Extreme Ultraviolet Interference Lithography at the Paul Scherrer Institut

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Extreme Ultraviolet Interference Lithography at the Paul Scherrer Institut J. Micro/Nanolith. MEMS MOEMS 8͑2͒, 021204 ͑Apr–Jun 2009͒ Extreme ultraviolet interference lithography at the Paul Scherrer Institut Vaida Auzelyte Harun H. Solak Christian Dais Paul Scherrer Institut Patrick Farquet Laboratory for Micro- and Nanotechnology and Paul Scherrer Institut Eulitha AG Laboratory for Micro- and Nanotechnology Villigen 5232, Switzerland Villigen 5232, Switzerland E-mail: [email protected] Abstract. We review the performance and applications of an extreme ultraviolet interference lithography ͑EUV-IL͒ sys- tem built at the Swiss Light Source of the Paul Scherrer Detlev Grützmacher ͑ ͒ Institute of Bio- and Nanosystems 1 Institut Villigen, Switzerland . The interferometer uses fully coherent radiation from an undulator source. 1-D ͑line/ Research Center of Jülich ͒ ͑ ͒ 52425 Jülich, Germany space and 2-D dot/hole arrays patterns are obtained with a transmission-diffraction-grating type of interferometer. Features with sizes in the range from one micrometer down to the 10-nm scale can be printed in a variety of resists. The Laura J. Heyderman Feng Luo highest resolution of 11-nm half-pitch line/space patterns ob- Paul Scherrer Institut tained with this method represents a current record for pho- Laboratory for Micro- and Nanotechnology ton based lithography. Thanks to the excellent performance Villigen 5232, Switzerland of the system in terms of pattern resolution, uniformity, size of the patterned area, and the throughput, the system has been used in numerous applications. Here we demonstrate the versatility and effectiveness of this emerging nanolithog- Sven Olliges raphy method through a review of some of the applications, Swiss Federal Institute of Technology ͑ETH͒ Zurich namely, fabrication of metallic and magnetic nanodevice Laboratory for Nanometallurgy components, self-assembly of Si/Ge quantum dots, chemi- Department of Materials cal patterning of self-assembled monolayers ͑SAM͒, and ra- Wolfgang-Pauli-Strausse 10 diation grafting of polymers. © 2009 Society of Photo-Optical Instru- Zurich, CH-8093, Switzerland mentation Engineers. ͓DOI: 10.1117/1.3116559͔ Subject terms: nanolithography; extreme ultraviolet; interference Celestino Padeste lithography; metal nanowire; quantum dot; magnetic nanostructure; Pratap K. Sahoo self-assembled monolayer; polymer grafting. Paul Scherrer Institut Paper 08163SSR received Oct. 26, 2008; revised manuscript re- Laboratory for Micro- and Nanotechnology ceived Feb. 5, 2009; accepted for publication Mar. 2, 2009; pub- Villigen 5232, Switzerland lished online Apr. 27, 2009. Tom Thomson University of Manchester Oxford Road 1 Introduction School of Computer Science Extreme ultraviolet interference lithography ͑EUV-IL͒ is a Kilburn Building newly emerging nanolithography method that combines the Manchester M13 9PL, United Kingdom advantages of a parallel fabrication process with high res- olution. These features make it an attractive tool for re- searchers who are increasingly in need of a nanopatterning Andrey Turchanin University of Bielefeld capability that is beyond what is available from other meth- Faculty of Physics ods such as photolithography, electron beam lithography Physics of Supermolecular Systems ͑EBL͒, and scanning probe lithography, in terms of reso- D-33615 Bielefeld, Germany lution or throughput. After early interference lithography experiments performed in the vacuum UV1 and EUV regions,2 dedicated EUV-IL tools have been set up using Christian David synchrotron3,4 and laser sources.5 Such tools using plasma- Paul Scherrer Institut based EUV sources are also being considered.6 Laboratory for Micro- and Nanotechnology In most reported EUV-IL work, the wavelength of Villigen 5232, Switzerland choice has been 13.4 nm. The reason behind this choice is manifold. First, the possible next-generation EUV lithogra- phy ͑EUVL͒ technology7 that is being developed for fabri- cation of future semiconductor devices uses this wave- length. The EUV-IL method has played an important role in 1932-5150/2009/$25.00 © 2009 SPIE the development of high-resolution resists for this technol- J. Micro/Nanolith. MEMS MOEMS 021204-1 Apr–Jun 2009/Vol. 8͑2͒ Auzelyte et al.: Extreme ultraviolet interference lithography at the Paul Scherrer Institut ogy by making high-resolution exposures available long before EUV projection tools become available.8,9 Second, it is relatively easy to fabricate diffraction gratings with suf- ficiently high diffraction and transmission efficiency at this wavelength on silicon nitride membranes. Finally, the short inelastic mean free path of photoelectrons created by EUV photons in a resist at this energy ͑92.5 eV͒ means that the blurring effect of photoelectrons will be insignificant down to sub-10 nm resolution. Of course, we should also mention that this wavelength allows an ultimate half-pitch ͑hp͒ res- olution of below 4 nm, which can be as