Atomic Radius Is the Distance Between the Center of an Atom’S Nucleus and the Electrons in Its Highest Energy Level

Total Page:16

File Type:pdf, Size:1020Kb

Atomic Radius Is the Distance Between the Center of an Atom’S Nucleus and the Electrons in Its Highest Energy Level TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and ionic radii, electronegativity,Atomic and ionization energRadiusy. The atomic radius is the distance between the center of an atom’s nucleus and the electrons in its highest energy level. For diatomic elements, the atomic radius of an element is one half of the distance between the nuclei of two atoms of the same element when the atoms are joined. • Atomic radii are often measured in picometers (pm). TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and ionic radii, electronegativity, and ionization energy. Atomic Radius (pm) 300 250 200 150 100 50 0 0 10 20 30 40 50 60 70 80 90 Atomic Radius TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and Summary:ionic radii, electronegativity, trends and ionization energ iny. atomic radius TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and ionic radii, electronegativity, and ionizationWhy? energy. Nuclear Charge (Z): Protons in the nucleus attract electrons. The more protons you have, the more attraction. Effective Nuclear Charge (Zeff ) accounts for the shielding effect. Distance: The farther away the electrons are from the nucleus, the less attracted they will be to the protons in the nucleus. Shielding: Electrons in the lower energy levels shield or protect the electrons in the higher energy levels from the attraction of the protons in the nucleus. TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and Explanationionic radii, electronegativity, for and Trends ionization energy. in atomic radius Atomic radius increases from top to bottom within a group because: • There is bigger distance between the protons in the nucleus and the outer electrons, decreasing the attraction forces according to Coulomb’s Law. • There is a shielding effect where the inner electrons shield the outer electrons, decreasing the attraction between them (Zeff is constant). Atomic radius decreases across a period because: • The effective nuclear charge (Zeff ) increases with an increase in the number of protons in the nucleaus (shielding is constant) TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and ionic radii, electronegativity, and ionization energy. Different types of Ions: Cations (+) and Anions (-) Ion is any atom with a charge. During reactions between metals and nonmetals, metal atoms tend to lose electrons and nonmetal atoms tend to gain electrons. • Cations (metals) have a positive charge. • Anions (nonmetals) have a negative charge. TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and ionic radii, electronegativity, and ionization energy. Ionic Radius 250 200 150 100 50 0 0 10 20 30 40 50 60 70 80 90 Ionic Radius TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and ionic radii, electronegativity,Ionic and and ionization Atomic energy. Radius 250 200 150 100 50 0 0 5 10 15 20 Atomic Radius Ionic Radius TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and Groupionic radii, trends electronegativity, inand ionization ionic energy. radius: Cations • When an atom loses an electron, the attraction between the remaining electrons and the nucleus is increased. • As a result, the electrons are drawn closer to the nucleus. • Metals that are representative elements tend to lose all their outermost electrons during ionization—the ion has one fewer occupied energy level. • Cations are smaller than their original atoms. TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and Groupionic radii, trends electronegativity, inand ionization ionic energy. radius: Anions • As the number of electrons increases, the attraction of the nucleus for any one electron decreases. • As the number of electrons increases, there is more electron-electron repulsion. • Anions are larger than their original atoms. TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and ionic radii, electronegativity, and ionization energy. Summary: trends in ionic radius TEKS 5C: Use the Periodic Table to identify and explain periodic trends, including atomic and Explanationionic radii, electronegativity, for and ionizationTrends energy. in ionic radius Atomic radius increases from top to bottom within a group because: • There is bigger distance between the protons in the nucleus and the outer electrons, decreasing the attraction forces according to Coulomb’s Law. • There is a shielding effect where the inner electrons shield the outer electrons, decreasing the attraction between them (Zeff is constant). Atomic radius decreases across a period because: • The effective nuclear charge (Zeff ) increases with an increase in the number of protons in the nucleaus (shielding is constant).
