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PROPOSED LABKLING
(FRONT P MEL)
(50s L()G(\)
TUFP'CIDE'I'M 9605
FUNGICIDE AND MARINE ANTIFQOI.AlfT FOR MANUFACTURING USE ONLY
For Por.ulating Anti.ildew and Antifouling Paints. Controls Mildew on Paint and Stain Fil.s. Protects Against Algae and Marine-Fouling OrganisaB on Antifouling Coatings.
Active Ingredient: Chlorothalonil (tetrachloroisophthalonitrile*). 96.0'
Inert Ingredients:. • 4.0' TOTAL: • 100.0\ ( *Covered under U.s. Patent Nos. 3,290,353; 3,331,735
Keep Out of Reach of Children
See side panel for additional precautionary statements
50s Biotech Corporation Agricultural Chemicals Business Painesville, Ohio 44077
EPA Reg. No. 50534-117 EPA Est. No. 35982-TX-1
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(LEl"'1' P ANRL )
TUFFCIDB':I:'M 960S
PRECAUTIONARY S'l'ATEMRNTS
Hazards to Huaans and Doaestic Aniaals
Danger
Corrosive, causes severe eye damage. May be c potential skin sensitizer.
Do not get in eyes, on skin, or on cloH.ing. Wear goggles or face shield, rubber gloves, long sleeve shirt, and long pants when mixing, loading and applying this product. May be fatal if inhaled. Do not breathe dust. Wear a ~ask or pesticide respirator jointly approved by the Mine Safety and Health Administration and th~ National Institute for Occupational S~fety and Health. Harmful if swallowed or absorbed through the skin. Remove contaminated clothing and wash before reuse.
First Aid: In cas~ of eye contact, flush eyes with Io.ater for 15 minutes; get medical ~ttention immediately. In case of skin contact, wash exposed areas of skin with soap and warm water. This product may produce temporary allergic side effects characterized by redness of the eyes, mild bronchial irrilation and redness or rash on exposed skin areas. Persons having allergic reaction should contact a physician. Note to physician: Persons having allergic reaction respond to treatment with antihistamines or steroid creams and/or systemic steroids. In case of irlhalation, remove person to fresh air and get medical attention immediately.
Environaental Hazards (c Do not discharge effluent containing this product directly into lakes, streams, ponds, estuaries, oceans or public waters unless this product is speci.fically identified and addressed in an NPDES permit. Do not discharge effluent containing this product into sewer systems without previously notifyin" the sewage treatment plant authority. For guidance, contact y' Ir State Water Board or Regional Office of the Environmentdl Proteclion Agency.
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( LKl"T PANEL)
TUI'FCIDETK 9605
PRECAUTIONARY STATEMENTS
Hazards to Huaans and Do.estic Ani.ala
Danqer
Corrosive, causes severe eye damage.
May be a potential skin sensitizer. Do not get in eyes, on skin, or on clothing. Wear goggles or fac€: ".hield, rubber gloves, long sleeve shirt and long pants when mixing, loading and applying this product. May be fatal if inhaled. Do not breathe dust. Wear a .nask or v( pesticide respirator jointly approved by the Mine Safety a.nd Health t Administration and the National Institute for Occupational Safety and Health. Harmful if swallowed or absocbed through the skin, Remove contaminated clothing and wash before reuse.
rirst Aid: In case of eye contact, flush eyes with water for 15 minutes; get medical attention immediately. In case of skin contact, wash exposed areas of skin with soap and warm water. This product may proGuce temporary allergic side effects character ized by redness of the eyes, mild bronchial irritati.on, and redness or rash on expos€:d skin areas. Persons having allergic reaction should contact a physician. Note to physician: Persons having allergic reaction respond to treatment With anti.histamines or steroid creams and/or systemic steroids. In case of 'nhalation, cell\ove person to fresh air and get medical attention immedlately.
