DOCSLIB.ORG

Catalytic Conversion of Direct Process High-Boiling Component to Chlorosilane Monomers in the Presence of Hydrogen Chloride

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Catalytic Conversion of Direct Process High-Boiling Component to Chlorosilane Monomers in the Presence of Hydrogen Chloride Europaisches Patentamt 19 European Patent Office Office europeen des brevets © Publication number : 0 635 51 0 A1 12 EUROPEAN PATENT APPLICATION © Application number : 94304886.8 © int. ci.6: C07F 7/12, C07F 7/16 @ Date of filing : 04.07.94 © Priority : 19.07.93 US 94593 Inventor : Halm, Roland Lee 507 Brentwood Drive Madison, Indiana (US) @ Date of publication of application Inventor : Dhaul, Ajay Kumar 25.01.95 Bulletin 95/04 710 Highland Avenue, Apt.7 @ Designated Contracting States : Carrollton, Kentucky (US) DE FR GB Inventor : Johnson, Richard Gordon Route 2, Box 492-E8 © Applicant : DOW CORNING CORPORATION Hanover, Indiana (US) P.O. Box 994 Midland, Michigan 48686-0994 (US) © Representative : Bullows, Michael Dow Corning Limited, © Inventor : Chadwick, Kirk Michael Cardiff Road 7 Erw'r Delyn Close Barry, South Glamorgan CF63 7YL, Wales (GB) Penarth, South Glamorgan (GB) © Catalytic conversion of direct process high-boiling component to chlorosilane monomers in the presence of hydrogen chloride. © The present invention is a process for con- verting a high-boiling component resulting from the reaction of an organochloride with silicon into commercially more desirable mono- silanes. The process comprises contacting the high-boiling component with hydrogen chloride at a temperature within a range of 250°C. to 1000°C. in the presence of a catalyst selected from activated carbon, platinum supported on alumina, zeolite, AICI3 and AICI3 supported on a support selected from carbon, alumina and sili- ca. < O In m CO CO LU Jouve, 18, rue Saint-Denis, 75001 PARIS 1 EP0 635 510 A1 2 The present invention is a process for converting ess. a high-boiling component, resulting from the reaction Our process may be run in any standard type re- of an organochloride with silicon, into more commer- actor for contacting silanes and hydrogen chloride. cially desirable monosilanes. The process comprises The process may be run as a batch process, semi- contacting the high-boiling component with hydrogen 5 continuous or continuous process. The process can chloride at a temperature within a range of 250°C. to be run, for example, in a fixed-bed reactor, a stirred- 1000°C. in the presence of a catalyst selected from bed reactor or a fluidized-bed reactor. Preferred is activated carbon, platinum supported on alumina, when the process is run as a continuous process in a zeolite, AICI3 and AICI3 supported on a support select- fluidized-bed reactor. ed from carbon, alumina and silica. 10 This present process is useful for converting a The high- boiling component useful in our process high-boiling component resulting from the reaction of results from a process typically referred to as the "Di- an organochloride with silicon to form monosilanes. rect Process," where an organohalide is reacted with The term "high-boiling component" refers to those silicon in the presence of a suitable catalyst to form materials with a boiling point above that of the diorga- monosilanes. The Direct Process is described more 15 nodichlorosilane formed by the reaction of the orga- fully in US-A 2,380,995 and US-A 2,488,487. It is the nochloride with silicon. For example when methyl main commercial process by which organohalosi- chloride is reacted with silicon, the diorganodichloro- lanes(i.e. monosilanes), for example dimethyldichlor- silane will be dimethyldichlorosilane and the high- osilane and trimethylchlorosilane, are formed. These boiling component will comprise those materials hav- organohalosilanes are reactive compounds which 20 ing a boiling point greaterthan that of dimethyldichlor- can undergo numerous reactions to form a variety of osilane, i.e. greater than 70°C. useful silicon containing compounds and polymers. A In a typical process for reacting an organochlor- major commercial use of organohalosilanes is in the ide with silicon, the reaction is conducted at a temper- production of polysiloxane polymers which are useful ature of 270°C. to 350°C., in the presence of a suit- as heat transfer fluids, lubricants and the like and 25 able catalyst. Gaseous product and unreacted feed which can be further processed, for example, to form are continuously removed from the process. The re- silicone elastomers, resins, sealants and adhesives. moved gaseous product and unreacted feed are sub- Operation of the Direct Process results not only sequently distilled to remove monosilanes leaving in the production of the desirable monosilanes, but behind a high-boiling component. also in a high boiling component typically considered 30 The high-boiling component is a complex mixture to be all materials with a boiling point higher than