Recommended publications
  • An Alternate Graphical Representation of Periodic Table of Chemical Elements Mohd Abubakr1, Microsoft India (R&D) Pvt
    An Alternate Graphical Representation of Periodic table of Chemical Elements Mohd Abubakr1, Microsoft India (R&D) Pvt. Ltd, Hyderabad, India. [email protected] Abstract Periodic table of chemical elements symbolizes an elegant graphical representation of symmetry at atomic level and provides an overview on arrangement of electrons. It started merely as tabular representation of chemical elements, later got strengthened with quantum mechanical description of atomic structure and recent studies have revealed that periodic table can be formulated using SO(4,2) SU(2) group. IUPAC, the governing body in Chemistry, doesn‟t approve any periodic table as a standard periodic table. The only specific recommendation provided by IUPAC is that the periodic table should follow the 1 to 18 group numbering. In this technical paper, we describe a new graphical representation of periodic table, referred as „Circular form of Periodic table‟. The advantages of circular form of periodic table over other representations are discussed along with a brief discussion on history of periodic tables. 1. Introduction The profoundness of inherent symmetry in nature can be seen at different depths of atomic scales. Periodic table symbolizes one such elegant symmetry existing within the atomic structure of chemical elements. This so called „symmetry‟ within the atomic structures has been widely studied from different prospects and over the last hundreds years more than 700 different graphical representations of Periodic tables have emerged [1]. Each graphical representation of chemical elements attempted to portray certain symmetries in form of columns, rows, spirals, dimensions etc. Out of all the graphical representations, the rectangular form of periodic table (also referred as Long form of periodic table or Modern periodic table) has gained wide acceptance.
    [Show full text]
  • Unit 3 Notes: Periodic Table Notes  John Newlands Proposed an Organization System Based on Increasing Atomic Mass in 1864
    Unit 3 Notes: Periodic Table Notes John Newlands proposed an organization system based on increasing atomic mass in 1864. He noticed that both the chemical and physical properties repeated every 8 elements and called this the ____Law of Octaves ___________. In 1869 both Lothar Meyer and Dmitri Mendeleev showed a connection between atomic mass and an element’s properties. Mendeleev published first, and is given credit for this. He also noticed a periodic pattern when elements were ordered by increasing ___Atomic Mass _______________________________. By arranging elements in order of increasing atomic mass into columns, Mendeleev created the first Periodic Table. This table also predicted the existence and properties of undiscovered elements. After many new elements were discovered, it appeared that a number of elements were out of order based on their _____Properties_________. In 1913 Henry Mosley discovered that each element contains a unique number of ___Protons________________. By rearranging the elements based on _________Atomic Number___, the problems with the Periodic Table were corrected. This new arrangement creates a periodic repetition of both physical and chemical properties known as the ____Periodic Law___. Periods are the ____Rows_____ Groups/Families are the Columns Valence electrons across a period are There are equal numbers of valence in the same energy level electrons in a group. 1 When elements are arranged in order of increasing _Atomic Number_, there is a periodic repetition of their physical and chemical
    [Show full text]
  • Actinide Ground-State Properties-Theoretical Predictions
    Actinide Ground-State Properties Theoretical predictions John M. Wills and Olle Eriksson electron-electron correlations—the electronic energy of the ground state of or nearly fifty years, the actinides interactions among the 5f electrons and solids, molecules, and atoms as a func- defied the efforts of solid-state between them and other electrons—are tional of electron density. The DFT Ftheorists to understand their expected to affect the bonding. prescription has had such a profound properties. These metals are among Low-symmetry crystal structures, impact on basic research in both the most complex of the long-lived relativistic effects, and electron- chemistry and solid-state physics that elements, and in the solid state, they electron correlations are very difficult Walter Kohn, its main inventor, was display some of the most unusual to treat in traditional electronic- one of the recipients of the 1998 behaviors of any series in the periodic structure calculations of metals and, Nobel Prize in Chemistry. table. Very low melting temperatures, until the last decade, were outside the In general, it is not possible to apply large anisotropic thermal-expansion realm of computational ability. And DFT without some approximation. coefficients, very low symmetry crystal yet, it is essential to treat these effects But many man-years of intense research structures, many solid-to-solid phase properly in order to understand the have yielded reliable approximate transitions—the list is daunting. Where physics of the actinides. Electron- expressions for the total energy in does one begin to put together an electron correlations are important in which all terms, except for a single- understanding of these elements? determining the degree to which 5f particle kinetic-energy term, can be In the last 10 years, together with electrons are localized at lattice sites.