Environaental Hazards ( ( Do not discharge effluent co~taining this product directly into lakes, streams, ponds, estuaries, oceans or public waters unless this product is specifically identified and addressed in (In NPDES permit. Do nol: discharge effluent containing this product into sewer systems without previously notifying the sewage treatment plant authority. For guidance, contact your State water Board or Regional Offlce of the Env'ronmental Protection Agency. j GRHBRAr, DIRECTiONS j inconsistentIt is a violation with its of labeling.Federal law to Use t;;5..3 product in a manner
Note to UseI': Technical chlo.othalonll llIay produce temporary IIllergic j side effects char !lete ri :zed by redness of the eyes, llIi Id "ronch ial irritation and redness or ras~ on expOsed skin arellS. Persons having allergic reaction should Contact a physician. j
DIRECTIONS FOR aSE j efer to PrOduct BUlletin PAD-98 for Use directions. 1fOTB': Formu .-tOl; of antifouling coatings are responsible for obtaining necessary ·,formation to register their paint formulation. j j
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STORAGE AND DISPOSAL
Do not contaminate water, food or feed by storage or disposal. Open dumping is prohibited.
Storage: Store in a dry place.
Pesticide Disposel: Pesticide wastes are toxic. Improper disposal of excess pesticide, pesticide formulation or rlnsate is a violatiun of Federal Law. If these wastes cannot be disposed of by us'~ according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Ha'7,ardous Waste representative at the nearest EPA Regional Office for guidance.
Container Disposal: Triple rinse (or equivalent), Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or incineration, or, if allowed by state and local autho. ities, by burning. If burned, stay out of smo~e.
NARRARTY AND LIMITATION OF DAMAGES
Seller warrants that this material conforms to its chemical descrip tion and is reasonably fit for the purposes stated on the label when used in accordanc~ with directions under normal conditions of usp and Buyer assumes the risk of any use contrary to such direct!;:,,,::;. Seller aakes no other ezpresll or i~lied warranty, including any other ezpress or i.plied walranty of Fitness or of Merchantability, and no ag~nt of Seller is authorized to do so ezcept in writing with a speci fic reference to this warranty. In no event shall Seller's liability for any breach of warranty e~ceed the purchase price of the rn~r~rial as to ~hich a claim is made.
Made in U.S.A.
\ nJFFCIDE\l'I 9605
Fungfcfde and Marfne Antffoulant
50S SIOIKII Corpor_
... ' MIl.,. Cft,,' $ lueIn ... 7528 "uOum Road, ,. O. Sox 3.. Product Bulletin P.'n ...... OhIO '4411 PAO-98
W •• CIDC '608 is a broad-:tpectrull !unqlclde and marine antl!oulinq aqent. It can be used by the protective coatlnqa industry in manu !acturinq mildew-resistant paints and stains and in manu!acturinq anti!oulinq marine coatlnqs.
l.... aNICAL DATA ComPOSition TetrachlorolsophthaJonitrile Actlw content, 'I, 98 F'ttyslcal state 3-5 mleron mlc Structural formula CH C'~CI " ,~:I~;r~': ~dd •. elV CH ·1· ' .. '.', 0:. : IIe><1p.nlH.idc Act. C J l. ':I:":'.'~t:rl. lot thc!l resticlde
Colour -Nhlt.,'IOht g~ ~~~c" ~~'!°.Jc.'}Jt7'~7 Specific gravity 1.8
MeltinO point. 'C 250-~1 Vapour presaur.. mm HO. at 4O'C <0.01 at 170'C 9.2 ilt 190'C 17.4 Stability Thermally Itable under nann.. tamperature. Ch.mlcaUy stable in alkallo. « pH 9) and acidiC aqueous m«2IL
Solubility at ~ 'C: In water 0.8 wm in xyleM 8% wIw in acetone 2% wIw APPLICATIo.S {iEST AVAUABLE. CUPf 'I'" Major apc>llcatlons In IJcottlcttve coati~ .,. p, • Control mould Orowth on 1IqU«)US Of ~,t baNd exterior palntL
• Control mould Orowth on aqu.aus Of ~ baNd lIa1nL • ·t •• • PIt,."t fungal growth on masonry paint.. , . • J>rt\eht foullno of mario. coati nos by aIgM. bemacl.., tubewonn .. muaMIa, hyrlrolda. lu!',ca'.. and bryazoML
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- low order. toxicity. - hydrolytic stability. -, extremely low water solubility for better control of leaching rate'3. - low vapour pressure. - fine particle size allowing higher loading than with liquids. - pH stability. - stahle to UV radiation.
