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Safety Data Sheet SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Name of the substance Lithium oxide (Li2O) Identification number 235-019-5 (EC number) Synonyms Lithium oxide (Li2O) * Dilithium oxide * LITHIUM OXIDE Document number 1LW Materion Code 1LW Issue date 30-September-2013 Version number 04 Revision date 11-January-2018 Supersedes date 14-July-2015 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Not available. Uses advised against None known. 1.3. Details of the supplier of the safety data sheet Supplier Company name Materion Advanced Chemicals Inc. Address 407 N. 13th Street 1316 W. St. Paul Avenue Milwaukee, WI 53233 United States Division Milwaukee Telephone 414.212.0257 e-mail [email protected] Contact person Noreen Atkinson 1.4. Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture The substance has been assessed and/or tested for its physical, health and environmental hazards and the following classification applies. Classification according to Regulation (EC) No 1272/2008 as amended Health hazards Skin corrosion/irritation Category 1B H314 - Causes severe skin burns and eye damage. Serious eye damage/eye irritation Category 1 Hazard summary Causes serious eye damage. 2.2. Label elements Label according to Regulation (EC) No. 1272/2008 as amended Contains: Lithium oxide Hazard pictograms None. Signal word None. Hazard statements H314 Causes severe skin burns and eye damage. Precautionary statements Prevention P280 Wear eye protection/face protection. Response P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Material name: Lithium oxide (Li2O) SDS EU 1LW Version #: 04 Revision date: 11-January-2018 Issue date: 30-September-2013 1 / 8 P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P363 Wash contaminated clothing before reuse. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Supplemental label None. information 2.3. Other hazards None known. SECTION 3: Composition/information on ingredients 3.1. Substances General information Chemical name % CAS-No. / EC REACH Registration No. INDEX No. Notes No. Lithium oxide 90 - 100 12057-24-8 - - 235-019-5 Classification: Skin Corr. 1B;H314 List of abbreviations and symbols that may be used above CLP: Regulation No. 1272/2008. DSD: Directive 67/548/EEC. M: M-factor vPvB: very persistent and very bioaccumulative substance. PBT: persistent, bioaccumulative and toxic substance. #: This substance has been assigned Community workplace exposure limit(s). SECTION 4: First aid measures General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 4.1. Description of first aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Take off immediately all contaminated clothing. Wash off with soap and water. Chemical burns must be treated by a physician. Get medical attention if irritation develops and persists. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Ingestion Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical advice/attention if you feel unwell. 4.2. Most important Burning pain and severe corrosive skin damage. Causes serious eye damage. Permanent eye symptoms and effects, both damage including blindness could result. acute and delayed 4.3. Indication of any Treat symptomatically. Chemical burns: Flush with water immediately. While flushing, remove immediate medical attention clothes which do not adhere to affected area. Call an ambulance. Continue flushing during and special treatment transport to hospital. Keep victim under observation. needed SECTION 5: Firefighting measures General fire hazards No unusual fire or explosion hazards noted. 5.1. Extinguishing media Suitable extinguishing Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). media Unsuitable extinguishing None known. media 5.2. Special hazards arising During fire, gases hazardous to health may be formed. from the substance or mixture 5.3. Advice for firefighters Special protective Wear suitable protective equipment. equipment for firefighters Material name: Lithium oxide (Li2O) SDS EU 1LW Version #: 04 Revision date: 11-January-2018 Issue date: 30-September-2013 2 / 8 Special firefighting Use water spray to cool unopened containers. procedures Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear personnel appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. For emergency Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the SDS. responders 6.2. Environmental No special environmental precautions required. precautions 6.3. Methods and material for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is containment and cleaning up possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. 6.4. Reference to other For personal protection, see section 8 of the SDS. For waste disposal, see section 13 of the SDS. sections SECTION 7: Handling and storage 7.1. Precautions for safe Provide adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. handling Wear appropriate personal protective equipment. Observe good industrial hygiene practices. 7.2. Conditions for safe Store in original tightly closed container. Store away from incompatible materials (see Section 10 of storage, including any the SDS). incompatibilities 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits Sweden. OELs. Work Environment Authority (AV), Occupational Exposure Limit Values (AFS 2015:7) Material Type Value Form Lithium oxide (CAS Ceiling 0,02 mg/m3 Inhalable dust. 12057-24-8) Biological limit values No biological exposure limits noted for the ingredient(s). Recommended monitoring Follow standard monitoring procedures. procedures Derived no effect levels Not available. (DNELs) Predicted no effect Not available. concentrations (PNECs) 8.2. Exposure controls Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should controls be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment General information Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Skin protection - Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Material name: Lithium oxide (Li2O) SDS EU 1LW Version #: 04 Revision date: 11-January-2018 Issue date: 30-September-2013 3 / 8 - Other Wear suitable protective clothing. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing, when necessary. Hygiene measures Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental exposure Environmental manager must be informed of all major releases. controls SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Solid. Form
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