the that can include compounds containing SiSi, SiOSi, particular diorganodihalosilane produced in the proc- SiCSi, SiCCSi and SiCCCSi linkages alone or in com- ess. The high-boiling component is a complex mix- bination in each molecule. The high-boiling compo- ture that includes compounds containing SiSi, SiOSi, nent can include silicon containing solids and soluble SiCSi, SiCCSi and SiCCCSi linkages in the mole- 35 and insoluble compounds of copper, aluminum and cules. Typical compounds are described in US-A zinc. The high-boiling component may contain, for ex- 2,598,435 and US-A 2,681,355. The high-boiling ample, organic substituted and non-organic substitut- component may also comprise silicon containing sol- ed silanes, disilanes, trisilanes, disiloxanes, silane ids and soluble and insoluble compounds of copper, oligomers, siloxane oligomers, silalkylenes and sili- aluminum and zinc. 40 con containing solids, all of which may be converted In current commercial operations for performing to monosilanes by our process. the Direct Process, the high-boiling component can The present process is especially useful for con- constitute as much as ten percent of the resultant verting polysilanes in the high-boiling component to product. Therefore, it is desirable to convert the high- monosilanes, where the polysilanes are described by boiling component into more commercially desirable 45 formula RaHbSinCI2n+2- a- b and where each R is a rad- products to both reduce low-value by-products and to ical independently selected from alkyls comprising improve raw material utilization. one to six carbon atoms, n = 2 to 20, a = 0 to 2n+2, b The prior art for converting the high-boiling com- = 0 to 2n+2 and a+b = 0 to 2n+2. ponent of the Direct Process into more usable mono- The polysilanes useful in the present process can silanes is represented by US-A 2,598,435; US-A so consist of n number of silicon atoms where n is an in- 2,681,355; US-A2,709,176 and US-A 2,842,580. teger from two to 20. Preferred is when n equals two. The aforementioned problems of the prior art are The polysilanes can be substituted with a=0 to 2n+2 solved by a catalyzed process for the high conversion number of R radicals, where each R is independently of a high-boiling component produced by the Direct selected from alkyls of one to six carbon atoms. The Process to monosilanes. Further, it is unexpected that 55 radical Rcan be methyl, ethyl, propyl and t-butyl. Pre- such a catalyzed process could employ readily avail- ferred is when R is methyl. able and inexpensive catalysts which can be easily The polysilanes in the high-boiling component retained in a reactor and have a long life in said proc- can contain b number of hydrogen atoms substituted 2 3 EP0 635 510 A1 4 on the silicon atoms, where b = 0 to 2n+2. der or pellets. The polysilanes in the high-boiling component In general, it is preferred that the activated carbon can also contain from zero to 2n+2 chlorine atoms. have a diameter within a range of 0.001 mm to 20 mm. The high-boiling component can contain silalky- More preferred is when the activated carbon has a di- lenes, where each silalkylene can comprise one or 5 ameter within a range of 0.01 mm to 5 mm and a sur- more silalkylene bonds described by formula Si(C)zSi face area greater than 1000 m2/g. and z is an integer from one to six. Preferred is when The weight of activated carbon in relation to the z is an integer from one to three. The silalkylene mol- weight of high-boiling componentand hydrogen chlor- ecules can comprise SiSi bonds and SiOSi bonds as ide added to the process will depend upon such fac- well as silalkylene bonds. The silicon atoms of the si- 10 tors as the type and size of the activated carbon, the lalkylene molecules can be further substituted with chemical composition of the high-boiling component, the radical R, where R is as previously described, with the process temperature and the type of reactor em- chlorine and with hydrogen. Preferred is when the sil- ployed. When the process is run as a batch or a semi- icon atoms of the silalkylenes are substituted with continuous process, a useful weight of activated car- methyl. is bon is considered to be within a range of 0.1 to 30 The preferred high-boiling component is one re- weight percent of the combined weight of the high- sulting from the reaction of methyl chloride with silicon, boiling component and the hydrogen chloride added the high-boiling component having a boiling point great- to the process. er than 70°C. This high-boiling component can contain The catalyst can be platinum supported on alumi- Me2CISiSiMe2CI, Me2CISiSiMeCI2, MeCI2SiSiMeCI2, 20 na. The amount of platinum can be from 0.1 to 10 Me2CISiSi(Me)(CI)SiMeCI2, Me2CISiCH2SiMe2CI, weight percent platinum. Preferred is when the Me2 CISiCH2SiMeCI2, MeCI2SiCH2SiMeCI2, Me2CIS amount of platinum is within a range of 0.5 to 2.0 (CH2)2SiMeCI2, Me2CISi(CH2)3SiMeCI2, Me2CISiCH2 weight percent.
