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CzechCzech www.spektroskopie.cz ABOUT US ChemicalChemical Ioannes Marcus Marci Spectroscopic Society (IMMSS) is a non-profit organization of scientific, educational and professional technical workers in spectroscopy, eventually legal entities engaged in scientific or application activities in this field, all associated in joint activities with the aims of promoting and fostering advancement in the field of spectroscopy. IMMSS has SocietySociety currently ca 110 members . Its history dates back to 1949 (Czechoslovak Spectroscopic Society). The Society is named after Ioannes Marcus Marci (1595-1667), a distinguished doctor, physicist and mathematician of the renaissance and rector of Charles University in Prague. Marci is sometimes denoted as a first spectroscopist in history and foreshadower of Newton since he had dealt with light refraction well before him, studied and explained the nature of the phenomenon of the rainbow. ACTIVITIES AWARDS IMMSS bulletin – published quarterly Ioannes Marcus Marci medal SymposiumSymposiumSymposiumSymposium (co)organization of conferences and workshops o awarded to eminent foreign and domestic scientists in recognition of their outstanding o national level: workshops/conferences in different fields of spectroscopy. The biggest one is the annual achievements in some of the spectroscopic Summer school of mass spectrometry (>200 participants). disciplines o international level: Czech-Slovak Spectroscopic Conference (biennial) o Ioannes Marcus Marci medal laureates SeriesSeriesSeriesSeries European Symposium on Atomic Spectrometry (ESAS) 2014 include five Nobel prize winners: Euro-Mediterranean Symposium on Laser-Induced Breakdown Spectroscopy (EMSLIBS) 2019 2222 prof. Eric Allin Cornell organization of competitons prof. Dr. Theodor W. Hänsch prof. Ahmed H. Zewail o The Young Authors’ Best Paper in Spectroscopy Competition – annualy in two categories: as the best dissertation in the field; as the best spectrosopic paper(s) published of author below Sir Harold W. Kroto the age of 35. prof. Robert F. Curl, Jr. o Petr Sedmera award - annually for outstanding work published in the area of nuclear magnetic resonance. In memory of Petr Sedmera, a renowned scientist who greatly contributed to the Honorary membership development of the field. o the merit award of those who have had o Vladimír Hanuš award - annually for outstanding work published in the area of mass contributed significantly to the development spectrometry. In memory of Vladimír Hanuš, a renowned scientist who greatly contributed to the development of the field. of IMMSS and spectroscopy STRUCTURE Executive board Atomic spectroscopy Special committees o chairman Molecular spectroscopy o education committee 2. konference2. konference Pokroky Pokroky anorganické anorganické chemie chemie th th o 1st and 2nd vice-chairman o Vibrational spectroscopy o committee for standards 18 18 Radiochemical Radiochemical Conference Conference and reference materials o scientific secretary o Magnetic resonance spectroscopy o committee for environmental research o treasurer o Luminiscence spectroscopy o nomenclature committee MariánskéMariánské Lázně, Lázně, Czech Czech Republic Republic o 4 section chairmen Mass spectroscopy 13-1813-18 May May 2018 2018 Main committee Special spectroscopic methods Auditing committee o X-ray spectrometry Bulletin editorial board o Instrumental radioanalytical methods BookletBooklet of Abstracts of Abstracts o Mössbauer spectroscopy o Spectroscopy and microscopy of nanostructures o Photoelectron spectroscopy BulletinBulletin Thanks to our general sponsors: RočníkRočník 16 16- Czech - Czech Chemical Chemical Society Society Symposium Symposium Series Series 16 (2) 16 (2) 49-268 49-268 (2018) (2018) ISSNISSN 2336-7202 2336-7202 http://www.ccsss.cz http://www.ccsss.cz www.fjfi .cvut.cz FACULTY OF NUCLEAR SCIENCES AND PHYSICAL ENGINEERING Part of the oldest technical university in Czech Republic 60years history from pure nuclear sciences to broad technical fi eld • Nuclear Engineering • Nuclear Chemistry • Radiological Physics • Quantum technologies • Pure or Applied Math and Physic Member of many scientifi c societies, cooperates with business and bringing the science to live for general public Czech Chemical Society Novotného lávka 5 | 116 68 Praha 1 tel.: + 420 222 220184 | www.csch.cz • Czech Chemical Society (CCS) is one of the oldest chemical societies in Europe. It was founded in 1866. • CCS has 2200 members in 30 working parties and divisions. • CCS members are from various areas, mainly academic and industrial. • CCS is a founding member of the Association of the Czech Chemical Societies (AČCHS). Activities • Organising national and international symposia and congresses. • Own research