DOCSLIB.ORG

Unit 5.1 Periodic Table: Its Structure and Function

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Unit 5.1 Periodic Table: Its Structure and Function Unit 5.1 Periodic Table: Its Structure and Function Teacher: Dr. Van Der Sluys Objectives • Mendeleev • Information in the Periodic Table – Metals, nonmetals and metalloids – Main Group, Transition Metals, Rare Earth and Actinide Dmitri Mendeleev (1869) In 1869 Mendeleev and Lothar Meyer (Germany) published nearly identical classification schemes for elements known to date. The periodic table is base on the similarity of properties and reactivities exhibited by certain elements. Later, Henri Moseley ( England,1887-1915) established that each elements has a unique atomic number, which is how the current periodic table is organized. http://www.chem.msu.su/eng/misc/mendeleev/welcome.html 1 Information About Each Element Atomic Number 1 H Atomic Symbol Average Atomic 1.00794 Mass Periodic Table Expanded View •The way the periodic table usually seen is a compress view, placing the Lanthanides and actinides at the bottom of the stable. •The Periodic Table can be arrange by subshells. The s-block is Group IA and & IIA, the p-block is Group IIIA - VIIIA. The d-block is the transition metals, and the f-block are the Lanthanides and Actinide metals 2 Periodic Table: Metals and Nonmetals 1 18 IA VIIIA 2 13 14 15 16 17 1 IIA IIIA IVA VA VIA VIIA • Layout of the Periodic Table: Metals vs. nonmetals 2 3 4 5 6 7 8 9 10 11 12 3 IIIB IVB VB VIB VIIB VIIIB IB IIB 4 Nonmetals 5 Metals 6 7 Periodic Table: Classification • Metals - Solids, luster, conduct heat and electricity, malleable and ductile • Nonmetals - Gases, liquids or low melting solids that are sometimes brittle and nonconducting • Metalloids - Have properties of both metals and nonmetals. Element along the stair case, except aluminum, which is a metal. • Noble gases - Monoatomic, unreactive gases Three Element Types: Main, Transition, Rare Earth • Main Group (Representative) • Transition metals • lanthanides and actinides (rare earth) 3 Across the Periodic Table Periods: Are arranged horizontally across the periodic table (rows 1-7). These elements have the same number of valence shells. 1 Their properties change systematically. 18 IA VIIIA 2 13 14 15 16 17 1 IIA IIIA IVA VA VIA VIIA 2nd Period 2 3 4 5 6 7 8 9 10 11 12 3 IIIB IVB VB VIB VIIB VIIIB IB IIB 4 5 6th Period 6 7 Down the Periodic Table •Families or groups: Are arranged vertically down the periodic table (columns or group, 1- 18 or 1-8 A,B). These elements have the same number electrons in the outer most shells, the valence shell. 1 18 IA VIIIA 2 Alkali Family: 13 14 15 16 17 1 IIA 1 e- in the valence shell IIIA IVA VA VIA VIIA 2 3 4 5 6 7 8 9 10 11 12 3 IIIB IVB VB VIB VIIB VIIIB IB IIB 4 Halogen Family: 5 7 e- in the valence shell 6 7 Infamous Families in Periodic Table Alkali Halogen Noble Gas Alkaline Chalcogens 1 (earth) 18 IA VIIIA 2 13 14 15 16 17 1 IIA Transition Metals IIIA IVA VA VIA VIIA 2 3 4 5 6 7 8 9 10 11 12 3 IIIB IVB VB VIB VIIB VIIIB IB IIB 4 5 6 7 4 Important Elements • Individual members of selected Elements & their 1 characteristics 18 IA VIIIA 2 13 14 15 16 17 1 H IIA IIIA IVA VA VIA VIIA He 2 Li C N O F 3 4 5 6 7 8 9 10 11 12 3 Na Mg IIIB IVB VB VIB VIIB VIIIB IB IIB Al Si P S Cl 4 K Ca Fe Cu Zn Br 5 Ag I 6 7 Summary • Periodic Table: Map of the Building block of matter • Type: Metal, metalloid and Nonmetal – Groupings: Representative or main, transition and Lanthanide/Actanides • Family: Elements in the same column have similar chemical property because of similar valence electrons – Alkali, Alkaline, chalcogens, halogens, noble gases • Period: Elements in the same row have valence electrons in the same shell. 5.