Load more

Recommended publications
  • Synthesis of Functionalized Poly(Dimethylsiloxane)S and the Preparation of Magnetite Nanoparticle Complexes and Dispersions
    Synthesis of Functionalized Poly(dimethylsiloxane)s and the Preparation of Magnetite Nanoparticle Complexes and Dispersions Kristen Wilson O’Brien Dissertation submitted to the Faculty of the Virginia Polytechnic Institute and State University in partial fulfillment of the requirements for the degree of Doctor of Philosophy In Chemistry Approved by: ____________________________ Judy S. Riffle, Chair ____________________________ ____________________________ Alan Esker Jack Lesko ____________________________ ____________________________ Timothy E. Long James E. McGrath August 21, 2003 Blacksburg, Virginia Keywords: Polymers, iron oxides; steric stabilization; magnetic fluids Copyright 2003, Kristen Wilson O’Brien Synthesis of Functionalized Poly(dimethylsiloxane)s and the Preparation of Magnetite Nanoparticle Complexes and Dispersions Kristen Wilson O’Brien (ABSTRACT) Poly(dimethylsiloxane) (PDMS) fluids containing magnetite nanoparticles stabilized with carboxylic acid-functionalized PDMS were prepared. PDMS-magnetite complexes were characterized using transmission electron microscopy, elemental analysis, and vibrating sample magnetometry. PDMS-magnetite complexes containing up to 67 wt% magnetite with magnetizations of ~52 emu gram-1 were prepared. The magnetite particles were 7.4 ± 1.7 nm in diameter. Calculations suggested that the complexes prepared using mercaptosuccinic acid-functionalized PDMS (PDMS-6COOH) complexes contained unbound acid groups whereas the mercaptoacetic acid- functionalized PDMS (PDMS-3COOH) complexes did not.
    [Show full text]
  • Catalytic Conversion of Direct Process High-Boiling Component To
    Patentamt |||| ||| 1 1|| ||| ||| ||| || || || || ||| |||| || JEuropaischesJ European Patent Office Office europeen des brevets (11) EP 0 635 510 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int. CI.6: C07F 7/1 2, C07F7/16 of the grant of the patent: 24.02.1999 Bulletin 1999/08 (21) Application number: 94304886.8 (22) Date of filing: 04.07.1994 (54) Catalytic conversion of direct process high-boiling component to chlorosilane monomers in the presence of hydrogen chloride Katalytische Umsetzung von hochsiedenden RLickstanden der Direktsynthese in Chlorosilanmonomere in Gegenwart von Chlorwasserstoff Conversion catalytique du residu a point d'ebullition eleve obtenu par le procede direct en chlorosilanes monomeres en presence de chlorure d'hydrogene (84) Designated Contracting States: • Dhaul, Ajay Kumar DE FR GB Carrollton, Kentucky (US) • Johnson, Richard Gordon (30) Priority: 19.07.1993 US 94593 Hanover, Indiana (US) (43) Date of publication of application: (74) Representative: 25.01.1995 Bulletin 1995/04 Spott, Gottfried, Dr. et al Patentanwalte (73) Proprietor: Spott, Weinmiller & Partner DOW CORNING CORPORATION Sendlinger-Tor-Platz 11 Midland, Michigan 48686-0994 (US) 80336 Munchen (DE) (72) Inventors: (56) References cited: • Chadwick, Kirk Michael EP-A- 0 082 969 EP-A-0155 626 Penarth, South Glamorgan (GB) EP-A- 0 537 740 EP-A- 0 564 109 • Halm, Roland Lee EP-A- 0 574 912 EP-A- 0 634 417 Madison, Indiana (US) FR-A- 1 093 399 US-A- 2 709 176 US-A- 3 432 537 CO o LO LO CO Note: Within nine months from the publication of the mention of the grant of the European patent, give CO any person may notice to the European Patent Office of opposition to the European patent granted.
