SDMS Document ' 1 SfV6^ n ! 65293 ; 4-'fVBO
g!B ANALYTICAL DATA REPORT PACKAGE for m
NORTH SEA LANDFILL
PART lit
OCTOBER 1987 01 > Submitted by: o o H2yH LABS, INC, ' HOLZMACHER, McLENDON and MURRELL. P.C. ^ Consulting Englnaers. Environmental Sclenllsls, Architects and planners <<> ^^ Melville, N.Y. RIverhead, N.Y. FalrMeld, N.J. T f| t> fr\jfA•i iJKL/ ^ mV l LABSI.MD9| , IPIVINC« . 97SBItO>^HOaOMfflOAO,MELVILLE. NY. 11747 •S16-«»4-304 i^ __ I: HOI^MACHER McLENDON and MURREU, P.C • ENVIRONMENTAL Mid tNOUSmiAL ANALYTICAL SERVICE u
ICP tO^VELaxnH CALIBRATION
AND SIATISUCS FOR FITIED OJWES.
CO PI > o o ts)
CO , en , CHAIN Of CUSTODY RECORD rnoJCCT NAUi
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CV«t«VN lo Huj*^R 3- f^ 3-S. a. o 9-»» a-xg) nL?> ^-^o I Mw'^H^ lA>_^±_L£__Lii-±.32- HK-^M-^M- V\w^M-0 \ A O^IS \ 0 \ v^ V •X-(^ nt'^H^S ^ 5" 1 P.e>> KUvrvfe; I A- ) 6 U U lC> -?UM-H:>. \R \0 \W \XC) "l.^H^<^ r r r Sasple Ralljpul^hed by jSeaole Rpioeived by'" Data pae aottleType F«3e<9aD r \ I ^"^ AUL_ ..ryi /, t^-^r^' tf CtJ \^ I'hkli^ r 'IJg^..^ MtK/?X---ffH:^^,/^y ) II ^ iLo± flL...uUjJ.y^^^-uiA ^ fee P Sr#^^^^- ',^^//) u ^ li/UMei'OU^^iMA../'t^ I—<1 -^&xy^j>7m ^ ijm ''IM A tiZH LAaOMTomr ZDf to Sgd/t'k^' Page 2 Oontiniinc Chain of Ogtady • ^"ft^ysis By Date AWLlvst S'iccvrttpe Date Custodian Sicrvrtiire Ol-iS-lri 1 1 : '^o: ciV iii- vj£:;ve.ie BTHi''iDP;- ariC; £T;r-C ^•o:, i.;v 1 c^ri !;iE..p i r^r; j. rip wDNTJr^UE ? Y '&aK urr -'ear- . .1 GniGV'it -••: :; i ': i ~jft !•; i.i m b e r- 'nt I nt en 'nt. & J n" eyi!; i 3-i /::5 No P.-:.-'-- ftS No Peak I 3 f-l/ft 130 or i^'.. 1 S-t i Cii tor'' Ai: i.Jw. ?5i^ ftV£Rft6E --• O V. R. S. D. = O. OOO £ranriir;p ^r-c:ii.i^:c SE iSb.Ci90 ' f a I-'. ilemerit Po'sitiori NuroDer- Intensity Pnt, 1 nt en; 'nt. £ I nt en ] SE No Peak! i H/^A SE No Peak I S N/A ISl No Pt'Sk' S W-'v Statistics for SE 196.090 V. R. S. D.. = 0. 000 Scariri J. np i-r.-"ourid SS i'Oo;'. SSS P^^ak Rep 1 i r at i c^ri T'tji-.r -'05. Off- Pf^ak Off Peak Is.rnsr.t Po-£iition I'-iLimbBr .Interis:. ty Pnt. 1 ivitsns t-'nt. S iritens. SE ]'\'.< PG&kl :. l^j/fi Sca^i^tics.- fov" SB SOti. 8..:.S '. h- £. D. = C. -.^O'.' Scarr-.irT ^P-o>.iri-- 7N c'iS.SSf. P'e&k Rer-l i cat i orr Peak Pos, Off Peak " •.': e rri i? r; t .1--' C' s i b 1 o rr .N :.i rii b e r- I n t e r: s i t y Pnt. 1 .Intens 2l\! No j-'eak ! 1 N./ft ZN No Peak I £ N..-'H IN ivo P'eak! 3 i-i/ft Statistics fov- 2N S13.SS6 H'v'EftftGE = 0 % R. S. C. = O. 000 Scarrninp Hro'.tnd P'E< £E'C). 353 y-'E:£\\: Re-'p 1 i Cat 1 cin f-''eak F'os. Off P'eak Oft Peak : i e ni e r 11 P •;• s i t i o r; N i.i m b e r I vi t e ris i t y Pnt. 1 Intens Pnt. S Inten; ::;i P, N:^ P'eak I N/.C) No Peak! N/H No Peak! H/P, Statistics, f NLUllDeV- ^rix ens i Pnt. i iritsris i-'nt . S I ri" e ri 5; CD N / h) 394 CD No F'eak ; N./ H 369 CD Y'ic Peak' N/'ft 3S7 it ar 1 st i CE for CD SSo. Oi HVERH6E (j > o o to 00 -It.-l'-aS ilJ 11:48:46 — S' v; R. S. D, = 'J. '•-'<-)(.! £31.S04 ^'eak Repi 1 csit i ori Peat-', Pos. Off Peak Of P'eai- -L1 eiiitjnt Pos-11 i on N i.i ni b e r I rs t B n s i t y Pnt. 1 Inten; P'nt. ; inte-.-'i Ni - I'io ^-'6:'ak 1 N./A 459 NI No Peak £ N..''A 4S£ Nl No P&&U. 3 N./A 454 Stat 1st ics for Ni £31. 6'04 P'v'ERftGE % R. S. D. = 0. O0<'j Scar;r\ i rip Ar-C'u rid BE £34.S6i r-' e a k R e r; 1 i C' a t .: C' 'i P' e a !•'. .-' o EI . Off Peak Off Peak :i3:::s>nt Position N i r;i b e r I r: t e n s ; t y Pnt. 1 Inten; it. £ Intens BE No Peak! i N / A PE Nr- P'eak: £ N/H BE No Peak! 3 N / A Stat i St ics for BE £34.S61 AVERAGE = O •/ R. S. D. O. OOO ScarIri i r 1 n Ar€• und M£57.61N 0 Peak Replication P'eak Pos. urf Peak Off Peak ! 1 e rn e n t P o s i t i o ri N u rn b e r I n t e n s i t y Pnt. 1 Intens Pnt. £ In-ens MN No F'eai' : 1 f'.! .•' A MN No Peak I £ N./A ;';N NO Peak: 3 :,/ • P; Stat i st ics for MN £57.610 ••- ^. s. r. ScanriiriQ ftroi-ind FE ;59, 940 Peak Replication Peak Pos. Off Peak Off Peak -1 e 1.1G n t k' C' e i t 1 o vi ••-i urn her intensity Pnt. 1 Intsns Pnt li iritens -E No Peak! 1 N/A ^- S • Is•:.• i-'eaK i iz. i\ / A ics for FE A'V'EIRHSE R.. S - D. I.J. '•.••:>'-. Scanr:?. •':£} Pir'-urid CR S't: / . / 1 fc P'e£ik Repi i cati Pea k Pos. Off PesK Off Peak /' ! i ernent P'os- i t i on Number Int ensity Pnt. 1 Intens Pnt. £ Intens' CR \-io PeaP. 1 N/fi 446 CR No Peak N/A 445 CR No Peak N./A 44S > Stat 1Et ics for CR £67.716 o AVERAGE o •/. R. S. D. 0. OOO Is) Scanninp P^T--ounc NG £79.079 P'eak Rcs'pl icat ion Peak Pos. Off Peak Off Peak 00 iemen';- P'osition Number Int ensi ty P'nt. 1 Intens Pnt. £ Intens (J '''ici Ncj P'eak ! 1 t'J./A M3 No Pes\U. \ lE.' N/A H v CI r. V-: Lv L:. ~ '.j V. i-5. ^.. D. = O. OOO Scarining Around AL 3J'0&.£i5 PeaP'. Replication P'eak P'os. Off Peak Off Peak /Lenierit P'osition Number Intensity Pnt. 1 intens Pnt. £ Int en;; Hi_ ->:li. 'J077 i N/A 376 AL -O. 0079 £ r'./A AL —O. CiC>S£ 3 N/A St at i st i cs for PiL 3'OS. £ 1 5 AVERAGE = O > o o CD (D 01-1S-19SS C- 11:57:39 — 3 y. R. S. D. = O- OOO Scanning Around CA 317.933 Peak Replication Pe£ik Pos. Off Peak 0-^f Peak [:: 1 G m e n t P' o s i t i o vi N u. rn b e r Intensity P'nt;. 1 Intens P'nt. £ Intens CA No P'eak N/ft CM i'Jc: i-'oaP N/A • CA No P'eaP N/A Stati'stics tor 'CA 317.933 AVERfiGE = 'D •/• R. S. D. = 0.000 'Scannirip A'rc^urid C'J 3£4,7'54 Pea.k Replication P'eak Pos. Off Peak Off Peak £le.:nent P'ositicn Number I rit !?n=. i ty Pnt. 1 Intens Pnt. ;! : Intens CO No Peak : 1 N/A 316 3J ;• •-' P'uak: £ N/P; 313 C'J No Peak ! 3 N/A 313 Statistics for CU 3£4.754 AVERAGE = O ••< R. 3. D. = 0. COO Scanning Around AG 3£S. C)68 P'eaP? Replication P'eeik P'os. Of-^ Peak Off P'eak •II ernent Position Number Intensity Pnt. 1 Intens Pnt. 1; Intens AG No Peak! i N/A AG No Peak! £ N/A AG No P'eak ; 3 N/' A Statistics for AG 3£8.068 AVERAGE = '-' :; R. S. D. = 0. 000 Scanri i ni p Ar^o uno E:A 455. 4'03 PeaP; Replication P'eak P'os. Off Peak. Off, .-•'eak Element P :• s 11 i o n !'•; u m b e r- 1 ri t e n s i t y P'nt. 1 Intens -'nt : ir.tens L'ri No P'eak' , 1 . N/A EA i'4C> Peak ! £ N/A BA No .-sal- ! 3 N/fi S-.avisties for BA 455.403 AVERP^GE = O % R. S. D. = 0. OO'O Scanning Around NA 598.995 P'eaPc Replication Peak P'os. Off P'eak Off Peak L 1 ernent Pos i t i on N urn ber Int ens i t y Pnt. 1 Intens Pnt, ; Intens NA -C>. OOJ5 1 N/A NA -O. 0005 £ N/A NPi -O. 0005 3 N/ft • Statistics for NA 588.995 AVERAGE = 0 '/• .R. S. D. = O, 0(JO iH_ANp; RE-CALCULHTED AT END OF CALIBRATION Enr.er STANDARD NUMBER •; 1 - 7) or -1 to EXIT: standard #£' solution aspiratinq — CONTINUE ? P'& al' iJ •: V fe r : • _• ••-•:• V d ,;riT:. eriE- P: Lr, 0, 'OI'CK;:- • i AC i,^. Of.-'., 7 £ PtG 0. oO'j'y 3^ St a'c 1 st i cs f or AG 3£S.06 AVERAGE = 4(;HJ'0 % R. S. D. zz 0. 367 STANDAKE) it£ > o o I Is) I OO cn 0l-i6-l'=»3S I? r£:07:4& — 4 •Zlernent Wavelength Ave Int V- R. S. D. Ref Blank Int Off P'eak Int Net 1 nx- P)G Zi£8. OSa 400C) C). 387 O 4OOO 3,n-i;er STANDPlRD NUMBER \l - 7) or -1 to EXIT: 3 ::> t a r-id a r-d M £ s:;:• 1 ut i on Sisp i r-at i ng - CDi';''I I N'JE ? Y Scanniriq Arciund AG 3£S. •^JGS P'eak F^epiication P'eak P'C'S. Off Peak Off Peak ;:i ernent Position .Number Intensity P'nt .1 I nt en; "nt. £ Intens r'.'S C;. 'Ci'.",>Ci8 i 1645.3 AG O. O'-'i'OS £ 1845S' AG -0. '.:i007 3 18481 St .vti-sties for AG 3£ii. (I>£8 AVERAGE = l&46£ STANDARD *t3 Elernefit Wavelength Ave Int •/- R. 3. D. Ref Blank Int Off P'eak Int Net Int AG 3£S.066 1B46£ O. 09O 0 1&46£ ;;-:te- STANDARD NUMBER <1 - 7) or -1 to EXIT: 4 Standard #4 solution asDiratino - CONTINUE ? Y Sca ;'ir. i •,-•: c A -.-• .':• unL AS 1 9 3. 75 5 P'eak Replication P'eak P'os. Off Peak Off Peak :: 1 e m e r, t P' o s i •;. i ci 'r i Number"- I -ri c e n 's i ',: yP'nt . i In'.er'is P-.-'it. £ Intens A'3 -0,0031 1 £90 138 141 P.-5 -'1'. 00£& £ £39 139 136 AS -0. 0'J£5 3 £S6 i " 9 Statistics fo-r A3 193.759 AVERAGE = £9£ % R. S. D. = 1.333 Scannirip Around BE 196.'O'd'O P'eak Replication P'eak P'os. Orf P'eak Off P-eak E1 em e ri •:. P :• -s i t:'. c-n- :'•! u r,-^ be r I n t e n s i t >- Pnt. 1 I-nteni P'nt. £ Inter' SE -(.">. 'Oij'JG 1 30£ 'SE -O. 00'05 £ £95 SE -'0. 00It.) 3 £89 S t a 11 s t i c s f o r S E 19 6. O 9 C) AVERAGE = £95 y. R. S. D. = £, 347 Scanriing PVround ZN £13.856 P'eak Repi icEit io'n P'eak P'os. Off Peak Off Peak U) Ilement Position Number" Intensity Pnt. 1 Intens Pnt. £ Inten PI > ZN , -O.00£e 1 4392 137 ZN -O.0030 £ 4393 134 o ZN -O.0031 3 4415 139 o Statistics for ZN £13.856 AVERAGE - '+40.;:) ••: R. S. D. - O. 303 00 Scani'ii-np PlY-ound P'B ££'0. 353 P' ear- R e p i i c a 11 o r-, P e a k P o s. Off Peak Off Peak P't Statistic-c ror Pt< ££0.733 AVERAGE = 3-h£ % R. S. D. = 1. 95^ Scannir-ig Around CD ££6. 5C>£ PeaPi Replicatiori P'eak P'os. Off Peak Off Peak '. 1 e rn e ri t P' o s i t i C' r: N u rr. b e "i"- " -•'i t e 'ri s 1.1 -,' P'nt. :•- In ten Pnt. £ Intens m PI > \ o ts) 03 01-18-1988 & i£:i6:i5 'CD 0.00£8 1 51 £6 406 CD O.00£S £ 5175 419 CD '0. Ci'OE fi 5 1 95 st at ist ics for CD ££6.50£ AVERAGE 5166 % R. '3. D. = 0. 673 Scanning Around NI £31.604 Peak Replicat ion P'eaP; P'cis. Off Peak Off Peak ?_" 1 ernent P'OS it ion Nurnbe-r Intensity Pnt. 1 intens Pnt. £ Intens NI -0.0013 1 £334 485 NI —0. 0015 £ ££98 4 7'5 Ni -0.0015 ££49 471 Stat ist ics f'O-r i-jl £31. E,0", AVERAGE = ££94 •: R. E. D. 1.853 Scann:, ng Around BE £34.861 Peak Replicat ion P'eak P'os. bff Peak Off Peak Ele.me-nt Posit ion Number" I-ntensi ty P'nt. 1 Intens Pnt. £ Inten; BE 0.0014 i 5E346 BE 0.0017 c! 5£435 BE 0.0019 . 5££43 Stat ist ics for BE £34.861 AVERAGE = 5,1:3-'^'-1 % R. S. D. = 0.184 •Scc,,''rrii:fii j Arou-r;d r^N £57'. t-i'j Peak Replicat ion P'eak P'os. Off Peak Off Peak E i ernent P'OS it ion I'-iurnber' Intensi ty Pnt. 1 I.'it ens •it. £ I.'it en; !-'1N -0.0006 1 17500 MN -'0. 0006 c! 17564 MN -0.0008 i744£ SzBX- i ::t ics f.:.r MN £5?'. 6lC AVERAGE 1750£ V. R. S. D. Scann 1---; '"• Pir ounr: FE £59. '3^.-0 P'eaP; .-•;epl ica w lor, r-'eak h'c*;;-. Off PeaK Off P'eaK El ernent Posit ion Number I-n tensity P'nt. 1 Inte-ns P'nt. £ I-nten; FE -0. 0'030 1 14 87 FE. -0. OOG'l! £ 1470 FE -0.0031 1464 Stat ist ics for FE £59.940 AVERAGE 1460 % R. S. D. 0. 60£ Scanning Around CR £67.716 Peak Replicat ion P'eak P'os. Off Peak E 1 ernent Posit ion Number Intensity Pnt. 1 Intens CR 0.00£5 1 5 i 53 CR 0.00£5 £ 3 1 7 1 CR 0.00£7 3135 •Stat ist ICS f o r C R £ 6 7.7 16 AVERAGE 3155 % R. S. D. 0. 53£ -'K i-'ear-- ::nt K I r-.z ti-i-; i^r^- -O. OOO'^ 1 835 NG -O.0O03 £ 837 fiG -O. 00C»4 3 819 'Statistics f o-r M G £ 7 3. O 7 '9 A'VERAGE = aS'O >; R. 5. D. = 1. 159 Scanning Ar"-ound AL 308. £15 PeaP; Replicatiori P'eak P'os. Off Peak Off Peak Element Position Number Intensity P'nt- 1 Intens Pnt. £ Inten; I-* O O 01-18-1988 Cf i£:£5:l9 — 6 AL 0.0010 1 991 386 AL O.O0l£ £ 976 387 AL O. 'ill009 £ 989 390 St at i st i cs f or A£ 308.£1 AVERAGE = 966 •/. R. S. D. = 0. 8£1 Scanning Around CA 317.933 P'eaP; Replication Pestk P'os. Off Peak Off Peak Hlerne-nt Position Number Intensity Pnt. 1 Intens P"nt. 2 Intens CA ~'0. 