then R' is a 0114 g and h possibly being integers such that g ranges hydroxyl radical derived from the addition reaction of an from 1 to 5 and h ranges from 0 to 500. alkylene oxide. 0115 When the radicals R represent a radical selected 0127. Whene and fare equal to zero, d may, for example, from the group constituted of C to Co alkyl radicals, where be equal to 3, 5 or 11. In this case, R', depending on the appropriate Substituted with one or more fluorine atoms, aryl nature of the substituent R, is an allyl ether, pentenyl ether radicals and aralkyl radicals, they may have the same or undecenyl ether radical, or an allyl Stearyl ether, pentenyl meaning as the radical R' as defined above. behenyl ether or undecenyl oleyl ether radical. 0116. It should be noted that the radicals R', RandR of 0128. Whene and fare other than Zero, an alkoxy radical the silicone polymers of general formula (I), as defined and an ester radical are present via a polyoxyalkylene group. above, may be randomly or statistically distributed, i.e. they may appear in the structure of the polymer without any 0129. Irrespective of the nature of e and f, d may, for determined order. Similarly, R, R and R may respectively example, be within the range from 3 to 5. feature radicals of different nature in a compound of general 0130. According to one embodiment, the radical R' may formula (1). be any one of the radicals defined above, or a combination 0117. According to one embodiment, of two or more of these radicals. 0118 in a): 0131) For example, R' may be an alkyl radical selected 0119) a may for instance range from 1.2 to 2.3 and, for from the group constituted of a methyl radical and a lauryl example, b and c, independently of each another, may radical, and combinations thereof. range from 0.05 to 1: 0132) Moreover, when R' may represent in the same general formula (I) two or more radicals, for example a 0120 in b): methyl radical and a lauryl radical, these radicals appear 0121 when R' is an alkyl radical, it may be a C to Cso randomly in the structure, and with a frequency that is alkyl radical, a C to Cs alkyl radical, a C to Co alkyl specific thereto. US 2007/01341.82 A1 Jun. 14, 2007

0133) For instance, at least 50% of the radicals R', at least represent a radical selected from the group constituted 70% of the radicals R and 100% of the radicals R', may be of the alkyl radicals as defined above, where appropri methyl radicals; ate substituted with one or more fluorine atoms, they have the same meaning as the radical R' as defined 0134) in c): above. 0.135 Q may for example be a divalent hydrocarbon based radical selected from the group constituted of: 0145 g, according to one embodiment, may be equal to 2. 0136 —(CH) , —(CH) , —CHCH(CH)—CH, (CH2) , (CH2) , (CH2) , (CH2) , 0146 h, according to one embodiment, may be within (CH2)s s (CH2) s (CH2)o s (CH2) —, the range from 1 to 50. —(CH) CH(CH2CHCH)—, —CH2— CH(CH2CH)— —(CH2). O—(CH) , —(CH2). 0147 According to one embodiment, the polyhydroxy O—(CH)—O—(CH) , —(CH). O— lated silicone surfactant of general formula (IV) that is CHCHCCH)— and —CH2—CH(CH)—COO(CH)—. suitable for use in the present invention may be such that: 0137 For instance, Q may be a divalent radical selected 0.148 a mayy rangerang from 1 to 1.4, and b and c, inde from the group constituted of—(CH)—and —(CH) . pendently of each other, range from 0.02 to 0.04, and 0.138 X may for example be a polyhydroxylated (0.9) R may be a C to Co. C to C or C to C, alkyl hydrocarbon-based radical comprising at least two rad1Cal, hydroxyl residues, and for instance a hydrocarbon based group selected from the group constituted of 0150 R may be represented by the formula (VIA): glyceryl derivatives and saccharide derivatives. CHOICH-CH(OH)CH-OH (VIA) 0.139. The glycerol residues may be compounds having in which n may range from 1 to 5, and the following formulae, in which Q has the same meaning as in the general formula (III), and S and t may be integers 0151 R may be represented by the formula (VIIA): within the range from 1 to 20, from 1 to 15, from 1 to 10 and from 1 to 5. —CH (CH)2SiO(CH3)2SiOSi (CH) (VIIA) in which m may range from 3 to 9. 0152. According to another embodiment, the polyhy droxylated silicone surfactant of general formula (I), which may be used in the cosmetic compositions according to the invention, is such that: 0.153 a may range from 1 to 1.4, and b and c, inde pendently of each other, range from 0.02 to 0.04. 0154) R' may be a methyl radical, O155 R may be represented by the formula (VIA) in which n may range from 1 to 5, and 0156 R may be represented by the formula (VIIA) in which m may range from 3 to 9. 0157 For example, the polyhydroxylated silicone surfac tant of general formula (I) used in the cosmetic composition 0140. In the above formulae, one or more hydroxyl in accordance with the invention may be selected from the groups may be replaced with alkoxy groups or ester groups. group constituted of polyglyceryl-3 polymethylsiloxyethyl dimethicone, laurylpolyglyceryl-3 polymethylsiloxyethyl 0141. The saccharide radicals that may be used in the dimethicone and polyglyceryl-3 disiloxane dimethicone, the general formula (III) may be of monosaccharide type. Such as glycosyl, mannosyl, galactosyl, ribosyl, arabinosyl, Xylo respective formulae of which are: Syl or fructosyl groups, of oligosaccharide type, such as 0158 Polyglyceryl-3 polymethylsiloxyethyl dimethi maltosyl, cellobiosyl, lactosyl or maltotriosyl, or of polysac cone (formula (VIII)): charide type. Such as cellulose or starch. 0142 For example, the saccharide groups may be of monosaccharide or oligosaccharide type; (VIII) 0143 in d): th i fy 0.144 each of the radicals R may for example repre (CH3)SiO —o —o –o Si(CH3)3 sent, independently of each other, a radical selected CH3 CH3 CH3 from the group constituted of C to Co. C to Co or C 3. b C to C alkyl radicals, where appropriate substituted with one or more fluorine atoms. When the radicals R US 2007/01341.82 A1 Jun. 14, 2007

in which: 0172 Among the silicone surfactants that may be used in the cosmetic compositions in accordance with the present 0159 SX: -CH(CH)SiO, Si(CH), invention, mention may also be made of the emulsifying 0160 Gly: —CHOCH-CH(OH)CH-OH silicone resins or elastomers sold by the company Shin-Etsu under the references KSG-310, KSG-320, KSG-330 and 0161 and a-1-1.4, b=0.02-0.04, c=0.02-0.04, m=3-9, KSG-340. n=1-5 0173 The term “the emulsifying silicone elastomer s 0162 Laurylpolyglyceryl-3 polymethylsiloxyethyl means a silicone elastomer comprising at least one hydro dimethicone (formula (IX)): philic chain other than a polyglycerol chain. 0.174 For example, the additional emulsifying silicone (IX) elastomer may be selected from the group constituted of polyoxyalkylenated silicone elastomers and mixtures RI Sx fy thereof. (CH3)3SiO Si-O Si-O –0 Si(CH3)3 0.175. The polyoxyalkylenated silicone elastomer may be a crosslinked organopolysiloxane that may be obtained via CH3 CH3 CH3 3. b C the crosslinking addition reaction of a diorganopolysiloxane containing at least one hydrogen bonded to silicon with a polyoxyalkylene containing at least two ethylenically unsat in which SX, Gly, a, b, c, m and n have the same meaning urated groups. as above and R' is either a methyl radical or a lauryl 0176) Polyoxyalkylenated elastomers that may be suit radical; able for use in the invention are for instance described in 0.163 Polyglyceryl-3 disiloxane dimethicone (formula patents U.S. Pat. No. 5.236,986, U.S. Pat. No. 5,412,004, (X)): U.S. Pat. No. 5,837,793 and U.S. Pat. No. 5,811487. 0.177 Polyoxyalkylenated silicone elastomers that may be used include those sold under the names KSG-21, KSG (X) 20, KSG-30, KSG-31, KSG-32, KSG-33, KSG-210, KSG CH3 Sx Gly 310, KSG-320, KSG-330, KSG-340 and X-226146 by the company Shin-Etsu, and DC9010 and DC9011 by the com (CH3)SiO pany Dow Corning. -o –o Ho 0.178 Among the silicone surfactants that may be used in l, Jr., Jr., J. the cosmetic compositions in accordance with the present invention, mention may also be made for example of hydro philic organopolysiloxanes belonging to the dimethicone in which Gly, a, b, c, m and n have the same meaning as polyethylene glycol family and may be chosen for instance above, and from the group comprising dimethicone copolyols, for 0164 SX: O(CH)SiO Si (CH), example cetyldimethicone copolyol, and derivatives thereof. 0165 or mixtures thereof. 0.179 The hydrophilic organopolysiloxane may be the product sold under the brand name Abil WE09 or Abil EM90 0166 According to one embodiment, the polyhydroxy by the company Degussa-Goldschmidt. The hydrophilic lated silicone surfactant of general formula (I) may for organopolysiloxane may also be the product sold under the example be selected from the group constituted of the reference KF-6017 by the company Shin-Etsu. polymers sold by the company Shin-Etsu under the refer ences KF 6100(R), KF 6104(R) and KF 6105(R). 