    [Show full text]
  • 1240 Date: December 1999 Revision: January 2009 DOT Number: UN 2534
    Right to Know Hazardous Substance Fact Sheet Common Name: METHYL CHLOROSILANE Synonym: Chloromethylsilane CAS Number: 993-00-0 Chemical Name: Silane, Chloromethyl- RTK Substance Number: 1240 Date: December 1999 Revision: January 2009 DOT Number: UN 2534 Description and Use EMERGENCY RESPONDERS >>>> SEE LAST PAGE Methyl Chlorosilane is a colorless gas with a distinctive odor. Hazard Summary It is used to make water repellant materials. Hazard Rating NJDOH NFPA HEALTH 3 - FLAMMABILITY 4 - REACTIVITY 2 W - CORROSIVE FLAMMABLE AND REACTIVE Reasons for Citation POISONOUS GASES ARE PRODUCED IN FIRE f Methyl Chlorosilane is on the Right to Know Hazardous CONTAINERS MAY EXPLODE IN FIRE Substance List because it is cited by DOT. f This chemical is on the Special Health Hazard Substance Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious; 4=severe List. f Methyl Chlorosilane can affect you when inhaled. f Methyl Chlorosilane is a DOT CORROSIVE material and contact can severely irritate and burn the skin and eyes. f Inhaling Methyl Chlorosilane can irritate the nose, throat and lungs. f Methyl Chlorosilane can cause chronic bronchitis with SEE GLOSSARY ON PAGE 5. coughing, phlegm and shortness of breath. f Methyl Chlorosilane is FLAMMABLE and REACTIVE and a DANGEROUS FIRE and EXPLOSION HAZARD. FIRST AID Eye Contact f Immediately flush with large amounts of water for at least 30 minutes, lifting upper and lower lids. Remove contact Workplace Exposure Limits lenses, if worn, while flushing. Seek medical attention No occupational exposure limits have been established for immediately. Methyl Chlorosilane. However, it may pose a health risk. Always follow safe work practices.
    [Show full text]
  • United States Patent Office Patented Feb
    3,168,542 United States Patent Office Patented Feb. 2, 1965 2 It is also often desired to separate mixtures of chloro 3,168,542 silanes having different organic substitutents attached to PROCESS FOR SEPARATENG MEXTURES OF silicon thereof into individual chlorosilane portions where CHOROSLANES EEgyd H. Saaffer, Sayder, N.Y., assignor to Unioia Car in each portion contains specific chlorosilanes having the bide Corporation, a corporation of New York same organic substituents attached to silicon thereof. No Drawing. Fied May 15, 1957, Ser.3. No. 659,204 Illustratively, in the manufacture of vinyl silicone elas 23 Claims. (C. 260-44S.2) tomers the proportion of vinyl groups contained by the elastomer affects the properties of the elastomers. By This invention relates to chlorosilanes and in particular controlling the amount of vinyl siloxane groups com to a process for separating specific chlorosilanes from mix O bined in the elastomers, the properties of such elasto tures of different chlorosilanes. mers can be controlled substantially as desired. This It is often desirable to separate mixtures of chloro can be advantageously accomplished by regulating the silanes of different functionalities into chlorosilane por relative amounts of substantially pure vinyl chlorosilanes tions such that each portion contains only chlorosilanes and coreacting chlorosilanes. When low purity chloro of a specific functionality and is substantially uncontami 5 silanes are employed additional variables are encountered nated by chlorosilanes of other functionalities. Illus thus complicating an otherwise simple operation. Simi tratively, it has been found that dimethylpolysiloxane larly, substantially pure diphenyldichlorosilane, dimethyl gums that are suitable for conversion to silicone elastom dichlorosilane, methylphenyldichlorosilane, and the like ers cannot be prepared directly by the hydrolysis of di are highly desirable.