GENERAL DIRECTIONS
It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
Note to User: Technical chlorothalonil may produce temporary allergic s.1de effects characterized by redness of the eyes, mild bronchial irritation and redness or rash on exposed skin areas. Persons having allergic reaction should contact a physician.
uIRECTIONS FOR USB
E~terior Paints and Stains
TUFFCIDE 960S is compatible with a ilide variety of surface coating resins, such as unmodified or alkyd-modified acrylic, vinyl acrylic, polyvinyl acetate, epoxy and polyester resins.
The selection of the proper dosage is dependent on the length of time mildew protection is desired, the mildew incidence in the market area in which the paint will be used and whether zinc oxide is used in the paint. Generally 200 to 500 grams of TUFFCIDE 960S per 100 liters of ( exterior paint or stain are sufficient for effective mildew control. When zinc olCide is used in conjunction with unmodified acrylic or alkyd-rr.odified acrylic latexes, an increase in mildew control has been observed without increasing the amount of TUFFCIDS 960S used. It is recommended the paint or stain formulator perform cost-performance evaluations to determine the optimum dosage r~te for his system.
TUFFCIOE 960S is a micromilled powder which is best dispersed du~!~~. the pigment grinding operation. Grinding equipment normall:r' usecl: In: the paint industry is entirely satisfactory...... , If an in-can preservative is used in combination with TtJFFc.~~E 960~ ... its co:npatibility should be examined first. Studies hllv~ showll certain in-can preservatives can react with dispersed TUFFCIDE.960S to produce yellowing. SOS Biotech Corporlltion can provide adv!ce"CJh': suitable in-can preservatives...... "" . \ BEST AVAILABLE CO[l
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Marine Antifouling Coatings TOPFCIDB 9605 is a unique antifouling biocide for use in marine coatings applied to ship and boat hulls and other submerged surfaces. TOPl'CIDB 9605 has demonstrated effectiveness against barnacles, algae and tubeworms, the principal forms of fouling on ocean-going vessels, and against mussels, hydroids, tunicn.tes and bryozoans, which are prevalent when the ship spends protracted periods at dockside. TUPFCIDB 9605 has prr;,ved effective as the sole antifouling agent in marine coatings based on chlorinated rubber, polychloroprene, acrylic/ rosin, alkyd/rosin and vinyl/rosin. When used with cuprous oxide or bis(tributyl tin) oxide, TU~GIDB 9605 has evi~enced a synergism that results in slime control on ship hulls. The low water solubility of TUPFCIDB 9605 makes it especially useful as an antislime adjuvant for use with copolymer ablative coatings. TUPPCIDE 9605 is added to the marine coating during the pigment v (( grinding operation. Dosage levels are dependent on the length of time antifouling protection is desired, the temperature of the waters in which the ship will operate and the ingredients in the marine coating. It is the responsibility of marine coating manufacturers to determine the necessary information needed to register their coating formu lation. The information in Tables 1-4 is based on tests conducted on experi men~al coatings applied to various substrates which were submerged in subtropical waters.
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,. TlIFFCIDE 980S ...... on WcIt Iuie , •• _file Neap"" Al>10'" s.4-e." .. Wood NeopfeM A0-10 e.3 Fibetgl&U Nec!'"...."e A[)'10 10.3 AlumInum Neoprene CO 5.2·1S''' . Wood NeopfeMWRT 5,3'" Wood NtoprWI. WRT 21.3 St... PartonO $-5'" 4.1 Wood
(1) N~. synthe1lc rubber. E.L duPont de N~ra & Co .. Inc. (2) Parton cniorfnaltd natural rubO«. Hercul... Inc. (31 Ref. to Tao," 3 and • for formulated coatings. (~ Ref. to Tables 2 and • for formulated coatings. !