0180. The organopolysiloxane compound may be totally or partially fluorinated. For example, the lower dialkyl 0167 According to yet another embodiment, the polymer siloxy groups may be substituted with one or more fluorine sold under the reference KF 6104(R) may be for instance atOmS. Suitable for preparing the cosmetic compositions in accor dance with the invention. 0181. According to one embodiment, a silicone surfac tant that may be used in a cosmetic composition in accor 0168 Among the other silicone surfactants that may be dance with the present invention may be a silicone Surfactant Suitable for use in the invention, mention may be made, in for example chosen from a polyhydroxylated silicone Sur a non-limiting manner, of the following Surfactants: factant, dimethicone copolyol, dimethicone copolyol ben 0.169 dimethicone copolyol, such as the product sold Zoate, dimethicone copolyol phosphates, polyoxyalkylena under the name Q2-5220 by the company Dow Corn ted silicone elastomers and the cyclomethicone/dimethicone ing: mixture, and mixtures thereof. 0170 dimethicone copolyol benzoate (Finsolv SLB 0182. The silicone surfactant may be present in the 101 and 201 from the company Finetex), cosmetic compositions in accordance with the present inven tion in a proportion of from 1% to 30% by weight, from 2% 0171 the cyclomethicone/dimethicone copolyol mix to 25% by weight, from 4% to 20% by weight, from 5% to ture sold under the name Q2-3225C by the company 20% by weight or from 10% to 15% by weight, relative to Dow Corning. the total weight of the composition. US 2007/01341.82 A1 Jun. 14, 2007

0183. A cosmetic composition according to the invention JP-A-08-109121 by Kao and the document by D. W. Van may also comprise at least one hydrocarbon-based surfac Krevelen “Properties of Polymers” (1990), p. 190. tant. 0199 A hydrocarbon-based surfactant may be selected 0184 For the purposes of the present invention, the term from the group constituted of partial esters of polyglycerol "hydrocarbon-based surfactant’ means a Surfactant essen and of isostearic acid, partial esters of polyglycerol and of tially formed from carbon and hydrogen atoms, and possibly oleic acid, and partial esters of Sorbitan and of oleic acid, and oxygen and/or nitrogen atoms, and free of silicon and mixtures thereof. fluorine atoms. These agents may, where appropriate, com 0200. As hydrocarbon-based surfactants that may be used prise ester, ether, amine and/or amide groups. in the composition according to the invention, it is also 0185. The hydrocarbon-based surfactants may be chosen possible to select polyglyceryl-2 monoisoStearate such as for example from nonionic, anionic, cationic and amphoteric Salacos 41 manufactured or sold by the company Nisshin Surfactants or alternatively emulsifying Surfactants. Oil Mills, polyglyceryl-3 diisostearate such as Lameform 0186 Reference may be made to Kirk-Othmer’s “Ency TGI manufactured or sold by the company Cognis, polyg clopaedia of Chemical Technology', volume 22, pp. 333 lyceryl-2 monooleate such as Rylo PG 29 manufactured or 432, 3rd edition, 1979, Wiley, for the definition of the sold by the company Danisco Ingredients, and Sorbitan properties and functions (emulsifying) of Surfactants, in monooleate such as Span 80 manufactured or sold by the particular pp. 347-377 of this reference, for the anionic, company Uniqema, and mixtures thereof amphoteric and nonionic Surfactants. 0201 The ionic surfactants used in the context of the 0187. As non-limiting illustrations of nonionic surfac present invention may be anionic, cationic or amphoteric. tants that may be used in the compositions according to the 0202 As illustrations of anionic surfactants that are suit invention, mention may be made for example of: able for the invention, mention may be made for example of: 0188 oxyethylenated and/or oxypropylenated ethers 0203 salts of C-C fatty acids, for example those of glycerol or of fatty alcohols; derived from amines, for instance triethanolamine 0189 fatty acid esters of polyethylene glycol; Stearate; 0204 polyoxyethylenated fatty acid salts, for example 0.190 oxyethylenated and/or oxypropylenated fatty those derived from amines or alkali metal salts, and acid esters of glycerol ethers; mixtures thereof 0191 oxyethylenated and/or oxypropylenated fatty 0205 phosphoric esters and salts thereof such as DEA acid esters of sorbitol ethers; Olleth-10 phosphate (Crodafos N 10N from the com 0.192 copolymers of ethylene oxide and of propylene pany Croda): oxide, condensates of ethylene oxide and propylene 0206 sulfosuccinates such as disodium PEG-5 citrate oxide with fatty alcohols, polyethoxylated amines or lauryl sulfosuccinate and disodium ricinoleamido MEA fatty amines, polyglycerolated fatty amides, polyglyc SulfoSuccinate; erolated diglycolamides, optionally oxyethylenated fatty acid esters of Sorbitan, fatty acid esters of Sucrose, 0207 alkylamido ether sulfates, monoglyceride sul polyoxyalkylenated fatty acid esters, optionally oxy fates and alkyl ether Sulfates such as sodium lauryl alkylenated alkylpolyglycosides, alkylglucoside esters, ether sulfate; N-alkylglucamine and N-acylmethylglucamine deriva 0208 alkylglycerylsulfonates, alkylsulfonates, alkyla tives and amine oxides, mide Sulfonates, alkylaryl Sulfonates, C-olefin Sul 0193 copolymers of propylene oxide and of ethylene fonates and paraffin Sulfonates; oxide; 0209) isethionates; 0210 acylglutamates such as disodium hydrogenated 0194 saccharide esters and ethers; tallow glutamate (Amisoft HS-21 R sold by the com 0.195 fatty acid esters of polyols: pany Ajinomoto), and mixtures thereof. 0196) and mixtures thereof. 0211 Triethanolamine stearate is for example suitable for the invention. This product is generally obtained by simple 0197) Surfactants that may also be suitable for use in the mixing of Stearic acid and triethanolamine. invention are those of hydrocarbon-based type having solu bility parameters Öd and Öa, according to the Hansen solu 0212 Illustrations of cationic surfactants that may for bility space, which satisfy the following conditions: example be mentioned include: 16.2s6s20 (Jen), 16.3s 819 (J/cm)/2 or 0213 alkyl-imidazolidiniums such as isostearyleth 16.9s 8s 18 (J/cm), and ylimidonium ethosulfate, 9.1 s6s20 (J/cm) 2, 10s 8, 18.1 (J/cm)/2 or 13s 8, s14.5 (J/cm)/2. 0214) ammonium salts such as N.N.N-trimethyl-1- 0198 The definition of the Hansen solubility parameters docosanaminium chloride (behentrimonium chloride), is well known to those skilled in the art and is for example 0215 optionally polyoxyalkylenated and/or quater described in the article by C.M. Hansen: “The three-dimen nized fatty amine salts, optionally polyoxyalkylenated sional solubility parameters”. J. Paint Technol. 39, 105 and/or quaternized fatty acid esters of amino alcohols, (1967). These parameters are also described in document quaternary ammonium salts such as tetraalkylammo US 2007/01341.82 A1 Jun. 14, 2007

nium, alkylamidoalkyltrialkylammonium, trialkylben 5%, less than 3%, less than 2% or less than 1% by weight Zylammonium, trialkylhydroxyalkylammonium, of water relative to the total weight of the composition. dialkylamidoalkyldimethyl-ammonium or alkylpyri These compositions may then for example be in the form of dinium chlorides or bromides and imidazoline deriva oily gels, oily liquids, pastes or Sticks or alternatively in the tives. form of a vesicular dispersion containing ionic and/or non ionic liquids. 0216 A composition according to the invention may also contain one or more amphoteric Surfactants, for instance N-acylamino acids such as disodium N-alkylaminoacetates Fatty Phase and cocoamphodiacetate and amine oxides such as Stear 0227. A cosmetic composition in accordance with the amine oxide, or alternatively silicone Surfactants, for present invention may comprise a fatty phase chosen for instance dimethicone copolyol phosphates Such as the roduct example from a liquid fatty phase, for instance oils, and a sold under the name Pecosil PS 100 by the company Phoenix fatty substance that is solid at room temperature (20-25°C.) Chemical, and also ulfobetaines, alkylaminoalkylbetaines, and atmospheric pressure, and mixtures thereof. alkylamidoalkylsulfotaines and imidazolium erivatives Such as those of amphocarboxyglycinate or of amphocarboxypro 0228. The term “oil means any fatty substance that is in pionate. liquid form at room temperature (20-25°C.) and at atmo spheric pressure. The liquid fatty phase may also contain, in Physiologically Acceptable Medium addition to oils, other compounds dissolved in the oils, such as gelling agents and/or structuring agents. 