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PMSE Washington F'2000 Preprint Template American Chemical Society Division of Polymeric Materials: Science and Engineering Spring 2009 PMSE Preprints Volume 100, Spring 2009 Salt Lake City, Utah, USA 22-26 March 2009 ISBN: 978-1-60560-960-7 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 www.proceedings.com Some format issues inherent in the e-media version may also appear in this print version. Copyright© (2009) by PMSE Division of ACS All rights reserved. Printed by Curran Associates, Inc. (2009) For permission requests, please contact PMSE Division of ACS at the address below. PMSE Division of ACS 5200 Bayway Drive Baytown, Texas 77520 Phone: (281) 834-0222 Fax: (281) 834-2395 [email protected] TABLE OF CONTENTS 6FDA-6FpDA as a Multipurpose Polymer: Synthesis and Influence of Casting Process on Gas Separation Properties of Ultra High MW 6FDA-6FpDA.........................................................................1 Javier de Abajo, Mariola Calle, José G. de la Campa, Carolina García-Sanchez, Angel E. Lozano, Antonio Hernandez, Angel Marcos-Fernandez, Dulce M. Muñoz, Laura Palacio, Pedro Pradanos, Alberto Tena Advances in Polymeric Systems .........................................................................................................................3 Eric Baer, A. Hiltner Characterization and Modelling of Organic Vapors Sorption, Diffusion and Swelling in High Free Volume Polynorbornene with Trimethyl-Silyl Side Groups .........................................................4 Michele Galizia, Maria Grazia De Angelis, Giulio Sarti Chlorine Resistant Membranes for Reverse Osmosis and Nanofiltration .....................................................5 James E. McGrath CO2 and Water Removal from Flue Gas...........................................................................................................6 M. Wessling, J. Potrek, D. Nijmeijer, S. Reijerkerk, K. Fischbein Corn (Sugars) Based Chemistries for the Polymer and Related Industries...................................................7 Michael Jaffe, George Collins, Anthony J. East, Willis Hammond, Zohar Ophir, Xianhong Feng, Paul Friedhoff Crosslinkable Polyimides for Natural Gas Purification ..................................................................................8 William J. Koros, Donald R. Paul, Adam Kratochvil Enhancing Gas Barrier by Confined Crystallization.......................................................................................9 A. Hiltner, Eric Baer Evolution of Gas Separation Membranes .......................................................................................................10 Donald R. Paul Gas Membrane Separations at MEDA™, The First 20 Years ......................................................................11 Greg Fleming Gas Transport Properties of Intrinsically Microporous Polymers...............................................................12 Ingo Pinnau, Sylvie Thomas, Michael D. Guiver, Naiying Du, Jingshe Song Graft Copolymer Coatings to Prevent Membrane Fouling...........................................................................13 Ravindra Revanur, Katrina Kratz, Kurt Breitenkamp, Bryan D. McCloskey, B.D. Freeman, Todd Emrick Hydrophilic-Hydrophobic Nanostructured Polymeric Materials for Desalination.....................................14 Ho Bum Park, B.D. Freeman, James E. McGrath Influence of Network Structural Modifications on the Properties of Crosslinked Poly(Ethylene Oxide) Copolymer Membranes for CO2 Separations............................................................18 D. S. Kalika, S. Kalakkunnath, M. K. Danquah, H. Lin, V. A. Kusuma, B.D. Freeman Novel Polymers of Intrinsic Microporosity for Membrane Gas Separation................................................19 Michael D. Guiver, Naiying Du, Jingshe Song, Gilles P. Robertson, Ingo Pinnau, Sylvie Thomas Permeability, Diffusivity and Solubility of Various Gases in Kurome Natural Lacquer Membranes ........................................................................................................................................................20 Kazukiyo Nagai, Tomomi Komatsuka, Takahisa Ishimura, Yoshimi Kamiya, Tetsuo Miyakoshi Physical Aging Behavior of Ultra-Thin Glassy Polymer Films.....................................................................22 Brandon W. Rowe, Donald R. Paul, B.D. Freeman Polydopamine: A Simple Membrane Modification to Increase Separation Efficiency...............................23 Bryan D. McCloskey, Ho Bum Park, B.D. Freeman Polymer-Based Materials for Separations Applications................................................................................24 B.D. Freeman Polymers with Sub-1-Nm Size Pores for Water Nanofiltration and Desalination Based on the