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WCAP-17021-NP, Rev. 1, Westinghouse Non-Proprietary Class 3 WCAP-17021-NP January 2010 Revision 1 Summary of Tests to Determine the Physical Properties of Buffered and Un-buffered Boric Acid Solutions P)Westinghouse A WESTINGHOUSE NON-PROPRIETARY CLASS 3 WCAP-17021-NP Revision 1 Summary of Tests to Determine the Physical Properties of Buffered and Un-buffered Boric Acid Solutions William A. Byers, PhD Fellow Engineer, Materials Center of Excellence W. L. Brown Fellow Engineer, LOCA Integrated Services II B. E. Kellerman* Sr. Engineer, LOCA Integrated Services II K. S. Shearer* Project Lead, LOCA Integrated Services II D. J. Fink Project Manager, LOCA Integrated Services II January 2010 Approved: C. H. Boyd* Manager, LOCA Integrated Services II This work was preformed under PWR Owners Group Project Number PA-ASC-0264, Revision 2 *Electronically approved records are authenticated in the electronic document management system. Westinghouse Electric Company LLC P.O. Box 355 Pittsburgh, PA 15230-0355 © 2010 Westinghouse Electric Company LLC All Rights Reserved WCAP-17021-NP.doc ii RECORD OF REVISIONS WCAP- 17021-NP January 2010 Revision 1 1ii LEGAL NOTICE This report was prepared as an account of work performed by Westinghouse Electric Company LLC. Neither Westinghouse Electric Company LLC, nor any person acting on its behalf: A Makes any warranty or representation, express or implied including the warranties of fitness for a particular purpose or merchantability, with respect to the accuracy, completeness, or usefulness of the information contained in this report, or that the use of any information, apparatus, method, or process disclosed in this report may not infringe privately owned rights; or B Assumes any liabilities with respect to the use of, or for damages resulting from the use of, any information, apparatus, method, or process disclosed in this report. COPYRIGHT NOTICE This report has been prepared by Westinghouse Electric Company LLC and bears a Westinghouse Electric Company copyright notice. As a member of the PWR Owners Group, you are permitted to copy and redistribute all or portions of the report within your organization; however all copies made by you must include the copyright notice in all instances. DISTRIBUTION NOTICE This report was prepared for the PWR Owners Group. This Distribution Notice is intended to establish guidance for access to this information. This report (including proprietary and non-proprietary versions) is not to be provided to any individual or organization outside of the PWR Owners Group program participants without prior written approval of the PWR Owners Group Program Management Office. However, prior written approval is not required for program participants to provide copies of Class 3 Non-Proprietary reports to third parties that are supporting implementation at their plant, and for submittals to the NRC. WCAP- 17021-NP January 2010 Revision 1 iv PWR OWNERS GROUP MEMBER PARTICIPATION* FOR PROJECT/TASK PA-ASC-0264 REV. 2 Participant Utility Member Plant Site(s) Yes No AmerenUE Callaway (W) X American Electric Power D.C. Cook l&2 (W) X Arizona Public Service Palo Verde Unit 1, 2, & 3 (CE) X Constellation Energy Group Calvert Cliffs 1 & 2 (CE) X Constellation Energy Group Ginna (W) X Dominion Connecticut Millstone 2 (CE) X Dominion Connecticut Millstone 3 (W) X Dominion Kewaunee Kewaunee (W) X Dominion VA North Anna 1 & 2, Surry 1 & 2 (W) X Duke Energy Catawba I & 2, McGuire 1 & 2 (W), Oconee 1, 2, 3 (B&W) X Entergy Palisades (CE) X Entergy Nuclear Northeast Indian Point 2 & 3 (W) X Entergy Operations South Arkansas 2, Waterford 3 (CE), Arkansas 1 (B&W) X Exelon Generation Co. LLC Braidwood 1 & 2, Byron 1 & 2 (W), TMI 1 (B&W) X First Energy Nuclear Operating Co. Beaver Valley 1 & 2 (W), Davis-Besse (B&W) X Florida Power & Light Group St. Lucie I & 2 (CE) X Florida Power & Light Group Turkey Point 3 & 4, Seabrook (W) X Florida Power & Light Group Pt. Beach l&2 (W) X Luminant Power Comanche Peak I & 2 (W) X Omaha Public Power District Fort Calhoun (CE) X Pacific Gas & Electric Diablo Canyon 1 & 2 (W) X Progress Energy Robinson 2, Shearon Harris (W), Crystal River 3 (B&W) X PSEG - Nuclear Salem 1 & 2 (W) X Southern California Edison SONGS 2 & 3 (CE) X South Carolina Electric & Gas V. C. Summer (W) X So. Texas Project Nuclear Operating Co. South Texas Project 1 & 2 (W) X Southern Nuclear Operating Co. Farley 1 & 2, Vogtle 1 & 2 (W) X Tennessee Valley Authority Sequoyah I & 2, Watts Bar (W) X Wolf Creek Nuclear Operating Co. Wolf Creek (W) X Xcel Energy Prairie Island l&2 X * Project participants as of the date the final deliverable was completed. On occasion, additional members will join a project. Please contact the PWR Owners Group Program Management Office to verify participation before