US 200701341 82A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2007/0134.182 A1 Shimizu et al. (43) Pub. Date: Jun. 14, 2007 (54) COSMETC COMPOSITION COMPRISING (30) Foreign Application Priority Data AN ESTER OF DIMERDLINOLEC ACID AND OF POLYOLCS) AND A SILICONE Dec. 8, 2005 (FR)............................................ O5 53,797 SURFACTANT (75) Inventors: Momoko Shimizu, Tokyo (JP); Emiko Publication Classification Tokunaga, Kanagawa (JP) (51) Int. Cl. Correspondence Address: A6IR 8/37 (2006.01) OLIFF & BERRIDGE, PLC P.O. BOX 19928 (52) U.S. Cl. ........................................... 424/64; 424/70.31 ALEXANDRIA, VA 22320 (US) (73) Assignee: L'OREAL PARIS (FR) (57) ABSTRACT (21) Appl. No.: 11/635,006 The present invention relates to an anhydrous cosmetic (22) Filed: Dec. 7, 2006 composition for caring for and/or making up the skin and/or the lips, comprising at least one ester of dimerdilinoleic acid Related U.S. Application Data and of polyol(s) or an ester thereof, the viscosity of which, (60) Provisional application No. 60/754,189, filed on Dec. measured at about 25°C., is greater than or equal to about 28, 2005. 20 000 mPa.s, and at least one silicone surfactant. US 2007/01341.82 A1 Jun. 14, 2007 COSMETC COMPOSITION COMPRISING AN 0012 For example, the cosmetic composition according ESTER OF DIMERDLINOLEIC ACID AND OF to the invention has a gloss and/or a gloss staying power that POLYOLCS) AND A SILICONE SURFACTANT is/are not affected, or that is/are even improved. 0001. This non provisional application claims the benefit 0013 Thus, according to one of these aspects, one subject of French Application No. 05 53797 filed on Dec. 8, 2005 of the present invention is an anhydrous cosmetic compo and U.S. Provisional Application No. 60/754,189 filed on sition for caring for and/or making up the skin and/or the Dec. 28, 2005. lips, comprising at least one ester of dimerdilinoleic acid and of polyol(s) or an ester thereof, the viscosity of which, 0002 The present invention relates to cosmetic compo measured at about 25°C., is greater than or equal to about sitions for caring for and/or making up the skin and/or the 20 000 mPa.s, and at least one silicone surfactant. lips, comprising an ester of dimerdilinoleic acid and of polyol(s) and a silicone surfactant. 0014 For the purposes of the invention, the term “anhy drous composition” means a composition containing less 0003. The compositions according to the invention may than 5% by weight, less than 3% by weight, less than 2% by show improved gloss and/or colour staying power. weight, less than 1% by weight of water relative to the total weight of the composition. 0004 The present invention also relates to a process for making up the human face and/or body using a composition 00.15 According to another of its aspects, a subject of the according to the invention. present invention is a cosmetic composition for caring for and/or making up the skin and/or the lips, comprising at least 0005. A composition according to the invention may, for one ester of general formula (I) below: example, be a makeup and/or care product intended to be R–OCO-R(-COO R—OCO-R), COO applied to the body, for example the face, and/or the lips, and R (I) may be a lipstick, a lip balm, a lip pencil, a liquid or Solid foundation, for example cast as a stick or a dish, a concealer in which: product, a skin colouring product, an eye makeup product, 0016 CORCO represents a dimerdilinoleate residue, for instance an eyeliner, for example in pencil form, a mascara for example in cake form, or alternatively an 0017 ORO represents a fatty alcohol dimer residue, eyeshadow or a lip gloss. 0018 OR represents a hydrocarbon-based monoalcohol 0006. Many cosmetic compositions exist for which gloss residue, and properties and colour effect properties of the deposited film, after application to the skin and/or the lips, are desired. 0019 n is an integer ranging from 1 to 15, These properties generally contribute towards the desired and at least one silicone surfactant. aesthetic effect. 0020. According to another aspect, a subject of the 0007 Moreover, it is also required that this aesthetic present invention is a cosmetic composition for caring for effect be maintained over time, for example in the face of the and/or making up the skin and/or the lips comprising at least various external factors liable to affect its gloss and/or colour one ester of general formula (II) below: properties. 