Hand-Book of Valuable Minerals : What They Are! What They
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Mineralogy and Geology of the \Vkgnerite Occurrence Co Santa Fe Mountain, Front Range, Cobrado
Mineralogy and Geology of the \Vkgnerite Occurrence co Santa Fe Mountain, Front Range, Cobrado GEOLOGICAL SURVEY PROFESSIONAL PAPER 955 Mineralogy and Geology of the Wignerite Occurance on Santa Fe Mountain, Front Range, Colorado By DOUGLAS M. SHERIDAN, SHERMAN P. MARSH, MARY E. MROSE, and RICHARD B. TAYLOR GEOLOGICAL SURVEY PROFESSIONAL PAPER 955 A detailed mineralogic study of wagnerite, a rare phosphate mineral occurring in the report area in Precambrian gneiss; this is the first recorded occurrence of wagnerite in the United States UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1976 UNITED STATES DEPARTMENT OF THE INTERIOR THOMAS S. KLEPPE, Secretary GEOLOGICAL SURVEY V. E. McKelvey, Director Library of Congress Cataloging in Publication Data Main entry under title: Mineralogy and geology of the wagnerite occurrence on Santa Fe Mountain, Front Range, Colorado. (Geological Survey Professional Paper 955) Includes bibliographical references. 1. Wagnerite Colorado Santa Fe Mountain. 2. Geology Colorado Santa Fe Mountain. I. Sheridan, Douglas M., 1921- II. Series: United States Geological Survey Professional Paper 955. QE391.W3M56 549'.72 76-10335 For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, B.C. 20402 Stock Number 024-001-02844-1 CONTENTS Page Metric-English equivalents .............................. Descriptive mineralogy Continued Page Abstract............................................................ 1 Wagnerite............................................... 5 Introduction.................................................... -
Trace Elements and Minerals in Fumarolic Sulfur: the Case of Ebeko Volcano, Kuriles
Hindawi Geofluids Volume 2018, Article ID 4586363, 16 pages https://doi.org/10.1155/2018/4586363 Research Article Trace Elements and Minerals in Fumarolic Sulfur: The Case of Ebeko Volcano, Kuriles E. P. Shevko,1 S. B. Bortnikova,2 N. A. Abrosimova,2 V. S. Kamenetsky ,3,4 S. P. Bortnikova,2 G. L. Panin,2 and M. Zelenski 3 1 Sobolev Institute of Geology and Mineralogy, SBRAS, Novosibirsk 630090, Russia 2Trofmuk Institute of Petroleum Geology and Geophysics, SBRAS, No. 3, Novosibirsk 630090, Russia 3Institute of Experimental Mineralogy RAS, Chernogolovka 142432, Russia 4EarthSciencesandCODES,UniversityofTasmania,PrivateBag79,Hobart,TAS7001,Australia Correspondence should be addressed to M. Zelenski; [email protected] Received 25 June 2017; Revised 13 October 2017; Accepted 14 December 2017; Published 20 March 2018 Academic Editor: Joerg Goettlicher Copyright © 2018 E. P. Shevko et al. Tis is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Native sulfur deposits on fumarolic felds at Ebeko volcano (Northern Kuriles, Russia) are enriched in chalcophile elements (As- Sb-Se-Te-Hg-Cu) and contain rare heavy metal sulfdes (Ag2S, HgS, and CuS), native metal alloys (Au2Pd), and some other low- solubility minerals (CaWO4, BaSO4). Sulfur incrustations are impregnated with numerous particles of fresh and altered andesite groundmass and phenocrysts (pyroxene, magnetite) as well as secondary minerals, such as opal, alunite, and abundant octahedral pyrite crystals. Te comparison of elemental abundances in sulfur and unaltered rocks (andesite) demonstrated that rock-forming elements (Ca, K, Fe, Mn, and Ti) and other lithophile and chalcophile elements are mainly transported by fumarolic gas as aerosol particles, whereas semimetals (As, Sb, Se, and Te), halogens (Br and I), and Hg are likely transported as volatile species, even ∘ at temperatures slightly above 100 C. -
Phosphates, Arsenates, Vanadates, Antimonates A