0217. A composition in accordance with the invention comprises a physiologically acceptable medium. 0229. The oil(s) may be present in a proportion of from 0.1% to 99% by weight, from at least 1% to 90% by weight, 0218. The term “physiologically acceptable medium' is from 5% to 70% by weight, from 10% to 60% by weight or intended to denote a medium that is particularly suitable for from 20% to 50% by weight relative to the total weight of the application of a composition according to the invention the cosmetic composition according to the invention. to the skin and/or the lips. The physiologically acceptable medium is generally Suited to the nature of the Support onto 0230. The liquid fatty phase that may be suitable for which the composition is to be applied, and to the aspect in preparing a cosmetic composition according to the invention which the composition is intended to be conditioned. may be selected from the group constituted of volatile or non-volatile, silicone or non-silicone oils, and mixtures 0219. The physiologically acceptable medium may com thereof. prise an aqueous and/or water-soluble phase and/or a fatty phase. 0231. For the purposes of the present invention, the term 'silicone oil” means an oil comprising at least one silicon 0220 According to one embodiment, the aqueous phase atom, and at least one Si-O group. or the fatty phase may form the continuous phase of the composition. 0232 The term “hydrocarbon-based oil means an oil mainly containing hydrogen and carbon atoms, and possibly 0221) This aqueous phase may, where appropriate, be oxygen, nitrogen, Sulfur and/or phosphorus atoms. thickened, gelled or structured by also incorporating therein a conventional aqueous gelling agent for example of mineral Volatile Oils origin, for instance clay, and/or of organic origin, for instance an aqueous gelling polymer. 0233. A composition in accordance with the invention 0222. According to another embodiment, a composition may comprise at least one volatile oil. in accordance with the invention may be in the form of a 0234 For the purposes of the present invention, the term Suspension, a dispersion, a Solution, a gel or an emulsion, for “volatile oil means an oil (or non-aqueous medium) example an oil-in-water (O/W), water-in-oil (W/O) or mul capable of evaporating on contact with the skin in less than tiple (W/O/W, polyol/O/W or O/W/O) emulsion, or in the one hour, at room temperature and at atmospheric pressure. form of a cream, a stick, a paste, a foam, a dispersion of The volatile oil is a volatile cosmetic oil, which is liquid at vesicles, for instance of ionic or nonionic lipids, a two-phase room temperature, for example having a non-Zero vapour or multi-phase lotion or a powder. pressure, at room temperature and atmospheric pressure, for instance having a vapour pressure ranging from 0.13 Pa to 0223 For the purposes of the present invention, the 40 000 Pa (10 to 300 mmHg), ranging from 1.3 Pa to 13 emulsions contain a lipophilic phase and a hydrophilic 000 Pa (0.01 to 100 mmHg) and ranging from 1.3 Pa to 1300 phase, the latter phase not systematically being water. Pa (0.01 to 10 mmHg). 0224 Thus, the cosmetic compositions in accordance 0235. The volatile hydrocarbon-based oils may be with the invention may be in the form of an anhydrous selected from the group constituted of hydrocarbon-based emulsion. oils containing from 8 to 16 carbon atoms, and for example 0225. For instance, the composition may contain, for branched C-C alkanes (also known as isoparaffins), for example, a continuous fatty phase, which may contain less instance isododecane (also known as 2.2.4.4.6-pentameth than 10% by weight of water, less than 5% by weight of ylheptane), isodecane, isohexadecane and, for example, the water or less than 1% by weight of water relative to the total oils sold under the trade names IsopartR) or Permethyl(R). weight of the composition. 0236 Volatile oils that may also be used include volatile 0226 For example, a cosmetic composition according to silicones, for instance volatile linear or cyclic silicone oils, the invention may be anhydrous, i.e. may contain less than for example those with a viscosity s8 centistokes (8x10 US 2007/01341.82 A1 Jun. 14, 2007 m/s), and for instance containing from 2 to 10 silicon atoms 0246 hydrocarbon-based oils of mineral or synthetic or from 2 to 7 silicon atoms, these silicones optionally origin, for instance: comprising alkyl or alkoxy groups containing from 1 to 10 carbon atoms. As a volatile silicone oil that may be used in 0247 synthetic ethers containing from 10 to 40 the invention, mention may be made for example of dime carbon atoms; thicones with a viscosity of 5 and 6 cSt, octamethylcyclotet 0248 linear or branched hydrocarbons of mineral or rasiloxane, decamethylcyclopentasiloxane, dodecamethyl synthetic origin such as petroleum jelly, poly cyclo-hexasiloxane, heptamethylhexyltrisiloxane, decenes, hydrogenated polyisobutene Such as Par heptamethyloctyltrisiloxane, hexamethyldi-siloxane, octam leam, and squalane, and mixtures thereof, and for ethyltrisiloxane, decamethyltetrasiloxane and dodecameth example hydrogenated polyisobutene, ylpentasiloxane, and mixtures thereof. 0249 synthetic esters, for instance oils of formula 0237 Volatile fluoro oils such as nonafluoromethoxybu RCOOR in which R, represents a linear or tane or perfluoromethyl-cyclopentane, and mixtures thereof, branched fatty acid residue containing from 1 to 40 may also be used. carbon atoms and R2 represents a hydrocarbon-based 0238. It is also possible to use a mixture of the oils chain that is for instance branched, containing from mentioned above. 1 to 40 carbon atoms provided that R+Re 10. 0239). A cosmetic composition according to the invention 0250) The esters may be chosen for example from fatty may comprise at least one volatile oil in a content ranging acid esters, for instance: from about 2% to about 70% by weight, ranging from about 0251 cetostearyl octanoate, isopropyl alcohol 5% to about 60% by weight or ranging from about 10% to esters, such as isopropyl myristate or isopropyl about 50% by weight of volatile oil relative to the total palmitate, ethyl palmitate, 2-ethylhexyl palmitate, weight of the composition. isopropyl Stearate or isostearate, isostearyl isostear ate, octyl Stearate, hydroxylated esters, for instance Non-volatile Oils isostearyl lactate, octyl hydroxy Stearate, diisopropyl 0240 For the purposes of the present invention, the term adipate, heptanoates, and especially isostearyl hep “non-volatile oil means an oil with a vapour pressure of less tanoate, alcohol or polyalcohol octanoates, than 0.13 Pa and for example oils of high molar mass. The decanoates or ricinoleates, for instance propylene non-volatile oils may be hydrocarbon-based oils for instance glycol dioctanoate, cetyl octanoate, tridecyl of animal or plant origin, synthetic oils, silicone oils or octanoate, 2-ethylhexyl 4-diheptanoate and palmi fluoro oils, or mixtures thereof. tate, alkyl benzoate, polyethylene glycol dihep tanoate, propylene glycol 2-diethylhexanoate, and 0241. A cosmetic composition according to the present mixtures thereof, C to Cs alcohol benzoates, hexyl invention may also comprise at least one non-volatile oil. laurate, neopentanoic acid esters, for instance isode 0242. The non-volatile oils may be chosen for example cyl neopentanoate, isotridecyl neopentanoate, isos from non-volatile hydrocarbon-based oils, which are option tearyl neopentanoate and octyldodecyl neopen ally fluorinated, and/or non-volatile silicone oils. tanoate, isononanoic acid esters, for instance isononyl isononanoate, isotridecyl isononanoate and 0243 Non-volatile hydrocarbon-based oils also suitable octyl isononanoate, and hydroxylated esters, for for the embodiment of the invention that may for instance be mentioned include: instance isostearyl lactate and diisoStearyl malate; 0244 hydrocarbon-based oils of animal origin, 0252 polyol esters and pentaerythritol esters, for 0245 hydrocarbon-based oils of plant origin such as instance dipentaerythritol tetrahydroxystearate/tet phytostearyl esters, such as phytostearyl oleate, phy raisostearate; to Stearyl isostearate and lauroyl/octyldodecyl/phy 0253 esters of diol dimers and of diacid dimers, to Stearyl glutamate, for example sold under the name such as Lusplan DD-DA5(R) and Lusplan DD-DA7R, Eldew PS203 by Ajinomoto, triglycerides consisting of sold by the company Nippon Fine Chemical and fatty acid esters of glycerol, the