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Safety Data Sheet Quality System Certified to ISO 9001:2008 SAI Global File #004008 Burlington, Ontario, Canada LIQUID TIN 421-LIQUID Safety Data Sheet Section 1: Identification Product Identifier and Other Means of Identification Product Name: Liquid Tin SDS Code: 421-Liquid Related Part # 421-125ML, 421-500ML Recommended Use and Restriction on Use Use: Electroless tin plating solution Uses Advised Against: Not available Details of Manufacturer or Importer Manufacturer MG Chemicals MG Chemicals (Head Office) 1210 Corporate Drive 9347-193 Street Burlington, Ontario L7L 5R6 Surrey, British Columbia V4N 4E7 CANADA CANADA +1-800-340-0772 +1-905-331-1396 FAX +1-800-340-0773 FAX +1-905-331-2682 E-MAIL [email protected] E-MAIL [email protected] WEB www.mgchemicals.com E-MAIL (Competent Person): [email protected] Emergency Phone Number For hazardous material incidents ONLY—leaks, spills, fires, exposures or accidents USA or CANADA: Call CHEMTREC : +1-800-424-9300 For emergencies involving dangerous goods—Collect 24/7 CANADA: Call CANUTEC : +1-613-996-6666 or *666 on cellular phones Page 1 of 15 Date of Creation: 11 April 2016 / Ver. 2.02 Quality System Certified to ISO 9001:2008 SAI Global File #004008 Burlington, Ontario, Canada LIQUID TIN 421-LIQUID Section 2: Hazards Identification Classification of Hazardous Chemical GHS Categories Criteria Category Signal Word Pictograms Eye Damage 1 Danger Corrosion Skin Corrosion 1 Danger Corrosion Corrosive to Metals 1 Warning Corrosion Reproductive Toxicity 2 Warning Health Carcinogenicity 2 Warning Health Sensitization Skin 1 Warning Exclamation Acute Toxicity Oral 4 Warning Exclamation Note: The degree of severity is ranked within each hazard class from 1 (Highest Severity) to up to 5 (Lowest Severity), which is opposite to HMIS and NFPA conventions. Severity category rankings do not allow comparisons between classes. Label Elements Signal Word DANGER Pictograms Hazard Statements H314: Causes severe skin burns and eye damage H290: May be corrosive to metals H361: Suspected of damaging fertility or the unborn child H351: Suspected of causing cancer H317: May cause an allergic skin reaction H302: Harmful if swallowed Section continued on the next page Page 2 of 15 Date of Creation: 11 April 2016 / Ver. 2.02 Quality System Certified to ISO 9001:2008 SAI Global File #004008 Burlington, Ontario, Canada LIQUID TIN 421-LIQUID Continued… Prevention Precautionary Statements P102 Keep out of reach of children. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe spray or mists. P280 Wear protective gloves/eye protection/face protection. P264 Wash hands thoroughly after handling. P234 Keep only in original packaging. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. Response Precautionary Statements P310 For all routes of exposure: Immediately call a POISON CENTRE/doctor. P308 + P313 IF exposed or concerned: Get medical advice/attention. P305 + P351 + IF IN EYES: Rinse cautiously with water for several minutes. Remove P338 contact lenses, if present and easy to do. Continue rinsing. P303 + P361 + IF ON SKIN (or hair): Take off immediately all contaminated clothing. 352 Wash with plenty of water or shower. P333 + P313 If skin irritation or rash occurs: Get medical attention. P363 Wash contaminated cloathing before reuse. P301 + P330 + IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P331 P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P390 Absorb spillage to prevent material damage. Storage Precautionary Statements P405 Store locked up. P406 Store in corrosion resistant container with a resistant inner liner. Disposal Precautionary Statements P501 Dispose of contents/container in accordance to local/regional/international regulations. Section continued on the next page Page 3 of 15 Date of Creation: 11 April 2016 / Ver. 2.02 Quality System Certified to ISO 9001:2008 SAI Global File #004008 Burlington, Ontario, Canada LIQUID TIN 421-LIQUID Hazards Not Otherwise Specified Not applicable Section 3: Composition/Information on Ingredients CAS # Chemical Name %(weight) 16872-11-0 fluoroboric acid 9–11% 13814-97-6 tin fluoroborate 9–11% 62-56-6 thiourea 4–6% Note: aqueous solution Section 4: First-Aid Measures Exposure Condition GHS Code/Symptoms/Precautionary Statements IF IN EYES P305 + P351 + P338, P310 Immediate Symptoms redness, pain, severe irritations/burns Response Rinse cautiously with water for at least 60 minutes. Remove contact lenses, if present and easy to do..Continue rinsing. Immediately call a POISON CENTRE/doctor. IF ON SKIN (or hair) P303 + P361 + P352, P310, P333 + P313, P363 