0004 1 1551 CA -O.'0003 £ 1555 CA -0.0001 3 1555 'Statistics fc^r CA 317.935 AVERAGE = 155-* •-. R. • 3. D. = - 0. lc-5 Scan-riing Arciund CU 3£4. 75'^ Peak Replication Peak P'os. Off Peak Off Peak •ii I ernent Position Number Intensity P'nt. 1 Intens P'nt. 2 Intens CU -O.00£5 1 3615 524 CU -O.0024 2 3651 CU -O. 0023 3 3650 Statistics for CU 324.754 AVERAGE = 3639 , :/. R. S. D. = 0. 558 Sc^.rr:";! rir.' A-round BA •S55.4';IJ3 Peak Replication Peak P'os. Off Peak Off Peak Element Pc'Sition Number Intensity Pnt. 1 Ii'.te'ns P'n";. £ I:'ite-ri£ EA -O. ':.')'J45 1 8-946 BA -O.0047 2 8930 BA -O.0046 3 8883 Statistics for BA 455.403 AVERAGE = 89£C! % - R. b. D> = O. 575 Sc::7-nninD Around NA 568.995 P'eaP; Rep^i iceit i C'''. P'eak P'os. Ut"T "--ec.K ^•VT r--eclK ^ 1 ernent Position Number Inte-fisity p-nt. 1 I-ntens .P'nt. £ Int en; NA -'0. O'OOS i 1£75 NA -O.0006 £ 1270 NA -0.0006 3 1279 Statistics for NA 588.995 AVERAGE = i£75 •/. R. S. D. = O. 340 STANDARD #4 E'lernent Wavelength P^ve Int •/. R.S.D. Ref Blank Int Off Peak Int Net BA 455.403 89£0 O. 573 BE £34.861 5234 1 O, 184 o CD ££6.50£ 5 1 66 O. 675. 411 CR £67.716 .i 1 ^w' O. 58£ 464 CU 3£4.754 5659 0. 558 I'iN £57.610 1 750£ O. 350 Nl £31.604 ££94 1 . l_,. wJ O 47: lal. -•>-•-• '-'--- 3ij8 i -.-£-.i • 0 t 0£ i'j U l-i _'•- i / . 'd 3 ^'- 1 554 0 165 1 554 MG £7'9. 07'9 830 - 1 159 o 830 NA 588. 995 1£75 0 540 o 1£75 '01-13-i'r*a8 * 1£,:31:45 SE 196.090 £95 £. ^.-H / V 295 AS 193.759 £9£ 1. 333 139 1 w<^ PB ££0.353 348 1. 954 '0 348 Enter 'STANDARD NUMBER •; 1 - 7> O'r -1 TO EX II Stand£ird #5 solution aspiratinq CONTINUE 'Scan-ri i-riQ A'round AS 195.7''59 P'eak Replication - Peak Pos. Off P'eaP; Off Peak '-'iernent 'P'osition Number Intensity Pnt. 1 Int ens Pnt. 2 Intens AS —J. '0027 1 944 149 1 40 AS -U. O-JET £ 919 147 140 AS —O. 0^I>£7 ~ 95-^ 149 135 Statistics for PiS l'93..75'9 A'-.'ERH3E =-- . 939 •/l R. S. D. = 1.90E' Scanning Around SE 196.C)'90 Peak Rep 1 i cat i on- Peak Pos. Off Peak 0"^f Peak Element Position Nurnber- I -nt ens i t y ••^•nt. 1 I-['it ens Pnt. £ I -nt en SE -O.OOll 1 983 SE -O.0012 2 949 SE -O.00lO 3 979 Statistics fo- CE 196.09 AVERAGE = 970 •'-• K. 5. D. = 1.3 b -r Sca-nning Around 2N 213.856 P'eak Replication P'eak P'os. urf P'eak Off -eak E i erne-rit Pos 11 i cin N-jrnZ'sr In-teTiG ity P'nt. 1 Intens Pnt. ZN -O.0026 1 22451 178 ZN -0.0027 2 22391 ZN -O.0026 5 22429 1 / Statistics for ZN £15.856 AVERAGE : = ££4£H % P.. S. - D. = 0. 154 Scanning Piround PB 22Ci. 353 P'eak Replication Peak P'os. Off Peak Off !^'eak Element Position Number Intensity P'nt. 1 I-ntens Pnt. ;; Intens P'B -O. 0022 1 1 140 PB -O.0021 £ , 1151 PB -0.0019 3 1126 Statistics for PB 220.353 AVERAGE = 1132 •/. R. S. D. = 0.617 Scanning Around CD 226.502 Peak Replication P'eak Pos. Off Peak Off Element Position Number Intensity P'nt. 1 Int en; Pnt. ;: CD 0.0023 1 25755 CD O. C)024 £ £530£ CD 0.00£6 3 £5385 Stat ist ics for CD -££6. 50£ AVERAGE = 25475 i->ca;':i'il •"iC; HrC'uriG Nl £j,:i . L-OH Peak t-;s'pl i,c:-at lori Peak, ~'C'\u... h-'eSiK i::. 1 s rn s ri x Posi,t ion Nu.mbe-r- int £•:-.£-1 ty : ".-•- e ri; - Ivi-nei'ft NI -0.0016 1 1 Ci 1 1 £ 5 £'-.-' NI -0. 0C>16 £ 9970 i\' I -0.0017 3 10091 511 Stat ist ics for NI £31.604 AVERAGE 10057 % R. S. D. 0. 76£ Ul PI > o o O CJ 01-18-1988 (P 12:41:04 — Scan-ni-ng Around BE 234.S61 Peak Replicat ion Peak Pos. Off Peak Off Peak E 1 ernent P'os i t ion Number Intensity Pnt. 1 I-riten; Pnt. £ Intens BE 0.0011 1 £74956 BE 0.0011 £ 275897 BE •0. O'Ol 1 3 276946 Stat ist,ics for BE £34.361 AVERAGE £75927 •/. R. S, D. = 0.364 Scanning Around MN £57.610 Peak Reelicat ion P'eak Pos. Off P'eak Off Peak E:1 ernent P'os it ion Nurnbe-r Intensity Pnt. 1 Intens Pnt. 2 Intens MN -0.0016 1 90575 MN -0.0017 2 907 1 1 ^iN -0.0017 £ 9 1 1 62 Stat ist ics for MN £57.610 AVERAGE 90825 •/. R. S, D. 0.351 'Scani'ii ng Around FE 259.940 Peak Replicat ion Peak Pos. Off Peak Off Peak Element Posit ion Number Intensity Pnt. 1 Intens Pnt. £ Int ens FE -0.0038 1 7107 ^~ d. -0.0036 •z- 7148 FE -0.0035 3 7149 Stat ist ic-3 for FE £5-9. 9-^0 AVERAGE 7135 •/. R. S. D. 0, 333 Scann1ng Piround CF\- 267.7^6 Peak Replicat ion P'eaP; Pos. Off Pe-ak Off Peak E:iemB-nt Posit io-n Number Intensity P'nt. 1 Intens -'rit. £ I-nte-rr 'L; --.' '0. 0'.)£3 J. 14671 CR 0.0024 i-' 14660 CR 0.0024 3 14644 49..:. St at ist ics for CR £67.716 AVERAGE 14656 •/. R. S. D. = C). 0'-:i'li Scanning Around MG 279.079 Peak Repl i c^-it iZ'r: Peak Pos. Dfi Peak Off £ i ernent Posit ion Nurnbe'r Intensity P'nt. Intens P'nt. ; 1 nt. ens:. / MG -0.0008 1 2871 MG -0.0007 2 2860 MG -CI. 0008 3 2879 Stat ist ics for MG £79.079 AVERAGE 2670 •/. R. S. D. = 0.339 Scanning Around AL 308.£15 Peak Replicat ion Peak Pos. Off Peak Off PeaP;! Eilernent P'os it io-n Number Intensity P'nt. 1 Intens Pnt. £ Int! AL Ci. '001 1 1 5376 4£8 O 1 C). C)C>1 ij CI 336£ 431 P~L (). C>C>C>9 jft 3336 4 £6 AVERPlLiE 33 V t. 'A f-. S. ' D. ~ '-.'•- £66 EiCcirii'i i riz .; Arounc: CA 317.933 Peak Repl icat i ori P'eak P'os. Off Peak Off Peak E!l ernent Posit ion Number inte-nsity p-nt. 1 Intens Pnt. 2 Int en; CA -0.0007 1 6119 'CA -0.oooe Zf 6079 CA -0.0006 606 C) St,.^t ist ics for CA 317.953 AVERAGE = 6086 % R. S. D. 0.500 U) PI > O o ts3 CD O en 01-18-1988 tf 12:46:59 — 9 Sc an-n in g Around cU 324 . 754 Peak Re piicat i ciri P'eak. P'os. Off P'eak Off Peak E 1 ernent P'osi t i o-ri ''Jurnbe'r"- Intensity :'nt. ; Inten; P'nt. £ Intens CU -0.0034 1 17729 36C> CU -0.0032 £ 17672 559 CU -O. C:030 3 17716 565 Stat ist ics for CU 3£4 . 754 AVERAGE = 17 706 % R. 3. D. = O. 1 70 Scanning Around BA 455 . 403 Peak Re pi ic-at io n Peak P'os. Off P'eak Off Peak Ell ernent ,Posi t i .on Number Intens i ty Pnt. 1 Intens Pnt. 2 Inrens BA -•0. C'047 1 45784 BA -0.0047 c! 43348 EA -C). C)047 w' H 39 IE- Statist ics for BA 455 . 403 AVERAGE = 43 348 •/. R. S. D. = 0. 146 Scann i-ng Around NA 588 . 995 Peak Re piicat ion Peak Pos. Off Peak Off Peak Element P'os 11 i oni Nurnber Intensity Pnt, 1 Inten; P'nt. 2 Int en; NA -0.0008 1 4531 , NA -'0. 00'03 2 4395 NA -Cl. OOiCi w* 4468 '-3-cat iso ics for NA 533 . 995 AVERAGE = 4 465 % R. S. D. = 1. i530 STANDARD M -' 1 ernent Wavelength A -•/G Int 'A R.S. p. ReRef Blank Int Off Peak int Net In"! BA 455. 405 4 3846 0. 146 O 45844 . '.~-C £34.361 d ;' Cl' 'z? 4I, / 0. 364 CD ££6. 5'0£ 25473 0. 399 CK £67.716 14653 C'. 0'92 ^96 CJ 3£4.754 17706 'C. 170 56 1 i-/t;'-; clZV. 61 0 90823 0. 351 NI £31.604 3 0057 0. 762 519 ' ZN £13.356 £2424 0. 134 177 AL 308.£15 w'ii» /O 0. 366 428 FE £59.940 7135 0. 533 0 CA 317.933 6086 0. 500 0 MG £79.079 2870 0. 539 0 NA 586.995 4465 i. 550 0 SE 196.090 970 1. 954 0 AS 193.759 , 959 i. 902 143 PB £20.353 1 132 0. 617 0 Enter STANDARD NUMBER • 1 - 7) or- - 1 to EXIT: £-1; andard #6 solution as p i -r a t i -ri Q -CONTINUE ? lan-riing A.-'ound 'oB £'06. 3£3 P'eak Repl i cat i ori Peak p. Off Peak Off Peak o£ r--:c. v-'eat-; : SB No Peak: SB No P'eak! S-t at 1 st ICS f o-f" SB E'Ob. S3: AVERAGE Cl 01-13-1938 •& 12:51:56 — 10 •/. R. S. D. = Cl. 000 STANDARD +»6 Element Wa-ve length A-ve Int •A R.S.D. Ref Bla-nk Int Off P'eak Int Net Int SB £06.635 O (.1. f.icici (.1 Enter STANDARD NUMBER <1 7) • or -1 to EXIT: 'Staridard #7 solutiori aspirating - CONTINUE Y Sca-nni-ng Around 'SE^ £C)6. 833 P'eak Replication Peak P'os. Off Peak Off Peak Element P'os; t ion Number Intensity Pnt. 1 Intens Pnt. £ Intens SB No Peak! 1 £67 SB No Peak! £ £64 SB . No Peak i 3 £69 St at i .it 1 c i • f or 'SB £Ci6. .£33 A'VERAGE = £67 % R. S. D. = 0. 944 STANDARD #7 Element Wavelength A-ve I-nt '/• R.S.D. Raf E'.lank Tnt Off Peak I-nt Net Int SB 206.833 £67 O.944 O 267 Enter STANDARD NUMBER (1 - 7) or -1 to EX IT: -1 STANDARD ^^1 ernent W^-ive length Ave Int •/. R.S.DR.3.E . Ref Blank Int Off Peak Int Net Int AG 3£fc.068 3 bo N/A Cl £80 BA 455.403 191 N/A C) 191 BE 25'T. 861 252 N/A C) CD ££6.50£ w'O^ N/A 3'90 CR £67.716 463 N/A 446 CU 524. 7'54 331 N/A 314 MN £57.610 36D N/A i[) N I £31. SCi-s- 42 Z N / A 453 ZN 213. 356 , 138 N/A 127 1 1 SB 2 06.333 £80 N/A Cl 23':' AL 3C^3. £15 436 N..'A 374 1 12 FE 259.940 167 N/A Cl 167 CA 317.933 420 N/A Cl 4£0 MG 279.079 323 N/A o NA 588.995 519 N/A Cl 519 SE 196.090 136 N/A- C) AS 193. 759 134 N/A 154 PB 220.355 156 N/A Cl statistics For Fitted Curve 01-18-1988 tf l£:5e:03 — £ Results For AG ££&.06S Low intensity High Intensity Intercept , Slope Curvaturt Cur-ve 1 380 1846£ -O.£1007 O. 0005: O. UUi-lUO Standard Tntensitv Co-ricen. Calc. Con. Con. Error "/. Error Order .i8u Cl. OCiCi O. OOO 0. OOCi 1 400C1 2. OOO £. OO 1 0. oc>i Cl. C>5 1 13462 lO.000 Cl. 005 -0. 05 1 Not in Stand£(rd No 'he RMS Error ii Cl. 0_iO'. Results For BA 455.403 Low Inte-nsity High I-fit e'risi ty I-ntercept Si ope Cu-rvat ure. Cu'f've 1 1'91 43343 —•J.CIH376 lO0£-i O. C-OCiCiC; Standard Intensity Concen. Calc. Con. Con. Error '. Error Order Ll. O'LlCl 0. CiOO C). OOO 1 t •* -Z' C- i I*"; w- C Cl fi w cA f' C Not in Standard 8920 2. oCiO 2. 0'^:>C' Results For BE 234.861 Low Intensitv High Intensity Intercept Slope Curvature I o O L'.rrve 1 "275927 —Cl. 01 O Cl 8 O. Cl Cl Cl O 4 Cl. 'O'OCiCiCi lit andard Intensit-y Conc^i. Calc. Cori. Con. Er-^ror % Error"- Ordi -^ 00 statist ics For Fitted Cur-ve 01-18-1938 C" 12:58:19 — 3 O. CKJU O. OOO Cl. (JCICI £ Not in Sta-ndard 3 Not in St a-ndard 4 52341 2. 528 2. 264 -O. 064 76 5 275927 11.641 11.978 O. 557 90 6 Not in St a-ridard 7 Not in Standard The RMS Error is 2.628-/. Results For CD 226.502 Low Intensity High Intensity Intercept 'Slope Cu"rvature Curve 1 -6 25Ci£l Ci. 00246 Ci.0CiC)41 0.00000 Standard Intensity Concen. Calc. Con. Con. Error '/. Error Order 1 -6 '0. OCiO Cl. 000 Cl. OCiO 1 £ Ncit in 'Stancard 3 Not iri Standard 4 4755 £.000 1.951 -'0. O-HS -£.44 1 5 25021 10.000 10.257 0.257 £.57 1 6 Not in 'Standard 7 Not in 'Stanaarc! The RMS Error is 2.505% RES u Its t- c:.r CR 26 ,'. 7 i 6 Low Inte-nsity High I nt-e.-'isity I-.'^tsrcept 'Slope Curvature; ' J u -r •-• e 1 17 14162 -0.C11237 0. 0Ci073 0.00000 Standard Intensity Concen. Calc. Con. Con. Error "/• Error Orde to PI 17 Cl. 000 O, Ci'OCi Cl. CiCiO > Not in Standard Nc^t in Standard O 2689 2. OOCi 1. 944 -O. 056 79 o 14162 ICi. CiCiO 10.292 O. 292 92 Nc't in Sta-ndard Not in Sta-ridard CO 7 o CD V ; 'Statistics For Fitted Curve 01-18-1988 & 12:58:34 — 4 "he RMS E-rror is ;. 857-/. Results For CU 324.754 Low Intensity P-tigh Intensity Intercept Slope Curvature Curve 1 17 1734J -O.OlOCib O. OCiCi59 O.'OOCiOO 'Stand srd i r"i t erisi ty Cciricen. Calc. Co*"!. Ccin. Error "/- Error Order -* 17 OCi'J O. OO'J Cl. CiCiO 1 2 Not in Standard t.^ Not iri Standard 4 3317 £. CiOCi 1. 952 -O. Ci48 40 5 17345 10. CiCi2 lOi 251 O. 250 50 6 Not ir, Standard -7 Not in Standard The RMS Error is 2. 449-/. Results F cr- MN 25 /. 610 Low Intensity High Intensity Intercept Slope CuT^v at- ure , ^;rve J, 6.5 9Ci3£3 -0.O4144 O. CiOCUl Cl. ClClClClCl 'St £: -rid a'rc I nt ens i t y Cc>riceri, Calc. C-on. Con. Errc-r irr-o,-"- 0""-dB 1 365 0. OCiO 0. OCiCi 0. 000 £ r,i.- ..- i-n Standard 3 .•••• C- 'i- i ri Standard 4 1 7502 2. OCiCi . 1.946 -0.054 -2., 63 5 90323 10. CiCiO 10.274 0. 