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Safety Data Sheet SAFETY DATA SHEET Revision Date 29-Feb-2020 Revision Number 3 1. Identification Product Name Spectroflux 135, Lithium tetraborate, Lithium fluoride, Strontium oxide & Vanadium(V) oxide, 84.9:8.4:4.6:2.1 w/w% Cat No. : 12091 Synonyms No information available Recommended Use Laboratory chemicals. Uses advised against Food, drug, pesticide or biocidal product use. Details of the supplier of the safety data sheet Company Alfa Aesar Thermo Fisher Scientific Chemicals, Inc. 30 Bond Street Ward Hill, MA 01835-8099 Tel: 800-343-0660 Fax: 800-322-4757 Email: [email protected] www.alfa.com Emergency Telephone Number During normal business hours (Monday-Friday, 8am-7pm EST), call (800) 343-0660. After normal business hours, call Carechem 24 at (866) 928-0789. 2. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute oral toxicity Category 4 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 1 Germ Cell Mutagenicity Category 2 Carcinogenicity Category 2 Reproductive Toxicity Category 2 Specific target organ toxicity - (repeated exposure) Category 2 Target Organs - Respiratory system. Label Elements Signal Word Danger ______________________________________________________________________________________________ Page 1 / 8 Spectroflux 135, Lithium tetraborate, Lithium fluoride, Revision Date 29-Feb-2020 Strontium oxide & Vanadium(V) oxide, 84.9:8.4:4.6:2.1 w/w% ______________________________________________________________________________________________ Hazard Statements Harmful if swallowed Causes skin irritation Causes serious eye damage May cause respiratory irritation Suspected of causing genetic defects Suspected of causing cancer Suspected of damaging the unborn child May cause damage to organs through prolonged or repeated exposure Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not breathe dust/fume/gas/mist/vapors/spray Response IF exposed or concerned: Get medical attention/advice Skin IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Storage Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Contact with acids liberates very toxic gas WARNING. Cancer - https://www.p65warnings.ca.gov/. 3. Composition/Information on Ingredients Component CAS-No Weight % Boron lithium oxide (B4Li2O7) 12007-60-2 84.9 Lithium fluoride 7789-24-4 8.4 Strontium oxide (SrO) 1314-11-0 4.6 Vanadium pentoxide 1314-62-1 2.1 4. First-aid measures ______________________________________________________________________________________________ Page 2 / 8 Spectroflux 135, Lithium tetraborate, Lithium fluoride, Revision Date 29-Feb-2020 Strontium oxide & Vanadium(V) oxide, 84.9:8.4:4.6:2.1 w/w% ______________________________________________________________________________________________ General Advice If symptoms persist, call a physician. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Inhalation Remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur. Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention if symptoms occur. Most important symptoms and Causes eye burns. Causes severe eye damage. effects Notes to Physician Treat symptomatically 5. Fire-fighting measures Unsuitable Extinguishing Media No information available Flash Point No information available Method - No information available Autoignition Temperature Not applicable Explosion Limits Upper No data available Lower No data available Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Oxides of boron. Lithium oxide. Hydrogen fluoride. Strontium oxide. Vanadium oxides. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Flammability Instability Physical hazards 4 0 0 N/A 6. Accidental release measures Personal Precautions Ensure adequate ventilation. Use personal protective equipment as required. Avoid dust formation. Environmental Precautions Should not be released into the environment. See Section 12 for additional Ecological Information. Do not allow material to contaminate ground water system. Do not flush into surface water or sanitary sewer system. Methods for Containment and Clean Sweep up and shovel into suitable containers for disposal. Keep in suitable, closed Up containers for disposal. ______________________________________________________________________________________________ Page 3 / 8 Spectroflux 135, Lithium tetraborate, Lithium fluoride, Revision Date 29-Feb-2020 Strontium oxide & Vanadium(V) oxide, 84.9:8.4:4.6:2.1 w/w% ______________________________________________________________________________________________ 7. Handling and storage Handling Wear personal protective equipment/face protection. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Avoid dust formation. Storage Keep containers tightly closed in a dry, cool and well-ventilated place. 8. Exposure controls / personal protection Exposure Guidelines Component ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL (TWA) Boron lithium oxide TWA: 2 mg/m3 (B4Li2O7) STEL: 6 mg/m3 Lithium fluoride TWA: 2.5 mg/m3 (Vacated) TWA: 2.5 mg/m3 IDLH: 250 mg/m3 TWA: 2.5 mg/m3 TWA: 2.5 mg/m3 Vanadium pentoxide TWA: 0.05 mg/m3 IDLH: 35 mg/m3 TWA: 0.05 mg/m3 Ceiling: 0.05 mg/m3 Legend ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH IDLH: NIOSH - National Institute for Occupational Safety and Health Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location. Personal Protective Equipment Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Powder Solid Appearance White to off-white Odor No information available Odor Threshold No information available pH Not applicable Melting Point/Range No data available Boiling Point/Range No information available Flash Point No information available Evaporation Rate Not applicable Flammability (solid,gas) No information available Flammability or explosive limits Upper No data available Lower No data available Vapor Pressure No information available Vapor Density Not applicable Specific Gravity No information available ______________________________________________________________________________________________ Page 4 / 8 Spectroflux 135, Lithium tetraborate, Lithium fluoride, Revision Date 29-Feb-2020 Strontium oxide & Vanadium(V) oxide, 84.9:8.4:4.6:2.1 w/w% ______________________________________________________________________________________________ Solubility No information available Partition coefficient; n-octanol/water No data available Autoignition Temperature Not applicable Decomposition Temperature No information available Viscosity Not applicable 10. Stability and reactivity Reactive Hazard Yes Stability Stable under normal conditions. Conditions to Avoid Incompatible products. Incompatible Materials Strong oxidizing agents, Acids Hazardous Decomposition Products Oxides of boron, Lithium oxide, Hydrogen fluoride, Strontium oxide, Vanadium oxides Hazardous Polymerization Hazardous polymerization does not occur. Hazardous Reactions None under normal processing. 11. Toxicological information Acute Toxicity Product Information Oral LD50 Category 4. ATE = 300 - 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Mist LC50 Based on ATE data, the classification criteria are not met. ATE > 5 mg/l. Component Information Component LD50 Oral LD50 Dermal LC50 Inhalation Lithium fluoride 143 mg/kg Not listed Not listed Vanadium pentoxide 474 mg/kg ( Rat, male ) LD50 = 50 mg/kg ( Rabbit
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