Immediate Symptoms redness, rash, pain, severed irritation/burns, blisters Delayed Symptoms chemical burn Response Take off immediately contaminated clothing. Wash with plenty of water or shower. Immediately call a POISON CENTRE/doctor. If skin irritation or rash occurs; or if exposed or concerned: Get medical advice/attention. Wash contaminated cloathing before reuse. IF INHALED P304 + P340, P310, P333 + P313 Immediate Symptoms cough, irritation of the respiratory track, burning sensation in throat and chest Delayed Symptoms chemical burn Response Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTRE/doctor. If exposed or concerned: Get medical advice/attention. Section continued on the next page Page 4 of 15 Date of Creation: 11 April 2016 / Ver. 2.02 Quality System Certified to ISO 9001:2008 SAI Global File #004008 Burlington, Ontario, Canada LIQUID TIN 421-LIQUID IF SWALLOWED P301 + P330 + P331, P310, P308 + P313 Immediate Symptoms mouth burns, burning sensation in throat and chest, abdominal pain, nausea, vomiting, shock Response Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTRE/doctor. If exposed or concerned: Get medical advice/attention. Section 5: Fire Fighting Measures Extinguishing Media In case of fire: Use extinguish media suitable for surrounding. Specific Hazards Will not burn. In a fire, this product can release toxic fumes and gases. Combustion Products Produces CO and CO2, boron oxides, boron trifluorides, sulfur oxides (SOx), hydrogen fluoride (HF), stannous fluoroborate Fire-Fighter Wear self-contained breathing apparatus and full fire-fighting turn-out gear. Section 6: Accidental Release Measures Personal Protection Use personal protection recommended in Section 8. Precautions for Do not breathe mist/spray. Ensure adequate ventilation. Response Remove all sources of extreme heat. Environmental Prevent spill from entering drains and waterways. Precautions Containment Methods Contain with inert absorbent (such as soil, sand, vermiculite). Cleaning Methods Sprinkle inert absorbent compound (sand, diatomite, acid binders, universal binders) onto spill, then sweep into a corrosion resistant (plastic) waste container. Wash spill area with soap and water to remove the last traces of residue. Disposal Methods Dispose of spill waste according to Section 13. Page 5 of 15 Date of Creation: 11 April 2016 / Ver. 2.02 Quality System Certified to ISO 9001:2008 SAI Global File #004008 Burlington, Ontario, Canada LIQUID TIN 421-LIQUID Section 7: Handling and Storage Prevention Keep out of reach of children. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eye, on skin, or on clothing. Do not breathe mist/spray. Do not eat, drink, or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Handling Wear protective gloves/clothing/eye protection. Take off immediately all contaminated clothing and wash them before reuse. Absorb spillage to prevent material damage. Wash hands thoroughly after handling. Storage Store in corrosion resistant container with a resistant inner liner. Keep tightly closed. Do not store together with strong bases, strong oxidizing agents, or foodstuff. Store locked up. Section 8: Exposure Controls/Personal Protection Substances with Occupational Exposure Limit Values Chemical Name Country Long Term Short Term Exposure Limits Exposure Limits (PEL) (STEL) tin and its inorganic ACGIH 2 mg/m3 Not established compounds: U.S.A. OSHA PEL 2 mg/m3 Not established (tin fluoroborate) Canada AB 2 mg/m3 Not established Canada BC 2 mg/m3 Not established Canada ON 2 mg/m3 Not established Canada QC 2 mg/m3 Not established Note: The ACGIH1, OSHA (Table Z-1), and Canadian provinces exposure limits were consulted. Limits from by RTECS2 database and data from suppliers’ SDS were also consulted. Short term exposure limits (STEL) are for 15 min and long term permissible exposure limits (PEL) for 8 h. Section continued on the next page Page 6 of 15 Date of Creation: 11 April 2016 / Ver. 2.02 Quality System Certified to ISO 9001:2008 SAI Global File #004008 Burlington, Ontario, Canada LIQUID TIN 421-LIQUID Engineering Controls Ventilation Keep airborne concentrations below exposure limits. Personal Protective Equipment Eye protection Wear appropriate protective eyeglasses or chemical safety goggles. Recommendation: Ensure that glasses have side shields for lateral protection. Skin Protection For likely contacts, use of protective gloves in butyl rubber, chloroprene, latex, or other chemically resistant gloves with a minimum thickness of 0.6 mm. For incidental contacts, use disposable nitrile with a minimum thickness ≥
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