274 2. 74 6 Not in Standard 7 Not in Standard The RMS Error is 2.710-/. Results For NI 231.604 Low Intensity High Intensity Intercept 'Slope Curvature lur-ve 1 - -35 '9538 O. Ci37££ 0.00106 O. OOCi'00 statistics For Fitted Curve 01-16-1988 C« 12:58:49 — :a-nda-r-~d I-nt ensity Concen. Calc. Con. Con. Error % Error Order 1 —35 Ci. CiCiCi Cl. (.10-O O.000 1 2 Not in Standar-^d 3 Not in Standard 4 1817 £'. 001 1. 969 -O. 032 -1. 61 5 9533 ICi. CiCi7 10. 179 O. 172 1. 72 6 Not in Standard 7 Not in 'Standard The RMS E-rror is 1.664% Results For ZN 213.856 Low Intensity High Intensity Intercept Slope Curvature Curve 1 11 22247 -0.00506 0. 00046 O.00000 Standard Intensity Concen. Calc Con. Con. Error % Error Order 1 - 1 1 • 0. OCiCi 0. OOO O. OClCl 2 Not i I'l 'i 'c a I'l a ard ^ Not in Standard 4 4263 £. 001 1. 957 -O. 0H4 -t;. c'o ir •p. :--q O ,2££47 10. CiCi6 10.£36 O. ££9 6 Not in Standard 7 Not in Standard RMS Error is C . C ^ w '- Results For SB £06.833 Low Intensity High Intensity I-ntercept Slope Cur-vature wUrve 1 O £80 :15. 38462 -O. 7692; (.1. oouoo , cn ' standard I-nt ensity Concen. Calc. Con. Con. Error '/. Er-r-or Ordt |Ti ' £30 0. 000 O. OO'O O. OCIO Not in Standard Not in Standard Not in Standard N C" t i n Staridard Cl £. O'JCl 215.585 585 1CI669. £. 'Statistics For Fitted Curve 01-18-1938 1? 12:59:04 7 267 10. OOCi 1 Cl. CiCiCi O. OCiO O. '00 "ne RMS E-rrc^r is 7544.235-/. Results For AL 508.215 Low I-nt ensity High Intensity Intercept Slope Curvature .1,1 rve 1 112 £"::<43 -Cl. 41704 Cl. 00377 Ci. OCiOCiO Staridard Inte-risity Cci-ricen. Calc. C-:n. Con. Error '• Er-.-'-Cir- Order 112 o. uuo o. CIO. Cl. O'Jt 1 N ;• t i -ri 'Stand a. r d Not in Standard 598 £'. OCiCi 1. 83= -O. 165 -8. 24 2943 . 0. CiOO 10.6S£ O. 686 6. GS Not in Standard 7 Not in Standard The RMS Error is 7.5B1% Results For FE 259. 94Ci lope C u r -V- a t i.t )•" e CU'.-VU; 1 1 O/• -O. £--r_'C.£ O. 0Cil47 •'. Cl. Staridard Intensity C.-once-n. Calc. Con, Cori, Error -/• Erro-r Order 1 167 .1. OC'O '•-'. i.i'.i: O. 001 £ Not i-n Sta-ndard 3 Not in Standard 4 1480 £. CiCiCi 1. 937 -Cl. '063 - w-. ± .-I 5 7135 10.OOO 10.£76 O. £76 2. 7o 6 Not in Standard 7 Not in Standard "he RMS Error is 2.965-/. Results For, CA 317.955 LC'v. I ntei-isi ty High' I-r11 e-nsi ty I nt er-cept SIope Ci.i-r"-•/at ur-e statistics For Fitted Curve 01-18-1988 C" 12:59:19 — 7 Cuf-^ve 1 42Ci 6086 -0.74112 O.CiCil76 O. OCiOOO St a rid ard I nt e'ns i t y Concen Calc. Con. Con. Error -/• Error Order 1 420 Cl. CiOCi' O. OOO o. 00(.l 2 Not in Standard 5 Not in Sta-ndard 4 1554 2. 'OCiCi 2. 'OO 1 0. 001 0. 04 5 6036 ICi. O'OO 9, 997 -O. CiCi3 -Cl. 03 6 Not in Standard 7 Not in Standard 1 e RMS Error is Ci. 055••: Results For MG 279.079 Low Intensity High Intensity Intercept Slope Curvature Curve 1 323 2870 -1.26915 0.00393 Ci. OOCiOO Standard Intensity Concen. Calc. Con. Con. Error -/• Error Order 1 «liCt^ 0. 000 0, 001 0. 001 1 2 Not in 'St aridard 5 Not i-n Standard 4 330 2. 000 1. 994 -Cl. C10& -O. sC' tzr 2870 ICi. OC)0 10.014 Cl. 01 4 O. 14 6 Not i •;"! St and a.-d 7 Not in Standard RMS Er -ro-;-- is 0.2 •i Results For NA 588.995 Low Intensity High Intensity Intercept Slope Curvature cn 4465 -1,£2376 0, CiO£56 O. OCiOOCi p] Curve 1 519 > Staridard Intensity Concen. Calc, Con, Con, Error :/- Error Orde! o 1 519 0, 000 0. 007 Cl. 007 1 £ Not in St£indard 5 Not in Sta-ndard CD 4 i£75 £. 000 1 . 946 -0.054 -£. 70 J. I-" (J .t ist ICS i-or Fitted Cur-'/e 01-13-1983 I? 12:59:35 — 6 5 4465 10. OCiCi 10.127 O. l£7 1. 27 6 Not in Staridard 7 Nc't in Sta-ndard lie RMS Ern: 2. 109-A Results For SE 196.090 L-ov) Intensity Hi ah Intensity Intercept Slope Curvature I—-./e 1 136 97Ci -1.63995 0,01214 O. OOOOCi ~ sirioar-d I rr':-ensity Coricen, CaAc. C.'- 1 136 O, CIOO 0. Oil O. Oil 2 Not i-n Standard 3 Not in St andard 4 295 2, 001 1. 940 -O. 061 -3. 05 ^ 970 10.006 10.132 O. 126 1. 26 6 Not in Staridard r-jot in Staridard Tne RP'iS Err-'OT"- is 2.334' Results For- AS 193.759 •nsity Hirjh Inte-nsity Int ere sot Sl-:ipe Cur-'-at u.-^e .u.---.'e i O 796 0. 0-3642' .. 01£44 Cl. '.':':iV-JO 1 n L £? 11 ^ 1 ^ y C-r'ncer, Con, ' C iiii"i. ErrC'r '-. Er 3^"dC:l 1 0 Cl. Odd V. (.196 •J. 096 £ N -z-t i ri S t a 'n d a r d 3 Not in Stancard 4 153 2- 000 2. 000 O. Cl'..10 O. OO 5 796 10,000 10.000 O. CIOO 0. 00 cn I 6 fvlot in Standard p] 7 Not in Standard > ' "he RMS Error is 1.E7E-11-/. o o CD Results For P'B 220. l-» statistics For Fitted Curve 01-13-1988 C" 12:59:49 Low Intensity i High Ints-nsity Intercept Slope Curvature Curve 1 156 1132 -1,60306 O.CiiOSO O. OOO'OO Standard Intensity Concen. Calc, Con, Con, Error -/• Error Order 1 156 Cl. OOCi O. 003 O. CiCiC 1 2 Not i-n Standard 3 Not in 'Standaro 4 348 2, 002 1. 981 -O. 021 -1. 07 5 11 32 10,010 10.054 O. Ci44 O. 44 6 Ncit in Sta-ndard 7 Not i-n Sta-ndard The RMS Error is O, 8i&-/. line Of Best Fit hf IIC 328.868 22164' :onc ~ m 2.S8 5 J1 1.59 im Press the ( m) key for POP-UP tienu. i&i;[Ciaw.!i'iiiitiBgMMiMiMWjyiMi Lin? Of Best Fit for BH 455.483 52611 a Cone l^ 2. 7.5S ie.S8 p-u? wenu. FiNE^ mm mil mmmPwss the (Honem ) keiiop cn i PI > ,- o o ^ I !-• I ^ ! line Of Best Fit for BE 234.861 321?98i Fifst Order Curve 24134?' t I \ mm 5 !/ :;onc 8J 2.91 5.82 8.73 11.64 Press the (dew) keg for POP-UP nenu, mmmmmmmFw mmmtim Line Of Best Fit for Q 226.592 232?3> y Mii ^M 2.58 Press the (How) ken for porup «enu, FiHELV mmmii line Of Best Fit for CB 267.716 16512 S .one m 2.59 7.59 im Press the (Hone) keg for PO?-UP wnu. FINE? mmm^ in ; PI 1 > \ o o CD too -Line Of Best Fit for 01 324.754 26387 H C>onc 8.^ 2,58 Press the (Howe) keg for POP-UP mm, FINELY mm MTU Line Of Best Fit for «H 257. Cone 8.^ 2.58 7.58 FIHELV mm Dftift Press the (Hone) keiijor POP-UP wnu. a«:^mMH»iiaiiaiHE}i« CO p] > o to CD W Line Of Best Fit for NI 231. 11252 vonc ^M 2.58 18.81 mm MTU mmmPress the (Howi ) keg for IPOP-UP wnu line Of Best Fit for 2N 213.856 26899 t .1 6525-^ y Cone 8.88 2.58 Press the ikm) kegforjop-uoenu. in ! Fl 1 > O I o : CO Line Of Best Fit for ftL 388.215 3319 vonc 7.58 18.88 Press the (Hone) keg for oop-up wnu. FINE? mmmfi cn PI > o to CD Ul Line Of Best Fit for FE 259.948 833?T e n s i t g Cone 7.58 18.88 Press the (Hone) keg for FiNELS mmnn cn P>I o to to Line Of Best Fit for CU 317.933 7385 »onc 7.58 18.8S Press the (How) key for ?op-up wnu. FiNEy mmmii -line Of Best Fit for NG 279.879 First Order Curve Cone 8.88 2.58 7.58 18.88 Press the (How) keg for poru? wnu, FiHE^ mmmk CD PI > O O to CD to 00 j/vH- ti2M LABS, INC. fvlS^^ i^tiA- ///^/U CUP LAB. NO. t^F^TTr.T OIL. FACTOR I CAc RLir Di^^ t^uc vag^£^ glMiC LCS xc\/ ?6S^66 /viiMfL S^p, cH C/^ O. ^/; 7_^c£^L^iM ^i'-> f^- Mn 8 ^ A--^ ^^^)f to "'•^fi w 4- 4^)V^ J/ \z ^3^^- mui^irV 13 4.^f-mio CD to CD I ' rii.-< trv.C l^Ad. fbC CrtL Ci^L CAL ^'^ rt^6^ (JiriffRK -bTO STO vc^. s^'.Ve %^ep prvvT i^ 5xcr?OL/fr'^'^ (3^ i) 3?S -0^^ J:0- 10.0 ...^. P K]', ^il.to4 60 o.Ao Oc2XO 2i3 aSt 4 ^.0 cao o.ioo I ^ 0? 5.0 Sb ^•^Q 0.3CO ------0 ^ ^^ 2.2.0.3531 Vh T — - -- - • ^ H3 Sn < Se nt.C^o i fe A Al Z'^b. ISZ so (£)-0 '^ Q 2S^.^Ao fe - - - {^-0 3-0 ^SO.o 1 (^ Ca A^2,.b93 ^.0 5.0 300.0 / Cc-nc. 0) t^.o^ ^.0 ^.0 /60.0 "^ ,,. Si^.^i^S a.o lO-O 5.0 50.0 J , . s ^v+CC. noVo 0/ /o^tSC-^ 8S-I20 90-/I0 75-122- 7S>Di- SSr^^S" pfecQL "^ fix .__,_ loVo . ^(V^IZl^ we r ~N cn o. PI > 5^ J?S.pJL.J?>-C«^- .^... O. ! to ?e.etx%:,^>reCl - {-go/fi ^O i^:rX>L' 50^/^ f^sD CO CJ o •i2A4 LABS, INC. S7S BAOAO HOUOW ROAO. MELVIue. NY. 11747 • SliB-«04.3O40 HOLZMACHEa McLENDON and MURRELL P.C • CWVIROMilENTAL •nd IWOOSTWIAL AWALYTICAL SgRVtCES Date m/st Duplicate Serial Initial Cup. CoDtrol AaoBt Dilution Element Result Result RPD Luut Result Spited Reooverv Result Difference Notes h. OO <)0 f^ ilo To lOO 10 ^^ /OO toe so .... jk.^^. 1 • \ Cd k^ O 9^00 }%D %0 o '41 Si?/. 3ox> 000 ^1 1 fe. 'J 1— CD CJ I-" if • • i2A4 LABS.INC . S7S 8AOAO HOUOW ROAO. MELVIUE. NY. 11747 • S I.D.t mtx3 46 Duplicate Serial iInitial Dip. Ccotrol SpiJied taouQt % Dilution Element Result Result RFD Linit Result »iJwd Reoooery Result Difference Notes ^3 ^3 cn 0\C p] ^ n LO so i^Po ^Ho <5oo °iQ > -r o Kf P(? loo 000 to fii I? 0 loo '\% CD U to Analyze Samples 01-18-1988 C« 13:01:36 — 1 No ft/S File Selected 1:HIGH £•; INTtR 3:NSEft3.£'14 4: SB STfiNDftRD •AC.ND: •• PG UP' to 'v'iew Mor-e Lines Fn iO or ''ESCape' to Stop ViewINTEK INTERELEMENT INTERFERENCE STANDARD Bepiri AnalysiE - Sample Number- 1 Ele. Wave— .Mea-ri l-'eak i-'lea'i Peak Net Peak Sym. lengtt"! ("'osition IriteriEity I riterisit V ZN £13.&5& Off Peak Int. 14£ O. OOi. 4536 4 394 CD 326.50£ Off Peak 2r.t. ^HO l.li.l'.,'^! •••4 M 1 5i:)01 NI £31 . 60'+ Off Peak Int . 4B5 — .1. ':!i'.'04 ££V8 17-:i3 BE c.'3A.Q61 -0.OOOG 540££ 540££ MN £57.61 -v. «;IM07 16077 lfc077 FE £59.9A -0. '.(•J06 165 9'-.19 165909 CR £-S7.7i6 Off P'eak irit.. =. 4&£ -0. 'jf.i'.i /•' 3£&4 £7S£ MG £7'J.07gt, —0. 'J'JiJS 3ag£i 58921 HL ji-'^it'. £ 1 5' Off f'eak int — 667 * -0.OOO3 17955 1 7£e6 CA 317.933 -O.0007 170168 170168 CU 3£4.754 Off Peak int. 5£0 -O. 0015 3747 34£7 cn , p] I > o Calculating Concentrations for Sample Number 1 o .to Elern- Wave- Net Peak Calculated Interference Net /> 0'^ ^ Sym. lengt^^ Intensity Co'ncentrat ion Correction Concentration U) ' CJ ! BE £34.861 540££ 2. 337 O. 015 2. 322 I OO CJ CD £26.50£ 5001 2. 052 2.052 ^'^ CR 2.^1.1\^ £782 2.012 £.012 100 Analyze Samples 01-18-1988 ifi 13:06:55 — £ CU 324. 754 34£7 £.017 O. Ci£4 1.993 fOO MN •'-. er -/ 61 ISO 7 7 £.012 2. 01 £ <=i^ Nl £31, 604 1793 1. 944 O. 074 1, 870 [00 7.N £13. S56 4 394 £. 018 o. ozo 1- 968 \oo AL 308. £15 1~'£88 64.696 64. 696 -Krt?- F£ £59. 94 165909 £44.418 £44, 416 \00 CA 317. 933 170168 £99.514 £99, 514 [•-IG £79. 079 38921 151.749 151. 749 —• Enter Number of Repl i cat i C'^fS/Measureme-rit INTERELEMENT I NTEHi-ERENCE STANDARD Becin An£;lvE-is - SaT:?.-";'^ '-i. r.i'i'er £ b ,1 e. Ua vG I'^tfzj'ar'f r-'tr',ii--. •••'• ft;:>ij !-•;.; t Ptjak Sy'ii- leriq-t, ri V- I ritti-f',, 11- Int ensity LN £1.I:. ii'5G Off ;-'eak l-.'.t. = 14£ 1 44 143 141 13t< Peak, intensity - •^558 5HO A5S£ 4563 0. '.:'.:Oe (w^ HI 4 4£C) CD £26-502 Off Peak Int, 4 £5 451 441 445 457 P'eak I'rit ensity = 55^3 5507 • t 54U 5470 5446 -O, 0007 5502 O, 765 5056 cn NI £31.604 PI > ; Off Peak I-r.t, 496 501 515 507 506 o ' Peak 1-rit e-risi t y = £280 ££66 i 305 ££84 £3£0 o to -O.00l£ ££91 0.934 1786 BE £34.861 iD Peak Interrsity = 54340 54386 5-: 187 54144 54417 CJJ -O.0009 54295 O.225 54295 MN 257.61 ia£i9 ibL FE £59.94 Ar.ajyze Samples •j 1-16-1988 0? 1.:.: 13:56 Peak rritefiE.! t-/ -- 1 L.EOECi I&E.-.C-M 1 I,.:-I-...J:'6'-J . 166541 167 10fi- -'.:.'.":(,,) 1 1 166459 •:'. c-it 166459 267.716 Off Peak int. = 478 M'/\ i-B£ 471 Peak I-rit evis;:-. •• .- - 3£-44 3£S9 3£54 3£65 --:>. ••'-••'.'1 1 3£67 . 0. 595 £789 MG £7':^. 079 Peak Inte-risity :-,.SSl£ 38494 33676 38725 3 6 7'4 4 -0.0010 38730 0.374 38730 AL 508.215 Off P'eak i-,-,t. obc' t-,. / w- 668 Peak I -('it en':=. 11 v iS'.'Si ia'-;>44 1 &0£O ; / '-i'-y-. -:''. :"-••.> I 1:BCa ti';.a 5n. -.1. s-L't.- :7 348 CA 317. •£*33 Peak Inte-nsi t-y = i7i084 :t-9£6£ i7-C'i3£ 17151 -0.0011 170384 0. 