Load more

Recommended publications
  • The Development of the Periodic Table and Its Consequences Citation: J
    Firenze University Press www.fupress.com/substantia The Development of the Periodic Table and its Consequences Citation: J. Emsley (2019) The Devel- opment of the Periodic Table and its Consequences. Substantia 3(2) Suppl. 5: 15-27. doi: 10.13128/Substantia-297 John Emsley Copyright: © 2019 J. Emsley. This is Alameda Lodge, 23a Alameda Road, Ampthill, MK45 2LA, UK an open access, peer-reviewed article E-mail: [email protected] published by Firenze University Press (http://www.fupress.com/substantia) and distributed under the terms of the Abstract. Chemistry is fortunate among the sciences in having an icon that is instant- Creative Commons Attribution License, ly recognisable around the world: the periodic table. The United Nations has deemed which permits unrestricted use, distri- 2019 to be the International Year of the Periodic Table, in commemoration of the 150th bution, and reproduction in any medi- anniversary of the first paper in which it appeared. That had been written by a Russian um, provided the original author and chemist, Dmitri Mendeleev, and was published in May 1869. Since then, there have source are credited. been many versions of the table, but one format has come to be the most widely used Data Availability Statement: All rel- and is to be seen everywhere. The route to this preferred form of the table makes an evant data are within the paper and its interesting story. Supporting Information files. Keywords. Periodic table, Mendeleev, Newlands, Deming, Seaborg. Competing Interests: The Author(s) declare(s) no conflict of interest. INTRODUCTION There are hundreds of periodic tables but the one that is widely repro- duced has the approval of the International Union of Pure and Applied Chemistry (IUPAC) and is shown in Fig.1.
    [Show full text]
  • Dmitri Mendeleev
    DOWNLOADABLE EXTRAS Atomic Structure: Part 1 1 Dmitri Mendeleev Dmitri Mendeleev was born on the 8th of February 1834 in Siberia, Russia. His father who was a teacher of the arts and politics, died when he was only thirteen. He was one of a large family and is thought to possibly have had 17 brothers and sisters. Due to his father’s death and a failed family business (a glass factory that burnt down) the family were very poor. Despite this, his mother wanted him to be educated at a higher level so she moved the family to St Petersburg in order for Dmitri to attend school. After graduating he became a teacher in the area of science. His passion was chemistry and he studied the capillarity of liquids (ability of a liquid to fl ow in a narrow space without any suction or pumping, like when water moves against gravity up a straw placed in a glass of water), the components of petrol and the spectroscope (a device that uses light to identify unknown materials). Because chemistry at the time was so disorganised, Mendeleev saw a need to establish a set of rules and guidelines that would be universal (able to be used across the world). He started by writing two very successful text books that included all of his chemistry knowledge. However he felt that this wasn’t enough and that the concepts of chemistry were too broad and unlinked. In 1869 he started to write a system that ordered the elements as these were the main concept behind a lot of other chemistry.
    [Show full text]
  • Dmitry I. Mendeleev and His Time
    Firenze University Press www.fupress.com/substantia Historical Article Dmitry I. Mendeleev and his time Citation: D. Pushcharovsky (2019) Dmitry I. Mendeleev and his time. Sub- Dmitry Pushcharovsky stantia 3(1): 119-129. doi: 10.13128/ Substantia-173 Lomonosov Moscow State University, Department of Geology, Vorob’evy gori, 1, 119899 Moscow, Russia Copyright: © 2019 D. Pushcharovsky. E-mail: [email protected] This is an open access, peer-reviewed article published by Firenze University Press (http://www.fupress.com/substan- Abstract. The history of the creation of Periodic table and of the Mendeleev’s discovery tia) and distribuited under the terms of Periodic Law is considered. The different approaches used by Mendeleev’s colleagues of the Creative Commons Attribution are discussed. The contribution of the Periodic system to the extension of the scientific License, which permits unrestricted ideas in geology and best of all in geochemistry and mineralogy is illustrated by the use, distribution, and reproduction discovery of new chemical elements and by the isomorphic replacements in minerals. in any medium, provided the original author and source are credited. The details of uneasy history of Mendeleev’s nomination to the St. Petersburg Academy and for the Nobel Prize are given. Data Availability Statement: All rel- evant data are within the paper and its Keywords. Periodic table, isomorphism, Nobel Prize, electronic structure of atom. Supporting Information files. Competing Interests: The Author(s) declare(s) no conflict of interest. Periodic table of chemical elements on the front of the main building of the Central Board of Weights and Measures in St. Petersburg; height – 9 m, area – 69 m2; red colour - ele- ments, known in the Mendeleev lifetime, blue colour – elements discovered after 1907 (Pub- lic domain) Substantia.