fatty acids of which described in patent application FR 03/02809; may have chain lengths ranging from C to C, these 0254 fatty alcohols that are liquid at room tempera chains possibly being linear or branched, and saturated ture, with a branched and/or unsaturated carbon or unsaturated; these oils are for instance heptanoic or based chain containing from 12 to 26 carbon atoms, octanoic triglycerides, wheatgerm oil, Sunflower oil, for instance 2-octyldodecanol, isostearyl alcohol, grapeseed oil, sesame oil, corn oil, apricot oil, castor oleyl alcohol, 2-hexyldecanol, 2-butyloctanol and oil, shea oil, avocado oil, olive oil, soybean oil, Sweet 2-undecylpentadecanol: almond oil, palm oil, rapeseed oil, cotton seed oil, hazelnut oil, macadamia oil, jojoba oil, alfalfa oil, 0255 higher fatty acids such as oleic acid, linoleic poppy oil, pumpkin oil, marrow oil, blackcurrant oil, acid or linolenic acid, and mixtures thereof, and evening primrose oil, millet oil, barley oil, quinoa oil, rye oil, safflower oil, candlenut oil, passion flower oil 0256 dialkyl carbonates, the two alkyl chains pos or musk rose oil; shea butter; or alternatively caprylic/ sibly being identical or different, such as dicaprylyl capric acid triglycerides, for instance those sold by the carbonate sold under the name Cetiol CC(R) by Cog company Stearineries Dubois or those sold under the nis; names Miglyol 810R, 812R) and 818(R) by the company 0257 non-volatile silicone oils, for instance non Dynamit Nobel, volatile polydimethylsiloxanes (PDMS), polydim US 2007/01341.82 A1 Jun. 14, 2007 11

ethylsiloxanes comprising alkyl or alkoxy groups 0267 For the purposes of the invention, a pasty com that are pendent and/or at the end of a silicone chain, pound may for example have a hardness at 20° C. ranging these groups each containing from 2 to 24 carbon from 0.001 to 0.5 MPa and for instance from 0.002 to 0.4 atoms, phenyl silicones, for instance phenyl trime MPa. thicones, phenyl dimethicones, phenyl trimethylsi loxy diphenylsiloxanes, diphenyl dimethicones, 0268 Among the pasty compounds that may be used in diphenylmethyldiphenyl-trisiloxanes and 2-phenyl the composition according to the invention, mention may be made of lanolins and lanolin derivatives, for instance acety ethyl trimethylsiloxysilicates, and dimethicones or lated lanolins, oxypropylenated lanolins or isopropyl lano phenyltrimethicones with a viscosity of less than or late, and mixtures thereof. Esters of fatty acids or of fatty equal to 100 Cst, and mixtures thereof; alcohols may also be used. Such as those containing from 20 0258 and mixtures thereof. to 65 carbon atoms, for instance triisostearyl or cetylcitrate; arachidyl propionate; polyvinyl laurate; cholesterol esters, 0259. The non-volatile oils may be present in a compo for instance triglycerides of plant origin Such as hydroge sition according to the invention in a content ranging from nated plant oils, viscous polyesters and mixtures thereof. 5% to 90% by weight, from 25% to 80% by weight or from Triglycerides of plant origin that may be used include 40% to 70% by weight relative to the total weight of the hydrogenated castor oil derivatives, such as Thixinr(R) from composition. Rheox. Solid Fatty Substances 0269 Mention may also be made of polyesters resulting from the esterification of a carboxylic acid and of an 0260 The composition according to the invention may aliphatic hydroxycarboxylic acid ester. For example, Riso also comprise at least one solid fatty phase selected from the cast(R) DA-L (ester derived from the esterification reaction of group constituted of waxes and pasty fatty Substances, and hydrogenated castor oil with dilinoleic acid in proportions of mixtures thereof. 2 to 1) and Risocast(R) DA-H (ester resulting from the 0261) The wax is solid at room temperature (25°C.), with esterification of hydrogenated castor oil with isostearic acid a reversible solid/liquid change of state, having a melting in proportions of 4 to 3) sold by the Japanese company point of greater than 30°C., which may be up to 200° C., a Kokyu Alcohol Kogyo. hardness of greater than 0.5 MPa and having in the solid 0270. As pasty compounds that are for example suitable state an anisotropic crystal organization. for formulating the cosmetic compositions in accordance 0262. It may be a hydrocarbon-based wax, a fluoro wax with the present invention, mention may be made of hydro and/or a silicone wax and may be of animal, plant, mineral genated cocoglycerides. or synthetic origin. 0271 Mention may also be made of pasty silicone com 0263. It may be chosen, for example, from beeswax, pounds Such as high molecular weight polydimethylsilox carnauba wax, candelilla wax, paraffin waxes, hydrogenated anes (PDMS) and for instance those containing pendent castor oil, synthetic waxes, for instance polyethylene waxes chains of the alkyl or alkoxy type containing from 8 to 24 (preferably with a molecular weight of between 400 and carbon atoms, and having a melting point of 20–55°C., for 600) or Fischer-Tropsch waxes, silicone waxes, for instance instance Stearyl dimethicones, such as those sold by the alkyl or alkoxy dimethicones containing from 16 to 45 company Dow Corning under the trade names DC2503(R) carbon atoms, ceresins or oZokerites, for instance isoparaf and DC25514(R), and mixtures thereof. fins with a melting point of less than 40° C., such as EMW-0003 sold by the company Nippon Seirou, C.-olefin Dyestuff oligomers, such as the polymers Performa V(R) 825, 103 and 260 sold by the company New Phase Technologies; ethyl 0272. A cosmetic composition according to the invention ene-propylene copolymers, such as PerformaleneR EP 700, may also comprise at least one dyestuff. and microcrystalline waxes with a melting point of greater 0273 Such a dyestuff may be chosen, for example, from than 85°C., such as Hi-Mic(R) 1070, 1080, 1090 and 3080, water-soluble or water-insoluble, liposoluble or non-lipo sold by Nippon Seirou, and mixtures thereof soluble, organic or mineral dyestuffs, for instance of the type Such as pigments or nacres, conventionally used in cosmetic 0264. According to one particular embodiment, the compositions. wax(es) used in the cosmetic compositions in accordance with the present invention may be present in a content 0274 The term “pigments' should be understood as ranging from about 5% to about 30%, from about 5% to meaning white or coloured, mineral or organic particles that about 25%, from about 10% to about 20% or from about are insoluble in an aqueous solution, which are intended to 10% to about 15% by weight relative to the total weight of colour and/or opacify the resulting film. the composition. 0275. The pigments may be present in a proportion of 0265 A cosmetic composition in accordance with the from 0.5% to 30% by weight, from 5% to 25% by weight or present invention may also comprise at least one pasty from 10% to 20% by weight relative to the total weight of compound. the cosmetic composition. 0266 For the purposes of the present invention, the term 0276. As mineral pigments that may be used in the “pasty compound' means a fatty compound with a revers invention, mention may be made of titanium oxide, Zirco ible Solid/liquid change of state, and comprising at a tem nium oxide or cerium oxide, and also Zinc oxide, iron oxide perature of 23° C. a liquid fraction and a solid fraction. The or chromium oxide, ferric blue, manganese violet, ultrama term “pasty Substance' also means polyvinyl laurate. rine blue and chromium hydrate. US 2007/01341.82 A1 Jun. 14, 2007