7£4 170384 CU 3£4,754 Off Peak Int. = 33'0 3£e P'eak Intensity = 3747 37,35 w, /' H Jj 3739 :7£: -0.0015 3737 O. £66 34 1£ Caiculatinq Concentrations fo-r Sample Number £ cNL[if\ El em. Wave- Net Peak Calculated Interference Net ' ^^ Syrn. length Intensity Concentration Correct iori Concentrat ior, \/'A,vA^-^'^ BE 234,861 54295 2. 349 O. 015 £, 334 CD £26,502 5058 2. 075 2. 075 CR 267.716 2789 2.017 2. 017 CU 324.754 3412 2. 009 O. 025 1. 964 MN 257.61 18219 2. 028 2. 028 NI 231.604 1786 1.936 O. 074 1.862 ZN 213.856 4420 2. 030 0. 050 1, 980 AL 308.215 17348 64.922 64.922 FE 259.94 166A59 245.229 Analyze Samples 01-18-1388 1:HIGH £:INTER 3:NSEA1£14 4: SB STANDARD •AEND: ' PG UP' to 'v'lew More Li-r.es Fr. lO or 'ESCape' to Stop '-./i €?v.;!-r:^EA 1 £ 1 nEn ter Number .3-1 Kep i i Co t i oris/fleasu-r-einent 1 Enter Result File Name ( rnaK|imum 8 ct^aracters ) NSEA1214 I Enter Sample Number 1 CALIBRATION BuANK I Begin Analysis - Sample Number 1 I Eie. Wave- Meari Peak: Mean P'eak Net Peak Sym. length Positiori Inte-risity Int er.£ it y ZN Hi J.'. 356 ! Off Peak Int. = 1 l3l i-.iC' P'ea k ! 1 4 5 CD ££6.50£ . Off-peak Ir,-i-. = I 39L •No Peak:; 39£ Nl £31.60'+ Off Peak Int. = ^ 47b No t-'eak ' ! 4 5£ -£6 BE £34.861 No Peak"; £36 £36 MN £57.61 No Peak!' 382 3S£ FE £59.94 No Peak! i lj81 181 CR £67.716 ! Off Peak Int, = 460 No Peak) -463 CU 324.754 j Off Peak Int. = ' 321 No Peak!' 352 .::l AG 328.068 No Peak! 384 •;84 I Calculating Ccincent rat ions for Sample Number 1 Elem. Wave— Net Peak Calculated Interference Net Sym. length Intensity Concentration Correct iC'n Concentration AG 328.068 384 0. 002 0, 000 < 0.010 BE 234.661 238 0. 000 0. 000 < 0. 005 Analyze Samplet .'1-18-1988 i« 13:30:37 — i:.R £67. 7 It. -U. Ml >.). •-) 1 (:> iiU 3£4. •,-5't 0. 0i;i6 O. 0£5 Mr; ,:v;^7.G 1 :i 3.-. >.'. '.'£'0 — l--t 'I. • :; 'I 0. •'>•>' 1 . I'i .:,:: .i. M:JI.. 1 •« I-I.; !:':,•.•..-> I t- i.i HLtll^Jt-. ,l- •'1.-,, .' •. ,:t V I •: -• • 't- . .• -•.'.. N. ^ 1 '4'-l CL ££':i. 50£ Off !-'r-.,il-- 1 r.t , i 'T r I 'r- rii. 1 I-. T . I- ;. .-::.:•:'. •:<'i "J, : ', . . |. U--1 ;'(.-,. I- »i.t. Nc. ^ '. ... • CO 3.-,-M. 754 - CM" f : c-r-. i-r' 1 rit . :• -Ji. N... I-t cM • j.t..<.i Al- .:.j ;-j.. '.'1-.3-, f-i.;- i-'r-.-ik ' 33c La 1 cu J at 1 rill L.i.i!,: c-nt r at i C'TIL T c^r baiiiplK- rJumtiei Elem. Wt-ive i-J'-'v. (-"(.ra'r 1 i c'.11 ," METHOD BLANK FILTERED Begin Analysis - Sample Number 3 Eie. Wave- Mean P'eak Mean Peak Net Peak Sym. length P'osition Intensity Intensitv ZN £13.356 Off Peak Int. 135 No Peak! CD ££6.50£ Off Peak Int. No I-'eak ' NI £31.GO4 Off Peak Int. ^tit. No Peak! -19 BE £34.361 No Peak! £38 MN £57.61 No Peak! 390 390 FE £59.94 No P'eak! 1 70 170 CR £67.716 Of r i 'es^k I rit. = No Peak' CU ^,:i'+. /54 Lifr Peak Int. = No Peak! I'M 9 A '3 3 £ 3. *:» 6 S N o P e a k ' Ca i CU 1 at irig Concentrations for Sample Number 3 Elem, Wave- NetlfPeak Calculated Interference Net Sym. leriDth Irite'^tsitv Concentration Correction Corccent rat ion AG 328.068 371 -0.005 O.000 < 0. C) 1 o BE 234.861 238 0. 000 0.OOO < 0. 005 CD £26.502 9 0.006 • 0. 0'J6 CR 267.716 -9 -0.019 0. 010 CU 324.754 33 0. 009 0.000 < 0. 0£5 MN £57.61 390 0. 0Ci3 0. 020 I^JI 231.604 -19 0. 017 0.000 < 0. 040 cn PI ZN 213. 856 9 -0.001 0. C)00 < 0. 020 > FE 259.94 170 0. 005 0. 020 o o ICV to Begin Analysis — Sample Number 4 CJ Ele. Wave- Mean Peak Mean Peak Net P'eak 03 Analyze Samples 01-18-1988 C« 13:39:£8 — 7 Sym. length Position Intensity Intensity ZN £1 3. 356 Of-;' P't^ak Int. = 14'.: -O. 0013 3A£i CD ££6.50£ Off (-'eak I rit. = 4£3 -O.00£7 £600 Nl £31.b04 Off P'eak Int. = -0.00£8 r,^-,'.-<^ 7879 BE £.i-T- ^^-t;, 1 -0. 00£7 £3677 Mr-4 i:',-. ,- . t.,1 -0. 00£5 £9663 Ft £S'i. •?4 -O. 00£1 I4b£6 CM £67.7i6 Cif f !'e?ak Int. - Hya -•j. 0025 •• /U ..^i-iy.; CU 324.754 Off Peak Int. 54 £ -O. >liO£7 ;:*y9 j;, 8651 AG 3£a. OtoS -'j. OC'35 331 i :-,31 1 Calcuiatiriu L.':T-:c-t'rit rat ions for 'iarni". • urrLjer-' H Elem. Wave- Net P'eak Calculated .1 nt erf ererice Net S y rn. 1 e ri c, t h 1 rit c---ris 11 v Concent rat i or, L o-r" r ec t i or, .C'ncent rat i on — AG 328-068 3811 1.897 0. 002 1. Li'Hb BE 234.861 £3677 1.019 0. 001 1 . C) 1 8 CD 226.502 260«:i 1.063 1. tJ66 CR 267.716 •.3062 2. 230 £, £30 HO CU 3£4.754 8651 5, 103 0. (J0£ 5, l(:i6 IDZ- MN £57.61 29663 3.326 J 3. 3£8 IIO Nl 231.604 7879 8.415 0, 007 8, 408 .or 2N £13. 856 8823 4. 056 0, 005 4. 051 103 FE £59.94 14626 21.323 21.3£3 \ I LCS I cn i p] I Begin Analysis - Sample Number 5 > I o Ele. Wave- Mean P'eak Mean Peak Net Peak o to Sym. length P'osition Intensity Int ens i t v ZN 213.856 Off Peak Int. 152 CJ -0.0011 9049 8897 CD 226.502 Analyze Samples 01-18-1968 G> 13:43:18 — 8 Off P'eak Int. = 424 -O. 00£6 -•996 NI £31.604 Off Peak Int. = 5 if. -O. 0'030 34 34 7969 BE £34.361 -O.003£ £3680 £363':' MN £57.61 -O. 003£ £9£a3 £9£&3 FE £59.94 -O.0027 14516 14516 CR £67.716 Off P'eak Int. = 50£ -O.0027 3566 20 f..^ CU .;£-•.. 754 Li-rr l-'eak Int. = 34;-. -0.003i yB£5 AG ,i£3.-.)63 -0.0037 37'9';i Calculating Cc-ncent rat ions for Sample Number / iCec t-yrn. lerigtn interis 1 ty L -r.iricerit rat i on i-orrect ion uoricerit r-at lori ^4 AG 328,068 ' ,3790 1 . 335 0. 002 1. 3 ;-*.,'- BE £34.361 £366u 1 . '..r 'H 0. O'Jl 1. 0 1 ti. ibZ^ CD £26. 50.-' Lilb'/c^ 1 . 0'^-7 1. Oti': 104, CR £67.716 30GH £. £ 1 / iij. £ i / II O L;U 3£4. 75't 353.-: 5. 0^7 0. '.)(.)£ 5. •."cl- lOi MN £57.61 £9283 3. £34 3. £34 MO NI £31,604 7969 a. 510 0. 007 3.5';)3 lOS" 2N 213, 656 8697 4. 090 0. 005 4. 085 \0<4 FE c'59. 94 14516 £ 1. 161 £1.161 ^^S' 763430 MW4b ;. Begin Analysis - Sample Number 6 Ele. Wave— Mean Peak Mean Peak Net Peak Sym. length P'osition Intensity Intensity ZN £13.356 Off Peak Int. = 130 -O.0012 256 126 CD ££6.502 Off Peak Int. = 410 No Peak! 41 1 NI £31.604 Off Peak Int. = 517 No Peak! 485 -32 BE 234.861 No Peak! 250 250 Analyze Samples 01-18-1988 & 13:48:07 — 9 MN £57.61 -0.0035 c'iic.":* f\L £59.94 -0.0029 1 64 3 164 3 CR £67.716 Off P'eak Int. = 467 No Peak! 521 MG £7'3. 079 -O. 0030 i '.")3i:» 1 ';.','3'7 AL 30a.£15 Off Peak Int. 391 No Peak! 517 l£fc. CA 317.955 -O-00£7 3990 3990 CU 3£4.754 Off P'eak Int. = -O.00£2 545 AG 323. 06S r>lo P'eak! 334 Calculating Coricentrat ions for Sample Number 6 Elem. Wave- Net P'eak Calculated Interference Net Syro. leriDth 1 nt ens i t v Coric-ent rat i on Correct i on Concent rat i or. AG 3£3.ObU 584 (.1. t.H.lv- O. O 1 o BE £34.661 £50 O. Ci'.)i O. O'JO o. ':i'J5 CO ££S.50£ 1 0. 00.i o. , ;.r,'5 CR £67.716 54 0. 0£7 • ) _ LU 3£4,754 ££4 O. 1££ O. O'-iO 0. 1 ££ t^iN £57. 6 i ££c:9 I.I. £ i £ 0. £l£- NI £51.604 O. 003 0. O'Jl '..1. 'J4'0 ZN £13.856 1£6 O. 053 0. cicn:) 0. •.:)53 AL 308,£15 126 O. 058 0. 1 50 FE £59.94 1645 2. 177 £. 1 7 7" C:A 317. 933 39 90 6. £'3'? 6. in'99 MG £79.079 1080 £. 977 C— r 977 763430 DUP MW4B Begin Analysis — Sample Number 7 Ele. Wave— Mean Peak Mean Peak Net Peak Sym. length P'c>sition Intensity Intensitv cn 1 PI I > I ZN £13.856 Off Peak Int, = 132 O -O.OO17 206 74 O to CD 226.502 Off Peak Int. = 400 No Peak! 395 NI 231.604 Analyze Samples 01-18-1988 C" 13:51:51 — 10 Off Peak Int. = 457 No P'eak! 469 1£ BE £34.861 No P'eak! 238 £38 I^IN £57. 61 —j. >.:i';'37 £059 £':J59 FE £59.94 -O.0030 147£ 147£ CR £67.716 Off Peak Int. = 449 No Peak' 513 64 MG 279.079 -0.0032 1014 1014 AL 308.215 Off Peak Int. = 383 NO Peak' 51 1 1£8 CA 317.933 -O. (:i(:!£7 'S&OS 5605 CU 324.754 Off Peak Int. -0.0013 4t.3 146 AG 328.068 No Peak! 374 374 Ca i CLi i at i riD Concent r-at ior;-;. fC'r SampJe Number Li em. wave — Net P'eaK Caic-ilated 1 .-it er^f er-erice Net 'Svf'"'. i eriat h 1 nteriE -] t\' C.;.nceriT-rat ion Cor'vect ion Conceritrat ic-ri I )i,r .t-ii^t . '-.'t.-i-' '..I. (.1..»'-.' i^L £34. 361 0. 000 O. 'J'OO 0. ',;>'.:) 5 CO ,-::£t-. ::;.';>£ O. 0<.>i-i O. 0iJ5. LR £67" . 7 IL O. '-1)34 O. 034 CU 3£4.754 146 0. 076 O. 076 MN £57.ti 2059 O. 192 O. 19£ Nl £31.604 1£ il'. 05'!' o. •:>':> 1 O. 04 9 ZN £13. 356 74 O. 0£9 O. 0£9 AL 303.£15 1£8 0. 065 0. 150 FE £59.94 147£ 1. 925 1. 9£5 CA 317.933 3605 5. 620 5. 620 MG £79.079 1014 £. 717 2. 71 7 763430 t- MW4B ^ Begin Arialysis - Sample Number B CD p] > Ele. Wave— Mean Peak Mean Peak Net Peak Sym. length Posit ic^n Intensity Intensity o ! to •• ZN £13.356 Off Peak Int. 130 -o. 001; 647 il7 CD 226.502 to v__ Analyze Samples 01-18-1988 & 13:55:55 — 11 Off Peak Int. = 397 -O. 0C)£5 521 124 Nl £51.604 Off Peak Int. == 467 -O. 0;>3i 653 386 BE £34.861 -0.0035 1395 1393 MN 257.61 -0.0033 3514 3514 FE 259.94 -0.0031 2181 2181 CR 267.716 Off Peak Int. = 453 -O. OO3'0 694 £4 1 MG £79. 079 -O. 0'.:.3£ ££87 r:£67 AL 308.215 Off Peak Int. = 33c: No Peak! 503 121 CA 317.953 -0.00£9 6S4£ 6542 CU 324.754 Off Peak Int. = 32i -O. 0029 853 AG 328.068 -O. 0040 541 541 Ca leu latino Concent-rat ic.ris- T.r.r- Sample Number 3 t- .11,; ri 1. U, a ve- r-jort P'eak L.:< ,1 (•-• 1.; i at tJC 1 rit er f c-r"e,-ice Net Syri-1. lengtn I rit eris 11 y !-.:-ric:, erit rat ion Ccir-rect 2 .:.-i •-•ric entrat ic.ri AG . _. Cl 063 54 1 ^.1. '7«9 1.1. •J:.f..- O. ij89 BE £34. 861 1393 0. 050 o. ':i'.:>':i O. 050 CD ££6. 50c- 124 0. Ele. Wave— Mean Peak Mean P'eak Net Peak CJ Sym. length P'osition Intensity Intensity ZN 213.856 Analyze Samples 01-18-1988 & 14:00:16 — 12 Off Peak Int, 131 -o. O'Jc: 278 147 CD 226.502 Off Peak Int. 391 No •.93 NI 231.604 Off Peak Int. 463 No Peak! 469 BE £34.861 No l--eak ! £29 229 MN £57.61 — 0. 'j',j4 J 1879 1879 FE £59.94 -0.003s 246 246 CR £67.7i6 Off Peak 1 nt. 466 r-4o Pt-a!-;: 461 fli.T £79.073 -M.1. '•.'•.13.}: 976 !/fc- AL 308.£15 Off Ceak I nt. 377 No -Peak: 393 16 CA 317.933 -0.00£3 3558 3538 CU 3£4.754 Off Peak I r,t. 32** No i--eak ! 369 MD AG 323.063 No r-'eai-'.' 382 582 Ca i c u 1 at i riD C'-'ricent-rat i'r.-rir,- for- Sample Number- 9 E i tiiiu Wave- Net P'eak i^^a i cuiated l-nter f e'f-eriCv; Net Sym. length Intensity Concentration Correc.tiori C.r'nceritrat ion AG 323. 068 36£ 0. 001 0. 0':"-:i < <;>. 01 '.'> BE £34. 861 , ££9 0. 000 0. 000 < 0. ':)05 CD £26. 502 2 0. 003 < 0. 005 CR £67. 716 — *^t 0. 016 .. 0. 01 0 CU 3£4. 754 45 0.017 O. OOO < 0. 025 MN £57. 61 1879 0. 172 0. 172 Ni C-ij X m 604 6 0. 044 0. C>00 0. <;)44 ZN C S ^m 856 147 0. 063 0. 000 0. 063 AL 308. £15 16 0. 557 < 0. 150 CD FE £59. 94 246 0. 117 0. 117 PI CA 517. 935 3558 5. 502 5. 502 MG 279. 079 976 2.568 2. 568 O 765450 FILTERED DUP MW4B o Begin Analysis - Sample Number lO Ele. Wave— Mean P'eak Mean P'eak Net Peak Sym. length Position Intensity Int ens i t y Analyze Samples 01-18-1988 & 14:03:58 — 13 ZN 213.856 Off Peak Int. = 127 —O. '.-•'^!>£3 £39 1 12 CD 226.502 Off Peak Int. = 397 No Peak! 388 -9 NI 231.604 Off Peak Int. = 469 No Peak! 470 1 BE 234.861 No Peak' £27 £27 MN £57.6i -O.OO^i 1372 1872 FE 259.94 -U.0033 235 CR 267.7 16 Off Peak Irit. = 46/ No i-'e-ak ' 467 O MG 279.079 -O.0034 991 991 AL 308.215 Off Peak Int. ,= 379 No Pea.;! 387 8 CA 317.933 -0.003';' Ii49 6 3H3B CU 3£4.754 Off Peak Int. = 3,i5 .