0008. In order to give cosmetic compositions good gloss (II) properties and for example good gloss staying power, it has HO-R-C-O-C-R-C-O-R)-OH been proposed to use "glossy oils such as oily polymers, for instance high-viscosity polybutenes, esters of fatty acids or O O of fatty alcohols with a high carbon number (typically greater than 16), or alternatively certain plant oils. in which: 0009. However, these compounds may under certain cir 0021 n is an integer ranging from 1 to 15, cumstances be tacky on application and/or over time, which may result in considerable unpleasant sensations and a 0022 COR'CO represents a dimerdilinoleate residue, feeling of discomfort for the user. 0023 ORO represents a diglyceryl residue of general 0010. The inventors have been able to observe, surpris formula (III) below: ingly, that the use of certain esters of dimerdilinoleic acid and of polyol(s), or an ester thereof, in combination with a silicone Surfactant, for instance polyglyceryl-3 polymethyl (III) siloxyethyl dimethicone, for preparing a cosmetic compo O-(-CH-CH-CH-O-CH-CH-CH-)-O sition, makes it possible to give these compositions O O improved colour staying power without affecting their com bination of aesthetic properties, such as the gloss effect and R's R" the gloss staying power, while at the same time affording a comfortable sensation on application. in which: 0011 For example, a cosmetic composition according to the invention may have the advantageous property of not 0024 R', reprepresents H or OR", reprepresents a fatty acid causing any tacky sensation after application. residue, and comprising at least one silicone surfactant. US 2007/01341.82 A1 Jun. 14, 2007 0025. According to another of its aspects, a subject of the 0037 As examples of alcohol residues that are suitable present invention is the use of at least one ester of dimer for use in the invention, mention may be made of hydro dilinoleic acid and of polyol(s) or an ester thereof, according carbon-based compounds comprising a hydroxyl function to the invention, in combination with at least one silicone and containing from 4 to 40 carbon atoms, from 6 to 36 Surfactant, for the preparation of a cosmetic care and/or carbon atoms, from 8 to 32 carbon atoms, f from 16 to 28 make-up composition with improved colour staying power. carbon atoms and from 18 to 24 carbon atoms. 0026. According to yet another of its aspects, a subject of 0038. As examples of monoalcohols that are suitable for the present invention is a process for making up and/or the invention, mention may be made, in a non-limiting caring for the skin and/or the lips, comprising at least one manner, of butanol, pentanol, propanol, hexanol, heptanol, step that consists in applying a composition in accordance octanol, decanol, dodecanol, hexadecanol, octadecanol, with the invention to at least part of a Support. eicosadecanol, phytosterol, isoStearol, Stearol, cetol, 0027. For example, the present invention makes it pos behenol, etc. sible to provide cosmetic compositions whose gloss staying power and/or gloss is not affected, or is even improved, Polvols while at the same time showing improved colour staying 0.039 The term “polyol is intended to denote any hydro power. carbon-based compound comprising at least two hydroxyl 0028. For instance, the present invention makes it pos functions and containing from 4 to 40 carbon atoms, from 6 sible to provide compositions whose colour staying power is to 36 carbon atoms, from 8 to 32 carbon atoms, from 16 to improved over time, for example with regard to various 28 carbon atoms and or from 18 to 24 carbon atoms. external attacking factors, such as meals or contact with 0040. The hydrocarbon-based chains may be interrupted, fabrics. where appropriate, by the presence of at least one heteroa 0029. For example, the present invention makes it pos tom, for example an oxygen atom. sible to provide cosmetic compositions that do not cause any 0041 A polyol or a polyol ester that is suitable for use in sensation of tack or discomfort when applied. the present invention may comprise, for example, from 2 to 12 hydroxyl functions, from 2 to 8 hydroxyl functions, or Ester of Dimerdilinoleic Acid and of Pollol(s) from 4 to 6 hydroxyl functions. 0030. In the expression “ester of dimerdilinoleic acid and of polyol(s) or an ester thereof, the term “or an ester 0042. Where appropriate, the hydroxyl functions, other thereof is intended to denote one of the derivatives of these than those already employed in an ester bond with the esters of dimerdilinoleic acid and of polyol(s) obtained dimerdilinoleic acid, may also be employed, wholly or either by reaction of alcohol function(s) of the polyol, which partly with other ester bonds via reactivity with acid mol are not employed in bonds of ester type with acid functions ecules other than the dimerdilinoleic acid.