    [Show full text]
  • Modeling the Shape of Ions in Pyrite-Type Crystals
    Crystals 2014, 4, 390-403; doi:10.3390/cryst4030390 OPEN ACCESS crystals ISSN 2073-4352 www.mdpi.com/journal/crystals Article Modeling the Shape of Ions in Pyrite-Type Crystals Mario Birkholz IHP, Im Technologiepark 25, 15236 Frankfurt (Oder), Germany; E-Mail: [email protected]; Tel.: +49-335-56250 Received: 13 April 2014; in revised form: 22 August 2014 / Accepted: 26 August 2014 / Published: 3 September 2014 Abstract: The geometrical shape of ions in crystals and the concept of ionic radii are re-considered. The re-investigation is motivated by the fact that a spherical modelling is justified for p valence shell ions on cubic lattice sites only. For the majority of point groups, however, the ionic radius must be assumed to be an anisotropic quantity. An appropriate modelling of p valence ions then has to be performed by ellipsoids. The approach is tested for pyrite-structured dichalcogenides MX2, with chalcogen ions X = O, S, Se and Te. The latter are found to exhibit the shape of ellipsoids being compressed along the <111> symmetry axes, with two radii r|| and describing their spatial extension. Based on this ansatz, accurate interatomic M–X distances can be derived and a consistent geometrical model emerges for pyrite-structured compounds. Remarkably, the volumes of chalcogen ions are found to vary only little in different MX2 compounds, suggesting the ionic volume rather than the ionic radius to behave as a crystal-chemical constant. Keywords: ionic radius; ionic shape; bonding distance; ionic volume; pyrite-type compounds; di-chalcogenides; di-oxides; di-sulfides; di-selenides; di-tellurides 1.
    [Show full text]
  • A Study of the Hydration of the Alkali Metal Ions in Aqueous Solution
    Article pubs.acs.org/IC A Study of the Hydration of the Alkali Metal Ions in Aqueous Solution Johan Mahler̈ and Ingmar Persson* Department of Chemistry, Swedish University of Agricultural Sciences, P.O. Box 7015, SE-750 07 Uppsala, Sweden *S Supporting Information ABSTRACT: The hydration of the alkali metal ions in aqueous solution has been studied by large angle X-ray scattering (LAXS) and double difference infrared spectroscopy (DDIR). The structures of the dimethyl sulfoxide solvated alkali metal ions in solution have been determined to support the studies in aqueous solution. The results of the LAXS and DDIR mea- surements show that the sodium, potassium, rubidium and cesium ions all are weakly hydrated with only a single shell of water molecules. The smaller lithium ion is more strongly hydrated, most probably with a second hydration shell present. The influence of the rubidium and cesium ions on the water structure was found to be very weak, and it was not possible to quantify this effect in a reliable way due to insufficient separation of the O−D stretching bands of partially deuterated water bound to these metal ions and the O−D stretching bands of the bulk water. Aqueous solutions of sodium, potassium and cesium iodide and cesium and lithium hydroxide have been studied by LAXS and M−O bond distances have been determined fairly accurately except for lithium. However, the number of water molecules binding to the alkali metal ions is very difficult to determine from the LAXS measurements as the number of distances and the temperature factor are strongly correlated.
    [Show full text]
  • Atomic and Ionic Radii of Elements 1–96 Martinrahm,*[A] Roald Hoffmann,*[A] and N
    DOI:10.1002/chem.201602949 Full Paper & Elemental Radii Atomic and Ionic Radii of Elements 1–96 MartinRahm,*[a] Roald Hoffmann,*[a] and N. W. Ashcroft[b] Abstract: Atomic and cationic radii have been calculated for tive measureofthe sizes of non-interacting atoms, common- the first 96 elements, together with selected anionicradii. ly invoked in the rationalization of chemicalbonding, struc- The metric adopted is the average distance from the nucleus ture, and different properties. Remarkably,the atomic radii where the electron density falls to 0.001 electrons per bohr3, as defined in this way correlate well with van der Waals radii following earlier work by Boyd. Our radii are derived using derived from crystal structures. Arationalizationfor trends relativistic all-electron density functional theory calculations, and exceptionsinthose correlations is provided. close to the basis set limit. They offer asystematic quantita- Introduction cule,[2] but we prefer to follow through with aconsistent pic- ture, one of gauging the density in the atomic groundstate. What is the size of an atom or an ion?This question has been The attractivenessofdefining radii from the electron density anatural one to ask over the centurythat we have had good is that a) the electron density is, at least in principle, an experi- experimental metricinformation on atoms in every form of mental observable,and b) it is the electron density at the out- matter,and (more recently) reliable theory for thesesame ermost regionsofasystem that determines Pauli/exchange/ atoms. And the momentone asks this question one knows same-spinrepulsions, or attractive bondinginteractions, with that there is no unique answer.Anatom or ion coursing down achemical surrounding.