--••'--*'+ 69 AG icLii. OhS N.:- Lai c oil at 1 rig Coricerit rat ions. ^ m Die N 1.1 m be r i O Elem. Wave- Net P'eak Calculated Interf et^erice Net Sym. ieridth Iritensitv Concerit r at i ori Cc-rrect i ori Concent rat i Cin AG 3£6.068 375 -O. Ele. Wave— Mean P'eak Mean P'eak Net Peak Sym. length P'osition Iritensity I rit ens i t y ZN C! 1 Jr • v^ ^ O Off Peak Int. = 132 -O. uC>££ 673 1.4 1 CD ££6.502 Off Peak Int. = 407 -0. 003£' 127 Nl £31.604 Off P'eak Int. = 4M7 -O.003£ 37 3 426 £34. 861 -O. '-:)':i39 1 380 1 380 MN £57. 61 -O. '-J'-;i4£ 3£57 3257 FE £59. 94 • -O. 0';:34 888 633 CR £67.716 Off P'eak Int. = 462 -O. 0032 604 142 MG £79.079 -0.0035 2214 2214 AL 3'03. 215 •Off P'eak int. = 381 No Peak! .^96 1^ LH 317.933 -0.0'j31 63.36 t-.33!: LU 324.754 Off P'ea k i nt. = 310 -O.0033 790 47£ AG 3£S. 063 -0. ';)«:i43 54b 54 3 Ca 1 cul at i rig Concent rat ic-ris for Sample Number li Elem. Wave- Net'- Peak CaIcui ated 1 nt er f ererice Net Sym. i ength Intensity Coriceritr at i .r,.ri Correct lori Cciriceritr at i on ( AG j£S. 068 548 O. 093 O. 000 O . 095 BE 234. 861 1380 O. 050 O. 000 . 050 CD c!c w* 502 127 0. 055 o.05 5 CR £67. 716 142 O. 091 o 091 CU 3£4. 754 472 O. 269 O. 000 0 269 MN 257. 61 3257 O. 3£8 0 528 in pi NI 231. 604 426 0. 490 O. OOO o 490 \ ZN 213. 856 541 0, 244 O. OOO 0 244 o AL 308. 215 15 -0,361 < o . 150 o FE 259. 94 888 1. 064 1 . 064 to CA 317. 933 6336 10.439 10 . 439 MG 279. 079 2214 7.435 7 . 435 01 763454 MW4A Analyze Samples 01-18-1988 * 14:12:14 — 15 Begin Analysis - oample Number 12 Ele. Wa-ve- Mean Peak Mean P'eak Net Peak Sym. lengtr-. l-'.i.sition Interisity Irit ensi t y ZN 213.356 Off Peak Int. = 133 -O.0026 348 215 CD ££6.50£ Off Peak Int. = 409 No Peak! 4 14 Ni £31.604 Off Peak Int. = 47£ f Calculatirig Concentrations for" Saiiiple Nutnber l£ Elem. Wave— Net P'eak Calculated , Inter-f ererice Net Sym. length Interisity Cc'ncentrat ion Correct iori Concent rat ic-ri AG 3£S.068 376 0. (.102 0. 0<:)3 < 0. 010 BE £34.861 £62 0, 001 0. 002 < 0. 005 CD 226.502 5 0, 005 0. 005 CR 267,716 59 0.031 0. 031 cn CU 324.754 93 0. 045 0. 003 0. 042 3^ MN 257.61 8524 0. 927 0. 927 NI 251.604 15 0. 051 0. 008 0. 045 o ZN 215.856 215 0. 094 0. 005 0. 089 to AL 308.215 601 4 2. 234 22.234 FE 259.94 17671 5.814 25. 814 CA 317.933 1912 2.633 2. 633 0) Me 279.079 1422 4. 321 4. 321 -J Analyze Samples 01-18-1988 If" 14:13:28 16 763434 FILTERED MW4A Begin Analysis - Sample Number 13 Ele. W^o/e- Meari P'eak Mean P'c^al; Net Peak Sym. leriQth Position Interisaty Intensi t >- ZN 213.356 Off Peak int. = 131 -O.0023 87 CD 226,50£ Off P'eak int. = 396 No Peak! 397 ul £31 . fc'-:)4 Off Peak Int. = 461 No Peak! 4fc. / o BE 234.861 No Peak! ££6 226 MN £57.61 -0. 0044 914 91^ FE 259.94 -O.0052 £14 214 CR £67.7 16 • Off Peal; Int. = 461 No Peak! Mij £79. 07'v -O. 0037 / 1 '.', • UT-r ,--eak r.T-. = No P'eak ! w-'.-lt. It. LA .il 7. •::'.^3 -'0. Calculating Conceritrat ions for Sample, Number 1 ji Elem. Wave— Net Peak Calculated Interference Net Sym. length Interisity Concent r-at icTi Ccrrrection Coricerit rat i .;.ri AG 528. 068 373 -0.004 <-). U<.)0 O. 010 BE 254. 861 226 O. 000 O. 0C)0 O. 005 cn CD 226. 502 1 O. 003 O. (1)05 p] CR 267. 716 -0.016 O. 010 > CU 324. 754 0. 021 0. 000 O. 025 o MN 257. 61 914 O. 062 O. 06£ o NI 231. 604 6 O. 044 O. 000 0. 044 10 ZN 213. 856 56 O. 021 O. 000 0. 0£l AL 308. £15 16 -O.357 O. 150 FE 259. 94 214 0. 070 O. 070 CO 317. 933 1602 2. 086 2. 086 Analyze Samples 01-18-1988 & i4:£3:26 — 17 MG 279.079 715 1. 5' 1 . 542 763438 MW4C Beq 1 n Aria J vt J ;> S ample Number 14 Ele. Wave- Mean. P'eak Mean Peak Net Peak Sym. length P'osition Intensity Intensitv ZN £13.356 Off P'£ai; 1 rit. = 1 3J. -'•.). ':)';;)£5 1 J.-0 CD ££6. :„.':i£ Off •'i-rTit-: irit. = No Peak! NI £3i.604 Off P'eak Int. =• 449 No Peak! •4b5 16 BE £34.361 No Peak! 232 MTvl £57.61 -0.':>04£ L-t-'^- 868 FE £59. •?4 -0. 0035 1274 CR £67.716 Off Pear: Irit. = r-io r--eak ' MG ^/'rt. :.;7-;' -O. 0033 I'JM'-? i'.l-4-^ AL 3':».3. £1L. Off t'L-ak. Irit. - HL> -0.0037 l£i 1 3'OS CP< 317.'933 -O. 0040 4 1 40 4 1 40 CU 324.754 Off P'eak 'Int. = -0. OC'35 44£ 1 19 AG 323.'Jbti No P'eak! 373 Ccilculat ing Coricentrat ions for Sample tJumber 14 Eiem. Wave- eak Ca]Lculate d Int er ference Net ity Concent rat i on cn Coirrec t i on Conceritrat ion PI > AG 3£8.068 373 -O.004 0. 000 < O. 010 BE 234.861 232 0. 000 0. 000 < 0. C>d5 o CD 226.502 6 0. 005 0. 005 to CR 267.716 22 0. 004 < O. OlO CU 524.754 119 0, 060 0. 000 0. 060 MN 257.61 868 0. 057 O. 057 li) NI 231.604 16 0.054 0. 000 0.054 CO ZN 213.856 130 0. 055 0. 000 O. 055 AL 308.215 808 £.626 2.626 Analyze Samples 01-18-1986 (•' 14:27:52 — 18 FE 259.94 1274 1. 633 1. 633 CA 517.953 4140 6. 564 6. 564 MG 279.079 1049 2. 855 763436 FILTERED MW4C Begin Analysis - Sample Number 15 Ele. Piave- Mean P'eak Meari P'eak Net Peak Sym, length P'osition Intensity Intensity ZN £12.356 Off P'eak Int. = K-J'r" -O. ':>0£5 1 '.itj. CD ££6.50£ Off Peak Int, = 409 No Peak! w.-H^ -1: NI £31.604 Off Peak Int. = 448 No Peak! ^bt.. It:. BE £34.361 No Peak! ££6 ££6 MN £57.61 -O.0047 FE £5'9. 94 -0. 0<;)34 £ 3 4 L R £b /-'. 7 1 c. OfT t^'e^B^ ir.t. - 45:^ Mo Peak! 7 MG £/'r. i.i7v -•;;. 004£ 353 AL 303.£i5 Off Peak Int. = 58£ No Peak' ^:7 CA .il ,'. •i<33;. -0. OU41 35 lu -i5 1 (.' CU 3£4. 754; Off P'eak Int. = 319 No Peak! 4.30 bl AG 328.068 No Peak! 376 376 Calculating Concent rat ic-ns for Sample Number 15 Elem. Wave- Net P'eak Calculated I rit erf erence Net cn \ Sym. length Intensity Conceritrat iC'n Correction Conceritrat 1 c AG 328.068 376 •0. 002 0. 000 < 0. 010 o BE 234.861 226 0. 000 Cl. 000 < 0, 005 to CD 226.502 -15 •0, 004 < 0. 005 CR 267.716 7 0. 007 < 0. 010 r" CU 324.754 61 0. 026 0.000 0. 026 iSi MN 257.61 572 0. 024 0. 024 O NI 231.604 18 0. 056 0. 000 0. 056 Analyze Samples 01-18-1988 i> 14:32:15 — 19 ZN £13.356 1 OS U. U45 O. OOO o. t.)45 AL 308.215 35 -O.£65 IJ. 1 50 FE £59.94 £34 0. (J 9 9 0. 099 CA 317.933 35 lO 5. M 5£ Ll 4'o£ MG £7'5. ^1 ,"•:;* 353 £. 1U4 •TJ • I'.iA 76344£ FIELD BLANK Begin Analysis - Sample Number 16 Ele. Wave— Mean P'eak Meari P'ea- Net Peak Sym. lenqth P-;.s 11 1 ori Irit er.-i i r -•,- I nter.s 11 v L^-i £13. 356 Off P'eak 1 riT . = : 3£ No P'eak! 16.;. CD ££6.50£ Off Peak Int. = 401 No Peak! 594 NI c:31.604 Off Peak Int. = 457 No Peak! •H64 B'ii £34.361 No Peak! -' --F, MN £57". 6 i i^i.;. P'eai;! 3 7 ',-' FL £'5'3. 94 i^i.i. P'ei-.K ! CR £67.7 16 Off Peak Int, = 469 No Peak! -- / MG £79.079 No P'eak! 3£1 .3£i AL 3':'S.£15 Off Peak^I.nt. = 366 -. No Peak! 363 CA 317,933 No P'eak! 4 5 3 HZl . CU 3£H,754 Off Peak Int, = 317 No Peak! 366 49 AG 3£8,063 No Peak' 383 583 Calculating Conceritrat ions fc^r Sample Number 16 cn PI Elem. Wave- Net P'eak Calculated Interference Net > Sym. length Intensity Concentration Correction Concentration o o AG 328.068 383 0. 002 O. OOO O. 010 to BE 234.861 228 0. 000 0. 000 O. 005 CD 226.502 -7 0. 000 O. 005 ID CR 267.716 -7 -0.017 O. 010 Ul CU 524.754 49 0. 019 O. 000 O. 025 Analyze Samples 01-18-1988 0? 14:j.6:40 — 20 MN £57.61 378 O. OOl O. (.>£<.> NI £31.604 7 0. 045 >.). OOO O. 04 5 ZN £13. 356 31 0. ciog O. OOO O. 0£0 AL 30B.£15 -0.4£8 O. 150 1-£ £5•^. 94 163 o. ':)02 O. OilO ,CA 31 7. 933 459 0. 069 O. £ii!>0 MG £79.079 3£1 -0.007 O. £<.)0 763446 TRIP BLANK Begin Analysis - Sample Number 1' Ele. Wave- Mean P'eaP; Mear-i Peak Net t^'t-ak S y m. 1 e ri Q t h P' o s i t i..-.. r i i n tuns 11 y 2N £13. 856 Off P'eak int. i'lo Pt-ak! 145 CD 2£6.50£ Off Peak int. 386 No k'eak, ' 111 £31. bC)4 Off P'eak int. - H76 L:.:. .-:^.-'-t. 361 ;•.-,:• • irj-k ££S P\i< £57''. bl !''<.:;• i-'tf-.k 37£ FE £59. 94 No Pe.-r-i' IbS 165 CR £67.716 Off Peak Int. No Peak! -4 I'lG £79.079 No Peak! AL 306.215 Off Peak Int. 1.3/ No Peak! 3,85 CA 317.953 No Peak! 423 CU 324.754 Off Peak Int. • lb No Peak! j)54 38 AG 528.068 No Peak! 374 374 cn PI Calculating Concentrations for Sample Number 17 > Elem. Wave- Net Peak Calculated Interference Net o Sym. length Intensity Concentration Correction Concentration to AG 328.068 374 -O. OO.i 0.010 BE 234.861 O, 000 O. OOO O. 005 Ul CD 226.502 7 O. 005 O. 005 to Analyze Samples 01-18-1988 e 14:42:42 — 21 CR £67.716 -4 -0.015 O. OlO CU 3^-4. 754 36 O. 01 £ O. '-'<.l"vl O. 0£5 MN £57.61 37£ O. 001 0. 020 r-a £31. 604 -£0 0. 016 O. 040 ZN £13.356 1£ O. 000 0. 0£0 AL 306.£15 •0. 4£5 O. 150 FE c:'5'3. 94 165 •0. 00£ 0. 0£0 CA 317.935 4£3 O. C>'L)5 O. £00 MG .•-:79. 079 •0. 003 '.>. £00 CALIBRATION BLANK btrqjr, i-irialysis — S^•^mple Number 18 Lie. Wave- Mean P'eak Mean P'eak Net P'eak '.r>ym. length Position Iritensity Int ensity 2N £13.856 Off Peak Int. 130 No Peak! 140 IV CD ££6.50£ Off Peak I nt. = .^95 No Peak! 391 -4 rii £31.604 Off P'eak 1 nt. No Peak' BE £3H.361 t Calculating Conceritrat ions for Sample Number 18 cn Elem. Wave- Net P'eak Calculated Interference Net p] Sym, length Intensity Ccmcentrat ion Correction Cc'ncentrat ion > o AG 328.068 575 -0.004 0. OlO o BE 234.861 225 0. OOC) 0. 0C>0 ( 0. 005 to CD 226.502 -4 0.001 0. 005 CR 267.716 -12 -0.021 0. 010 VB CU 324.754 46 0.017 0.000 < 0. 025 Ul MN 257.61 371 0. OOl : 0.020 CJ _y Ar.aiy-e Samples <:i: - 1 S- 1 938 li" 14: 45 : 33 '..I. t.l'**.! .;i; Ll 3. 356 10 <-!. '.>£'j > I, .'.'<. 3-1 ic-:.4 0' IM 'I. ',')£',") .„;. i t'4) ir-i lysis — Samp 1 c Ele. Wave— Mean I'liian P'eak rjer, i-'ti-ak Sym. lerigth P'o'j i J •'!-? eris 11 v i >-.-!. r>ri« 1 V CJ \ ; i \ .'ll; ;, ij ^1.76. 5-.>£ Uff Ped; ii-.t. 33' :-Pi. •• ..-'.H / rii. £31. 604 ; 11 7 P'eak ,i r-d . N.;. : • ;,',: r::i',. 3b 1 N.:- .-- 'iT-' £:_•/. 61 i'J.:. - P'L-ak 1. • 1 ri(j C'c.nct-rit r-at i..-r •3t.mpJf' Numbt. r L i trill, Wave — Net P'eak i. a 11.. ..i: ai eu 1 nt er terc-r.., (.- Net 'oyrii. lerigt("i Intensitv L. •fi< t-r,-'. r-,-,t i •:. ri LCT fee t i -.i-i i. rit rat lor AG 3£3. '::i63 - '.>. i.»0.-i I). 1,1 l. ' '.11 1 0 cn BE £34.661 '1'. 000 O. '.>• 1. PI CD £a'b. t-..<:i£ i'.i '.I. '.»'.) / '.1. 1.1''7 , CR £67. 7 16 -Ic -•;>. o£i 0. 0 1 o CU 3£4.754 '.I. '.'1 4 U. > il.lt.! o 1 4'.) 0. 025 to Mrg £57. 61 376 O. 'JOl 0. 020 NI £31 . 6';'4 _<;i. 03£ 0. O'.i'I) 0. 040 ZN £1 3. 35b 16 O. C>0£ O. 0C>0 0. 020 kD Ul FE .£59.94 168 O. 002 0. 020 ccv ccv Analyze Samples 01-18-1988 & 14:46:24 — 2: Begin Analysis — Sample NumPer 20 Eie. Wave- Mear. P'eak Mean P'eak Net Peak feym. 1 ength P'.i.si t \ • i ritensi ty Int ens ity 2N £13.656 Off P'eak Int. 153 -O. 0i.:i£5 9146 8993 CD ££6.502 Off Peak Int. 434 -O. 0t:i37 3001 £567 NI £31.604 Off Peak Int. 504 -o. 'J03;-- b530 30 £6 BE £34.861 -0. 0.:»3L* £4£43 £4£43 MN £57. 61 -0. ':;i04 i £9411 £9411 FE £59. 94 -0. 0'-:i33 14576 14576 CR 267.716 Off Peak Int. 503 -O. C>'..i37 34 60 £957 CU 324.754 Off Peak Int. = 338 — 0. '!i"j4 ,! 9 1 1 6 377 6 i-U- i£3. Caic-i.;iat irig Conccntrat io '.:,.! '£.ai;ipje NLufiber c'.O Eiem. Wave- rJet Peak Lalcuiated interference rOet Sym. lerigth Intensity 'C.i.ricerr. rat lori Correct i ori L.z-ricent r at i on /e^c AG 3£3.063 3814 1. 398 0. 002 1.896 ^C BE £34.361 24243 1. 04 3 0. Oiji 1. 042 lOM- CD ££6.50£ 2567 1. 055 , 1. 055 iOt CR 267.716 2957 2. 139 2. 139 109- CU 324.754 8778 5. 185 0, C)02 5. 181 joM MN 257.61 29411 3. 299 3. 299 NI 231.604 8026 8.571 0. 