0277. It may also be a pigment having a structure that tinted nacres sold for example by the company Engelhard may be, for example, of sericite/brown iron oxide/titanium under the names Nu-antique copper 340XB (Cloisonne) and dioxide/silica type. Such a pigment is sold, for example, Brown CL4509 (Chromalite); the nacres with a copper glint under the reference Coverleaf R NS or JS by the company sold for isntance by the company Engelhard under the name Chemicals and Catalysts, and has a contrast ratio in the Copper 340A (Timica); the nacres with a red glint sold for region of 30. example by the company Merck under the name Sienna fine (17386) (Colorona); the nacres with a yellow glint sold for 0278. The dyestuff may also comprise a pigment having instance by the company Engelhard under the name Yellow a structure that may be, for example, of silica microsphere (4502) (Chromalite); the red-tinted nacres with a golden type containing iron oxide. An example of a pigment having glint sold for example by the company Engelhard under the this structure is the product sold by the company Miyoshi name Sunstone G012 (Gemtone); the pink nacres sold for under the reference PC BALL(R) PC-LL-100 P, this pigment instance by the company Engelhard under the name Tan consisting of silica microspheres containing yellow iron opale G005 (Gemtone); the black nacres with a golden glint oxide. sold for example by the company Engelhard under the name 0279 Among the organic pigments that may be used in Nuantique bronze 240 AB (Timica); the blue nacres sold for the invention, mention may be made of carbon black, instance by the company Merck under the name Matte blue pigments of D&C type, lakes based on cochineal carmine or (17433) (Microna); the white nacres with a silvery glint sold on barium, strontium, calcium or aluminium, or alternatively for example by the company Merck under the name Xirona the diketopyrrolopyrroles (DPP) described in documents Silver, and the golden-green pinkish-orange nacres sold for EP-A-542669, EP-A-787730, EP-A-787731 and WO-A-96/ instance by the company Merck under the name Indian O8537. Summer (Xirona), and mixtures thereof. 0280 The term "nacres' should be understood as mean 0286 The cosmetic composition according to the inven ing coloured particles of any form, which may or may not be tion may also comprise at least one water-soluble or lipo iridescent, for example produced by certain molluscs in their soluble dye in a content ranging from 0.5% to 30% by shell, or alternatively synthesized, and which have a colour weight and for example ranging from 5% to 25% by weight effect via optical interference. relative to the total weight of the cosmetic composition. 0281. The nacres may be selected from the group con 0287. The liposoluble dyes are, for example, Sudan Red, stituted of nacreous pigments such as titanium mica coated DC Red 17, DC Green 6, B-carotene, soybean oil, Sudan with an iron oxide, mica coated with bismuth oxychloride, Brown, DC Yellow 11, DC Violet 2, DC Orange 5 and titanium mica coated with chromium oxide, titanium mica quinoline yellow. The water-soluble dyes are, for example, coated with an organic dye and also nacreous pigments beetroot juice or methylene blue. based on bismuth oxychloride. They may also be mica 0288 The cosmetic composition according to the inven particles at the Surface of which are Superposed at least two tion may also contain at least one material with a specific Successive layers of metal oxides and/or of organic dye optical effect. stuffs. 0289. This effect is different from a simple conventional 0282) Examples of nacres that may also be mentioned hue effect, i.e. a unified and stabilized effect as produced by include natural mica coated with titanium oxide, with iron standard dyestuffs, for instance monochromatic pigments. oxide, with natural pigment or with bismuth oxychloride. 0290 For the purposes of the invention, the term “stabi 0283 Among the commercially available nacres that may lized' means lacking the effect of variability of the colour be mentioned are the nacres Timica R, Flamenco(R) and with the angle of observation or in response to a temperature Duochrome R (on mica base) sold by the company Engel change. hard, the Timiron(R) nacres sold by the company Merck, the 0291 For example, this material may be selected from Prestige(R) nacres on mica base sold by the company Eckart the group constituted of particles with a metallic glint, and the Sunshine(R) nacres on synthetic mica base sold by the goniochromatic colouring agents, diffracting pigments, ther company Sun Chemical. mochromic agents, optical brighteners, and also fibres. Such 0284. The nacres may for example have a yellow, pink, as interference fibres. Needless to say, these various mate red, bronze, orange, brown and/or coppery colour or glint. rials may be combined so as to afford the simultaneous manifestation of two effects, or even of a novel effect in 0285 As illustrations of nacres that may be used in the accordance with the invention. context of the present invention, mention may be made of gold-coloured nacres sold for instance by the company 0292. The particles with a metallic glint that may be used Engelhard under the name Brilliant gold 212G (Timica), in the invention are for instance selected from the group Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 constituted of: (Chromalite) and Monarch gold 233X (Cloisonne); the 0293 particles of at least one metal and/or of at least bronze nacres sold for example by the company Merck one metal derivative, under the names Bronze fine (17384) (Colorona) and Bronze (17353) (Colorona) and by the company Engelhard under 0294 particles comprising a monomaterial or multi the name Super bronze (Cloisonne); the orange nacres sold material organic or mineral Substrate, at least partially for isntance by the company Engelhard under the names coated with at least one layer with a metallic glint Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) comprising at least one metal and/or at least one metal and by the company Merck under the names Passion orange derivative, and (Colorona) and Matte orange (17449) (Microna); the brown 0295 mixtures of the said particles. US 2007/01341.82 A1 Jun. 14, 2007

0296 Among the metals that may be present in the said 0303 Examples of pigments with a polymeric multilayer particles, mention may be made, for example, of Ag, Au, Cu, structure that may be mentioned include those sold by the Al, Ni, Sn, Mg, Cr, Mo, Ti, Zr, Pt, Va, Rb, W, Zn, Ge, Te and company 3M under the name Color Glitter(R). Se and mixtures or alloys thereof. Ag., Au, Cu, Al, Zn, Ni, 0304 Examples of liquid-crystal goniochromatic par Mo and Cr, and mixtures or alloys thereof (for example ticles that may be used include those sold by the company bronzes and brasses) are preferred metals. Chenix and also the product sold under the name Helicone(R) 0297. The term “metal derivatives” is intended to denote HC by the company Wacker. compounds derived from metals, such as oxides, fluorides, 0305 According to one embodiment, a composition chlorides and sulfides. according to the invention may comprise at least one dye stuff chosen, for example, from organic dyestuffs and inor 0298 Illustrations of these particles that may be men ganic dyestuffs, such as pigments and nacres, and materials tioned include aluminium particles, such as those sold under with a specific optical effect, and mixtures thereof. the names Starbrite 1200 EAC(R) by the company Siberline and Metalure(R) by the company Eckart. 0306 According to one embodiment, a composition according to the invention may comprise not more than 30% 0299 Mention may also be made of metal powders of by weight of dyestuff relative to the total weight of the copper or of alloy mixtures such as the references 2844 sold composition. by the company Radium Bronze, metallic pigments, for instance aluminium or bronze, such as those sold under the Fillers names RotosafeR 700 from the company Eckart, silica coated aluminium particles sold under the name Visionaire 0307 The cosmetic compositions in accordance with the Bright Silver(R) from the company Eckart, and metal alloy invention may also comprise at least one filler, of organic or particles, for instance the silica-coated bronze (alloy of mineral nature, which for example makes it possible to give copper and Zinc) powders sold under the name Visionaire them improved stability with regard to exudation. Bright Natural Gold(R) from the company Eckart. 0308 The term “filler should be understood as meaning 0300. They may also be particles comprising a glass colourless or white solid particles of any form, which are in an insoluble form and dispersed in the medium of the Substrate, for instance those sold by the company Nippon composition. Being of mineral or organic nature they make Sheet Glass under the name Microglass Metashine.R. it possible to impart body or rigidity to the composition, 0301 The goniochromatic colouring agent may be cho and/or softness, a matt effect and uniformity to the makeup. sen, for example, from interference multilayer structures and 0309 The fillers used in the compositions according to liquid-crystal colouring agents. the present invention may be of lamellar, globular or spheri 0302) Examples of symmetrical interference multilayer cal form, fibres or in any other form intermediate between structures that may be used in compositions produced in these defined forms. accordance with the invention are, for example, the follow 0310. The fillers according to the invention may or may ing structures: Al/SiO/Al/SiO/Al, pigments having this not be surface-coated, and for instance they may be surface structure being sold by the company Dupont de Nemours; treated with silicones, amino acids, fluoro derivatives or any Cr/MgF/Al/MgF/Cr, pigments