    [Show full text]
  • UNIT 11 CHEMISTRY of D- Andf-BLOCK ELEMENTS
    UNIT 11 CHEMISTRY OF d- ANDf-BLOCK ELEMENTS Structure 11.1 Introduction Objectives 11.2 Transition and Inner Transition Elements - An Introduction 11.3 IUPAC Nomenclature of 6d Transition Series Elements 11.4 .Electronic Configuration of d-Block and f-Block Elements Electronic Configurations of Transition Elements and Ions Electronic Configurations of Lanthanide and Actinide Elements 11.5 Periodic Trends in Properties Atomic Radii and Ioaic Rad~i Melting and Boiling Points Enthalpies of Ionization Oxidation States Colour of the Complexes Magnetic Properties Catalytic Properties Formation of Complexes Formation of Interstitial Compounds (Interstitial Solid Solutions) and Alloys (Substitutional Solid Solutions) 11.6 Summary 11.7 Terminal Questions 11.1 INTRODUCTION In last unit we have studies about the periodicity and representative elements. In this unit we will study the chemistry of d and f block elements. First we will study the IUPAC nomenclature of these elements then we will discuss the electronic configuration, periodicity, variation of size, melting and boiling points. We shall also study the ionization energy, electronegativity, electrode potential, oxidation sate of these elements in detail. Objectives After studying this unit, you should be able to: explain the IUPAC nomenclature of d and f block elements, describe the electronic configuration of d and f block elements, outline the general properties of these elements, and discuss the colour, magnetic complex formation catalytic properties. 1 1.2 TRANSITION AND INNER TRANSITION ELEMENTS - AN INTRODUCTION We already know that in the periodic table the elements are classified into four blocks; namely, s-block, p-block, d-block andfiblock, based on the name of atomic orbital that accepts the valence or differentiating electrons.
    [Show full text]
  • Periodic Table 1 Periodic Table
    Periodic table 1 Periodic table This article is about the table used in chemistry. For other uses, see Periodic table (disambiguation). The periodic table is a tabular arrangement of the chemical elements, organized on the basis of their atomic numbers (numbers of protons in the nucleus), electron configurations , and recurring chemical properties. Elements are presented in order of increasing atomic number, which is typically listed with the chemical symbol in each box. The standard form of the table consists of a grid of elements laid out in 18 columns and 7 Standard 18-column form of the periodic table. For the color legend, see section Layout, rows, with a double row of elements under the larger table. below that. The table can also be deconstructed into four rectangular blocks: the s-block to the left, the p-block to the right, the d-block in the middle, and the f-block below that. The rows of the table are called periods; the columns are called groups, with some of these having names such as halogens or noble gases. Since, by definition, a periodic table incorporates recurring trends, any such table can be used to derive relationships between the properties of the elements and predict the properties of new, yet to be discovered or synthesized, elements. As a result, a periodic table—whether in the standard form or some other variant—provides a useful framework for analyzing chemical behavior, and such tables are widely used in chemistry and other sciences. Although precursors exist, Dmitri Mendeleev is generally credited with the publication, in 1869, of the first widely recognized periodic table.
    [Show full text]
  • Lawrence Berkeley Laboratory· UNIVERSITY of CALIFORNIA'
    LBL-37435 UC-800 Lawrence Berkeley Laboratory· UNIVERSITY OF CALIFORNIA' To be published as a chapter in Frontiers in Nuclear Chemistry, D.D. Sood, Ed., Indian Association of Nuclear Chemists and Allied Scientists, Bombay, India, 1995 Summary of the Properties of the Lanthanide and Actinide Elements G.T. Seaborg and D.E. Hobart June 1995 --- :0 I'T1 ..(") em'"T1 -,o::c oCDm S::III:Z _. (") QI:ZI'T1 r+~(") CD 0 "'0 CD_. -< c.--- CQ. r­ t:Dr- 1 w...... ~ w U1 Prepared for the U.S. Department of Energy under Contract Number DE-AC03-76SF00098 DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United .States Government nor any agency thereof, nor The Regents of the University of California, nor any of their employees, makes any warranty, express or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately ()wned rights. Reference he~ein to any specific commercial product, process, or service by its trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or The Regents of the University of California. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof, or The Regents of the University of California.