    [Show full text]
  • High-Purity Silicon
    PROCESS ECONOMICS PROGRAM SRI INTERNATIONAL Menlo Park, California 94029 Abstract Process Economics Program Report No. 184 HIGH-PURITY SILICON (October 1988) This report summarizes the technology and economics of producing high-purity silicon (‘polysilicon”) suitable for making single-crystal silicon for semiconductors or photovoltaic cells. In the commercial processes, the raw material-metallurgical-grade silicon--is con- verted to trichlorosllane (TCS) , which is purified and then decomposed to high-purity silicon. In the Siemens process, TCS is made by reacting metallurgical-grade silicon with hy- drogen and SiCW in a two-stage vapor-phase reaction in a fluidized bed. The TCS is purified by distillation and is decomposed at 1125OC in the presence of hydrogen. Purified silicon is deposited on heated filaments in a bell-jar reactor. In an alternative process, practiced commercially by Union Carbide, TCS is converted to sllane (SiHJ by disproportionatlon. Chlorosilanes are recycled, and purified silane is de- composed at 805OC. Purified silicon Is deposited on heated filaments in a bell-jar reactor. According to our analysis, this is a more expensive process. Other processes for making high-purity silicon are now under development. Some of them use other intermediates such as SiF, or SiBr,. PEP’85 RHSrnM Report No. 184 HIGH-PURITY SILICON by ROBERT H. SCHWAAR and TOM McMlLLAN with contributions by JAMES J. L. MA and ROSEMARY BRADLEY ccl I October 1988 a A private report by the m PROCESS ECONOMICS PROGRAM Menlo Park, California 94025 For detailed marketing data and information, the reader is referred to one of the SRI programs specializing in marketing research.
    [Show full text]
  • Influence of Silicon on High-Temperature
    Solar Energy Materials & Solar Cells 160 (2017) 410–417 Contents lists available at ScienceDirect Solar Energy Materials & Solar Cells journal homepage: www.elsevier.com/locate/solmat Influence of silicon on high-temperature (600 °C) chlorosilane interactions with iron crossmark ⁎ Josh Allera, , Nolan Swainb, Michael Babera, Greg Tatarb, Nathan Jacobsonc, Paul Gannonb a Mechanical and Industrial Engineering, Montana State University, Bozeman, MT 59717, USA b Chemical and Biological Engineering, Montana State University, Bozeman, MT 59717, USA c NASA Glenn Research Center, Cleveland, OH 44135, USA ARTICLE INFO ABSTRACT Keywords: High-temperature ( > 500 °C) chlorosilane gas streams are prevalent in the manufacture of polycrystalline Iron silicon, the feedstock for silicon-based solar panels and electronics. This study investigated the influence of Chlorosilane metallurgical grade silicon on the corrosion behavior of pure iron in these types of environments. The Silicon experiment included exposing pure iron samples at 600 °C to a silicon tetrachloride/hydrogen input gas mixture Silicon tetrachloride with and without embedding the samples in silicon. The samples in a packed bed of silicon had significantly Iron silicide higher mass gains compared to samples not in a packed bed. Comparison to diffusion studies suggest that the Corrosion increase in mass gain of embedded samples is due to a higher silicon activity from the gas phase reaction with silicon. The experimental results were supported by chemical equilibrium calculations which showed that more- active trichlorosilane and dichlorosilane species are formed from silicon tetrachloride in silicon packed bed conditions. 1. Introduction most common material added to a chlorosilane gas stream is silicon. Silicon may be present in a fluidized bed reactor used to convert silicon Chlorosilane species are used at high temperatures in the refine- tetrachloride to trichlorosilane or deposition equipment used to deposit ment, manufacture, and deposition of silicon and silicon-containing silicon on a wafer.
