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Hydrazine Sulfate, 1% W/V) Turbidity Stock Solution I (Hydrazine Sulfate, 1% w/v) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 10/06/2014 Revision date: 05/15/2018 Supersedes: 10/06/2014 Version: 1.1 SECTION 1: Identification 1.1. Identification Product form : Mixtures Product name : Turbidity Stock Solution I (Hydrazine Sulfate, 1% w/v) Product code : LC26300 1.2. Recommended use and restrictions on use Use of the substance/mixture : For laboratory and manufacturing use only. Recommended use : Laboratory chemicals Restrictions on use : Not for food, drug or household use 1.3. Supplier LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 [email protected] - www.labchem.com 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin sensitization, Category H317 May cause an allergic skin reaction 1 Carcinogenicity Category H350 May cause cancer 1B Hazardous to the aquatic H402 Harmful to aquatic life environment - Acute Hazard Category 3 Hazardous to the aquatic H412 Harmful to aquatic life with long lasting effects environment - Chronic Hazard Category 3 Full text of H statements : see section 16 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H317 - May cause an allergic skin reaction H350 - May cause cancer H412 - Harmful to aquatic life with long lasting effects Precautionary statements (GHS-US) : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P261 - Avoid breathing mist, vapors, spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves, eye protection. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P308+P313 - IF exposed or concerned: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P405 - Store locked up. 05/15/2018 EN (English US) Page 1 Turbidity Stock Solution I (Hydrazine Sulfate, 1% w/v) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations P501 - Dispose of contents/container to comply with local, state and federal regulations 2.3. Other hazards which do not result in classification Other hazards not contributing to the : None under normal conditions. classification 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS -US classification Water (CAS-No.) 7732-18-5 99 Not classified Hydrazine Sulfate, ACS (CAS-No.) 10034-93-2 1 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation:dust,mist), H331 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Skin Sens. 1, H317 Carc. 1B, H350 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center/doctor/physician if you feel unwell. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects : May cause cancer. Symptoms/effects after inhalation : May cause an allergic skin reaction. Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Eye irritation. 4.3. Immediate medical attention and special treatment, if necessary Obtain medical assistance. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Reactivity : The product is non-reactive under normal conditions of use, storage and transport. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. 05/15/2018 EN (English US) 2/7 Turbidity Stock Solution I (Hydrazine Sulfate, 1% w/v) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Clean up any spills as soon as possible, using an absorbent material to collect it. 6.1.1. For non-emergency personnel Protective equipment : Safety glasses. Gloves. Emergency procedures : Evacuate unnecessary personnel. Only qualified personnel equipped with suitable protective equipment may intervene. Avoid breathing dust/fume/gas/mist/vapors/spray. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. Notify authorities if product enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Avoid breathing mist, vapors, spray. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Take all necessary technical measures to avoid or minimize the release of the product on the workplace. Limit quantities of product at the minimum necessary for handling and limit the number of exposed workers. Provide local exhaust or general room ventilation. Wear personal protective equipment. Floors, walls and other surfaces in the hazard area must be cleaned regularly. Avoid contact with skin and eyes. Hygiene measures : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep container closed when not in use. Store locked up. Store in a well-ventilated place. Keep cool. Incompatible products : Strong bases. Strong oxidizers. Incompatible materials : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Hydrazine Sulfate, ACS (10034 -93 -2) Not applicable Water (7732 -18 -5) Not applicable 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Material should be handled in a laboratory hood whenever possible. Environmental exposure
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