007 8. 564 ,'<;? ZN £13.856 8993 4. 135 0. 005 4. 130 10 3, 14576 21,249 FE 259.94 21. 249 >"< 763590 MW5C Begin Analysis - Sample Number 21 Ele. Wave— Mean P'eak Mean P'eak Net Peak Sym. length P'osition Intensity Intensity ZN 213.856 Analyze Samples 01-18-1988 C" 14:53:21 — £4 Off Peak Int. 141 -O. 0'J£7 826 68f CD ££6.50£ Off Peak Int. 394 No P'eak ! 443 H-zi NI £31.604 Off Peak Int. 476 No Peak' 511 BE £34.361 -O. 003b 399 399 MN £57.61 -O.0039 14555 14555 FE £59. 94 -O. 0';)3£ 31223 512£5 CR £67. 7 1 f-, Off P'e-ak Int. 47 A No P'eak: 515 41 r-iG £7''9. '7/9 -'-.i. v03i> 5£0£ 5£0£ PHL 306. Hit- Off P'eak Int. = 713 -O. 0030 18703 17990 CA 317.933 -0.0040 18628 18628 CU 3£4.754 Off Peak Int. -O.004 1 dC>0 476 AG 3£3. '-.•>b3 No Peak : 381 381 Calculating uc.ricent r fit iorPs for- Sample r>Ji.imber £1 Elem. Wave- Net P'eak Calculated IntBrfGrencB' Net Sym. length Iriterisity Concentration Correctiori Conceritrat i ori AG 3£8.068 381 0. 001 0. 0':)5 •: !."> . 0 1 0 BE £54.861 399 0. 007 0. ';i':)3 •: 0. OCi5 CD £26.502 49 0. 023 0. (:i£3 CR 267.716 41 0. 017 , 0. 017 CU 524.754 476 0. 272 0. 005 0. 267 MN 257.61 14555 1.612 1. 612 NI 231.604 35 0. 074 0.014 0. 060 ZN 213.856 685 0. 310 0. 009 0. 301 AL 508.215 17990 67.340 67.340 51225 45.799 45. 799 FE 259.94 cn CA 517.953 18628 32. 127 32.127 PI MG 279.079 5202 19.163 19. 183 O 765590 DUP MW5C O to Begin Analysis - Sample Number 22 uD Ul Ele. Wave- t»1ean P'eak Mean Peak Net Peak 01 Sym. length Position Intensity Int ens ity Analyze Samples 01-18-1988 (? 14:56:58 — ZN 213. 856 Off Peak 1 nt. 14.i —0. iCl'J£"!:< Si£ 669 CD ££b. 5'-i£ Off Peak 1 nt. 4£4 No Peak' 446 NI £31.604 Off Peak i rit . - H73 No Peak! 517 39 BE £34.361 -0.0048 336 386 MN £57'. 3 1 -•0. ',,"j^£ 14 365 14 365 FE £5'i.. -H'V —0. 'J'J33 3 Cl 7 6 7 30767 CR £67. 7 3 b Off >:-eak 1 rit. 467 No Peak' 515 48 MG £79.079 -0.0036 5197 5197 AL 306.£15 . Off Peak I nt. 704 -0. •J0£7 13584 1 76SO CA 317. •:J33 -0. 0':.i37 XHHS'S- 13435 CU 3£'-i. 754 Off P'eaP; I nt. V-'-.'l- HL''C: AG -:i,73. 'Ji„-8 l-.j,;, :>t--.;i; • 335 Ca 1 c 1.11 «:>t 1 r-i::; Cc..--i.LC'iit r at i .z.ns foi b;aii:-..ie ivlumper ££ Elem. Wave— Net Peak Ca 1 c u 1 ateo Intsr f^renaer Nsi Sym. lerigth Intensity Concentration L.ii-rr-e-ct i c.ri CoriC-e-nt r-at i .r-r: AG 3£S.063 385 o. oCi O. <'.>'J5 < 0. 01 o BE 234.661 586 O. 007 0.003 < O. 005 CD 226.502 22 O. 01 1 0. 01 1 CR 267.716 48 O. 025 O. 023 CU 524.754 482 0. 275 u. (.)'.-)!: 0. 270 MN 257.61 14565 1. 590 1. 590 NI 251.604 59 O. 079 O. 014 O. 065 ZN 213.856 669 O. 303 O. 009 0. 294 cn PI AL 308.215 17880 66.925 66.925 > FE 259.94 30767 45.126 45.126 CA 317.935 18485 31.875 31. 875 O 5197 O MG 279.079 19.163 19.163 to 763590 SPIKE MW3C KD Ul Begin Analysis - Sample Number 23 •O Analyze Samples 01-18-1988 C- 15:01:03 — 26 Ele. Wave- Mean Peak Mean Peak Net Peak Sym. leriDtt'i P'osition Interisity Intensity ZN £13.856 Off Peal.' int . 137 -i.i. OO^S 1L47 1110 CD ££6.50£ Off Peak Int, 4'04 -0. 0042 15£ NI ,^31. 6o4 Off Peak I nt. 464 = • — ') 'O03.£ 9ijl BE £34.361 -0. '7)'036 1571 15/1 MN £57.6l -0. ';>'J40 1 6067 1 6'-.'6 7 FE £59.94 -0. '1>03£ 31 £-£9 313£9 CR £67.716 Off P'eak 1 rit. = 473 -0, 0035 675 £02 MG £79,079 -0. 0036 6479 6479 AL 308.£l5 Off Peak I nt. = - 710 -0. '-:)C)£8 1 S93£ I oc'c'c' CA 317.933 —0. 0033 £l&3i £1631 CU 3£-'^i. 7 '3''-' Off P'eak Int. = -y~_-t=- -0. '-li03'9 l'.>bb 74 1 AG 328.068 -0. 7i04 3 Hi 3 5 Calculating Concent»-at ioris for Sample- r-Jumoer £; Elem. Wave- Net Peak Calculated Interference Net Sym. lerigth Int ens ity loncerit rat i ori Cc.rrectiori Concent rcit i on AG 328. 068 535 O. 086 0. 005 O. 081 BE 254. 861 1571 O. 058 O. 005 O. 055 CD 226. 50,z 152 0. 065 0. c)65 CR 267. 716 202 O. 135 O. 155 CU 524. 754 741 0. 428 O. 005 0. 423 MN 257. 61 16067 1. 783 1. 783 NI 251. 604 437 O. 014 0. 488 cn O. 502 PI ZN 213. 856 1110 0. 506 0. 009 0. 497 > AL 308. 215 18222 68.214 68. 214 FE 259. 94 31829 46.692 o I 46. 692 o CA 317. 933 21631 57.426 37.426 M I MG 279. 079 6479 24.203 24.203 ID 763590 FILTERED MW3C cn 03 Analyze Samples 01-18-1988 C- 15:05:10 — 27 Begin Analysis - Sample Number 24 Ele. PJave- Mean P'eak Mean Peak Net Peak Sym. 1 r:.rii:: r,! i P'os i t i on I nt e'ris 11 y Intensi t-; ZN £13.356 Off Peak Int. = 137 -O. 0026 , £'.i7 70 CD £££.. 50£ Off Pe-ak int. = 397 No Peak ' 331' -8 Off P'eai-; Irit. = 457 No P'eak ' •! , .V 15 E Ca i cul at iriD C.r-ricent rat ions for Sample r-Jumber c:A Elem. Wave— Net P'eak Calculated , 1 nt erf erence Net Sym, length Interisity Concentr at iori Correction Conceritrat ion AG 328, 06& 381 0. ';ioi 0. OOO < 0. OlO BE 234, 861 236 0. Ci'Ci'J 0. 000 < 0. C>05 CD 226. 502 -8 0. 001 < 0. 005 CR 267. 716 4 0. 009 < 0. 010 cn p] CU 324. 754 85 O. 040 0. OOO 0. 040 MN 257. 61 1430 O. 121 0. 121 NI 231. 604 15 0. 053 0. 000 0. 055 o ZN 213. 856 O. 027 0. 000 0. 027 o 70 to AL 308. 215 71 0. 150 < 0. 150 FE 259. 94 271 0. 154 0. 154 CA 517. 955 2900 4.576 4. 376 CO Ul MG 279. 079 698 1.475 1.475 Analyze Samples 01-18-1988 & 15:10:57 — 28 765590 DUP FILTERED MW3C Begin Analysis - Sample Number 25 Lie. PJa-.-e- f'-iean Peak Mear. Peak Net Peak Sym. 1 engt h P'.DH- i t i on I nt eric 11 y Interisi t y ZN £l 3. 356 Off Peak Int. = 139 -O.0020 30 B 69 CD ££6.50£ Off T'tak Int. = 4v. £ No Peak! 401 Ni £31. 604 Off P'eak Int. = 464 No Peak! 16 BE 234.361 No Peak! £31 £31 MN 257.61 -O. 0041 1406 1406 FE 259.94 -O.0032 £6£ £62 CR 267. 71 6 Off Peak Ir.t. = 464 No Peak! 4 59 MG £79. •:i7'3 —'.). 0038 L33 bWi AL 306.215 Off P'eak I-fit. = 33;-. No Peak! '4 / •;,) tf. / CA 317.933 -O. 004':;> L • '*^,-" *f £'3 £4 CU 3£4,754 Off Peak Int. = 3Ci4 -O. 0(:ii9 .i.9b 3H AG 328. 068 - No F'eak ! 333 !:33 Calculating Concentrations for Sampl^ r Elem. Wave— Net P'eak Calculated Interference Net Sym. length Intensity Concent rat i ori Correction Concent rat iori AG 328.068 385 O. 002 (."). 000 < 0. C>10 cn BE 234.861 251 0. 000 O. O'j'j < 0. 005 PI > CD 226.502 -1 O. 002 < 0. 005 CR 267.716 -5 0. 016 < 0. 010 o CU 524.754 94 0. 046 0. OOC) 0. Ci46 o to MN 257.61 1406 0. 1 18. 0. 1 18 NI 231.604 16 0. 054 0. 0C)0 0. 054 ZN 213. 856 69 0. 027 C>. OC>C) 0. 027 cn AL 508.215 87 0. 089 < 0. 150 o FE 259.94 262 0. 141 0. 141 CA 317.933 2924 4.418 4. 418 Analyze Samples 01-16-1988 e 15:14:23 — 29 MG 279.079 688 1.436 1. 436 763590 SPIKE FILTERED MW3C Begin Analysis — Sample Number £6 Ele. Wave- Mean P'eak Mean Peak Net Peak Sym. lerigth P'osition Intensity 1ntensity ZN £13.656 Off Peak Int. 150 '.i'.iii£ CD L:£6. '303 Uf f P'e,-af-, i rit. 4-.it.-^ — U- V'.-iLS.ti 11: Ni £-il . 6'It4 Off Peak int. 474 0. 0C>35 836 362 BE £34.861 0. C>037 13.^ 1 1361 MN 257.61 Cl. CiC'4Ci £3CiO 260CI FE 259.94 0. i.")Ci3£ 94 £ 942 CR ,267. 7 16 Off Peak int, •Hb'.i MG £79.0/3 -:.<. '7033 1931 1931 AL 303.£l5 Off P'eak Int. ii.<£ No P'G-aP; ! 47C1 88 CA 317.953 -O. 0040 5702 5702 CU 324.754 Off P'eak Int. = 3ie —0. 0Ci4 1 814 496 AG 3£a. 068 . -Ci. 0O49 543 543 Calculating Concentrations for Sample Number 26 Elem. Wave- Net Peak Calculated Interference Net Syrn. length Intensity Concentration Correction Concentration cn PI AG 328,068 543 0. 090 0. C)00 O. 090 BE 234.861 1361 0. 049 0. 000 O. 049 o ; CD 226.502 115 0. 050 O. 050 o 1 CR 267.716 133 0. 084 0. 084 to CU 324.754 496 0. 283 0. C>C)C) O. 283 MN 257.61 2800 0. £77 O. 277 (JD NI 231.604 562 0. 422 0. OOO O. 422 cn ZN 213. 856 533 0. 240 0. OOO O. 240 AL 308.215 88 -0.086 0. 150 Analyze Satnples 01-18-1988 0? 15:18:55 — 50 FE 259.94 942 1. 144 1. 144 CA 317.933 5702 9. 320 9. 3£0 MG 279.079 1931 6. 3£3 6. 323 763594 MW3A. Benin Analysis - Sample Numbe*- £7 Lie. Wave— Mean Peak Meari P'eak Net Peak Sym. length P'osition Intensity Interisi t y 2N £13.856 Off Peak Int. --^ 1 3( -0. .,7C>£3 i '.19 CD ££6. 5<:)£ urf P'eak Int. = 36; No Peak! 417 Nl £31.604 Off Peak Int. = 47; No Peak! 482 7 BE £34.361 No P'eak! £4£ £4£ MN £57.61 -O. Ci045 3099 3099 Fb £5-5.94 -Cl.'.;)036 395'."i 3'"^50 Ci-: £67 . 7 1 6 'Iff P'eak Int. - 4 7. No Peak! H':)0 17 MG c:73. 07'3 --0. 0Ci.:.'9 1334 1334 AL 3Ci6. £l5 Off Peak Int. = 4 14 -O. C)C-31 £015 1 60 1 CA 317.935- -C'. C)036 ^30'.'1 7 3CiC)7 CU 3£4.754 Off Peak Int. = 320 -O.0025 48£ lb£ AG 328.068 No P'eak! Calculating Concentrations for Sample Number £7 cn Elern. Wave- Net P'eak Calculated Interference Net PI > Sym. length Intensity Concentration Correction Concentration o AG 328.068 375 0. C)03 0.001 < 0. 010 o to BE 234.861 £42 0. 000 0.001 < 0. 005 CD 226.502 32 0. 016 0. 016 CR 267.716 17 0. 000 < 0. 010 ID ! CU 324.754 162 0. 086 0. 001 0. 085 cn , MN 257.61 3099 0. 511 0. 311 •^ ! NI 231.604 7 0.045 O. 004 0. 041 Analyze Samples 01-18-1988 C- 15:24:13 — 31 ZN 213.356 109 O. C)45 O. 003 O. 042 AL 303,£15 1601 5. 613 5. 613 FE £59. 94 8950 1£.953 1£.953 CA 317.333 3O07 4. 565 4. 565 MG £7'-:}. '.J /•- 1534 3. 975 3. 975 763594 FILTERED MW5A Begiri AnSilysis — Satnple Number £3 Ele. Wave— Mean P'eak, Mean Peak Net P'eak '5-yri-i. 1 engt h P'.z.s i -r, i .rir.- I r. L .-^ --IH i t y I nt eris 11 y Zl-v £ 13. 656 Off P'eak Int. = 134 -0. OCi£l 19; b 1 CD £26.502 Off Peak Int. ;9t} No P'eak ! :.86 -1£ Wi 231.604 Off Peak, Int. = rvJo PeaP;! 4b.i. Bl- £34.861 No Peak! £26 !'lr-.i £57.61 -0.0045 i :• 33 he £59.94 -C'.'JCi3£ CR • £67.716 C:f f P'eak I nt. , = No P'eak! Mb £79.079 -Cl. C)058 975 AL 308.£15 Off Peak Int. = s3i No Peak! .;• ^5 14 CA 317.933 -C). C>035 ;664 £664 CU 324.754 Off Peak Int. 318 -O.0004 396 78 AG 328. C)68 No Peak ! 3 75 cn Calculating Conceritrat ions fcir Sample Number 28 PI > Elem. Wave— Net P'eak Calculated Interference Net Syrn. length Intensity Concentration Correction Concentration o to AG 528.068 575 -0. 0C)5 0. 000 < C>. 010 BE 254.861 226 0. 000 0. 000 < 0. 005 ID CD 226.502 -12 -0.002 < 0. 005 cn CR 267.716 -4 -0.015 < 0. 010 CJ CU 324.754 78 0. 036 0. 000 0. 036 Analyze Samples 01-18-1988 & 15:28:41 — 32 MN £57.61 1338 <:i. Ill Cl. 1 1 1 Nl £31.604 13 O. 051 0. C>00 Cl. 051 ZN £13.356 61 C>. 0£3 O. OC)0 C). C>23 AL 308.£15 14 :J. 364 Cl, 150 FE £59. 94 355 0. £75 Cl. £75 CA 317. 933 £664 3. 959 3. 959 MG £79.079 975 £. 564 2. 564 765598 MW3B Begin Analysis - Sample Number £9 Eie. Wave— Meari Peak r'l ;-.• .:i •.-1 i-'eai-- Net P'eak, •c;5 y m. length P' o s i t i •:. ri . :•:'. i.-r;i;r. J -i;'V 1 rit e-r.s 31 v 2N £13.356 Off Peak Int. = 130 -Cl. 0025 .i.b£ CD 226.502 Off Peak I-nt. = 399 No Peak! '+1.S i-'-ii £31 . 604 Off Peak Int. = 4-:.3 No Pe-r-.k, ! i-C-: b3'i. ;7bi !''io P- ?.^i--, ' .is 3 C-M 3 MN £57. 61 -O. CiC'46 :7Cil7 27Cii7 PL -59.94 -O.':.':i33 CH 1 9'ji£4 O: £67. 7 16 Off P'eak Int. = 467 No Peak! 4 38 £1 MG £79.':i79 -O.';;>':>37 ->395 'i395 AL 308. £15- Off Peak Int. = 373 No Peak! 4-.1 73 CA 317.955 -0. C"i054 ;4j,iC' 243 iO CU 524.754 Off Peak Int. = 3lfc -O,0025 476 158 AG 328,068 No Peak! 384 384 cn PI Calculatirig Concentrations for Sample Number 29 > O Elem. Wave— Net Peak Calculated Interference Net O Sym. lerigth Intensity Concentration Correction Concentration to AG 528.068 584 0. C)02 0. 003 < 0.010 CD BE 254.861 243 0. 000 0. 002 < 0. 005 Ol CD 226.502 14 0. 008 0. ooe Analyze Samples 01-18-1988 (? 15:33:02 — 33 CR £67.716 21 Cl. 003 < 0. 01 0 CU 3£4.754 158 0. 085 0. 003 0. oeo MN £57.bl £7017 3. 027 3. 027 NI £31.604 63 0. 104 0. 009 C'. 095 ZN £13.356 363 0. 162 0. OC>6 0. 156 AL 303.£15 73 - 0.142 / 0. 150 FE £59.94 199£4 £9.136 £9.136 CA 317.933 £4310 M£. I53 H3.153 MG £79.079 4395 ifc. 0 1 0 1 6. 01 O 763593 FILTERED MW3B Begir. Arialysis - 'Sample Number Ele. , PJove- Mean P'eak r-'ii-i,;-; P'eak r ZN £13.656 Off Peak Int. = 1£9 -Cl. 0Ci£9 ££4 CD ££6.50£ Off P'eak Int. = 39il99 No Peak! 4 £'..1 Nl £31 . bC)4 Off P'eal; Irit. = 47.-,' No Peak! 4 73 b BE £34.361 No Peak' 3113 MN 257.61 -Cl.'0045 £b£5i ^6£5i FE 259. 94 -O. C)032 17598 17 593 CR 267.716 Off P'eak Int. = No Peak! 456 -IS MG 279.079 -0.0034 4337 4 337 AL 308.215 Off Peak Int. = 381 No Peak! 399 18 CA 517.953 -0. 0C)54 a: :.597 £3597 CU 324.754 Off P'eak Int. = 316 O. OOC)6 385 69 cn : AG 528.068 No Peak! 376 376 P] I O Calculating Concent rat ic^ns for Sample Number ^O O to Elem. Wave— Net Peak Calculated Interference Net Sym. length Intensity Concentration Correction Concentration CD cn I OG 328.068 376 -O.002 O. 003 < O. 01C> Analyze Samples 01-18-1988 tf 15:37:37 — 34 BE 234. 861 239 O. oc»o 0, Ci02 < 0. Ci05 CD 226. 50£ 21 Cl. oil 0. oil CR £67. 716 -18 -0. 0£5 < 0. 010 CU 3£4. 754 69 C). 031 0. 003 0. Ci£3 i'li-,' ''3^'-ij »' M bl 26251 £. 940 £. •94Ci Nl 3 3 1 . bCi4 6 0. C144 0, 006 < 0. Ci4C> 2N £13. 356 95 Ct. 039 0. 005 0. Ci34 AL 306. £15 18 -0. 349 ( 0. 150 FE £59. 94 17598 -, tr 706 £5. 706 CA 317. 933 23597 40, 695 40.895 MG £79. 079 4 337 15. 782 15.73£ 7&3bC)£ f-lELD BLANK 1 -•< e Q i r 1 H ri a \ y s i s - S a m p 1 e i'-i i.i ir. u e i "3 1 Eie. Wave- Mean P'eak Mean Peak Net Peak •Sym. length Position Intensity Intensity ZN £13.356 Off P'eak Int. _ = i£b No Peak! 14£' 16 CO ££b. 5':i£ -J ft P'eak Int. = 3'?ici No Peak! .:.9c: r-a c:3l. bi:i4 Off Peak Int. = 463 No Peak! 456 -7 BE £34.861 No Peak! ££8 ££6 MN £57.61 No Peak! 336 386 FE £59.94 No Peak! 172 CR £67.716 Off Peak Int. = 454 No Peak! 4-.2 MG £79.079 No Peak! AL 308.£15 Off Peak Int. = 375 No Peak! 384 9 457 457 CA 317.955 No Peak! CO CU 324.754 Off Peak Int. = 314 351 No Peak! 37 O AG 328.068 No Peak! 575 375 O to Calculating Concentrations for Sample Number 31 CD cn CD Elem. Wave- Net Peak Calculated Interference Net Sym. length Intensity Concentration Correction Concentration Analyze Samples 01-18-1988 tf 15:41:56 — 3? AG 328.068 375 -Cl. 003 - Cl. OCiO I 0. OlO BE £34.861 228 0, OCiO Cl. OCiCi 0, Ci05 CD ££6.50£ £ 0, 003 0, 0Ci5 LR £67. 716 — i^ -0, 014 0, 01 Cl CU 3£4.754 37 0. 012 Cl. OciCi Cl, 025 MN £57.61 386 0. 002 0, 020 NI £31.604 -7 0. 030 0. CKKi : 0, 040 ZN 213.856 16 0. Cici2 Cl. OOCI 1 0. 020 AL 308,215 9 -0, 383 ' 0. 150 FE 259,9H 172 0, 008 0. cl£0 CA 317,933 457 Cl. 065 0. £0.:i MG £79.079 V-£'0 -Cl. C>'J3 Cl. £00 7 63606 TRIP BLANK Begin Analysis — Sarnple ^^iu^l-Iber Ele. Wave- Mean P'eak Mean P'eak Net Peak Sym. lerigth Position Intensity Intensity ZN £13.656 Off P'eak Int. = 1 £4 No Peak' CD ££6. 5Ci£ Off Peak Int. = 4Ci3 No P'eak I 39 i -12 NI £31.604 Off Peak Int. = 464 No P'eak '. H45 -19 BE 234.861 No Peak! 224 MN £57.61 No Peak! 378 376 FE £5'5. 94 No Peak! 1 69 169 CR £67.716 Off Peak Int. = 451 No Peak! 450 -1 MG 279.079 No Peak! 321 3£1 AL 308.215 Off Peak Int. = 365 cn i PI No P'eak! 376 > CA 317,955 No Peak! 455 455 o CU 524,754 o Off Peak Int. = 515 to No P'eak ! 354 39 AG 528.068 No Peak! 37Ci 370 «JD , cn •^ I Calculating Concentrations for Sample Number 52 Analyze Samples ••'1-18-1988 C« 15: 56 -lem. Wave- Nl -! >''i- ler.Qth 1 rrr, - (.alcul ated J r,t r- .':r.cerit rat i on L • .r •"^•«- Net -' ' -:•.:(:•. Cib3 L'oncentrat i,:.r, '•-••--•'. ;:*bl - C'. '.".ll - ''• c:.:-t,. L....;- 0. 0C"7 •|. Cl J :• '•' •-:3: . ,• 1^. -<-'. Ovi£ -' •--.:-• 4. V;;.^ ->.i. 013 - .-57.01 O. 0l3 0. Ci: ' 77-. i . t-.,;,.:» O.'OOJ 0. Cl,; * •-C:. ;r.n. O- Cil7 0. 03 O. C".l 1 O. Ci-< - Cl. 4'4 3 '.'. -.1.. - . '..'•.'"i ••>. i :,. '.'. '--li .-• -.1. ' 1.; '•^f>H f J UN BbKll.M •'-- ; I • ~''.' -1 HZJ^' .-•."i.'«. A, .• , '•-'-• i'':<--it-- •"-'J9. -JM 373 R 7.b /. •/ .i c-. 16?5 or7 .,•<-,.,,. j,_^_ : 63, N- "eak Off Peak i,-,t :10 w ^•'•••' Pe£.k PI Al., -i'^6. 06o r.j,:. Peak' 3/2 -/£ ^-^cui,,,,.^ Concentrations for c; , to ^ns Tor SsiMple Number 3- tlom. Wave- ^^-t P.=^L. CD cn correction Concentration 00 Analyze Samples 01-18-1988 li' .;:-•: 43 :£ 3 — 37 AG 3£8.063 1.1. '.11.11,1 BL £34.3b1 Cl. ".ll 1' I CD ££6.5vi.: i, k ,Vt;-7. .- , :;- I ^J .••.-•'. ,-L'( !--lN £5/. bl 1.1. <.•'.!; U'I c.M . b^.>'i 0. C7'-3 2N £l.v. 35b O. '.I'l.-i l"). . 1. I., 1 FE £59.94 i L.;- CL''.!(...:: U1GI:,S'I bS.i b. Beti 1 1-1 I k .-.•- : -. •i-.;.ii r!i'_- rr. er..,-. . i 1 :.l t r. Ll'J ^:ij.-. ;:JL.;,.. f.-i f P'4--i-.k J ;-: 1.-. ' 01+ P.:v:.l- Of T i 't^ak 1 r.t . = ;-..:,. •'. •.^^ • CU 3£4. 754 Off Peak }.-,t. No- K'tc.k' 4. A(J 323.063 Mo Pf^ak ' 1 Ul \ ! PI 7 Ca 1 c u 1 at 1 rill CC'riceri (. r rit lor.s for- Sainpli- rMiiintr'ti > : 1 Elem, Wave- N<,-t P'e^ik Calculated I nter t eierice Net Sym. lerigtti Irit eriE. i t y Concent rat i ori Lorrectiori Concentr at i .i-ri to AG 323. Cib3 b75 -O, 0'.i3 O. CiOO < Cl. Olu BE £34,861 ££4 C), 00(1 Cl, OOO < O, C)05 cn CD £26,502 1 1 Cl, 007 O. 007 CR 267,716 -7 -O,017 < O. OlO CU 324.754 43 O.015 0.000 < O- 025 MN 257.61 378 O. OOl < 0. 020 Analyze Samples 01-18-1988 & 15:51:15 — 36 NI 231.604 0.011 Cl. ClClO O. 040 2N £13.856 1£ O. OOO O. OCIO O. 02Ci FE £59.94 163 O. 0C)2 O. 02CI CC'-J Begin Analysis - Sample Number b5 Ele. Wave— Meari Peak Mean Peak Net P'eak Sym. length Posit iC'n Intensity Int ens ity ZN £13.856 Off Peak Int. 144 -O. 0Ci£3- 896c 3316 CD 226.502 Off Peak Int. 418 -C'. Ci037 2862 2444 NI £51.604 Off Peak Int. 51! -C). 0052 8384 7869 BE £54.861 -O. Ci055 25758 23758 MN 257.61 -0.0036 29C>63 29Ci63 FE 259.94 -0.0028 14511 14511 CR 267.716 Off Peak Int. 481 -Cl. 0Ci30 3477 2996 CU 524.754 Off Peak Int. = 337 -O. 0Ci36 9041 8704 AG 328,068 -C). CiCi42 3845 3845 Calculating Concentrations for Sample Number 35 Elem. Wave- Net P'eak Calculated Interference Net / J&i^O- Sym. length Intensity Concentration Correction Conceritrat icus^ cn ' PI AG 326. 068 3843 1.914 O. C)C»£ 1.912 <=lf > 1 BE 254. 861 23758 1. 022 O. OOl 1. 021 102. 1 CD 226. 502 2444 1. 004 1. 004 lOO oO ' CR 267. 716 2996 2. 168 2. 168 to ; CU 324. 754 8704 5. 139 O. 002 5. 137 !Sl MN 257. 61 29063 3. 259 3. 259 NI 231. 604 7869 8. 404 Cl. 007 8. 397 !?^ ZN 213. 856 8818 4. 054 0. 005 4. 049 o FE 259. 94 1A511 21.154 21. 154 NSEAiaiA 3 sHIGH 2:INTER 3:NSEA1214 4: SB STANDARD Analyze Samples 01-18-1988 C- 15:55:05 — 59 •/CEND; 'PG UP" to View More Lines Fn 10 or 'ESCape' to Stop ViewINTER INTERELEMENT INTERFERENCE STANDARD Begin Analysis - Sample Number 56 Ele, Wave— Mean P'eak Mean Peak Net Peak Sym. length Position Intensity Intensi ty ZN 213.856 Off P'eak Int, 145 -0. 0023 4461 4316 CD 226. 5Ci2 Off Peak Int . = 460 -0. 0056 5502 5042 Nl £31.604 Off Peak Int , = 49-M -0. Ci030 £357' 1843 BE £34.861 -Cl. 0035 549S,£ 54932 MN £57.61 -0. 0035 : 8Ci£4 1 3024 FE - £59,94 -0. 0027 167917; 16791O CR c'67.716 Off Peak Int = 486 -0. C)028 3£46 £760 MG £79.079 -0. 0052 33576 38576 AL 3C>8. £15 Off Peak; Int • := £.36 -0. C)021 17946 1 7258 CA 317.933 -0. 0052 17 10'j 4 171094 CU 324.754 Off Peak Int • = ' 324 -0. 0058 3756 .i432 Calculating Co-ncent rat ions for Sample Number 56 Elem. Wave- Net Peak Calculated Interference Sym. length Intensity Concentration Correction Conce ntrat ion ' ^ yi BE 234.861 54982 2.579 0. 015 2. 364 /Ol CD 226.502 5042 2. 069 2. 069 100 CR 267.716 2760 1.996 1.996 ^^ CU 324.754 5432 2. 020 0. 025 1.995 MN £57.61 1802A 2. 006 2. 006 NI £31.604 1843 1.997 0.075 1.9£2 Analyze Samples 01-18-1988 e 15:59:19 — 40 ZN 213.856 4316 1. 982 Cl. C15C1 1.932 ^^ AL 508.215 1 7258 64.583 64.583 FE 259.94 167910 247.369 247,369 lOC CA 317.933 17 i Ci94 301.148 301,146 MG 279. Ci79 33576 150,393 150,393 --.>, /^ /7;./g> Tr«y N*^ Test s^ .;/?//^' Cwp ubrJ«- IUia\t << au -(^ct «k»ft- )Jor(hpec^ (-^ hgffS I rri.,' ioiou!'- ^-'' ^" faj c^ou^ <^- Ics s:^ /o// ;^ ^ TV ' "ily uo dio Lf^ 2k 10 ^ 7c n ^ H w ^f I^ I^PDINU .{g.- ^ ^0 ^5v •I! /,'/-- eo ^-W ^s - Vl ''vV. ( i:roiVi:ro iv e 21 (ta, ^C'^l b /|(^>j //•^•:^ 7L 21 /u a /yc .-J iTL 23 -^Z -^ .'I <.Y ,'^' /- / La;'i. c ZH I <^ 2S rK <-^ o.f' 6 6 C '/c ri 26 cuJ fe^-t.^ <^ 21 ciiC^ tuu •:i 28 .1 u 0-- O^ r— O CJ .•^..'Oi.ti^L-i e»ri,i^c .-ru 4» u».»u«.Si <^£CiPiCi: crrhEff-^'-. •i 7c^ ..f- %^^— 3^ Jl > j ^e^ JJ^o^lr 21 if>?>km ^5: •^^^ffe ^ ^^ 'i? a » M2: /IO /(?0%n ^(x? ^s~ /•-Tt •fewiS £ -le^wds ^ 2£ iufeMi <^ ?6 ./•/ l^O^ I ^ g/ />/fl^' ^^ 58 dig Uo^: ^5 d^ Ics A£ ^87oY^c ^0 ?^^o^ ' % cn -PI. > 30 o I to ID .' =. .--X .3^r-\ ;i=>^c:-fcr^*^<^ 3/-*0 Sv^-t^cri R:^i=>or-*-t OPERATOR MONIKA DARRON DATE 12-31-S7 BATCH NORTHSEA # 12 TRAY # 1 PROGRAM 2 Se INSTRUMENT MODE ABSORBANCE CALIBRATION MODE CONCENTRATION MEASUREMEtvlT MODE PEAK HEIGHT LAMP POSITION 1 LAMP CURRENT (mA) .J SLIT WIDTH (nm) 1 . 0 SLIT HEIGHT NORMAL WAVELENGTH (nm) 196. 0 SAMPLE INTRODUCTION SAMPLER AUTOMI X ING TIME CONSTANT 0. 05 MEASLlREriENT TIME '.sec) 1.0 REPLICATES 1 &ACP::GROUrvlD CORRECTION ON FURNACE PARAMETERS [MPERATLRE TIME GAS FLOW GAS T- READ (C) 1 .' -_1 5.0 3.0 NORMAL NO '"' 90 2.0 3.0 NORMAL rjc -" 1 05 -30. 0 3.0 NORMAL ,NC •••! 1 20 3C>. Cl 3. 0 NORMAL l-i3 CT 70C' 5.0 -r ,-;, NORMAL I-.'O A. 7CJ0 15.0 3. 0 NORMAL no _ 700 5. ^ •* 0. 0 NORMAL NC s 2400 1.1 0. 0 NORMAL T'EE 9 24(10' 2.0 0. 0 NORMAL YES 1 0 240C1 1.0 3. 0 NORMAL NO SAMPLER PARAMETERS. VOLUMES RECALIBRATION RATE 0 SAMPLE CONC 7.RSD MEAN READ INGS UG/L ABS BLANK 0 0. 01 1 0.011 STANDARD 1 20 0. 0 0.233 O. '^7..'^ STANDARD '7 40 0. C) 0.554 0.554 STANDARD "T; 60 0. 0 0. 830 Cl. 830 STANDARD 4 eo C'. C' 1 . 120 1. 120 STANDARD 5 100 0. Cl 1. -342 1 . 342 .A:£ r UiHCEHTRftTlOH ijG/L lie SAMPLE 1 1 0. ',;,. 0. 011, 0 . 0 j r. 5AMFLE ^' 1 ,", 0 0.011 0 . C: 1 1 SAMPLE T 52 0. 0 0.716 C'. 7 1 6 SAr-PLE ^ ,54 1' 0. 746 0. 746 CT 5A!-1=-Lii- 1 '• : 11 •1. 0'19 '1- . 1 ". i'V r;;,;.ip| r c 1 C' •'.C '1C:.7 '".'. C)''17 ~ q B.:.!-iP-LE: C' O. 107 '-• . J',-' 33:-iFLE c. 1 ..- ',•-'. ','11 '1 0. <-' 10 bAflF'LE r't 1 '::. ••.dOr.- Cl. (••^>^ -r-MPLE 1 '•_•' 8 •-,' ij 0.097 0. C197 SAMPLE 1 1 9 Cl C'. 103 0. 1 03 SPiMPLE 12 1 0 i'l 0. 010 C'. 01 Cl SAMPLE 1 7. J ' ' C\ 0. 010 0. C' 1 Cl SAMPLE 14 10 Cl '1.114 0. 114 cn J, w,- 1 yi C'. 006 0. 00 c. SA.'-lPLE PI SP-iMPLE 1 6 1 i'. 0 0.009 0. C1C19 > SAMPLE 17^ 0 i" • 0 0. 006 0. 006 o SAMPLE is' Cl C- o 0. 005 Cl. 005 o SAMPLE 19 3 C' 0 0. 038 0. 033 to SAMPLE 20 1 0 . 0 0. CiOB 0.0',:>e SAMPLE 21 1 '-:-'. (J 0.007 0. OC'7 SAMPLE 7"^ 7 0 . 0 0. 087 0. 087 SAMPLE f—.-T 1 (.) 0.010 0.010 CP '3,:-iMPLE 24 1 0 . c> 0. 008 o.ooe SAMPLE CONC 7.RSD MEAN READINGS UG/L ABS SAMPLE 25 6 0.0 0.073 0.073 SAMPLE 26 1 0.0 0.009 0.009 SAMPLE 27 1 0.0 0.012 0.012 SAMPLE 28 0 0.0 0.004 0.004 SAMPLE 29 0 0.0 0.003 0.003 SAMPLE 30 8 0.0 0.092 0. 092 SAMPLE 31 0 0.0 0.003 0.003 SAMPLE 32 1 0.0 0.012 0.012 SAMPLE 33 10 0.0 0.117 0.117 SAMPLE 34 1 0. 