    [Show full text]
  • Periodic Table 1 Periodic Table
    Periodic table 1 Periodic table This article is about the table used in chemistry. For other uses, see Periodic table (disambiguation). The periodic table is a tabular arrangement of the chemical elements, organized on the basis of their atomic numbers (numbers of protons in the nucleus), electron configurations , and recurring chemical properties. Elements are presented in order of increasing atomic number, which is typically listed with the chemical symbol in each box. The standard form of the table consists of a grid of elements laid out in 18 columns and 7 Standard 18-column form of the periodic table. For the color legend, see section Layout, rows, with a double row of elements under the larger table. below that. The table can also be deconstructed into four rectangular blocks: the s-block to the left, the p-block to the right, the d-block in the middle, and the f-block below that. The rows of the table are called periods; the columns are called groups, with some of these having names such as halogens or noble gases. Since, by definition, a periodic table incorporates recurring trends, any such table can be used to derive relationships between the properties of the elements and predict the properties of new, yet to be discovered or synthesized, elements. As a result, a periodic table—whether in the standard form or some other variant—provides a useful framework for analyzing chemical behavior, and such tables are widely used in chemistry and other sciences. Although precursors exist, Dmitri Mendeleev is generally credited with the publication, in 1869, of the first widely recognized periodic table.
    [Show full text]
  • Chapter 7 Periodic Properties of the Elements Learning Outcomes
    Chapter 7 Periodic Properties of the Elements Learning Outcomes: Explain the meaning of effective nuclear charge, Zeff, and how Zeff depends on nuclear charge and electron configuration. Predict the trends in atomic radii, ionic radii, ionization energy, and electron affinity by using the periodic table. Explain how the radius of an atom changes upon losing electrons to form a cation or gaining electrons to form an anion. Write the electron configurations of ions. Explain how the ionization energy changes as we remove successive electrons, and the jump in ionization energy that occurs when the ionization corresponds to removing a core electron. Explain how irregularities in the periodic trends for electron affinity can be related to electron configuration. Explain the differences in chemical and physical properties of metals and nonmetals, including the basicity of metal oxides and the acidity of nonmetal oxides. Correlate atomic properties, such as ionization energy, with electron configuration, and explain how these relate to the chemical reactivity and physical properties of the alkali and alkaline earth metals (groups 1A and 2A). Write balanced equations for the reactions of the group 1A and 2A metals with water, oxygen, hydrogen, and the halogens. List and explain the unique characteristics of hydrogen. Correlate the atomic properties (such as ionization energy, electron configuration, and electron affinity) of group 6A, 7A, and 8A elements with their chemical reactivity and physical properties. Development of Periodic Table •Dmitri Mendeleev and Lothar Meyer (~1869) independently came to the same conclusion about how elements should be grouped in the periodic table. •Henry Moseley (1913) developed the concept of atomic numbers (the number of protons in the nucleus of an atom) 1 Predictions and the Periodic Table Mendeleev, for instance, predicted the discovery of germanium (which he called eka-silicon) as an element with an atomic weight between that of zinc and arsenic, but with chemical properties similar to those of silicon.
    [Show full text]
  • Hobart Mendeleev 2-3-11.Pdf
    Czar Nicholas II and Alexi at Tobolsk, Siberia in 1917 - Beinecke Library, Yale University Dr. David Hobart Los Alamos National Laboratory Academician Boris Myasoedov Secretary General Russian Academy of Sciences U N C L A S S I F I E D LA-UR-09-05702 U N C L A S S I F I E D National Laboratory From Modest Beginnings Dmitri Ivanovich Mendeleev was born on February 8th, 1834 in Verhnie Aremzyani near Tobolsk, Russian Empire From modest beginnings in a small village in Siberia an extraordinary Russian chemist conceived of a profound and revolutionary scientific contribution to modern science: the Periodic Table of the Elements. The Greek Periodic Table ~ 400 BC As with most profound discoveries a number of important developments and observations were made prior to that discovery Definition of an Element In 1661 Boyle criticized the experiments of “alchemists” - Chemistry is the science of the composition of substances - not merely an adjunct to the art of alchemy - Elements are the un-decomposable constituents of material bodies - Understanding the distinction between mixtures and compounds, he made progress in detecting their ingredients - which he termed analysis Robert Boyle 1627-1691 The Atomic Theory The Greek philosopher Democritus first proposed the atomic theory but centuries later John Dalton established the scientific foundation: - All atoms of a given element are identical - The atoms of different elements can be distinguished by their relative weights Democritus of Abdera John Dalton 460-370 BC 1766-1844 Early Knowledge and Discovery The elements gold, silver, copper, tin, Searching for the “Philosopher’s lead, mercury, and others were known Stone” German alchemist Henning from antiquity.