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ilolliN .. ~ on .. 11_ Woode COIting ,. TUFF'CIDE 9605 Code OnweclaM Herd SNII .... SaIt 10,. TotIII • I"ou!Inf' ~.,.. 1'01 M", eo ... l;e OS 1e' 5.2 5 i' 8 OS teo 1!to 3 5 e OS 23' 5.3 9 10 t2 Control' 0.0 3 • •
, Neap,.". CO J Neoprene WRT J Comm'iCIaI antifouling palnt. (averaged) • Alg.., bvgula and tunlCe1 .. I BlJT1acl .... tubeworma, oy.ters and ~
.~ ". p .... A.l).10 ,. TUF.FCIDE 960S ,...... ~ OnW.... C I "'" Code ,. oIWaloh ...... Co ... ..tbr~ 1-4 • . • OSHea US 0 ~ 15 OSH 1Q8 5.315 0 15 15 DSN 133 7110 0 0 0 . , OSH 143 g.... 0 • - 2 2 ..
\ Product BuUetJn • Table 4 contalne the lormul.. lOf th ... palnta.
T8b6e4
F«mIMCode 119111 .- ,.e., OS oa oa DIN DIN DIN DaN W..... 1. l' U 10 101 1~ 141 Neoprene AD-10 -- - 13.40 13.40 10.~ ".:IS ( NeopreneCG 11100 1S-00 - - - - - Neopre!le WRT - - 1~.OO -- - - r nJFFClOE 960S s.3O 1S-00 ~.30 5.305 5.34 7~ 9.40 Benton .. zr ThIcMn. O.~ 0.07 O.oe 0.54 0.06 0.07 0.11 TollJen4t :)g.38 34.02 - 00.71 81.20 .,.42 ~.80 Benzene :)g.37 34.01 78.75 - - -- Xylene -- - - - 1S-~7 11.35 ZJnc Oxide 0.75 0.75 0.75 - - 0.« - MagnesIum oxIde 0.71 • ------I - MSTS' O.l~ O.l~ O.I~ - - - - TETA' 1.00 1.00 - .- - - - SlIIcat" - - -_. -- 9.~ - TItanIum dIoxide - - - .- 10;SU 2.84 Methyl ethyl ketQM - . - - - - 3.11 - Talc ------5.90 Pnth.~lne blue ------5.e7
------J ~ Product Bulletin
Typical formulations lor chlorinated natural rubbef, Icryllctrosln, alky1dlroaln and vlnyl/rOlln coath :qa lellow.
Chiortr .., Natural "ubtIw eo.lInt Ing*lent Parion 54 c:tIlortnatlld rubber TOIuen. 18.9% dioxide ~.O Tlt~lurn 18.9 nMCIDE 960S 8.2 100.0% Physical Constants
TUFFClDE 960~arlon 5-11 0.43 SolidI, weight ". 46.00 SolidI, \IOIume % 30.00 TUFFCIOE 9605 YOlume % Dry Solids 17.20 PoI.indI PM gallon 9.,lS ! Acryt~ Co.dng Acrylic rolln Roaln 6.0% Oloctylphthatate 12.0 Xylene 2.0 Red Iron oxide 20.0 Talc 10.0 • 20.0 Batyt.. 10.0 Cuproul oxide 1M TUFFCIDE 9605 5.0 100.0% PhysiCal Con.tant. (( TUFFCIDE 9SQS'Resin + Rosin 0.28 Solids. welght ". 80.00 Solld~ YOIume ~. TUFFC DE 9605 volume % ~ Dry Solids 7.2.Q Pou~ P*f gallon 13,SO
· .. . , Arcrcn " eoello. ., . .. RosIn · ..... UnN«foll 21.0% Fatty ICld 7.0 , . , '" , .... lead 0Xlde 3.0 .' , , Mlnglllnl drier, 8% 1.0 . " 1.0 .. VM&P~ · .. , .. Miner. IPWftI 10.0 . Aect If\)n OXIde 11.0 ' ...... ~Oldde 11.0 TUFFC I DE 9605 ao ... • 10,0 " 100.0%
~ PhytIcaJ Const ant, ruFFC10E q60~aln + Ao~n 0.32 SoIIdI.~% 79.00 So1tc't~UIM'" 5UO TUFFC DE 9605 ~ume'" DrySoikD 17.80 PoundI per ~Jon 1•. 10 \IIi., • .... c.o.tli'I Vlnyf realn VAGH' 11.2% AoeIn Red /ton oxide 17 TalC 15.1 '1.2 ZInc oxide 7.1 Metftyf I~tyf ketone Xyl.~ 20.0. Prtimbl 0' hntone X1 18.0 iI\4 Met/lan04 0.5 nJFFCIDE 9605 0.2 110 100.0% 'f')roduct Union C&I'bId. Corp. '''(~ 0' P'hyllcaJ Const3tlts TUFFClnE 96GSfResin + Rosin Solid .. Wetght % 0.87 Solid .. volume % 81.80 nJFrCrnE 9605 'IOlumc ..... l8.2O Cry Solldt 1* gallon 25.00 Pounda 11.15
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\ PRECAIJ'l'IONART STATEMKN'l'S
Hazards to Huaans and no.estic Aniaals
Danger Corrosive, Causes Severe Eye Damage
