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Effective Use of Filling Simulations to Balance Hot Society of Plastics Engineers 6666tthh AAnnnnuuaall TTeecchhnniiccaall CCoonnffeerreennccee ooff tthhee SSoocciieettyy ooff PPllaassttiiccss EEnnggiinneeeerrss Plastics Encounter at ANTEC 2008 May 4 – 8, 2008 Milwaukee, Wisconsin, USA Volume 1 of 4 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 www.proceedings.com ISBN: 978-1-60560-320-9 Some format issues inherent in the e-media version may also appear in this print version. COPYRIGHTED © 2008 BY THE SOCIETY OF PLASTICS ENGINEERS. PO BOX 403, BROOKFIELD, CONNECTICUT 06804-0403 REPRODUCTION IN WHOLE OR IN PART WITH OUT WRITTEN PERMISSION IS PROHIBITED. Society of Plastics Engineers 66th Annual Technical Conference of the Society of Plastics Engineers 2008 TABLE OF CONTENTS VOLUME 1 AUTOMOTIVE – D31 AUTOMOTIVE DIVISION INTERACTIVE SESSION POLYMER FLOW ANALYSIS ON AN AUTOMOTIVE INSTRUMENT PANEL.................................. 1 Bhagat, Harsh COMPOSITES – D39 COMPOSITE PROCESSING AND APPLICATION SELF-REINFORCING THERMOPLASTIC COMPOSITES ................................................................. 6 Lesser, Alan; McCarthy, Thomas; Yoon, Joonsung HYDROXYAPATITE- POLYLACTIDE COMPOSITE FOR BONE REPAIR...................................... 11 Olson, James; Shaw, Montgomery; Sun, Shih-Po; Wei, Mei STRUCTURAL REINFORCED INJECTION MOLDING OF FIBERGLASS AND POLYDICYCLOPENTADIENE........................................................................................................... 14 Hoekstra, Nicole; Lao, Edward IMPROVING WATER RESISTANCE OF WOOD-PLASTIC COMPOSITES THROUGH CO-EXTRUSION................................................................................................................................. 19 Jin, Shan; Matuana, Laurent DEVELOPMENT OF GRUBBS' CATALYZED COMPOSITIONS AS A SINGLE - COMPONENT AMBIENT CURABLE BINDER.................................................................................. 24 Feng, Jianxin; Gogos, Costas; Wan, Chen; Young, Ming-wan COMPOSITES - INTERACTIVE NEXT GENERATION ANTIMICROBIALS FOR WOOD FILLED PLASTICS ................................... 29 Woods, William EFFECT OF SHEAR MIXING CONDITIONS ON EMI SHIELDING EFFECTIVENESS AND ELECTRICAL PROPERTIES OF VGCNF FILLED THERMOPLASTIC................................... 34 Al-Saleh, Mohammed; Sundararaj, Uttandaraman EFFECT OF FILLERS SHAPE FACTOR ON THE PERFORMANCE OF THERMALLY CONDUCTIVE POLYMER COMPOSITES ........................................................................................ 39 Hong, Chang Min; Kim, Sungjun; Lee, Young Jun; Park, Sun Ho RHEOLOGICAL AND MECHANICAL PROPERTIES OF HDPE-WOOD COMPOSITES: EFFECTS OF FILLER-FILLER AND POLYMER-FILLER INTERACTIONS ................................................................................................................................. 44 Huang, Han-Xiong; Zhang, Jing-Jing UV-CURING OF ACRYLATE THIN FILMS ON PARTICULATES THROUGH FREE RADICAL POLYMERIZATION MECHANISM ................................................................................... 49 Feng, Jianxin; Gogos, Costas; Lu, Chunmeng; Patel, Subhash; Tan, Victor; Teng, Shu-Li; Wang, Peng; Young, Ming-wan; Zhang, Qi; Zhu, Linjie ELECTRICAL & ELECTRONIC – D24 ELECTRICALS & ELECTRONICS MATERIALS: SYNTHESIS, CHARACTERIZATION AND APPLICATIONS DEVELOPMENT OF ION CONDUCTIVE POLYMER GELS WITH ADDITION OF IONIC LIQUID ..................................................................................................................................... 54 Guo, Jiao; Min, Kyonsuku DEVELOPMENT OF ANHYDROUS PROTON CONDUCTING POLYELECTROLYTE BLENDS BASED ON SULFONATED BISPHENOL A POLYETHERIMIDE AND 1H- 1,2,4-TRIAZOLE ................................................................................................................................. 59 Guhathakurta, Soma; Min, Kyonsuku EFFECTS OF SOLVENT-CASTING CONDITIONS ON THE MORPHOLOGY AND PROPERTIES OF DISULFONATED POLY (ARYLENE ETHER SULFONE) COPOLYMER FILMS FOR POLYMER ELECTROLYTE MEMBRANES ......................................... 64 Baird, Donald; Lane, Ozma; Lee, Myoungbae; McGrath, James CONTINUOUS SOLUTION CASTING AND PROPERTIES OF SULFONATED POLY(ARYLENE ETHER SULFONE) COPOLYMER MEMBRANES FOR FUEL CELLS................................................................................................................................................. 69 Baird, Donald; Huang, Jianhua; McGrath, James RHEOLOGICAL, MECHANICAL AND THERMAL PROPERTIES OF PVDF/CARBON NANOFIBER (CNF) COMPOSITE ..................................................................................................... 74 D'Souza, Nandika; Vidhate, Shailesh PREPARATION OF POLYSTYRENE COATED M-NA SINGLE CRYSTALS AND THEIR NLO PROPERTIES................................................................................................................. 78 Ambekar, Abhishek; Pardhy, Neeraj ENGINEERING PROPERTIES & STRUCTURE – D26 ADVANCES IN BIO-DERIVED MATERIALS HIGH WATER BARRIER NANOBIOCOMPOSITES FOR COATING AND LAMINATION APPLICATIONS.......................................................................................................... 82 Lagaron, Jose BIO-DEGRADABLE POLY(HYDROXYBUTANOIC ACID) COPOLYMERS FOR AGRICULTURAL MULCH FILM APPLICATIONS ............................................................................ 87 Krishnaswamy, Raj; Orzolek, Mike A STUDY OF THE EFFECTS ON MECHANICAL PROPERTIES OF WPC DUE TO SMALL INCLUSIONS OF GLASS FIBER REINFORCEMENTS (GRF) ........................................... 92 Rizvi, Ghaus; Semeralul, Hamid THERMAL STABILIZATION OF BIODEGRADABLE POLY-HYDROXY-BUTYRATE (PHB) IN MELT EXTRUSION, PART 1: POLY-OLIGOMERIC-SILSESQUIOXANES (POSS)................................................................................................................................................ 95 Dodiuk, Hanna; Kenig, Sam; McCarthy, Stephen; Schwier, Chris; Shaked, Yanir ADVANCES IN POLYOLEFINS THE ROLE OF MOLECULAR PARAMETERS OF PP IN THE SENSITIVITY TO SPECIFIC NUCLEATION................................................................................................................. 100 Cermak, Roman; Chvatalova, Lenka; Obadal, Martin; Vychopnova, Jana STRACTURE AND INTERFACIAL ADHESION OF PP/PBS SANDWICH INJECTION MOLDINGS....................................................................................................................................... 105 Aoki, Naoya; Fujita, Yuji; Hamada, Hiroyuki; Kotaki, Masaya; Sano, Hironari; Yoshida, Toshihiro ULTRASONIC DECROSSLINKING OF CROSSLINKED POLYETHYLENE ................................. 109 Isayev, Avraam; Jenkins, John MISCIBILITY AND CRYSTALLIZATION OF OBC / EO BLENDS.................................................. 114 Baer, Eric; Chen, Hongyu; Hiltner, Anne; Khariwala, Devang; Wang, Haopeng; Weinhold, Jeff ADHESION OF ELASTOMERIC COPOLYMERS TO POLYOLEFINS .......................................... 119 Ansems, Patricia; Baer, Eric; Dias, Peter; Hiltner, Anne; Kamdar, Akshay; Lin, Yijian; Poon, Benjamin ENGINEERING PROPERTIES AND STRUCTURE POLYMERIC MEMBRANES FOR SELECTIVE PERMEATION OF CO2 AND O2 ........................ 124 Baer, Eric; Freeman, Benny; Hiltner, Anne; Pethe, Vishwas; Wang, Haopeng EFFECT OF FORCED ASSEMBLY NANOLAYERING ON THE PHYSICAL AGING OF A POLYSULFONE FILM ............................................................................................................ 129 Baer, Eric; Hiltner, Anne; Langhe, Deepak; Paul, Donald; Ponting, Michael INVESTIGATION OF FIBER ORIENTATION IN FILLING AND PACKING PHASES .................... 134 Chiu, Hsian-Sen; Hsieh, Dar-Der; Hsu, Chih-Chung; Yamabe, Masashi ANALYSIS OF THERMOPLASTIC PROPERTIES AFTER CRYOGENIC TREATMENT AND NORMALIZATION ................................................................................................................... 139 Dibble, Benjamin; Dropik, Martin; Lewis, Dean; Tullai, David EFFECT OF ORIENTATION ON THE INDENTATION HARDNESS AND ELASTIC RECOVERY OF A TRANSPARENT NYLON .................................................................................. 144 Baer, Eric; Hiltner, Anne; Song, John; Thompson, Geoffrey; Yang, Yankai INTERACTIVE SESSION - EPSDIV KINETICS OF MICROEMULSION COPOLYMERIZATION FOLLOWED BY RAMAN SPECTROSCOPY ............................................................................................................................ 149 Corona, Miguel; Flores, Jorge; Mendizabal, Eduardo; Puig, Jorge THE FORMATION OF STRUCTURE IN PTFE POROUS MEMBRANES INDUCED BY THE UNIAXIAL STRETCHING OPERATION.................................................................................. 154 Juin-Yih, Lai; Lei-Ti, Huang; Ping-Shun, Hsu; Shia-Chung, Chen EFFECT OF NORBORNENE CONTENT ON THE PHYSICAL PROPERTIES OF CYCLO OLEFIN COPOLYMERS..................................................................................................... 159 Han, J.; Kang, Ho-Jong; Kim, Jaehyun POLYMER MODIFIERS & ADDITIVES INTERACTIVE SESSION RELATING NANOCLAY DIMENSIONS AND ARRANGEMENT TO BARRIER PROPERTIES OF POLYMER NANOCOMPOSITES ...................................................................... 163 Gupta, Rakesh; Statler Jr, David STRUCTURE-PROPERTY RELATIONSHIPS IN NANOCOMPOSITES NANOCOMPOSITES FROM POLY(ETHYLENE-CO-METHACRYLIC ACID) IONOMERS: EFFECT OF NEUTRALIZATION OF ACID GROUPS ON MORPHOLOGY AND PROPERTIES............................................................................................... 168 Cui, Lili; Paul, Donald; Troeltzsch, Christina EVALUATION OF SHAPE MEMORY PROPERTIES OF POLYURETHANE NANOCOMPSOITES WITH
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