having this structure being other Substance that promotes the dispersion and compat sold under the name Chromaflair R by the company Flex; ibility of the filler in the composition. MoS/SiO/Al/SiO/MoS. FeO/SiO/Al/SiO/FeO, and FeO/SiO/FeO/SiO/FeO, structures being sold under 0311 For the purposes of the present invention, the terms the name Sicopearl(R) by the company BASF: MoS/SiO/ “mineral fillers' and “inorganic fillers' are used inter mica oxide/SiO/MoS. FeO/SiO/mica oxide/SiO/ changeably. FeO: TiO/SiO/TiO, and TiO/Al2O/TiO, SnO/TiO/ 0312 Among the mineral fillers that may be used in the SiO/TiO/SnO; FeO/SiO/FeO: SnO/mica/TiO/SiO/ compositions according to the invention, mention may be TiO/mica/SnO, pigments having these structures being sold made of talc, mica, silica, trimethyl siloxysilicate, kaolin, under the name Xirona R by the company Merck (Darms bentone, precipitated calcium carbonate, magnesium car tadt). By way of example, these pigments may be the bonate, magnesium hydrogen-carbonate, hydroxyapatite, pigments of silica/titanium oxide?tin oxide structure sold boron nitride, hollow silica microspheres (Silica Beads(R) under the name Xirona Magic R) by the company Merck, the from Maprecos), glass or ceramic microcapsules, silica pigments of silica/brown iron oxide structure sold under the based fillers, for instance Aerosil(R) 200 or Aerosil(R) 300: name Xirona Indian Summer R by the company Merck and Sunsphere(R) L-31 and Sunsphere(R) H-31 sold by Asahi the pigments of silica/titanium oxide/mica?tin oxide struc ture sold under the name Xirona Caribbean Blue(R) by the Glass; Chemicelen(R) sold by Asahi Chemical; composites of company Merck. Mention may also be made of Infinite silica and of titanium dioxide, for instance the TSG series Colors(R pigments from the company Shiseido. Depending sold by Nippon Sheet Glass, and mixtures thereof. on the thickness and the nature of the various coats, different 0313 Among the organic fillers that may be used in the effects are obtained. Thus, with the structure FeO/SiO/ compositions according to the invention, mention may be Al/SiO/FeO, the colour changes from green-golden to made of polyamide powders (Nylon R. Orgasol from red-grey for SiO layers of from 320 to 350 nmi; from red to Atochem), poly-8-alanine powder and polyethylene powder, golden for SiO layers of from 380 to 400 nmi; from violet polytetrafluoroethylene powders (Teflon.R.), N-lauroyl-L- to green for SiO layers of from 410 to 420 nmi; from copper lysine, starch, tetrafluoroethylene polymer powders, hollow to red for SiO layers of from 430 to 440 nm. polymer microspheres such as Expancel(R) (Nobel Industrie), US 2007/01341.82 A1 Jun. 14, 2007 precipitated calcium carbonate, magnesium carbonate, mag 0321) The measurements are taken, for example, on the nesium hydrogen carbonate, metal Soaps derived from inner face of the forearm, washed and dried naturally at organic carboxylic acids containing from 8 to 22 carbon room temperature for 5 minutes. The cosmetic composition atoms and for example from 12 to 18 carbon atoms, for to be tested, for example a lipstick, is applied to five areas example Zinc Stearate, magnesium Stearate or lithium Stear of the inner face of the forearm. The area of skin on which ate, Zinc laurate or magnesium myristate, Polypore R L 200 the measurements are taken should be at least greater than 1 (Chemdal Corporation), silicone resin microbeads (for cm. In general, the measurements are taken on circular example Tospearl(R) from Toshiba), polyurethane powders, areas equal to about 3 cm in diameter. for instance powders of crosslinked polyurethane compris ing a copolymer, the said copolymer comprising trimethylol 0322. It is necessary for about the same amount of hexyllactone. For example, it may be a polymer of hexam cosmetic composition to be applied to each of the three ethylene diisocyanate/trimethylol hexylactone. Such par areas. This may be checked by measuring the weight of the first and the second cosmetic composition, after each of the ticles are for instance commercially available, for example, applications, or by preparing beforehand equivalent amounts under the name Plastic Powder D-400R) or Plastic Powder of sample to be tested. In general, for a surface area of 1 cm, D-800R from the company Toshiki, and mixtures thereof. an amount equal to about 2 mg is necessary (if the Surface 0314. A filler may be present in a cosmetic composition area has a diameter of 3 cm, then an amount of about 14 mg in accordance with the invention in a proportion of from is required). 0.5% to 40% by weight and for example from 5% to 30% by 0323. After applying the cosmetic composition, the weight of filler relative to the total weight of the composi colour, L*a*b*(C), is measured at each of the three tion. areas, and the mean value obtained corresponds to the initial 0315 A filler that is suitable for the invention may be, for colour of the product. The colour measurement may be example, a filler whose mean particle size is less than 100 performed using a Minolta colorimeter of the CR300, um and for instance between 1 and 50 um, for example CM500, CM1000 or CM2000 series. The Minolta calorim between 4 and 20 Lum. eter of the CR300 series is used in particular. 0324. The test of colour resistance to oil is performed by Additives applying to the test areas about 14 mg/cm of oil of food type 0316 A cosmetic composition according to the invention onto each area of the forearm (rapeseed oil, soybean oil or may, furthermore, also comprise any additive usually used in Sunflower oil) followed by manual massaging for a few the field under consideration, selected from the group con seconds, for example for 2 to 5 seconds and in instance for stituted of film-forming agents and, where appropriate, 2 seconds. A thickness of a commercial white paper hand auxiliary film-forming agents, gums, semi-crystalline poly kerchief Such as a Kleenex tissue is then applied to the area mers, gelling agents, antioxidants, essential oils, preserving for about 5 seconds at a force of about 100 g/f, this force agents, fragrances, neutralizers, moisturizers, antiseptics, possibly being applied using a DPZ-5N digital pressure vitamins such as vitamin B3 or E and derivatives thereof, dynamometer from the manufacturer Imada Co. Ltd. and anti-UV agents, and mixtures thereof. 0325 The value of the colour resistance to oil, H, is equal to the difference between the mean colour La'ab (C) of Colour Staying Power of the Composition the composition remaining on the forearm after massaging with oil and application of the handkerchief, and the mean 0317. The term “colour staying power' is intended to colour L*a*b*(C) initially measured, denote the property of a cosmetic composition according to the invention of transferring to a minimum extent onto objects with which it may come into contact, and the 0326. The test of colour resistance to oil is a test that for property of withstanding interaction with liquids, for example makes it possible to evaluate the remanence of a instance tears or Sweat, or contact with food during a meal, cosmetic composition Such as a lipstick during a meal. for instance in the case, for example, of lipstick, and the property of not migrating from the initial line of the makeup, 0327. For example, the colour resistance to oil of a for example in the case of lipsticks, into the wrinkles and deposit of a composition according to the invention, once fine lines around the lips. spread onto a Support, may be less than or equal to about 20, less than or equal to about 15, less than or equal to about 10, 0318. A film of cosmetic composition applied to the skin, or less than or equal to about 8. mucous membranes and/or the lips may generally be impaired during contact with liquids, Such as water or drinks consumed, for example, during a meal, or alternatively oils, Gloss and Gloss Staying Power for instance food oils, or else sebum or saliva. 0328. The term “gloss” is intended to denote the gloss of 03.19 Thus, the colour staying power of a cosmetic a composition as may be conventionally measured using a composition may be characterized by at least one of the gloSSmeter, via methods known to those skilled in the art. following parameters: the colour resistance to oil, the trans 0329. For example, the gloss may be measured using a fer resistance and the colour resistance to water. test performed in vitro using a Muti-Gloss 268 glossmeter (Minolta, Tokyo, Japan). 