activities. • Publishing monthly journal „Chemické listy“. • CCS is a member of ChemPubSoc Europe consortium. • CCS is a founding member of EuCheMS (formerly FECS). • CCS is an affiliate member of the International Union of Pure and Applied chemistry(IUPAC). • CCS conducts agenda of European Chemist Registration Board (ECRB). Benefits for Members • Affiliate membership in IUPAC. • Subscription discount for „Chemické listy“ and other journals published by ChemSocEurope. • Introduction to potential membership in prestigious European chemicalsocieties (RSC, GDCh, GÖCh, SFC). • Possibility to receive European professional designation EurChem. Czech Chem. Soc. Symp. Ser. 16, 49-268 (2018) RadChem 2018 elcome to the 18th Radiochemical Conference. The conference is held in Mariánské Lázně, the second W largest Czech spa and the largest and most beautiful city – garden in the Czech Republic. RadChem 2018 aims at maintaining the more than 55 year tradition of radiochemical conferences (the 1st Radiochemical Conference was held in 1961), dealing with all aspects of nuclear- and radiochemistry, organised in the Czech Republic (or formerly in Czechoslovakia). We strive to continue in the tradition of organising a fruitful and well attended platform for contacts between experts working in both basic and applied research in all aspects of nuclear- and radiochemistry. More than 300 scientists from 36 countries registered for the conference. The verbal sessions, where more than 170 plenary, invited and contributed presentations are scheduled to be presented, will be complemented by the corresponding poster sessions. Selected “hot topics” in nuclear- and radiochemistry will be covered in six plenary opening lectures delivered by invited recognized experts. These talks will include laureate lectures by winners of two prestigious medals – Ioannes Marcus Marci Medal awarded by the Ioannes Marcus Marci Spectroscopic Society (won by Dr. Peter Bode) and Vladimír Majer Medal awarded by the Czech Chemical Society (won by Prof. Jukka K. Lehto). In conjunction with the technical programme, an exhibition covering technologies, equipment, technical and management services in areas pertaining to the theme of the conference will be held. The extensive social programme is expected to provide an opportunity for informal contacts and dis- cussions among the participants. Among others, RadChem 2018 is a proud host of the 50th anniversary celebration of the Journal of Radioanalytical and Nuclear Chemistry. The interaction of all the above ac- tivities is hoped to maintain the high standard of this long-lasting series of conferences and through this contribute to the flourish of our Science. RadChem 2018 Organising Committee 49 Czech Chem. Soc. Symp. Ser. 16, 49-268 (2018) RadChem 2018 Table of Contents 1. Plenary 51 2. Chemistry of Nuclear Fuel Cycle, Radiochemical Problems in Nuclear Waste Management 55 3. Chemistry of Actinide and Trans-actinide Elements 95 4. Separation Methods, Speciation 114 5. Nuclear Analytical Methods 143 6. Radionuclides in the Environment, Radioecology 174 7. Radiation Chemistry 217 8. Radiopharmaceutical Chemistry, Labelled Compounds 228 9. Production and Application of Radionuclides 240 10. Education 250 Author Index 255 50 Czech Chem. Soc. Symp. Ser. 16, 49-268 (2018) RadChem 2018 1. Plenary PLN.L01 (Id: 704) PLN.L02 (Id: 871) SUPERHEAVY ELEMENTS OF THE D.I. TOWARDS INCREASED COOPERATION MENDELEEV’S PERIODIC TABLE. AND COORDINATION OF R&I ACTIVITIES PRESENT AND FUTURE FOR DECOMMISSIONING Sergey Dmitriev Christine Georges Joint Institute for Nuclear Research CEA, France [email protected] CEA (French Alternative Energies and Atomic Energy Commission) is both the operator of important nuclear The synthesis of super heavy elements (SHE) with facilities all over the nuclear cycle, in charge of major atomic numbers 113-118 has been achieved in the 48Ca- new built or D&D projects and a R&D group with dy- induced reactions. The seventh period of the Periodic namic policy of technology transfer. The position of Table has been completed. Unique data on the nuclear- CEA in D&D is unique because of the number and the physical properties of isotopes of the new elements have wide diversity of facilities under decommissioning, with been obtained. Pioneering experiments on the chemical some high level of contamination. properties of elements 112(Cn), 113 and 114(Fl) have Innovative solutions are thus being developed in 6 main been carried out [1]. axes to protect the operators, to minimize the overall The discovery of an Island of stability of SHE has costs and the volumes of waste: brought up a whole new series of questions: ¢ Can there be nuclei heavier than synthesized su- - Investigations in the facilities per heavy nuclei? - Radiological measurement of