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SAFETY DATA SHEET Issuing Date 05-Jul-2016 Revision Date 05-Jul-2016 Revision Number 3 This safety data sheet was created pursuant to the requirements of 29 CFR 1910.1200 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Turbidity Product Number 893 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Laboratory use only Uses advised against No information available Details of the supplier of the safety data sheet Supplier ERA, A Waters Company Supplier Address 16341 Table Mountain Parkway, Golden, CO 80403 USA Non-Emergency Telephone Number +1-303-431-8454 E-mail address [email protected] Emergency telephone number Company Emergency Phone In case of EMERGENCY call CHEMTREC Day or Night Number Within USA and Canada: 800-424-9300 International Call Collect: +1-703-527-3887 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Skin sensitization Category 1 Carcinogenicity Category 1B GHS Label elements, including precautionary statements Emergency Overview Signal word Danger Hazard Statements Causes severe skin burns and eye damage May cause an allergic skin reaction May cause cancer _____________________________________________________________________________________________ Page 1 / 10 893 - Turbidity Revision Date 05-Jul-2016 _____________________________________________________________________________________________ . Appearance Clear to slightly cloudy Physical state Liquid Odor Odorless Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Precautionary Statements - Response Immediately call a POISON CENTER or doctor/physician Specific treatment (see supplemental first aid instructions on this label) Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Skin IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse If skin irritation or rash occurs: Get medical advice/attention Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Rinse mouth. DO NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0 % of the mixture consists of ingredient(s) of unknown toxicity Other information Harmful to aquatic life with long lasting effects Repeated or prolonged skin contact may cause allergic reactions with susceptible persons Interactions with Other Chemicals No information available. 3. COMPOSITION/INFORMATION ON INGREDIENTS Note: only the components contributing to the product's GHS hazard classification are listed in this section. Chemical name CAS No Weight-% _____________________________________________________________________________________________ Page 2 / 10 893 - Turbidity Revision Date 05-Jul-2016 _____________________________________________________________________________________________ Methenamine 100-97-0 0.25 - 3.75 Hydrazine Sulfate 10034-93-2 0.025 - 0.375 4. FIRST AID MEASURES First aid measures General Advice Immediate medical attention is required. Show this safety data sheet to the doctor in attendance. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Seek immediate medical attention/advice. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Seek immediate medical attention/advice. May cause an allergic skin reaction. Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If breathing is difficult, (trained personnel should) give oxygen. Delayed pulmonary edema may occur. Get medical attention immediately if symptoms occur. Ingestion Do NOT induce vomiting. Rinse mouth immediately and drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Use personal protective equipment as required. Wear personal protective clothing (see section 8). Most important symptoms and effects, both acute and delayed Most Important Symptoms and Burning sensation. Itching. Rashes. Hives. Effects Indication of any immediate medical attention and special treatment needed Notes to Physician Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause sensitization in susceptible persons. Treat symptomatically. _____________________________________________________________________________________________ Page 3 / 10 893 - Turbidity Revision Date 05-Jul-2016 _____________________________________________________________________________________________ 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media CAUTION: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases and vapors. Product is or contains a sensitizer. May cause sensitization by skin contact. Uniform Fire Code Corrosive: Other--Liquid Sensitizer: Liquid Hazardous Combustion Products Carbon oxides. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental precautions Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage if safe to do so. Should not be released into the environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. _____________________________________________________________________________________________ Page 4 / 10 893 - Turbidity Revision Date 05-Jul-2016 _____________________________________________________________________________________________ 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Use only with adequate ventilation and in closed systems. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture. Store locked up. Keep out of the reach of children. Store away from other materials. Incompatible Products Acids. Bases. Oxidizing agent. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems