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ANNUALANNUAL REPORTREPORT 20042004 INSTITUTE OF NUCLEAR CHEMISTRY AND TECHNOLOGY EDITORS Prof. Jacek Michalik, Ph.D., D.Sc. Wiktor Smułek, Ph.D. Ewa Godlewska-Para, M.Sc. PRINTING Sylwester Wojtas © Copyright by the Institute of Nuclear Chemistry and Technology, Warszawa 2005 All rights reserved CONTENTS GENERAL INFORMATION 9 MANAGEMENT OF THE INSTITUTE 11 MANAGING STAFF OF THE INSTITUTE 11 HEADS OF THE INCT DEPARTMENTS 11 SCIENTIFIC COUNCIL (2003-2007) 11 SCIENTIFIC STAFF 14 PROFESSORS 14 ASSOCIATE PROFESSORS 14 SENIOR SCIENTISTS (Ph.D.) 14 RADIATION CHEMISTRY AND PHYSICS, RADIATION TECHNOLOGIES 17 SPECTRAL AND CONDUCTOMETRIC PULSE RADIOLYSIS STUDIES OF RADICAL CATIONS DERIVED FROM N-ACETYLATED OLIGOPEPTIDES CONTAINING METHIONINE AND GLYCINE RESIDUES K. Bobrowski, D. Pogocki, G.L. Hug, C. Schöneich 19 BIMOLECULAR HOMOLYTIC SUBSTITUTION (SH2) REACTION WITH HYDROGEN ATOMS. TIME-RESOLVED ELECTRON SPIN RESONANCE DETECTION IN THE PULSE RADIOLYSIS OF α-(METHYLTHIO)ACETAMIDE P. Wiśniowski, K. Bobrowski, I. Carmichael, G.L. Hug 20 PHOTOCHEMISTRY OF 4-(METHYLTHIO)PHENYLACETIC ACID. STEADY-STATE AND LASER FLASH PHOTOLYSIS STUDIES P. Filipiak, G.L. Hug, K. Bobrowski, B. Marciniak 22 RADIATION-INDUCED MODIFICATION OF SHORT PEPTIDES MODELLING ENKEPHALIN FRAGMENTS G. Kciuk, G.L. Hug, K. Bobrowski 23 ELECTRON PARAMAGNETIC RESONANCE STUDY OF RADIATION-INDUCED RADICALS IN 1,3,5-TRITHIANE AND ITS DERIVATIVES G. Strzelczak, A. Janeba, B. Marciniak 24 PULSE RADIOLYSIS STUDY OF THE RADICAL REACTIONS IN IONIC LIQUIDS. INTERMEDIATE – – – SPECTRA IN THE SYSTEM Br2 /BR /SCN IN THE IONIC LIQUID METHYLTRIBUTYLAMMONIUM BIS[(TRIFLUOROMETHYL)SULFONYL]IMIDE J. Grodkowski, M. Nyga, J. Mirkowski 26 SINGLET OXYGEN-INDUCED DECARBOXYLATION OF CARBOXYL SUBSTITUTED THIOETHERS M. Celuch, D. Pogocki 27 ELECTRON PARAMAGNETIC RESONANCE STUDY OF ETHYL RADICALS TRAPPED IN SYNTHETIC H-rho ZEOLITE M. Danilczuk, H. Yamada, J. Michalik 29 ESR AND ESEEM STUDY OF SILVER CLUSTERS IN SAPO-17 AND SAPO-35 MOLECULAR SIEVES J. Sadło, J. Michalik, A. Prakash, L. Kevan 31 SILVER AGGLOMERATION IN ANALCIME J. Turek, J. Michalik 33 INFLUENCE OF IONISING RADIATION ON POLY(SILOXANEURETHANES) E. Kornacka, I. Legocka, K. Mirkowski, J. Sadło, G. Przybytniak 34 RADIATION-INDUCED MODIFICATION OF FILLERS USED IN NANOCOMPOSITES Z. Zimek, I. Legocka, K. Mirkowski, G. Przybytniak, A. Nowicki 36 RADIATION CHEMISTRY OF RADIOACTIVE TRANSURANIUM (TRU) WASTE, TO BE STORED IN THE WASTE ISOLATION PILOT PLANT (WIPP) REPOSITORY: FINAL CONCLUSIONS Z.P. Zagórski 38 ALIPHATIC-AROMATIC POLYMER BLENDS AS A PROPOSAL FOR RADIATION RESISTANCE W. Głuszewski, Z.P. Zagórski 39 CHEMICAL CONSEQUENCES OF NUCLEAR STABILITY P.P. Panta 41 RADIOLYTIC DEGRADATION OF HERBICIDE 4-CHLORO-2-METHYLPHENOXYACETIC ACID (MCPA) BY γ-RADIATION FOR ENVIRONMENTAL PROTECTION A. Bojanowska-Czajka, P. Drzewicz, G. Nałęcz-Jawecki, J. Sawicki, C. Kozyra, M. Trojanowicz 42 PROGRESS IN THE DETECTION OF IRRADIATED FOODSTUFFS IN THE INCT W. Stachowicz, K. Malec-Czechowska, K. Lehner 46 DETECTION OF IRRADIATED SPICES ADDED TO MEAT PRODUCTS K. Malec-Czechowska, W. Stachowicz 48 PROPERTIES OF THE FILMS BASED ON MILK PROTEINS RELATED TO THE INTERACTION IN THE NON-IRRADIATED AND GAMMA-IRRADIATED PROTEIN-POLYSACCHARIDE SYSTEM K. Cieśla, S. Salmieri, M. Lacroix 50 POLYESTER FILMS MODIFIED BY CHEMICAL COMPOSITION AND PHYSICAL TREATMENT STUDIED BY X-RAY DIFFRACTION METHODS K. Cieśla, R. Diduszko 52 “SELF-CALIBRATED” EPR DOSIMETERS WITH ALANINE AND SUGAR AS RADIATION SENSITIVE MATERIALS Z. Peimel-Stuglik, S. Fabisiak 54 RADIOCHEMISTRY, STABLE ISOTOPES, NUCLEAR ANALYTICAL METHODS, GENERAL CHEMISTRY 59 NEW STRONTIUM-82/RUBIDIUM-82 GENERATOR A. Bilewicz, B. Bartoś, R. Misiak, B. Petelenz 61 APPROACHES TO ESTIMATE THE IONIC RADIUS OF Po2+ K. Łyczko, A. Bilewicz, W. Brüchle, B. Schausten, M. Schädel 62 CHARACTERIZATION STUDIES AND CYTOTOXICITY ASSAYS OF Pt(II) CHLORIDE COMPLEXED BY N-(2-METHYLTETRAHYDROFURYL)THIOUREA L. Fuks, M. Kruszewski, N. Sadlej-Sosnowska, K. Samochocka 63 TRANSITION METAL COMPLEXES WITH URONIC ACIDS D. Filipiuk, L. Fuks, M. Majdan 67 TRICARBONYL(N2-METHYL-2-PYRIDINECARBOAMIDE)CHLORORHENIUM(I) AS A PRECURSOR OF RADIOPHARMACEUTICALS L. Fuks, E. Gniazdowska, J. Narbutt, W. Starosta 69 DENSITY FUNCTIONAL CALCULATIONS ON TRICARBONYLTECHNETIUM(I) COMPLEXES WITH AMIDES OF PICOLINIC AND THIOPICOLINIC ACIDS AND RELATED LIGANDS M. Czerwiński, J. Narbutt 71 GALLIUM ISOTOPES EFFECTS IN THE DOWEX 50-X8/1.5÷3.0 M HCl SYSTEMS W. Dembiński, I. Herdzik, W. Skwara, E. Bulska, I.A. Wysocka 75 EFFECT OF TEMPERATURE AND THE MECHANISM OF BAND SPREADING IN CATION EXCHANGE SEPARATION OF RARE EARTH ELEMENTS BY ION CHROMATOGRAPHY K. Kulisa, R. Dybczyński 77 ACTIVATION ANALYSIS OF SOME ESSENTIAL AND TRACE ELEMENTS IN BLACK AND GREEN TEA E. Chajduk-Maleszewska, R. Dybczyński, A. Salvini 79 POTENTIAL OF RADIOCHEMICAL NEUTRON ACTIVATION ANALYSIS AS A PRIMARY RATIO METHOD H. Polkowska-Motrenko, B. Danko, R. Dybczyński 80 SPECIATION ANALYSIS OF INORGANIC SELENIUM AND TELLURIUM IN MINERAL WATERS BY ATOMIC ABSORPTION SPECTROMETRY AFTER SEPARATION BY SOLID PHASE EXTRACTION J. Chwastowska, W. Skwara, E. Sterlińska, J. Dudek, L. Pszonicki 84 EVALUATION OF AIR POLLUTION AT THREE URBAN SITES IN POLAND USING INAA Z. Szopa, R. Dybczyński, K. Kulisa, M. Bysiek, M. Biernacka, S. Sterliński 85 CENTRAL EUROPEAN CRYSTAL GLASS OF THE FIRST HALF OF THE 18th CENTURY J. Kunicki-Goldfinger, J. Kierzek, P. Dzierżanowski, A.J. Kasprzak 89 ELECTRICAL PARAMETERS OF POLYPYRROLE NANOTUBULES DEPOSITED INSIDE TRACK-ETCHED MEMBRANE TEMPLATES M. Buczkowski, D. Wawszczak, W. Starosta 93 SYNTHESIS AND ELECTROCHEMICAL CHARACTERIZATION OF Li1.1V3O8 BY COMPLEX SOL-GEL PROCESS A. Deptuła, T. Olczak, W. Łada, M. Dubarry, A. Noret, D. Guyomard, R. Mancini 94 A NEW COMPLEX METHOD OF SAXS DATA ANALYSIS IN THE CASE OF MONOSACCHARIDE GELS H. Grigoriew 98 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART XLIX. THE CRYSTAL AND MOLECULAR STRUCTURE OF AN IONIC CALCIUM(II) COMPLEX WITH PYRAZINE-2,3-DICARBOXYLATE AND WATER LIGANDS W. Starosta, J. Leciejewicz 99 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART L. THE CRYSTAL AND MOLECULAR STRUCTURE OF A ZINC(II) COMPLEX WITH PYRAZINE-2,3-DICARBOXYLATE AND WATER LIGANDS M. Gryz, W. Starosta, J. Leciejewicz 100 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART LI. THE CRYSTAL AND MOLECULAR STRUCTURE OF AN IONIC CALCIUM(II) COMPLEX WITH PYRAZINE-2,3-DICARBOXYLATE NITRATE AND WATER LIGANDS W. Starosta, J. Leciejewicz 101 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART LII. THE CRYSTAL AND MOLECULAR STRUCTURE OF A CALCIUM(II) COMPLEX WITH PYRAZINE-2,3-DICARBOXYLATE AND WATER LIGANDS W. Starosta, J. Leciejewicz 101 CRYSTAL CHEMISTRY OF COORDINATION COMPOUNDS WITH HETEROCYCLIC CARBOXYLATE LIGANDS. PART LIII. THE CRYSTAL AND MOLECULAR STRUCTURE OF A COPPER(II) COMPLEX WITH PYRAZINE-2,6-DICARBOXYLATE AND CHLORIDE LIGANDS W. Starosta, J. Leciejewicz 102 RADIOBIOLOGY 103 INTERACTION OF DINITROSYL IRON COMPLEXES WITH DNA H. Lewandowska, M. Kruszewski 105 IRON REGULATORY PROTEIN 1 