    [Show full text]
  • Dichlorosilane Safety Data Sheet
    Dichlorosilane Safety Data Sheet P-4587 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Issue date: 01/01/1980 Revision date: 01/27/2021 Supersedes: 03/09/2017 Version: 1.0 SECTION: 1. Product and company identification 1.1. Product identifier Product form : Substance Substance name : Dichlorosilane Chemical name : Dichlorosilane CAS-No. : 4109-96-0 Formula : SiH2Cl2 Other means of identification : Chlorosilane A-199, DCS 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Industrial use; Use as directed. 1.3. Details of the supplier of the safety data sheet Praxair, Inc. 10 Riverview Drive Danbury, CT 06810-6268 - USA T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146 www.praxair.com 1.4. Emergency telephone number Emergency number : Onsite Emergency: 1-800-645-4633 CHEMTREC, 24hr/day 7days/week — Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887 (collect calls accepted, Contract 17729) SECTION 2: Hazard identification 2.1. Classification of the substance or mixture GHS US classification Flam. Gas 1 H220 Press. Gas (Liq.) H280 Acute Tox. 2 (Inhalation: gas) H330 Skin Corr. 1B H314 Eye Dam. 1 H318 STOT SE 3 H335 2.2. Label elements GHS US labeling Hazard pictograms (GHS US) : GHS02 GHS04 GHS05 GHS06 Signal word (GHS US) : Danger Hazard statements (GHS US) : H220 - EXTREMELY FLAMMABLE GAS H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED H314 - CAUSES SEVERE SKIN BURNS AND EYE DAMAGE H330 - FATAL IF INHALED CGA-HG22 - CORROSIVE TO THE RESPIRATORY TRACT CGA-HG11 - SYMPTOMS MAY BE DELAYED CGA-HG01 - MAY CAUSE FROSTBITE.
    [Show full text]
  • Synthesis and Characterization of Well-Defined Regular Star Polyisoprenes with 3, 4, 6 and 8 Arms
    Synthesis and Characterization of Well-Defined Regular Star Polyisoprenes with 3, 4, 6 and 8 Arms Item Type Article Authors Ratkanthwar, Kedar R.; Hadjichristidis, Nikos; Pudukulathan, Zubaidha Citation Kedar R. Ratkanthwar, Nikos Hadjichristidis and Pudukulathan Zubaidha. Synthesis and characterization of well-defined regular star polyisoprenes with 3, 4, 6 and 8 arms, Chemistry Journal, 2013, 3, 90-96. Eprint version Publisher's Version/PDF Publisher Scientific Journals Journal Chemistry Journal Rights Archived with thanks to Chemistry Journal Download date 26/09/2021 10:20:56 Link to Item http://hdl.handle.net/10754/555815 Ratkanthwar et al / Chemistry Journal (2013), Vol. 03, Issue 03, pp. 90-96 ISSN 2049-954X Research Paper Synthesis and Characterization of Well-Defined Regular Star Polyisoprenes with 3, 4, 6 and 8 Arms Kedar Ratkanthwar 1,2 , Nikos Hadjichristidis 2,3 * and Zubaidha Pudukulathan 1** 1School of Chemical Sciences, S.R.T.M. University, Nanded 431606 (MS) India 2Department of Chemistry, University of Athens, Panepistimiopolis, Zografou, 15771 Athens, Greece 3Div. of Phy. Sci. & Engi. KAUST Catalysis Center, King Abdullah Uni. of Sci. and Tech. (KAUST), Thuwal, Saudi Arabia 1Tel.: +912462229518; Fax: +912462229245 2Tel.: +302107274330; Fax: +302107221800 3Tel.: +96628080789; Fax: +96628021272 E-Mail: [email protected] *; [email protected] ** Abstract Three series of regular well-defined star polyisoprenes (PIs) with 3, 4 and 6 arms (each series: same arm molecular weight) have been synthesized by anionic polymerization high vacuum techniques and chlorosilane chemistry. In addition, three linear PIs with practically the double arm molecular weight of the corresponding series (2-arm star PIs) have been synthesized, as well as one 8-arm star PI.