0320 Measurement of the colour resistance to oil may be an adequate parameter for characterizing a composition 0330. Such a test may be performed on a sample of according to the invention, and may be performed as fol Bio-Skin synthetic skin (of the type Fat-Skin Beaulax, lows. Tokyo, Japan) 3 cmx4.5 cm in size prepared by applying a US 2007/01341.82 A1 Jun. 14, 2007 first coat of cosmetic composition, for example a lipstick, in 0343 A composition according to the invention may be the direction of the length of the support, in the form of obtained by heating the various constituents to the melting continuous strips, so as to cover an area of 2.5 cm x4 cm. A point of the highest-melting waxes, followed by pouring the second coat of the composition is applied over the first coat molten mixture into a mould (crucible or finger stall). It may in a similar manner to the first, offset widthwise by about also be obtained by extrusion, as described in patent appli half the width of a strip in order to obtain a uniformly cation EP-A-0 667 146. covered surface. 0344) The present invention also relates to a cosmetic 0331. After applying the two coats of compositions, the method for making up and/or caring for the skin and/or the gloss is measured with a gloSSmeter by measuring the lips, comprising at least one step that consists in applying a reflectance at an angle of about 60° taken relative to the composition in accordance with the invention to at least part perpendicular to the Surface. The gloss is for example of a Support. measured 10 minutes after applying the cosmetic composi 0345 The present invention further relates to a cosmetic tion. method for the preparation of a cosmetic composition for 0332 The measurement is repeated, for example at least caring for and/or making up the skin and/or the lips, which five times, and a mean is determined of the values remaining has improved colour staying power comprising at least a after removing the lowest value and the highest value. step that consists in combining at least one ester of dimer dilicoleic acid and of polyol(s), or an ester thereof, the 0333. A composition according to the invention may viscosity of which, measured at 25° C., is greater than or have a gloss at least greater than or equal to 7, greater than equal to 20 000 mPa.s with at least one silicone surfactant. or equal to 8 and greater than or equal to 9. For example, said ester and said silicone surfactant may be 0334 The term “gloss staying power' is intended to as defined above. denote the remanence of the gloss of a composition as may 0346 According to another of its aspects, a subject of the be measured using a gloSSmeter via methods known to those present invention is a synthetic Support comprising a com skilled in the art. position in accordance with the invention on at least part of 0335 For example, the protocol as defined above may be its Surface. followed by applying a fabric to the sample of synthetic skin comprising the two coats of cosmetic compositions. Such a 0347 A cosmetic composition according to the invention may for example be in the form of a lip makeup and/or care fabric may be, for example, a Kleenex tissue. composition, Such as a lipstick, a lip balm or a gloss. 0336. The fabric may be applied using a press, for example of mass 1.5 kg, for a defined time, for example 2 0348 For the purposes of the present invention, and seconds, in a controlled manner with a rheometer (Exponet unless otherwise indicated, the word “one' should be under 32 texture). stood as meaning “at least one'. 0337 Next, the gloss of the sample is measured as 0349 The examples of compositions below are given as defined above, and the value obtained is indicative of the illustrations and with no limiting nature on the invention. CaC. 0338 A composition according to the invention may EXAMPLE 1. have a gloss staying power of greater than or equal to about 0350 4, for example greater than or equal to about 5, for example greater than about 6. 0339 According to one embodiment, a subject of the present invention is the use of at least one ester of dimer - Lipstick dilinoleic acid and of polyol(s) or an ester thereof, the Compound % mass viscosity of which, measured at about 25°C., is greater than Polyglyceryl-3 polymethylsiloxyethyl 1O.OO or equal to about 20 000 mPa.s, in combination with at least dimethicone (KF-6104 from Shin-Etsu) one volatile oil and at least one film-forming agent, for the Sononyl isononanoate 6.60 preparation of a cosmetic composition for caring for and/or Polybutylene S.OO Neopentylglycol dicaprate 2S.OO making up the skin and/or the lips, which has improved Hydrogenated polyisobutene S.OO gloss staying power, or even also improved colour staying BHT O.OS power. Silica dimethylsilylate 2.OO Polyglyceryl-2 isostearate 1O.OO 0340 For instance, the ester, the film-forming agent and dimerdilinoleate copolymer the volatile oil may be, for example, as defined above. (Hailuscent ISDA (HAI)) Bis-behenylisostearyl/phytosteryl- 5.60 0341. A composition in accordance with the invention dimerdilinoleyl dimerdilinoleate may be prepared in the usual manner by a person skilled in (Plandool-G (NFC)) the art. It may thus be in cast form, for example in the form Polyethylene (M = 500) 6.60 Candelilla wax 2.OO of a stick or wand, or in the form of a soft paste in a heating Polyglyceryl-2 trilisostearate 1O.OO bag or in the form of dishes that may be used by direct Sononyl isononanoate 3.00 contact or with a sponge. Titanium dioxide O.2O D&C Red 7 W O12 C O45 0342 For example, it may constitute a cast foundation, a ron oxides O.95 cast makeup rouge or eyeshadow, which is for instance Yellow 5 Lake O.85 coloured, a lipstick, a lip gloss or a concealer product. US 2007/01341.82 A1 Jun. 14, 2007 16

each other, a hydrogen atom or OR and OR" representing, -continued independently of each other, a C-C hydrocarbon-based monoalcohol residue. Lipstick 8. The composition according to claim 7, wherein R' and Compound % mass R" both represent a hydrogen atom. 9. The composition according to claim 7, wherein OR and Blue 1 Lake O.20 Ethylene glycol dimethacrylate/lauryl 1.00 OR" both represent an identical or different hydrocarbon methacrylate copolymer based monoalcohol residue. N-Lauroyl-L-lysine 1.00 10. The composition according to claim 1, comprising an Flamingo Orange 320 C 2.80 Timiron Super Silk O.SO ester of general formula (I) below: MP 1005 R OCO-R(-COO-R-OCO-R), COO Timiron Super Red 1.00 R (I) Simethicone O.20 wherein: TOTAL 1OO COR CO represents a dimerdilinoleate residue, ORO represents a fatty alcohol dimer residue, Procedure OR represents a hydrocarbon-based monoalcohol resi 0351. An oily phase is prepared by mixing, while heating due, and (about 95° C.), the oils, the silicone surfactant and the polyglyceryl-2 isoStearate dimerdilinoleate copolymer n is an integer ranging from 1 to 15. (Hailuscent ISDA). 11. The composition according to claim 10, wherein 0352. The oily phase thus prepared is stirred at about 95° ORO represents a dimerdilinoleyl residue. C. and the fillers are added to the mixture. 12. The composition according to claim 10, wherein OR represents a hydrocarbon-based monoalcohol residue 0353. The waxes, the pigments in the form of a pigmen selected from the group constituted of behenyl, isostearyl tary paste, prepared by mixing the dyestuffs with the polyg and phytosteryl residues, and mixtures thereof. lyceryl-2 triisoStearate, the isononyl isononanoate, the sim 13. (canceled) ethicone and the bis-behenyl/isostearyl/phytosteryl 14. The composition according to claim 1, comprising an dimerdilinoleyl dimerdilinoleate (Plandool-G) are then added to the mixture. ester of general formula (II) below: 0354) The mixture thus obtained is then poured into a lipstick mould and left to cool until a solid composition is (II) obtained. HO-R-C-O-C-R-C-O-R)-OH 0355 The gloss staying power of the composition is O O measured as described previously, and has a value of 6.3. wherein: 1. An anhydrous cosmetic composition for caring for and/or making up the skin and/or the lips, comprising at least n is an integer ranging from 1 to 15, one ester of dimerdilinoleic acid and of polyol(s) or an ester thereof, the viscosity of which, measured at about 25°C., is CORCO represents a dimerdilinoleate residue, greater than or equal to about 20 000 mPa.s, and at least one ORO represents a diglyceryl residue of general formula silicone surfactant. (III) below: 2. The composition according to claim 1, wherein the said ester has a molecular weight ranging from about 2000 to about 25 000 g/mol. (III) 3. The composition according to claim 1, wherein the O-(-CH-CH-CH-O-CH-CH-CH-O polyol is a diol. 4. The composition according to claim 2, wherein the O O ester comprises an alternating sequence of dimerdilinoleate R's R's residue(s) and of residue(s) related to the said diol(s). 5. The composition according to claim 3, wherein the diol is selected from the group constituted of a fatty alcohol wherein: dimer, a monoglycerol or polyglycerol, a C-C monoalky lene or polyalkylene glycol, 1,4-butanediol and pentaeryth R's represents H or OR's represents a fatty acid residue. ritol. 15. The composition according to claim 14, wherein the 6. The composition according to claim 5, wherein the fatty fatty acid residue featured by OR's is an isostearyl residue. alcohol dimer is the product of hydrogenation of a fatty acid 16. The composition according to claim 1, wherein the dimer obtained by dimerization of a C-C unsaturated fatty said ester is selected from the group constituted of the esters acid. having the following INCI nomenclature: polyglyceryl-2 7. The composition according to claim 4, wherein each of isostearate/dimerdilinoleate copolymer, bisbehenyl/isos the two ends of the said sequence respectively bears a unit tearyl/phytosteryl dimerdilinoleyl dimerdilinoleate, and OR" and OR", with R" and R" representing, independently of mixtures thereof. US 2007/01341.82 A1 Jun. 14, 2007 17