592 DESCRIPTIVE MINERALOGY Epistdite. A niobate of uncertain composition. Analysis shows chiefly SjOz, TiOz, NkO, H20. Monoclinic. In rectangular plates, also in aggregates of curved foha. Basal cleavage perfect. H. = 1-1.5. G. = 2.9. Color white, grayish brownish. Refractive index 1.67. Bound in pegmatite veins or in massive albite from ~llianehaab,Greenland. Plumboniobite. A niobatc of yttrium, uranium, lead, iron, etc. Amorphous. H. = 5-5'5. G. = 4.81. Color dark brown to black. Found in mica mines at Morogoro, German Enst Africa. Oxygen Salts 4. PHOSPHATES, ARSENATES, VANADATES, ANTIMONATES A. Anhydrous Phosphates, Arsenates, Vanadates, Antimonates Normal phosphoric acid is H3P04, and consequently normal phosphates I 11 m have the formulas RtPOa, R3(PO4)2 and RPO4, and similarly for the arse- nates, etc. Only a comparatively small number of species conform to this simple formula. Most species contain more than one metallic element, and in the prominent Apatite Group the radical (CaF), (CaCI) or (PbCI) enters; " in the Wagnerite Group we have similarly (kF) or (ROH). XENOTIME. Tetragonal. Axis c = 0.6187, zz' (1 11 A ill) = 55" 301, 22" (111 A 771) = 82" 22'. In crystals resembling zircon in habit; sometimes compounded with zircon in parallel position (Fig. 462, p. 173). In 972 rolled grains. Cleavage: m (110) perfect. Fracture uneven and splintery. Brittle. H. = 4-5. G. = 4.454.56. Luster resinous to vitreous. Color yellowish brown, reddish brown, hair-brown, flesh-red, grayish white, wine-yellow, pale yellow; streak pale brown, yellow- ish or reddish. Opaque. Optically + . w = 1.72. e = 1-81. -
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Geochemical Journal, Vol. 41, pp. 149 to 163, 2007 Boron isotope fractionation accompanying formation of potassium, sodium and lithium borates from boron-bearing solutions MAMORU YAMAHIRA, YOSHIKAZU KIKAWADA* and TAKAO OI Department of Chemistry, Sophia University, 7-1 Kioi-cho, Chiyoda-ku, Tokyo 102-8854, Japan (Received March 18, 2006; Accepted June 22, 2006) A series of experiments was conducted in which boron minerals were precipitated by water evaporation from solutions containing boron and potassium, sodium or lithium at 25°C, and boron isotope fractionation accompanying such mineral precipitation was investigated. In the boron-potassium ion system, K2[B4O5(OH)4]·2H2O, santite (K[B5O6(OH)4]·2H2O), KBO2·1.33H2O, KBO2·1.25H2O and sassolite (B(OH)3) were found deposited as boron minerals. Borax (Na2[B4O5(OH)4·8H2O) was found deposited in the boron-sodium ion system, and Li2B2O4·16H2O, Li2B4O7·5H2O, Li2B10O16·10H2O, LiB2O3(OH)·H2O and sassolite in the boron-lithium ion system. The boron isotopic analysis was con- 11 10 ducted for santite, K2[B4O5(OH)4]·2H2O, borax and Li2B2O4·16H2O. The separation factor, S, defined as the B/ B isotopic ratio of the precipitate divided by that of the solution, ranged from 0.991 to 1.012. Computer simulations for modeling boron mineral formations, in which polyborates were decomposed into three coor- dinated BO3 unit and four coordinated BO4 unit for the purpose of calculation of their boron isotopic reduced partition function ratios, were attempted to estimate the equilibrium constant, KB, of the boron isotope exchange between the boric – acid molecule (B(OH)3) and the monoborate anion (B(OH)4 ). -
UCLA Electronic Theses and Dissertations
UCLA UCLA Electronic Theses and Dissertations Title Use of Boron in Detergents and its Impact on Reclamation Permalink https://escholarship.org/uc/item/2rw7k2r7 Author Ghavanloughajar, Maryam Publication Date 2015 Peer reviewed|Thesis/dissertation eScholarship.org Powered by the California Digital Library University of California UNIVERSITY OF CALIFORNIA Los Angeles Use of Boron in Detergents and its Impact on Reclamation A thesis submitted in partial satisfaction of the requirements for the degree Master of Science in Civil Engineering by Maryam Ghavanloughajar 2015 ABSTRACT OF THE THESIS Use of Boron in Detergents and its Impact on Reclamation By Maryam Ghavanloughajar Master of Science in Civil Engineering University of California, Los Angeles, 2015 Professor Michael K. Stenstrom, Chair Many parts of the world are experiencing severe water drought and it affects societies both economically and environmentally. Therefore, conservation practices are essential to balance water supply and demand. Greywater or wastewaters from showers and luandries, if treated well can be a reliable source for activities such as irrigation, toilet flushing and car washing. Greywaters are not as contaminated as sewage but still may require treatment before reuse. The application of insufficiently treated water for irrigation can cause harm to plants and animals. Pollutant such as boron in greywater is of particular interest because many plants are sensitive to even low concentrations. High concentrations of boron can induce toxicity, reduce growth rate and yield in plants. Therefore, proposed greywater treatment systems need to consider the sensitivity of plant species and boron concentrations and potential removal. This thesis reviews boron chemistry, its effect on plants and currently available boron removal technologies. -