    [Show full text]
  • Trichlorosilane Safety Data Sheet
    Trichlorosilane Safety Data Sheet P-4823 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Issue date: 01/01/1984 Revision date: 02/09/2021 Supersedes: 10/25/2017 Version: 1.0 SECTION: 1. Product and company identification 1.1. Product identifier Product form : Substance Substance name : Trichlorosilane CAS-No. : 10025-78-2 Formula : Cl3HSi Other means of identification : Chlorosilane A-19, Silicochloroform, trichloromonosilane 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Industrial use; Use as directed. 1.3. Details of the supplier of the safety data sheet Praxair, Inc. 10 Riverview Drive Danbury, CT 06810-6268 - USA T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146 www.praxair.com 1.4. Emergency telephone number Emergency number : Onsite Emergency: 1-800-645-4633 CHEMTREC, 24hr/day 7days/week — Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887 (collect calls accepted, Contract 17729) SECTION 2: Hazard identification 2.1. Classification of the substance or mixture GHS US classification Flam. Liq. 1 H224 Water-react. 1 H260 Acute Tox. 3 (Inhalation) H331 Skin Corr. 1A H314 Eye Dam. 1 H318 STOT SE 3 H335 2.2. Label elements GHS US labeling Hazard pictograms (GHS US) : GHS02 GHS05 GHS06 GHS07 Signal word (GHS US) : Danger Hazard statements (GHS US) : H224 - EXTREMELY FLAMMABLE LIQUID AND VAPOR H260 - IN CONTACT WITH WATER RELEASES FLAMMABLE GASES WHICH MAY IGNITE SPONTANEOUSLY H314 - CAUSES SEVERE SKIN BURNS AND EYE DAMAGE H331 - TOXIC IF INHALED CGA-HG04 - MAY FORM EXPLOSIVE MIXTURES WITH AIR CGA-HG22 - CORROSIVE TO THE RESPIRATORY TRACT Precautionary statements (GHS US) : P202 - Do not handle until all safety precautions have been read and understood.
    [Show full text]
  • Silicon Tetrachloride Safety Data Sheet P-4824 This SDS Conforms to U.S
    Silicon tetrachloride Safety Data Sheet P-4824 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication. Issue date: 01/01/1984 Revision date: 03/12/2021 Supersedes: 12/12/2016 SECTION: 1. Product and company identification 1.1. Product identifier Product form : Substance Substance name : Silicon tetrachloride CAS-No. : 10026-04-7 Formula : Cl4Si Other means of identification : Chlorosilane A-160 / Tetrachlorosilane / Silicon Chloride / Silicon Tetrachloride 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Industrial use; Use as directed. 1.3. Details of the supplier of the safety data sheet Praxair, Inc. 10 Riverview Drive Danbury, CT 06810-6268 - USA T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146 www.praxair.com 1.4. Emergency telephone number Emergency number : Onsite Emergency: 1-800-645-4633 CHEMTREC, 24hr/day 7days/week — Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887 (collect calls accepted, Contract 17729) SECTION 2: Hazard identification 2.1. Classification of the substance or mixture GHS US classification Acute Tox. 2 (Oral) H300 Acute Tox. 2 (Inhalation) H330 Skin Corr. 1A H314 Eye Dam. 1 H318 2.2. Label elements GHS US labeling Hazard pictograms (GHS US) : GHS05 GHS06 Signal word (GHS US) : Danger Hazard statements (GHS US) : H300+H330 - FATAL IF SWALLOWED OR IF INHALED H314 - CAUSES SEVERE SKIN BURNS AND EYE DAMAGE EUH-014 - REACTS VIOLENTLY WITH WATER CGA-HG22 - CORROSIVE TO THE RESPIRATORY TRACT Precautionary statements (GHS US) : P202 - Do not handle until all safety precautions have been read and understood.