17. The composition according to claim 1, wherein it g and h are integers such that granges from 1 to 5 and comprises from 5% to 90% by weight of the said ester h ranges from 0 to 500. relative to the total weight of the composition. 20. The composition according to claim 19, wherein: 18. The composition according to claim 1, wherein the silicone surfactant is selected from the group constituted of a ranges from 1 to 1.4, and b and c, independently of each a polyhydroxylated silicone Surfactant and an emulsifying other, range from 0.02 to 0.04, and silicone resin or elastomer, and mixtures thereof. R" is a C to Co alkyl radical, 19. The composition according to claim 1, wherein the polyhydroxylated silicone surfactant is of general formula R’ is represented by the formula (VIA): (IV): —CHOICH-CH(OH)CH-OH (VIA) R',R,R, SiO4 bey2 (IV) wherein in ranges from 1 to 5, and wherein: R is represented by the formula (VIIA): a) a, b and c are such that a ranges from 1 to 2.5; and b and c, independently of each other, range from 0.001 to —C2H4(CH3)2SiO(CH3)2SiOSi(CH3)3 (VIIA) 1.5, wherein m ranges from 3 to 9. 21. The composition according to claim 20, wherein R' is b) R', which may be identical or different, is selected from a methyl radical. the group constituted of: 22. The composition according to claim 18, wherein the C to Co alkyl radicals, where appropriate Substituted polyhydroxylated silicone surfactant is selected from the with one or more fluorine atoms and amino and/or group constituted of polyglyceryl-3 polymethylsiloxyethyl carboxyl groups, dimethicone, laurylpolyglyceryl-3 polymethylsiloxyethyl dimethicone and polyglyceryl-3 disiloxane dimethicone, aryl and aralkyl radicals, and and mixtures thereof. the radicals of general formula (V): 23. The cosmetic composition according to claim 18, wherein the emulsifying silicone elastomer is selected from —CH2—O-(CHO) (CHO) R' (V) the group constituted of polyoxyalkylenated silicone elas wherein: tomers, and mixtures thereof. 24. The composition according to claim 1, further com R" is a C to Co. hydrocarbon-based radical or a prising at least one liquid fatty phase selected from the group radical R (Co)— with R being a C to Cso constituted of Volatile oils and non-volatile oils, and mix hydrocarbon-based radical, and tures thereof. d, e and fare integers such that d ranges from 0 to 25. The composition according to claim 24, wherein the 15, and e and f independently of each other, range said volatile oil is selected from the group constituted of: from 0 to 50, and hydrocarbon-based oils containing from 8 to 16 carbon combinations thereof, atoms, c) R is a radical represented by the general formula (VI): linear or cyclic silicone oils having a viscosity is 8 cen -Q-O-X (VI) tistokes (8x10 m/s), wherein: volatile fluoro oils such as nonafluoromethoxybutane or perfluoromethyl-cyclopentane, and Q is a divalent C to Co. hydrocarbon-based radical optionally including at least one ether bond and/or at mixtures thereof. least one ester bond, and 26. The composition according to claim 24, wherein the said non-volatile oil is selected from the group constituted of X is a polyhydroxylated hydrocarbon-based radical, oils of animal origin, oils of plant origin and oils of synthetic d) R is an organosiloxane group of general formula (VII): or mineral origin, and mixtures thereof. 27. The composition according to claim 1, further com prising at least one solid fatty phase selected from the group (VII) constituted of waxes and pasty fatty Substances, and mix R tures thereof. -CH2-(SiO)-SR, 28. The composition according to claim 1, further com prising at least one dyestuff. R 29. The composition according to claim 28, wherein the dyestuff is selected from the group constituted of organic with: dyestuffs and inorganic dyestuffs. 30. The composition according to claim 1, wherein it is in each of the radicals R representing, independently of the form of a Suspension, a dispersion, a solution, a gel, an each other, a radical selected from the group consti emulsion, or a multiple emulsion (W/O/W or polyol/O/W or tuted of C to Co alkyl radicals, where appropriate O/W/O) or in the form of a cream, a stick, a paste, a foam, substituted with one or more fluorine atoms, and aryl a vesicular dispersion, a two-phase or multi-phase lotion or and aralkyl radicals, a powder. US 2007/01341.82 A1 Jun. 14, 2007 18

31. The composition according to claim 1, said compo ORO represents a diglyceryl residue of general formula sition being a lip makeup and/or care composition. (m) below: 32. A cosmetic composition for caring for and/or making (III) up the skin and/or the lips, comprising at least one ester of O- (-CH-CH-CH-O-CH-CH-CH-) -O general formula (I) below: O O R–OCO-R(-COO R—OCO-R), COO R's R's R (I) wherein: wherein which: R's represents H or OR's represents a fatty acid residue, and comprising at least one silicone Surfactant. CORCO represents a dimerdilinoleate residue, 37. The composition according to claim 36, wherein the fatty acid residue featured by OR's is an isostearyl residue. ORO represents a fatty alcohol dimer residue, 38. The composition according to claim 36, said compo sition being anhydrous. OR represents a hydrocarbon-based monoalcohol resi 39. A cosmetic method for the preparation of a cosmetic due, and composition for caring for and/or making up the skin and/or the lips, which has improved colour staying power, com n is an integer ranging from 1 to 15, prising at least a step that consists in combining at least one ester of dimerdilinoleic acid and of polyol(s), or an ester and at least one silicone Surfactant. thereof, the viscosity of which, measured at 25°C., is greater than or equal to 20 000 mPa.s, with at least one silicone 33. The composition according to claim 32, wherein in Surfactant. which ORO represents a dimerdilinoleyl residue. 40. A cosmetic method for the preparation of a cosmetic 34. The CComposition according to claim 32, wherein in composition for caring for and/or making up the skin and/or which OR represents a hydrocarbon-based monoalcohol the lips, which has improved colour staying power, com prising at least a step that consists in combining at least one residue selected from the group constituted of behenyl, ester of dimerdilinoleic acid and of polyol(s), or an ester isostearyl and phytosteryl residues, and mixtures thereof. thereof, the viscosity of which, measured at 25°C., is greater 35. The composition according to claim 32, said compo than or equal to 20 000 mPa.s, with at least one silicone sition being anhydrous. Surfactant, wherein the said ester is as defined according to claim 1. 36. A cosmetic composition for caring for and/or making 41. A cosmetic method for the preparation of a cosmetic up the skin and/or the lips, comprising at least one ester of composition for caring for and/or making up the skin and/or general formula (II) below: the lips, which has improved colour staying power, com prising at least a step that consists in combining at least one (II) ester of dimerdilinoleic acid and of polyol(s), or an ester HO-R-C-O-C-R-C-O-R)-OH thereof, the viscosity of which, measured at 25°C., is greater than or equal to 20 000 mPa.s, with at least one silicone O O Surfactant, wherein the silicone surfactant is as defined according to claim 18. 42. The cosmetic method for making up and/or caring for wherein: the skin and/or the lips, comprising at least one step that consists in applying to at least a portion of the said Support n is an integer ranging from 1 to 15, a composition as defined according to claim 1. CORCO represents a dimerdilinoleate residue, k k k k k