May be a potential skin sensitizer. Do not get in ey~s, on skin, or on clothing. Wear goggles or face shield, rubber gloves, long sleeve shirt and long p~nts when mixing, loading and applying this product. May be fatal if inhaled. Do not breathe dust. Wear a mask or pesticide respirator jOintly approved by the Mine Safety and He~lth ~dministration and the National Institute for Occupational Safety and Health. Harmful if swallowed or absorbed through the skin. Remove contaminated clothing and wash before reuse.
First Aid: In case of eye contact, flush eyes wi th water for 15 ""{(' minutes; get medical attention immediately. In case of skin contact, wash exposed areas of skin with soap and warm water. This product may produce temporary allergic side effects character ized by redness of the eyes, mild bronchial irritation, and redness or rash on exposed skin areas. Persons having allergic reaction should contact a physici'ln. Note to physician: Persons having allergic reaction respond to treatment with antihistamines or steroid creams and/or systemic steroids. In case of inhalation, remove person to fresh air and get i,edical attention immediately.
Environ.Ental Hazards
Do not discharge effluent containing this product directly into lakes, streams, ponds, estuaries, oceans or public waters unless this product is sped eically identified and addressed in an NPDES permit. Do not discharg<; effluent containing this product into sewer systellt5 without previously notifying the sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office 0':: the Environmental Protection Agency.
STORAGE AND DISPOSAL
Do not contaminate water, food or feed\ by storage or disposal. 'Open dumping is prohibited.
Storage: Store in a dry place.
Pesticide Disposal: Pesticide wastes are toxic. Improper dfsposal of excess pesticide, pesticide formulal·.ion or rinsate is a violation of Federal law. If these wastes cannot be disposed- of by use ac.corrUo{J to label instructions, contact your State Pesticide or Environmentt'J. Control Agency, or the Hazardous Waste representative at the n€~:~~~ EPA Regional Office for guidanc~.
H~- IWA!lflBU cop{1 \
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Container Disposab Triple rinse (or equivalent). Then offer for recyclIng or reconditioning, or puncture and dispose of in a sanitary landfill, or incineration, or, if allowed by state a"'ld local author itie'3, by burning. If burned, stay out of smoke.
MAIlRANTY AND L IMITATION OF DAMAGJro
Seller warrants that this material conforms to '.b (:hemical descrip tion and i:3 reasonably fit for the purposes stat~d or, the label when used in accordance with directions under normal conc~tions ?f use and Bu:'er assumes tile risk of any llse contrary·to suci, jirecdon:!:. SeJ.. er _kea no other ellpres/J O\: i.plied warnmty, im.-luding any other express or i.plied warranty of Fitness or of Merch~nt~bilitYI and no Agent of Seller iSl autborhed to do so except in wrH:~!,g with a speci fic reference to this warrao.ty. Ir. no event shall S~Uer' fl li3.bIli ty for any breach of w~rranty exceed the purchase price of the material as to which a claim is made.
CONTAINER
TOFFCIDE 960S is shipped in polyethylene-lined fiber drums which can be tr iple-r lnsed to remove residual a·lst.
EPA Registration No. 50534-117
PAD-98 (4/3/85)
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