Design Rules for Discovering 2D Materials from 3D Crystals
Design Rules for Discovering 2D Materials from 3D Crystals by Eleanor Lyons Brightbill Collaborators: Tyler W. Farnsworth, Adam H. Woomer, Patrick C. O'Brien, Kaci L. Kuntz Senior Honors Thesis Chemistry University of North Carolina at Chapel Hill April 7th, 2016 Approved: ___________________________ Dr Scott Warren, Thesis Advisor Dr Wei You, Reader Dr. Todd Austell, Reader Abstract Two-dimensional (2D) materials are championed as potential components for novel technologies due to the extreme change in properties that often accompanies a transition from the bulk to a quantum-confined state. While the incredible properties of existing 2D materials have been investigated for numerous applications, the current library of stable 2D materials is limited to a relatively small number of material systems, and attempts to identify novel 2D materials have found only a small subset of potential 2D material precursors. Here I present a rigorous, yet simple, set of criteria to identify 3D crystals that may be exfoliated into stable 2D sheets and apply these criteria to a database of naturally occurring layered minerals. These design rules harness two fundamental properties of crystals—Mohs hardness and melting point—to enable a rapid and effective approach to identify candidates for exfoliation. It is shown that, in layered systems, Mohs hardness is a predictor of inter-layer (out-of-plane) bond strength while melting point is a measure of intra-layer (in-plane) bond strength. This concept is demonstrated by using liquid exfoliation to produce novel 2D materials from layered minerals that have a Mohs hardness less than 3, with relative success of exfoliation (such as yield and flake size) dependent on melting point. -
Industrial Minerals and Rocks in the 21St Century
Industrial Minerals and Rocks in the 21st Century Milos Kuzvart Charles University, Prague NONMETALLICS: DEFINITION, CLASSIFICATION, OCCURENCE, ORIGIN, UTILIZATION The term 'industrial mineral' is not defined so strictly as the term 'ore' which is mostly a source of metal, or as that of 'fossil fuel' (coal, oil, natural gas), which is predominantly a source of energy. In both the latter cases the characteristic feature is the chemistry of the ore (besides the content of impurities, dressability, etc.) or fuel (besides the content of dirt bands, sulfur, etc.). The characteristic features of industrial minerals, however, líe in their physical properties (e.g., fibrosity of asbestos, insulatory properties of mica, the high specific gravity of barite). In this artiele raw materials of several types are considered under the term "industrial mineral s and rocks": 1. raw materials that are used in industry in variously prepared forms as minerals (e.g., talc, asbestos, diamond) or rocks (diatomite, bentonite, ochre); 2. raw material s that serve as a source of non-metallic elements (ftuorite for ftuori ne, apatite for phosphorus) or their simple compounds (e.g., borates for H3B03 or B 20 3); 3. raw materials of non-metallic habit that are source of metals, and also of their com pounds employed in other than metallurgical industries (e.g., beryl as a source of BeO, magnesite of MgO, bauxite or Al-rich laterite as a source of Alz03; all these three oxides are refractory materials); 4. building material s (rocks for aggregate, together with gravel and sand for concrete, decorative stone and roofing slate, limestone for cement and lime, brickloam). -
Sintering and Mechanical Properties of Magnesium and Fluorine Co-Substituted Hydroxyapatites