ACTIVITIES AND PROTEIN LEVEL ARE DECREASED IN THE LIVERS OF SUPEROXIDE DISMUTASE 1 KNOCKOUT MICE P. Lipiński, R. Starzyński, T. Bartłomiejczyk, M. Kruszewski 106 CHROMOSOMAL ABERRATIONS, SISTER CHROMATID EXCHANGES AND SURVIVAL IN HOMOLOGOUS RECOMBINATION REPAIR DEFICIENT CL-V4B CELLS (Rad51C MUTANTS) EXPOSED TO MITOMYCIN C A. Wójcik, L. Stoilov, I. Szumiel, R. Legerski, G. Obe 107 COMPARISON OF SISTER CHROMATID EXCHANGE INDUCTION IN Rad51C MUTANTS TREATED WITH MITOMYCIN C OR UVC A. Wójcik, L. Stoilov, I. Szumiel, R. Legerski, G. Obe 108 REPAIR OF DNA DOUBLE STRAND BREAKS IN DIFFERENTIALLY RADIOSENSITIVE GLIOMA CELLS X-IRRADIATED AND TREATED WITH KINASE INHIBITOR PD 98059 I. Grądzka, I. Buraczewska, B. Sochanowicz, I. Szumiel 109 REPAIR OF DNA DOUBLE STRAND BREAKS IN DIFFERENTIALLY RADIOSENSITIVE GLIOMA CELLS X-IRRADIATED AND TREATED WITH TYRPHOSTINE AG 1478 I. Grądzka, I. Buraczewska, B. Sochanowicz, I. Szumiel 110 EPIDERMAL GROWTH FACTOR RECEPTOR ACTIVATION IN X-IRRADIATED GLIOMA CELLS M059 K AND M059 J I. Grądzka, B. Sochanowicz 111 NO EFFECT OF INHIBITION OF POLY(ADP-RIBOSYLATION) ON THE FREQUENCY OF HOMOLOGOUS RECOMBINATION. I. ENZYMATIC ASSAY M. Wojewódzka, T. Bartłomiejczyk, M. Kruszewski 112 NO EFFECT OF INHIBITION OF POLY(ADP-RIBOSYLATION) ON THE FREQUENCY OF HOMOLOGOUS RECOMBINATION. II. FLOW CYTOMETRY M. Wojewódzka, T. Bartłomiejczyk, T. Ołdak, M. Kruszewski 114 ADAPTIVE RESPONSE: STIMULATED DNA REPAIR OR DECREASED DAMAGE FIXATION? I. Szumiel 115 NUCLEAR TECHNOLOGIES AND METHODS 117 PROCESS ENGINEERING 119 INFRARED SPECTRA OF SO2 DISSOLVED IN POLAR SOLVENTS: WATER, METHANOL, NITROBENZENE A. Mikołajczuk, C. Paluszkiewicz, A.G. Chmielewski 119 DETERMINATION OF SULFUR ISOTOPE RATIO IN COAL COMBUSTION PROCESS M. Derda, A.G. Chmielewski 120 BRIEF COST ANALYSIS OF ELECTRON BEAM FLUE GAS TREATMENT METHOD A. Pawelec, B. Tymiński 121 BOUNDARY LAYER PHENOMENA IN FILTRATION UNITS FOR RADIOACTIVE WASTE PROCESSING G. Zakrzewska-Trznadel, M. Harasimowicz 122 APPLICATION OF MEMBRANE METHODS FOR SEPARATION OF GAS MIXTURES IN SYSTEMS GENERATING ENERGY FROM BIOGAS M. Harasimowicz, G. Zakrzewska-Trznadel, A.G. Chmielewski 123 JUICE AUTHENTICITY CONTROL BY STABLE ISOTOPE MEASUREMENTS R. Wierzchnicki, M. Derda, A. Mikołajczuk 124 WATER ISOTOPE COMPOSITION AS A TRACER FOR THE STUDY OF MIXING PROCESSES IN RIVERS. PART I. PRELIMINARY STUDIES A. Owczarczyk,