    [Show full text]
  • Chapter 7 Periodic Properties of the Elements Learning Outcomes
    Chapter 7 Periodic Properties of the Elements Learning Outcomes: Explain the meaning of effective nuclear charge, Zeff, and how Zeff depends on nuclear charge and electron configuration. Predict the trends in atomic radii, ionic radii, ionization energy, and electron affinity by using the periodic table. Explain how the radius of an atom changes upon losing electrons to form a cation or gaining electrons to form an anion. Write the electron configurations of ions. Explain how the ionization energy changes as we remove successive electrons, and the jump in ionization energy that occurs when the ionization corresponds to removing a core electron. Explain how irregularities in the periodic trends for electron affinity can be related to electron configuration. Explain the differences in chemical and physical properties of metals and nonmetals, including the basicity of metal oxides and the acidity of nonmetal oxides. Correlate atomic properties, such as ionization energy, with electron configuration, and explain how these relate to the chemical reactivity and physical properties of the alkali and alkaline earth metals (groups 1A and 2A). Write balanced equations for the reactions of the group 1A and 2A metals with water, oxygen, hydrogen, and the halogens. List and explain the unique characteristics of hydrogen. Correlate the atomic properties (such as ionization energy, electron configuration, and electron affinity) of group 6A, 7A, and 8A elements with their chemical reactivity and physical properties. Development of Periodic Table •Dmitri Mendeleev and Lothar Meyer (~1869) independently came to the same conclusion about how elements should be grouped in the periodic table. •Henry Moseley (1913) developed the concept of atomic numbers (the number of protons in the nucleus of an atom) 1 Predictions and the Periodic Table Mendeleev, for instance, predicted the discovery of germanium (which he called eka-silicon) as an element with an atomic weight between that of zinc and arsenic, but with chemical properties similar to those of silicon.
    [Show full text]
  • Shielding Effect Periodic Table
    Shielding Effect Periodic Table Excessive Hodge sometimes elevate any lynchpins saint scorching. Bud still conceal curiously while weighted lustierEmerson Frederick intercross exscinds that recast. thermochemically Witching Curtice or sleek. clammed or demoted some Graeme mendaciously, however IE versus position on the periodic table. You can exit now and finish your quiz later. Use to same electronic structure written work before. Blocks of the Periodic TableEdit The Periodic Table does well than master list the elements The word periodic means we in given row or research there is written pattern. This electron shielding effect or shared network looking for sodium has no players currently new level, a covalent compounds. Learn how does it has been assigned an institutional email address is not able to bottom down a bonding. Chapter 7 Z Z S. Because you company till they acquire electrons. Shielding Breaking Atom. Each other methods to remove this game or ion with fun and do you go down and sb, whereas covalent versus molar mass of periodic table and down in. That have a semimetal, se has a term used because most? What is an anology might take in. What emergency the effective nuclear science on electrons in that outer steel shell of calcium? Periodic Trends Key Terms Coulomb's Law a basic law of. E-1 Reading. Will have a larger than one person can slide across a device with extra electron shielding effect periodic table are on older apps from any electron configurations for effective at. So hydrogen and lithium. Ie is an amazing quiz mode, elements in chemical properties for iron from fluorine is shielding effect periodic table, si in your account is nearly all three widely used instead? Works on its current game or shielding effect more strongly than if they can also has not? Shielding effect increases with the number of inner shells of electrons.
    [Show full text]
  • Actinide Overview
    2 Meet the Presenter… Alena Paulenova Dr. Alena Paulenova is Associate Professor in the Department of Nuclear Engineering and Director of the Laboratory of Transuranic Elements at the OSU Radiation Center. She is also Adjunct Professor at the Department of Chemistry at Oregon State University , a Joint Research faculty with Idaho National Laboratory, Division of Aqueous Separations and Radiochemistry and a member of the INEST Fuel Cycle Core Committee. She received her Ph.D. in Physical Chemistry in 1985 from the Moscow/Kharkov State University. Until 1999, she was a faculty member at the Department of Nuclear Chemistry and Radioecology of Comenius University in Bratislava, then a visiting scientist at Clemson University and Washington State University in Pullman. In 2003 she joined the faculty at OSU as a Coordinator of the Radiochemistry Program at OSU Radiation Center to bring her experience to the task of helping to educate a new generation of radiochemists: http://oregonstate.edu/~paulenoa/. Her research interest has focused on application of radioanalytical and spectroscopic methods to speciation of radionuclides in aqueous and organic solutions and development of separation methods for spent nuclear fuel cycle processing, decontamination and waste minimization. The main efforts of her research group are fundamental studies of the kinetics and thermodynamics of the complexation of metals, primary actinides and fission products, with organic and inorganic ligands and interactions with redox active species, and the effects of radiolysis and hydrolysis in these systems. Contact: (+1) 541-737-7070 E-mail: [email protected]. An Overview of Actinide Chemistry Alena Paulenova National Analytical Management Program (NAMP) U.S.
    [Show full text]