Polymerization of Surfactant Liquid Crystals..........................................................................................25 Douglas L. Gin, Meijuan Zhou, Evan S. Hatakeyama, Parag R. Nemade, Brian R. Wiesenauer, Jason E. Bara, Robert L. Kerr, Richard D. Noble Removal of Volatile Organic Compounds from Water by Hydrophobic Polymer Membranes Containing Ionic Liquid ..............................................................................................................26 Tadashi Uragami, You Matsuoka, Eiji Fukuyama, Takashi Miyata Separation of Hematopoietic Stem and Progenitor Cells from Human Peripheral Blood Through Polyurethane Foaming Membranes Modified with Several Amino Acids ...................................28 Akon Higuchi, Siou-Ting Yang, Pei-Tsz Li Thermally Rearranged Polymers for Gas Separation Membranes ..............................................................29 Young Moo Lee Upper Bound: Past and Present.......................................................................................................................30 Lloyd M. Robeson Block and Graft Copolymers for Toughening Polylactide ............................................................................31 Marc Hillmyer Development of New Routes to Benign Polymeric Materials ........................................................................32 Geoffrey W. Coates Macromolecules and Materials Using Olefin Metathesis...............................................................................33 Robert H. Grubbs N-Heterocyclic Carbenes: Catalysts for Controlled Polymerization Reactions ..........................................34 Robert M. Waymouth, James L. Hedrick, Wohnee Jeong, Eun-Ji Shin, Darcy Culkin, Szilard Csihony Organocatalytic Polymerization: A Versatile Strategy for Polymer Synthesis ...........................................35 James L. Hedrick, Robert M. Waymouth, Fredrik Nederberg, Russell Pratt, Bas Lohmeier, Wohnee Jeong, Eun-Ji Shin, Nahrain Kamber, Darcy Culkin, Szilard Csihony Polymers Based Upon Building Blocks Derived from N-Heterocyclic Carbenes: Synthesis and Applications................................................................................................................................................36 Christopher W. Bielawski Application of Maleimide-Functional Poly(Lactide)s for the Preparation of Multi- Functional and Architectureally Diverse Polymers by Thiol-Ene ‘click' Chemistry ..................................37 Matthew J. Stanford, Ryan J. Pounder, Andrew P. Dove Block Polymer Templated Membranes for Ultrafiltration............................................................................38 Marc A. Hillmyer C3-Symmetric Amine Tris(Phenolate) Complexes of Group 4 and 14 Metals for the Highly Stereoselective, Solvent-Free Polymerization of Lactide ...............................................................................39 Matthew G. Davidson, Amanda J. Chmura, Catherine J. Frankis, Matthew D. Jones Ecobionanocomposites: New Bioplastics with Improved Use Temperatures ..............................................43 John R. Dorgan, Birgit Braun, Laura O. Hollingsworth Electrically Conducting 3-Dimensional Porous Scaffolds for Bone Regeneration ......................................45 M. Brett Runge, Mahrokh Dadsetan, Avudaiappan Maran, Michael J. Yaszemski Mixed Micelle Formation Through Stereocomplexation Between Enantiomeric Poly(Lactide) Block Copolymers .....................................................................................................................47 Kazuki Fukushima, Fredrik Nederberg, Sung Ho Kim, Jeremy P. K. Tan, Yi Yan Yang, Robert M. Waymouth, James L. Hedrick New Degradable Polymers Made from Natural Compounds Bile Acids by ROMP ...................................49 Julien E. Gautrot, Jie Zhang, Yu Shao, X. X. Zhu Novel Shape Memory Using Thermal Hysteresis of Crystalline Phase Transition in Cross- Linked Polybutylene Succinate........................................................................................................................51 Kazuhiko Inoue, Midori Yamashiro N-Trimethylsilyl Amines for Controlled Ring-Opening Polymerization of Amino Acid N- Carboxyanhydrides and Facile End Group Functionalization of Polypeptides ..........................................53 Hua Lu, Jianjun Cheng One-Pot Synthesis of Well-Defined Polyester Nanoparticles and their Post-Modification.........................54 Alice van der Ende, Evan J. Kravitz, Vasanth Sathiyakumar, Eva Harth Organic Nanoparticles Via Intramolecular Cross-Linking of Poly(Propargyl Glycolide) .........................56 Gregory L. Baker, Erin B. Vogel, Xuwei Jiang, M. R. Smith III Organometallic Catalysts for the ROP of Lactones and Cyclic Carbonates:
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