    [Show full text]
  • Mendeleev's Periodic Table of the Elements the Periodic Table Is Thus
    An Introduction to General / Inorganic Chemistry Mendeleev’s Periodic Table of the Elements Dmitri Mendeleev born 1834 in the Soviet Union. In 1869 he organised the 63 known elements into a periodic table based on atomic masses. He predicted the existence and properties of unknown elements and pointed out accepted atomic weights that were in error. The periodic table is thus an arrangement of the elements in order of increasing atomic number. Elements are arranged in rows called periods. Elements with similar properties are placed in the same column. These columns are called groups. An Introduction to General / Inorganic Chemistry The modern day periodic table can be further divided into blocks. http://www.chemsoc.org/viselements/pages/periodic_table.html The s, p, d and f blocks This course only deals with the s and p blocks. The s block is concerned only with the filling of s orbitals and contains groups I and II which have recently been named 1 and 2. The p block is concerned only with the filling of p orbitals and contains groups III to VIII which have recently been named 13 to 18. An Introduction to General / Inorganic Chemistry Groups exist because the electronic configurations of the elements within each group are the same. Group Valence Electronic configuration 1 s1 2 s2 13 s2p1 14 s2p2 15 s2p3 16 s2p4 17 s2p5 18 s2p6 The type of chemistry exhibited by an element is reliant on the number of valence electrons, thus the chemistry displayed by elements within a given group is similar. Physical properties Elemental physical properties can also be related to electronic configuration as illustrated in the following four examples: An Introduction to General / Inorganic Chemistry 1.
    [Show full text]
  • Mendeleev's Periodic Table
    Mendeleev’s Periodic Table Ck12 Science Say Thanks to the Authors Click http://www.ck12.org/saythanks (No sign in required) AUTHOR Ck12 Science To access a customizable version of this book, as well as other interactive content, visit www.ck12.org CK-12 Foundation is a non-profit organization with a mission to reduce the cost of textbook materials for the K-12 market both in the U.S. and worldwide. Using an open-source, collaborative, and web-based compilation model, CK-12 pioneers and promotes the creation and distribution of high-quality, adaptive online textbooks that can be mixed, modified and printed (i.e., the FlexBook® textbooks). Copyright © 2016 CK-12 Foundation, www.ck12.org The names “CK-12” and “CK12” and associated logos and the terms “FlexBook®” and “FlexBook Platform®” (collectively “CK-12 Marks”) are trademarks and service marks of CK-12 Foundation and are protected by federal, state, and international laws. Any form of reproduction of this book in any format or medium, in whole or in sections must include the referral attribution link http://www.ck12.org/saythanks (placed in a visible location) in addition to the following terms. Except as otherwise noted, all CK-12 Content (including CK-12 Curriculum Material) is made available to Users in accordance with the Creative Commons Attribution-Non-Commercial 3.0 Unported (CC BY-NC 3.0) License (http://creativecommons.org/ licenses/by-nc/3.0/), as amended and updated by Creative Com- mons from time to time (the “CC License”), which is incorporated herein by this reference.
    [Show full text]
  • A Brief History of the Development of the Periodic Table
    This outline was created by Western Oregon University A BRIEF HISTORY OF THE DEVELOPMENT OF THE PERIODIC TABLE Although Dmitri Mendeleev is often considered the "father" of the periodic table, the work of many scientists contributed to its present form. In the Beginning A necessary prerequisite to the construction of the periodic table was the discovery of the individual elements. Although elements such as gold, silver, tin, copper, lead and mercury have been known since antiquity, the first scientific discovery of an element occurred in 1649 when Hennig Brand discovered phosphorous. During the next 200 years, a vast body of knowledge concerning the properties of elements and their compounds was acquired by chemists (view a 1790 article on the elements). By 1869, a total of 63 elements had been discovered. As the number of known elements grew, scientists began to recognize patterns in properties and began to develop classification schemes. Law of Triads In 1817 Johann Dobereiner noticed that the atomic weight of strontium fell midway between the weights of calcium and barium, elements possessing similar chemical properties. In 1829, after discovering the halogen triad composed of chlorine, bromine, and iodine and the alkali metal triad of lithium, sodium and potassium he proposed that nature contained triads of elements the middle element had properties that were an average of the other two members when ordered by the atomic weight (the Law of Triads). This new idea of triads became a popular area of study. Between 1829 and 1858 a number of scientists (Jean Baptiste Dumas, Leopold Gmelin, Ernst Lenssen, Max von Pettenkofer, and J.P.