    [Show full text]
  • Manipulating Siloxane Surfaces: Obtaining the Desired Surface Function Via Engineering Design
    RESERVE THIS SPACE Manipulating Siloxane Surfaces: Obtaining the Desired Surface Function via Engineering Design Julie A. Crowe, Kirill Efimenko, and Jan Genzer* Department of Chemical and Biomolecular Engineering North Carolina State University Raleigh, North Carolina 27695 *Email: [email protected] Abstract We present a synopsis of recent accomplishment in our group in the area of surface-functionalized silicone elastomer networks. Specifically, we show that by combining mechanical manipulation of poly(dimethylsiloxane) (PDMS) networks with activation via ultraviolet/ozone (UVO) treatment and subsequent chemical modification of the pre- activated surfaces, one can generate so-called mechanically assembled monolayers (MAMs). This technology can be successfully applied to create a variety of surfaces, including dense polymer brushes, long-lived superhydrophobic surfaces, molecular gradients comprising tunable length scales and two- dimensional chemical gradients. In addition, the UVO modification of mechanically strained PDMS sheets provides a convenient route for creating “buckled” elastomeric sheets. These surfaces have a multitude of applications; ranging from anti-fouling surfaces to directed particle assembly. Finally we demonstrate control of surface wettability and responsiveness using poly(vinylmethylsiloxane) (PVMS) networks. We have shown that PVMS surfaces can be chemically tailored by reacting with thiols. The degree of response (including response rate) of such surfaces to hydrophobic-hydrophilic interactions can be adjusted by varying the chemical and structural properties of the side-group modifiers. Introduction Commercial interest in siloxane elastomers has lasted for over 50 years. The most-widely used material in this category is poly(dimethylsiloxane) (PDMS) (R = -CH3 in Figure 1). The high flexibility of the Si-O bond, the greater Si-O-Si bond angle and length relative to the C-C-C bond, and low energy barriers to rotation, contribute to very low glass transition temperature of PDMS (Tg ≈150 K).
    [Show full text]
  • Hyperbranched and Highly Branched Polymer Architecturessynthetic
    5924 Chem. Rev. 2009, 109, 5924–5973 Hyperbranched and Highly Branched Polymer ArchitecturessSynthetic Strategies and Major Characterization Aspects Brigitte I. Voit* and Albena Lederer Leibniz Institute of Polymer Research Dresden, Hohe Strasse 6, 01069 Dresden, Germany Received February 20, 2009 Contents 1. Introduction 1. Introduction 5924 “Life is branched” was the motto of a special issue of 1 2. Synthesis of Hyperbranched Polymers 5925 Macromolecular Chemistry and Physics on “Branched 2.1. General Aspects and Methodologies 5926 Polymers”, indicating that branching is of similar importance in the world of synthetic macromolecules as it is in nature. 2.1.1. Step-Growth Approaches 5926 The significance of branched macromolecules has evolved 2.1.2. Chain-Growth Approaches 5928 over the last 30 years from just being considered as a side 2.1.3. OtherSyntheticApproaches 5931 reaction in polymerization or as a precursor step in the 2.2. Examples of hb Polymers Classified by 5932 formation of networks. Important to this change in perception Reactions and Chemistry of branching was the concept of “polymer architectures”, 2.2.1. hb Polymers through Polycondensation 5932 which formed on new star- and graft-branched structures in 2.2.2. hb Polymers through Addition Step-Growth 5932 the 1980s and then in the early 1990s on dendrimers and Reactions dendritic polymers. Today, clearly, controlled branching is 2.2.3. hb Polymers through Cycloaddition 5934 considered to be a major aspect in the design of macromol- Reactions ecules and functional material. 2.2.4. hb Polymers through Self-Condensing Vinyl 5937 Hyperbranched (hb) polymers are a special type of Polymerization dendritic polymers and have as a common feature a very 2.2.5.
    [Show full text]