Journal of Biomaterials and Nanobiotechnology, 2013, 4, 1-11 1 http://dx.doi.org/10.4236/jbnb.2013.41001 Published Online January 2013 (http://www.scirp.org/journal/jbnb) Sintering and Mechanical Properties of Magnesium and Fluorine Co-Substituted Hydroxyapatites Samia Nsar, Amel Hassine, Khaled Bouzouita* Laboratory of Industrial Chemistry, National School of Engineering, Sfax, Tunisia. Email: *[email protected] Received September 5th, 2012; revised October 17th, 2012; accepted November 10th, 2012 ABSTRACT Biological apatites contain several elements as traces. In this work, magnesium and fluorine co-substituted hydroxyapa- tites with the general formula Ca9Mg(PO4)6(OH)2-yFy, where y = 0, 0.5, 1, 1.5 and 2 were synthesized by the hydrother- mal method. After calcination at 500˚C, the samples were pressureless sintered between 950˚C and 1250˚C. The substi- tution of F− for OH− had a strong influence on the densification behavior and mechanical properties of the materials. Below 1200˚C, the density steeply decreased for y = 0.5 sample. XRD analysis revealed that compared to hydroxyl- fluorapatite containing no magnesium, the substituted hydroxyfluorapatites decomposed, and the nature of the decom- position products is tightly dependent on the fluorine content. The hardness, elastic modulus and fracture toughness of these materials were investigated by Vickers’s hardness testing. The highest values were 622 ± 4 GPa, 181 ± 1 GPa and 1.85 ± 0.06 MPa·m1/2, respectively. Keywords: Hydroxyapatite; Magnesium, Fluorine; Sintering; Mechanical Properties 1. Introduction tite containing magnesium and fluorine would be more suitable for dental and orthopedic applications. Hydroxyapatite (HA) is widely used in orthopedic and Hence, it is thought worthwhile to synthesize and char- reconstructive surgery thanks to its excellent bioactivity acterize Mg/F-co-substituted hydroxypatites. -
Thermal Characterization of Magnesium Containing Ionomer Glasses
Thermal characterization of magnesium containing ionomer glasses ELENI MARIA KARTELIA Supervisor: Dr. A. Stamboulis Thesis submitted for the degree of MRes Biomaterials University of Birmingham School of Engineering Department of Metallurgy and Materials September, 2010 University of Birmingham Research Archive e-theses repository This unpublished thesis/dissertation is copyright of the author and/or third parties. The intellectual property rights of the author or third parties in respect of this work are as defined by The Copyright Designs and Patents Act 1988 or as modified by any successor legislation. Any use made of information contained in this thesis/dissertation must be in accordance with that legislation and must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the permission of the copyright holder. ACKNOWLEDGMENTS I would like to thank my supervisor Dr. A. Stamboulis for her help and encouragement during my project. Without her support, I feel that I would not have been able to complete this work. I would also like to express my gratitude to Dr. D. Holland at University of Warwick for her helping on DSC measurements. Many thanks are given to academic staff and technicians of the School of Metallurgy and Materials. I would like to thank sincerely the Phd students Praveen Ramakrishnan, Georgina Kaklamani, Siqi Zhang and Mitra Kashani for their significant help through my experimental work. Last but not least, I would like to thank my family for their support and understanding. Special thanks to Thanos Papaioannou. 2 TABLE CAPTIONS CHAPTER 2: MATERIALS AND METHODS Table 2.1.2: Composition of Mg substituted alumino-silicate glasses. -
The Crystal Structure of Althausite, Mg.(P04)2(OH,O)(F,D)
----- ----- American Mineralogist, Volume 65, pages 488-498, 1980 The crystal structure of althausite, Mg.(P04)2(OH,O)(F,D) CHRISTIAN R0MMING Kjemisk Institutt, Universitetet i Oslo, Blindern, Oslo 3, Norway AND GUNNAR RAADE Instituttfor Geologi, Universitetet i Oslo, Blindern, Oslo 3, Norway Abstract The crystal structure of althausite was solved by direct methods and refined to a final R value of 0.022 for 1164 high-angle reflections (sin 8/A > 0.45A -I) with I> 2.50. The position of the hydrogen atom was found from a difference Fourier synthesis. The structure is ortho- rhombic Pnma with a = 8.258(2),b = 6.054(2),c = 14.383(5)A.Magnesium atoms occur in both five- and six-fold coordination, and the coordination polyhedra are highly distorted. The Mg octahedra form chains along b by edge-sharing. Hydroxyl and fluorine occur in a largely ordered