    [Show full text]
  • The Periodic Table Why Is the Periodic Table Important to Me? • the Periodic Table Is the Most Useful Tool to a Chemist
    The Periodic Table Why is the Periodic Table important to me? • The periodic table is the most useful tool to a chemist. • You get to use it on every test. • It organizes lots of information about all the known elements. Pre-Periodic Table Chemistry … • …was a mess!!! • No organization of elements. • Imagine going to a grocery store with no organization!! • Difficult to find information. • Chemistry didn’t make sense. Dmitri Mendeleev: Father of the Table HOW HIS WORKED… SOME PROBLEMS… • Put elements in rows by • He left blank spaces for increasing atomic weight. what he said were undiscovered elements. • Put elements in columns (Turned out he was by the way they reacted. right!) • He broke the pattern of increasing atomic weight to keep similar reacting elements together. The Current Periodic Table • Mendeleev wasn’t too far off. • Now the elements are put in rows by increasing ATOMIC NUMBER!! • The horizontal rows are called periods and are labeled from 1 to 7. • The vertical columns are called groups are labeled from 1 to 18. Groups…Here’s Where the Periodic Table Gets Useful!! • Elements in the Why?? • They have the same same group number of valence have similar electrons. chemical and • They will form the same physical kinds of ions. properties!! • (Mendeleev did that on purpose.) Families on the Periodic Table • Columns are also grouped into families. • Families may be one column, or several columns put together. • Families have names rather than numbers. (Just like your family has a common last name.) Hydrogen • Hydrogen belongs to a family of its own.
    [Show full text]
  • THE PERIODIC TABLE Introduction • Dmitri Mendeleev Is the Father Of
    THE PERIODIC TABLE • Total number of electrons in the highest energy shell gives the group number. Introduction • If the electron configuration ends with s or p orbitals, it • Dmitri Mendeleev is the father of periodic table. He belongs to A group. arranged elements in a table according to atomic masses. He • If the electron configuration ends with d or f orbitals, it discovered many elements and left blank spaces for the belongs to B group. undiscovered ones. • Henry Moseley solved the puzzle of periodic table after Example 1 the discovery of noble gases. He arranged elements in his Determine the period and group of following atoms in the table according to atomic numbers. After his study the periodic table. modern periodic table appeared. a. 3Li • The modern periodic table contains physical and chemical b. 20Ca properties of elements. It is arranged according to increasing c. 14Si atomic numbers. d. 35Br • Horizontal rows are called periods. There are 7 periods beginning with a metal and ending with a noble gas. Solution 2 1 nd • Vertical columns are called groups or family. There are 8A a. 3Li: 1s 2s 2 Period, 1A group 2 2 6 2 6 2 th and 8B groups. The group 8B contains 3 columns. A groups b. 20Ca: 1s 2s 2p 3s 3p 4s 4 Period,2A Group 2 2 6 2 2 are called main or representative groups. And B groups are c. 14Si: 1s 2s 2p 3s 3p 3rd Period, 4A Group 2 2 6 2 6 2 10 5 called transition metals. d. 35Br: 1s 2s 2p 3s 3p 4s 3d 4p 4th Period, 7A Group The periodic table and Electron configuration • The elements which have almost similar chemical and Example 2 physical properties are put in the same groups.
    [Show full text]
  • Mendeleev's Periodic Table Background Dmitri Mendeleev Was
    Class set Mendeleev’s Periodic Table Background Dmitri Mendeleev was a Russian scientist who is widely recognized as the chemist who arranged the Periodic Table with the elements in the order of atomic weight. He observed that when arranged this way there was a “periodicity” of recurring similar properties. Other scientists were working on this same task at the time, but Mendeleev was the only one who left spaces in his table and predicted that new elements would be discovered that had the properties that matched the blanks. Mendeleev wrote everything known about the 60 elements that existed at that time on cards, and used those cards to arrange the elements by atomic weight and properties. Objective In this activity, you will use your knowledge of Periodic Trends to identify unknown elements and place them correctly in the Periodic Table. Materials • Mendeleev Periodic Table Cards • Scissors Procedure 1. Cut out the element cards – there are 34 total cards that represent the main block elements (Groups 1, 2, 13-18) in the first five periods. 2. Arrange the cards that include the element’s name as they are arranged on the Periodic Table. There will be 10 blank spaces when you have completed this step. 3. Review the properties listed on the unknown cards and place the cards in the proper place using what you know about periodic trends and metallic properties. 4. When you have finished fill complete the conclusion section below. American Association of Chemistry Teachers |1-263 1 Mendeleev’s Periodic Table Name ____________________ Period _______________ Pre lab (complete before lab) Define the following words: 1.
    [Show full text]