sending this document to participants not listed above. WCAP- 17021 -NP January 2010 Revision I V PWR OWNERS GROUP INTERNATIONAL MEMBER PARTICIPATION*FOR PROJECT/TASK PA-ASC-0264 REV. 2 Participant Utility Member Plant Site(s) Yes No British Energy Sizewell B X Electrabel (Belgian Utilities) Doel 1, 2 & 4, Tihange 1 & 3 X Hokkaido Tomari I & 2 (MHI) X Japan Atomic Power Company Tsuruga 2 (MI) X Kansai Electric Co., LTD Mihama 1, 2 & 3, Ohi 1, 2, 3 & 4, X Takahama 1, 2, 3 &4 (W & MHI) Korea Hydro & Nuclear Power Corp. Kori 1, 2, 3 & 4 X Yonggwang I & 2 (W) Korea Hydro & Nuclear Power Corp. Yonggwang 3, 4, 5 & 6 X Ulchin 3, 4, 5 & 6 (CE) Kyushu Genkai 1, 2, 3 & 4, Sendai 1 & 2 (MHI) X Nukleama Electrarna KRSKO Krsko (W) X Nordostschweizerische Kraftwerke AG Beznau 1 & 2 (W) X (NOK) Ringhals AB Ringhals 2, 3 & 4 (W) X Shikoku Ikata 1, 2 & 3 (MHI) X Spanish Utilities Asco I & 2, Vandellos 2, X Almaraz 1 & 2 (W) Taiwan Power Co. Maanshan 1 & 2 (W) X Electricite de France 54 Units X * This is a list of participants in this project as of the date the final deliverable was completed. On occasion, additional members will join a project. Please contact the PWR Owners Group Program Management Office to verify participation before sending documents to participants not listed above. WCAP- 17021-NP January 2010 Revision 1 vi TABLE OF CONTENTS L IST O F TA B LE S ...................................................................................................................................... vii LIST O F F IGU R E S ................................................................................................................................... v iii LIST OF ACRONYMS AND ABBREVIATIONS .................................................................................. ix EX E C U TIV E SU MM A RY ........................................................................................................................... x S IN T R O D U C T ION ........................................................................................................................ 1-1 1.1 B A C K G RO U N D ............................................................................................................. 1-1 1.2 PU RPO SE OF TH E TESTS ............................................................................................ 1-2 1.3 T E ST M AT R IX ................................................................................................................ 1-3 2 PHA SE 1: D EN SIT Y ................................................................................................................... 2-1 3 PH A SE 2: V ISC O SIT Y ............................................................................................................... 3-1 4 PHA SE 3: SURFA CE TEN SION ................................................................................................ 4-1 5 PHA SE 4: SOLUBILITY LIM ITS ......................................................................................... 5-1 6 C O N C L U SIO N S .......................................................................................................................... 6-1 7 RE F E R E N C E S ............................................................................................................................. 7-1 APPENDIX A DETAILED RESULTS OF DENSITY AND VISCOSITY TESTING ...................... A-i APPENDIX B DETAILED RESULTS OF SURFACE TENSION TESTING ................................... B-1 APPENDIX C DETAILED RESULTS OF SOLUBILITY TESTING .............................................. C-1 APPENDIX D CALIBRATION DATA FOR VISCOSITY MEASUREMENT ................................. D-1 APPENDIX E CALIBRATION DATA FOR SURFACE TENSION MEASUREMENT .......... E- 1 WCAP- 17021-NP January 2010 Revision 1 vii LIST OF TABLES Table 2-1 Results of Density Testing ............................................................................................... 2-2 Table 3-1 Results of Viscosity Testing ............................................................................................. 3-2 Table 4-1 Results of Surface Tension Testing .................................................................................. 4-2 Table 5-1 Boric Acid Precipitation Lim its ....................................................................................... 5-2 WCAP-17021-NP January 2010 Revision 1 viii LIST OF FIGURES Figure 2-1 Density of Buffered and Un-Buffered Boric Acid at 65.6°C ......................................... 2-4 Figure 2-2 Density of Buffered and Un-Buffered Boric Acid at 100.0°C ....................................... 2-4 Figure 2-3 Density of Buffered and Un-Buffered Boric Acid at 150'F .......................................... 2-5 Figure 2-4 Density of Buffered
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