distribution among two different structural sites and occupy alternating posi- tions along 'channels' parallel to b. Partial vacancy in the (OH,F) sites is confirmed, the pop- ulation factor for the F site being 81 percent. The crystal-chemical formula of althausite is therefore Mg4(P04)2(OH,0)(F,D) with Z = 4. The cleavages in althausite, {001} perfect and {101} distinct, occur along planes crossing relatively few bonds and leave the chains of Mg octahedra unbroken. Bond-strength calcu- lations for althausite and wagnerite are presented and the OH content in wagnerite is dis- cussed. Preliminary results of hydrothermal syntheses indicate the existence of a series from F- wagnerite to OH,F-wagnerite and from OH-althausite to OH,F-althausite. -
Pegmatite Genesis: State of the Art
Eur. J. Mineral. 2008, 20, 421–438 Published online August 2008 Paper presented at the symposium “Granitic Pagmatites: the State of the Art”, Porto, May 2007 Pegmatite genesis: state of the art Wm. B. “Skip” SIMMONS* and Karen L. WEBBER Department of Earth and Environmental Sciences, University of New Orleans, New Orleans, LA 70148, USA *Corresponding author, e-mail: [email protected] Abstract: No one universally accepted model of pegmatite genesis has yet emerged that satisfactorily explains all the diverse features of granitic pegmatites. Genesis from residual melts derived from the crystallization of granitic plutons is favoured by most researchers. Incompatible components, fluxes, volatiles and rare elements, are enriched in the residual melts. The presence of fluxes and volatiles, which lower the crystallization temperature, decrease nucleation rates, melt polymerization and viscosity, and increase diffusion rates and solubility, are considered to be critical to the development of large crystals. A number of new concepts have shed light on problems related to pegmatite genesis. Cooling rates calculated from thermal cooling models demonstrate that shallow-level pegmatites cool radically more rapidly than previously believed. Rapid cooling rates for pegmatites represent a quantum shift from the widely held view that the large crystals found in pegmatites are the result of very slow rates of cooling and crystal growth. Experimental and field evidence both suggest that undercooling and disequilibrium crystallization dominate pegmatite crys- tallization. London’s constitutional zone refining model of pegmatite evolution involves disequilibrium crystallization from an undercooled, flux-bearing granitic melt. The melt is not necessarily flux–rich and the model does not require the presence of an aqueous vapor phase. -
University of California Los Angeles USE of BORON in DETERGENTS
University of California Los Angeles USE OF BORON IN DETERGENTS AND ITS IMPACT ON RECLAMATION A thesis submitted in partial satisfaction of the requirements for the degree Master of Science in Civil Engineering by Maryam Ghavanloughajar Summer, 2015 1 Table of Contents 1. Abstract ................................................................................................................................................. 3 2. Introduction .......................................................................................................................................... 3 3. Literature Review .................................................................................................................................. 7 3.1. Chemical properties of boron ....................................................................................................... 7 3.1.1. Boric acid ............................................................................................................................. 12 3.1.2. Borax ................................................................................................................................... 15 3.2. Boron impact on plants ............................................................................................................... 17 3.3. Survey of boron in products........................................................................................................ 21 4. Boron removal technologies ..............................................................................................................