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Adsorption of Methylene Blue Dye from Aqueous Solution Using Hyperbranched Polyester: Isotherm and Thermodynamic Studies

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Adsorption of Methylene Blue Dye from Aqueous Solution Using Hyperbranched Polyester: Isotherm and Thermodynamic Studies IJEP 40 (11) : 1127-1137 (2020) Adsorption Of Methylene Blue Dye From Aqueous Solution Using Hyperbranched Polyester: Isotherm And Thermodynamic Studies D. Manjula Dhevi1*, T. Vasanth1, A. Sivaraman2 and A. Anand Prabu2 1. SRM Institute of Science and Technology, Department of Chemistry, Faculty of Engineering and Technology, Kattankulathur - 603 203, Tamil Nadu 2. Vellore Institute of Technology, Department of Chemistry, School of Advanced Science, Vellore - 632 014, Tamil Nadu *Corresponding author, E-mail: [email protected] In the present study, hyperbranched polyester (HBP), a biodegradable material having a large number of terminal OH groups was used as an adsorbent to study the removal efficiency of Methylene Blue (MB) dye from synthetic aqueous solution. The adsorption process was carried out as a function of varying parameters, such as agitation time (20-180 min), adsorbent dosage (0.05-0.6 g of adsorbent/50 mL dye solution), initial dye concentration (6-50 mg/L), pH (2-12) and solution temperature (303.15-323.15 K). Maximum dye adsorption was observed under 150 min of agitation time, 0.25 g of adsorbent/50 mL dye solution, 6 mg/L of dye solution and at pH 4 for 99% removal of dye, whereas a removal efficiency of 90% was achieved at 30oC solution temperature. Adsorption isotherms were investigated and found that the data fitted well for Freundlich adsorption isotherm. Thermodynamic data reveal that the adsorption process is feasible and spontaneous as indicated from the negative value of Go. KEYWORDS Hyperbranched polyester, Methylene Blue dye, Adsorption capacity, Adsorption isotherm, Thermodynamics REFERENCES 1. Renugadevi, N., et al. 2010. 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