small as a quarter of the wavelength ͑␭͒: Fig. 1 The interference schemes of two- and four-grating designs to ␭ expose line and hole/dot patterns, respectively. hp = , 4 sin͑␪/2͒ where ␪ is the angle between two diffracted beams. and the beamline optics, as well as the top-up mode of Several different EUV-IL schemes have been realized or operation of the SLS storage ring. With the typical flux of proposed. A Lloyd’s mirror interferometer, which is a 20 to 50 mW/cm2, dot and line patterns in polymethyl wavefront division method, was used to expose linear grat- methacrylate ͑PMMA͒ resist can be exposed within 10 sec. ings and 2-D patterns in a double exposure scheme.5,10,11 The beam is switched on and off by a fast mechanical shut- Amplitude division interferometers, one involving beam- ter placed in front of the exposure chamber. Substrates splitter gratings with two recombining mirrors12 and an- ranging from several square centimeters chips up to other that has two cascaded gratings,13 were also recently 200 mm wafers can be exposed. demonstrated. The EUV-IL system at the Paul Scherrer In- The basic interference scheme that is used at the PSI stitut ͑PSI͒ in Villigen, Switzerland,4 whose application is system is illustrated in Fig. 1. The spatially coherent inci- the subject of this review, uses a diffraction-grating-based dent beam is diffracted by linear gratings that are patterned wavefront division scheme.2,3 We describe this scheme in on a single, partially transparent membrane. The resulting more detail in the following section. In addition to two and mutually coherent beams interfere at a certain distance multiple beam interference methods, a holographic ap- along the beam direction. The interference fringes are used proach was also demonstrated.3 to expose a pattern in a resist film. The schemes in Fig. 1 create periodic patterns that have half the period of the interferometer grating. The size and shape of each exposure 2 Extreme Ultraviolet Interference Lithography pattern is the same as the size and shape of the grating. System at the Paul Scherrer Institut Pairs of diffraction gratings with different periods can be The EUV-IL system at the XIL beamline of the Swiss Light placed on a single mask and the resulting pattern printed Source ͑SLS͒ uses light that is generated by a 42-pole un- simultaneously in one exposure step. In this way, patterns dulator with a 212 mm period, which is inserted into the from the micrometer down to the nanometer scale can be 2.4 GeV electron storage ring. The SLS, as a third genera- created in a single exposure in EUV-IL. tion synchrotron, is constructed to provide a spatially co- Two linear gratings are used to create lines, while hole/ herent beam for photon energies of up to about 100 eV, dot patterns can be made in one exposure step by the inter- 15 thanks to the small size and divergence of the electron ference of three or more diffracted beams ͑Fig. 1͒. More beam.14 The spatial coherence is essential for the basic complex structures such as rings and crosses can be made 16 wavefront division interference scheme that is used at this by eight-beam interference. Depending on the design of beamline. The temporal/longitudinal coherence of the light the mask, the relation between the period of the diffraction emanating from the source is related to the spectral band- gratings and the fringe pattern varies. For example, in a width ⌬␭/␭. For an undulator, this is related to the number four-beam scheme, demagnification factors of 2 or ͱ2 ͑in of magnetic poles, which translates to a rather large spectral terms of pattern period͒ are obtained depending on the rela- width of about 2.5% for our source. To get a narrower tive phases of the interfering beams.16 This demagnification bandwidth, the beam can be filtered using a monochro- factor is very helpful for the mask fabrication. For example, mator. However, this leads to a significant loss of photon 200 nm period gratings written on a mask will expose flux. The diffraction-grating-based interference schemes 100 nm period lines on the sample. Examples of two- and described next are achromatic. Therefore in most experi- four-beam masks mounted on stainless steel rings are ments the interferometric exposures are performed using shown in Fig. 2. The masks are prepared using electron the full bandwidth of the undulator radiation without addi- beam lithography ͑EBL͒ and reactive ion etching pattern tional spectral filtering. However, the beam is filtered by a transfer processes on 100-nm Si3N4 membranes coated pinhole to guarantee full spatial coherence at the interfer- with a thin Cr film.17 The gratings are written in a resist ometer. The resulting beam at the interferometer has a with EBL and later etched into the Cr film. The thickness of width of about 3 to 5 mm ͓full width at half maximum the grating metal layer, the grating duty cycle, and the ma- ͑FWHM͔͒, which depends on the diameter of the pinhole terial ͑e.g., Cr͒ determine the EUV diffraction efficiency. used for spatial filtering.
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