0 0.012 0.012 SAMPLE 35 1 0.0 0.014 0.014 SAMPLE 36 11 0.0 0.129 0.129 SAMPLE 37 Cl 0.0 0.004 0. 0C>4 SAMPLE 38 1 0. c> 0.010 0.010 SAMPLE 39 4 9 C).0 0.681 0.6&1 SAMPLE 40 1 0.0 0.007 Cl. Ci07 SAMPLE 4] Cl Cl. 0 0.005 Cl. Ci'!'5 SAMPLE 42 29 0. 0 0.365 0.365 cn PI > o to Te^ riy 3 11 -vi^WcIV* R»t«\t*" au.fid:. ^.. ^''^'- --^^^ i^r I^PD OC 1 ^ -^ 1 I0l>/illc- \P-^y^-^cJ 1 .^^:^<(.^A />6. kz 76^ ^.?.- 1 ^^' f "-i y 1 / j '^3 /^c./ ^3c I ^s' r«v \ ^ro - o 3-4 \t?c ^.30 ^-•5 /c^^-y. /?c c t ? ^ 7 « j-j:. - '• •^r OJ PXi^,^ ^- -' • 1 i^^ ^' V 1 \D'^j •.&(^'<^ 1 :r^3 4.^A u 37 •^^ 38 b-/. ^^^ -/ ^f'P^T? u ^"i |-^^c- ^M^ y^- /^o/ Rc^ ao V/b'^ ^M c- I u ^w /V^ 4,1 v^ f ll'O- ^ V\z k.- ^3f. ;^7 Cr/^Cc 4^ u ^3 b./ /^y...,^ ^"v . KH Lo^^ &-^,..i< '•• -^. 1 ilrhKi^ k ^ 5- /•- .;,— y^/di^ Ti-rlf u r 1 (6 11 h^ i« IJ \^ Zo ^• IJ 21 22 IJ 23 2V IJ '2? 26 IJ 27 28 V\ i I. - cn 30 PI ; i,_.^ i I 1 O ! J-,=tO.- 1 1 •'1 IJD ' 1 1 -J 1 ^ \ MJ I « •>« 1 — .- rt.. ,.,v,,.^, 1,^.., ..•a.w «"»•..>.'T,c,. , - -J. .M._. M ».»\_i» „<.<.,. ,<.P?tCpF.,i„C. >.C,<<-C'I, Tr^-^ Ai_^ -Tc^.. _ r/5 6 - - 1 • AjS- ..i/r-C.^ •!--.• ?...c'/^ ^ --^ A^ly,i:^ Cwp Ub fO«. 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'4J OPERATOR N.K.r-JAMBOODIRI DATE 01-06-88 BATCH NORTHSEA # 12 TRAY # 1 PROGRAM Pb INSTRUMENT MODE ABSORBANCE CALIBRATION MODE CONCENTRATION MEASUREMENT MODE PEAK HEIGHT LAMP POSITION 1 LAMP CURRENT (mA) 5 SLIT WIDTH (nm) 0.5 SLIT HEIGHT NORMAL WAVELENGTH 'inm. 233.3 SAMPLE It-4TRQDUCTI0N SAMPLER AUTOMI XING TIME CONSTANT 0. Cl5 MEASUREMENT TIME (sec) 1 . 0 REPLICATES 1 BACKGROUND CORRECTION ON FURNACE PARAMETERS STEP TEMPERATURE TIME GAS FLOW GAS TYPE READ NO. 1 TS 5. 0 3. 0 ,NORMAL NO ^ 90 2,0 3. 0 NORMAL NO "T 1 05 25.0 3. 0 NORMAL NO 4 120 25.0 3. 0 NORMAL NO 5 400' 5.0 3. 0 NORMAL HQ 6 4C>C' 15.0 3. 0 NORMAL NO 7 400 5.0 0. 0 NORMAL NO 8 2''i'l'0 1.0 0. 0 NORMAL YES 9 20C'Ci 2.0 0. 0 NORMAL YES 10 250 c.) 1.0 3.0 NORMAL NO SAMPLER PARAMETERS VOLUMES (uL) SOLUTION BLANK MODIFIER BLANK — 20 r* O STANDARD 18 O STANDARD 6 14 to STANDARD 3 12 STANDARD 12 8 STANDARD 16 4 SAMPLE 20 0 o RECALIBRATION RATE 0 RESLOFE RATE 45 SAMPLE CONC V.RSD MEAN READINGS UG/L ABS BLANf-: 0 0.017 0, 017 STANDARD 1 10 0. 0 0.116 0. 116 STANDARD <-> 30 0. 0 0. 438 0.438 STANDARD "T; 40 '1. 0 0.531 0.531 STANDARD 4 60 0. 0 0.843 0, 843 STANDARD 5 80 C>. '0 0.967 0,967 1. 3e y / ^y 3,888 1=::. COHCENTRftTlOH ciG/L n SAMPLE (.) 0. 0 '0. C.'0.3 0. OCi.3 -SAMPI,..E I'l 0. •:"' 0. 003 Cl. 003 SAMPLE 50 0. '1 0. 630 0. -seo 'r,:-,MPLE 49 o. C; 0. 661 0.661 SAMPLE 6- --, - 0. 068 0.068 SAMPLE 6 0. '1 0. 066 0.066 SAMPLE 26 Cl. 0 0.358 0. 358 SAMPLE 0.0 0. 376 0.376 SAMPLE b C). 0 0. 074 0. 074 SAMPLE 10 ti 0. •:.•' 0.070 0.070 SAMPLE 1 1 26 '0. C-' 0.352 0.352 SAMPLE 12 41 C>, 0 0.550 0.550 SAMPLE 13 38 0, Cl 0.519 0.519 SAMPLE 14 .-1.^: '1. '0 0.722 0. 722 SAMPLE 15 Ci 0,0 0. CK13 0.003 SAMPLE 16 C) 0, 0 Cl. (102 0. 002 SAMPLE 17 10 0.0 0. 112 0. 112 SAMPLE 18 10 0, 0 0. 122 0. 122 SAMPLE 19 C'. C) 0. 370 0.370 SAMPLE 20 1 0.0 0. 007 0.007 SAMPLE 21 1 0.0 0.012 0.012 SAMPLE 20 0.0 0.257 0.257 SAMPLE O 0.0 0. 002 0.002 SAMPLE 24 0 0. 0 0.003 0.003 SAMPLE CONC •/IRSD MEAN READINGS UG/L ABS SAMPLE 25 19 0.0 0.236 0.236 SAMPLE 26 0 0. 0 C'. il'OCi C>. C)00 SAMPLE 27 0 0. 0 Cl. C)Ci3 Cl. 003 SAMPLE 2S 4 0. 0 0. 042 0.042 SAMPLE 29 4 0.0 0. 044 0.044 SAMPLE "T_,--, 24 0.0 0.317 0. 317 SAMPLE 31 'Ti — 0. 0 0. 31 6 0.316 SAMPLE "T T* 3 0. 0 0.037 0.037 SAMPLE -r "T .\ 0. Cl 0. 0-39 0.039 SAMPLE 3^ T>T 0. 0 0.316 0.316 SAMPLE -TrT C) 0.0 0. Ci06 C). 0C.)6 SAMPLE 36 C' 0. Cl C).003 0. 003 SAMPLE -•; — 5 0. 0 0. C'S'S 0. 058 SAMPLE — p 5 Cl. 0 0. 056 0.056 SAMPLE 39 0. 0 0.335 0. 335 SAMPLE 4!>SviJ-- ::v:i^--..-.^9- ,0.0 0. 106 0. 106 SAMPLE -•wi' ' " 9 '0. 0 Ci. cl 9 -. 0. C'99 SAMPLE 42 ^ / 0. 0 0. 376 0.376 SAMPLE 4-3 1 '"). o Cl. C'Ob Cl. 'OCiS SAMPLE 44 1 Ci. '1 0. C'Ci? 0. 007 SAMPLE 47 Ci. c> 0.632 0. 632 cn PI > o to CP IO tr*y N*. -^ Test n. ra5"-' *->» — 3>Ac 4i»-L g a A»^y» M-ICA/' Cwp UbN)«- fUta\t*'^ *IU <;ict. t^^.K/'£-^.=^'^. [ CU-6/<^r,i ^^ z }),^. PU^K <^~ 3 L ^ S- 4/ ^0 2 i (ic ^ i Dicy LC^ 52_ /c^ •/ Hcc 1 5- -rC- --; <- ^.o ^'yO 0k fc G 4):,. ^. .i ^-<;. ^^0 N.rPN((i 7 -i ZL- O ^^^' 22 \ic r- 8 L.C s • 5 1 /cj-ZCu *1 10 L It 12 L \3 W • 3 L ir 16 L 17 {« H 20 «. L 21 22 L 23 • 2V zs . 26 L 27 28 1 21 . 30 PI s - (— * CD , CD u-,.^L_ 1 ,»,>x .«„<.«, . .rra»,,<*,.,{»...,» c-ff u.'. ir.' V <^ r-" i ^t ( »p:> ts d "fc r^ <^ OPERATOR N.K..NAMBOODIRI DATE 01-06-88 BATCH NORTHSEA #12 TRAY # 11 PROGRAM Pb INSTRUMENT MODE ABSORBANCE CALIBRATION MODE CONCENTRATION MEASUREMENT MODE PEAK HEIGHT LAMP POSITION 1 LAMP CURRENT (mA) SLIT WIDTH (nm) 0.5 SLIT HEIGHT NORMAL WAVELENGTH (nm) 283. 3 SAMPLE INTRODUCTION SAMPLER AUTOMI X ING TIME CONSTANT MEASUREMENT TIME (sec) 1.0 REPLICATES 1 BACKGROUND CORRECTION ON FURNACE PARAMETERS STEP TEMPERATURE TIME GAS FLOW GAS TYPE READ NO. (C) (sec) (L/min) COMMAND 1 75 5.0 3.0 NORMAL NO T* 90 2.0 3.0 NORMAL NO "T 105 25.0 3.0 NORMAL NO 4 120 25.0 3. 0 NORMAL NO 5 400 5.0 3.0 NORMAL NO 6 4C)0 15.0 3.0 NORMAL NO 7 400 5.0 0. 0 NORMAL NO S ^OQC) 1.0 0.0 NORMAL YES 9 20C>0 2.0 0.0 NORMAL YES ,10 250C) 1. 0 •3. 0 NORMAL NO SAMPLER PARAMETERS VOLUMES (uL) cn SOLUTION BLANK MODIFIER PI > BLANK 20 o STANDARD 1 18 o STANDARD 2 6 14 to STANDARD 3 8 12 STANDARD 4 12 8 ID STANDARD 5 16 4 SAMPLE 2C> Cl RECALIBRATION RATE orci nC'ET D/\-rc- SAMPLE CONC 7.RSD MEAN READINGS UG/L ABS BLANK 0 0.017 0.017 STANDARD 1 10 0. 0 0. 110 0. 110 STANDARD '7* 30 0. 0 0.398 0..398 STANDARD "T 40 0.0 0. 528 0.528 STANDARD 4 60 0.0 0.788 0.788 STANDARD =; 80 0. 0 1 . 007 1. 007 CuNiErtlKHTIOH IJG'L i-'i SAMPLE SAMPLE SAMPLE SAMPLE fo^^ I SAMPLE i! X- SAMPI„„E SAMPLE SAME S-AflPLE SAMRI.E SAMPL SAMPLE SAMPLE in tn SAMPLE > SAMPLE SAMPLE o o SAMPLE to SAMPLE SAMPLE CD SAMPLE 03 SAMPLE CJI SAMPLE SAMPLE SAMPLE Trty N: S TaSt ^A Cwp UbfO«. R«>«\t*'^ 4U.'fict- a.fc. )Jf,r'tis4,*^}'L^ jsfiisi. Win ^/F^ ii^hLk ^/^ LJ^ /^z. i^z^ A^ Xi/^ « y^p^ i^J^ 1^1. I tf-i^*'A >'-t c__ :rjL^-L£.c2- AJ^ fLFPflt y^UJ U^ £/ ^ <^WAV?^ Z-AJ? ? I ^ n I "J'/" 8 :^jo<. 4^?y 111^ ei.\^fi-^cL jnd^ v-ir ^^^ ) JPPAJ^L 10 4!^.,r y^^ ^: Z^:^ 5 II ;»;^ ^3 e> n e? M.JL. -Al \Z J£l± ^ ^ ^ ?g>^^^ ^t^u*^ 4^v^ \3 20 4/<^2, ^ 1^ p PD/iC^ f^.'-m Jd h/4^^ ^ 21 J^gi ^^l- JL-L£^ } 22 Z/^ /;^y^^^ 23 JiiLL ^L 6 ^ ^rpN<^ i> !^ i>Jf>^^ Vi d^^fA 6^1^ 2? ±£JL. )^A Vr ^^ 26 W^//^ ^ ^ 2) 27 TpP^ ^/^^ 28 i2j£. ^: 2$^ ^FP^^ y^i^ tf-^ /:l-:t'<^'cl V\ J^p"^^^ ^//> .cn,., PI 30 fl^f 'P^ L£JL. l^^ > J3.- O IO 00 ^ ^ •._..,^ij /•.. I«<• • k»» at < e r^»r i ^ r. n-r-tK-ali" MMMbi p^^.. Tf^H^^ TtSt X^ AH ^UiLyf ^ \ LCS jj* V* T l^^l ^ J> PJ .! o to 0) 03 Nl v/. t^ X .ain Si:»^€=:-fc r^^<=^ .30/^0 Sv^-fci • P3 cr» c^ -fc OPERATOR WILLIAM FITTERER DATE 01 -13-88 BATCH NORTHSEA #12 TRAY #1 PROGRAM 5 Sb SAMPLE CONC •/.RSD MEAN READINGS UG 'L ABS BLANK 0 0.011 0.011 STANDARD 1 20 0.0 0. 116 0. life STArJDARC ^ 40 0.0 0.223 , 0.223 STANDARD 3 80 0.0 0.437 0.437 STANDARD 4 120 0.0 0.632 0.632 STANDARD e- 1 60 0. c> 0.794 0. 794 I). 01 J .^^ 8.808 COHCEHTRHTIOH UG/L I?6 SAMPLE 1 1 0. 0 0. Ci04 0. 004 SAMPLE r> ^ 0.0 0. <109 - 0. 009 SAMPLE y^ 102 0.0 0.547 0.547 SAMPLE 4 102 0. 0 0.547 0.547 SAMPLE 5 13 0. 0 0. 075 0. 075 SAMPLE 6 2 0. 0 0. 009 0. 009 SAMPLE 7 105 0.0 0. 562 0.562 SAMPLE 8 112 0.0 0. 596 0.596 SAMPLE 9 2 0.0 0.011 0.011 SAMPLE 10 1 0.0 0. 006 0. 006 SAMPLE '1 1 1 1 C-i 0. Cl 0. 584 0. 584 SAMPLE 12 1 0, 0 0.003 0. 003 SAMPLE 13 1 0.0 0.004 0.004 SAMPLE 14 105 0. 0 0.562 0.562 SAMPLE CONC RSD MEAN READINGS •ii UG/L ABS SAMPLE 15 1 0,0 0.007 0.007 •^-AMPI.F ,16 0 0. 0 0. 003 0. 003 SAMPLE 17 0.0 0.017 0,017 SAMPLE 18 0.0 0.013 0.013 SAMPLE 19 107 0.0 0.572 0.572 SAMPLE 20 1 0.0 0.009 0.009 SAMPLE 21 1 0.0 0.007 0.007 SAMPLE 22 112 0.0 0.595 0.595 SAMPLE 23 r> 0.0 0.011 0.011 SAMPLE 24 1 0.0 0.004 0.004 SAMPLE 106 0.0 0.568 0.568 S,;iMPI,.E 26 •1. 0 0.011 0.011 SAMPLE 1 0.0 0.007 0.007 SAMPLE 28 1 0. 0 0.007 0.007 SAMPLE 2o 1 0. 0 0. 0Ci8 0. 003 SAMPLE 3Ci 102 Cl. 0 0.547 0.547 SAMPLE 31 1 C). 0 0.005 0.005 SAMPLE 32 1 C.I. •: j 0.009 0.009 SAMPLE 33 1 CiO 0.0 0.540 0.540 SAMPLE 34 100 0.0 0.535 0.535 SAMPLE 35 0.0 0. 013 0. 013 SAMPLE 36 0. 0 0.012 0.012 SAMPLE 37 1 0. cl C). cl05 0.005 SAMPLE 38 1 0.0 0.006 0. (:i06 SAMPLE 39 86 0. 0 0.468 0.468 SAMPLE 40 0.0 0.011 0.011 SAMPLE 41 0.0 0.012 0.012 SAMPLE 42 89 0. c' 0.484 0.484 SAMPLE 43 0.0 0, 010 0, 010 SAMPLE 44 Cl. c> cn m > o o to CD 03 0) V--' .dr^ r-- X <^ I ><=: -fc t^O OPERATOR WILLIAM FIT itrvtf^ DATE 01-13-88 BATCH NORTHSEA #12 TRAY #1 PROGRAM Sb INSTRUMENT MODE ABSORBANCE CALIBRATION MODE CONCENTRATION MEASUREMENT MODE PEAK HEIGHT LAMP POSITION 1 LAMP CURRENT (mA) 5 SLIT WIDTH (nm) 0.5 SLIT HEIGHT NORMAL WAVELENGTH (nm) 231. '^ SAMPLE INTRODUCTION SAMPLER AUTOMIXItvlG TIME CONSTANT 0.05 MEASUREMENT TIME (sec) 1.0 REPLICATES 1 BACKGROUND CORRECTION ON FURNACE PARAMETERS STEP TEMPERATURE TIME GAS FLOW GAS TYPE READ NO, (C) (sec) (L/min) COMMAND 1 75 5. 0 3. 0 NORMAL NO 7 90 2.0 3. 0 NORMAL NO "7; 105 25. 0 3. 0 NORMAL NO ^ 120 25. 0 3. 0 NORMAL NG 5 800 5.0 3. Cl NORMAL NO 6 SOO 15.0 3.0 NORMAL NO 7 800 2.0 0.0 NORMAL NO a 2C1C10 1.0 0. 0 NORMAL YES o 2CulCi 1 .0 0. 0 NORMAL YES 10 200 SAMPLER PARAMETERS VOLUMES BLANK 20 STANDARD 18 Ci STANDARD 4 16 0 STANDARD 8 12 0 STANDARD 12 8 0 STANDARD 16 4 0 SAMPLE 20 0 RECALIBRATION RATE 0 RESLOPE RATE 45 MULTIPLE INJECT NO HOT INJECT NO PRE INJECT NO rnc. *"••"-"_'.. .^-V T K I TcrT" NU /^•KN Cwp UbfOo. R«w\t*'^ 4il ficl ^ ^.. A'-s^^CTT) *~^* tfifU. C^lf^UL I c Pit^- h/c-i^ U- C h <'---/^v-. /1/ r-C' '^C'-/ 1^1. ^ ^- C i. 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Pi,li.vJ^ C 10 > 1 37 -71.1 A ^^ ^ 1 0 38 lyi-'f, • h ^ •~^- , c- '-'"(X'lL. 3<^ -+ 2 0 4 ^^ '^: -/C'/.t't', ^ V^-^4?^ C lO ^1 P^.>-^3S -'- ,' :.' C '•; > '-^c- 1 '. i ^2 f 2 0 '•i^^'^ ^ [hc^ . /^^-w. .- , .•;;, 45- L C <, ••1 .t.- '•/ c .4 r C 1- -re -i-^^ t 16 )7 (« H ^ 20 21 \ 22 23 2V 2? 26 27 28 21 1 1 30 . 1 ,.^ > \ 0 i to : 1 1 ^ 1 to ..M . ^., OPERATOR N. F,. NAMBGODT RI DATE 01-02-68 BATCH NORTHSEA *t 12 TRAY # PROGRAM 1 As INSTRUMENT MODE ABSORBANCE CALIBRATION MODE CONCENTRATION MEASUREMENT MODE PEAK HEIGHT LAMP POSITION .1. LMMF CURRENT iliTiA) SLIT WII'TH inm,' C-i. 5 SLIT HEIGHT NORMAL WAVELENGTH ^nm) l'?3.7 SAMPLE INTRODUCTION SAMPLER AUTOMIXirJG TIME CONSTANT 0. Ci5 MEASUREMENT TIME Csec) 3. 1 REPLICATES 1 BACKGROUND CORRECTION CN FURNACE PARAMETERS ;TEP "EMPERATURE ' TIME GAS FLOW1 GAS TYPE READ fCi Csec) (L/(Tiir COMMANE . NORMAL NC NORMAL NO -;.o. o> NORMAL NO Zo. 0 NORMAL NO SC'Ci 5. C' NORMAL NO 80'!' 15. 0 NORMAL NO SCiO cr NORMAL NO 1. 1 NORMAL YES 2500 2. 0 NORMAL YES 10 "5'10 1.0 NORMAL ^;a SAMPLER PARAMETERS 'v'OLUMES (uL) SOLUTION BLANI: MODIFIER cn BLANK ,2C) PI STANDARD 4 16 5" STANDARD 8 12 O STANDARD 12 B o STANDARD 16 4 to STANDARD 2Ci C) SAMPLE 2Ci (li CJ RECALIBRATION RATE SAMPLE CONC %RSD MEAM READINGS UG\L ABS EL AN!: C) 0. 01 2 0. c,i ], 2 - ••.'•.NDAFD 1 2Ci .". 11 0.31'^ 0.315 STANDARD ^! 40 0, 0 0. 33 ~ '.-'. 6 J " STANDARD "T toO 0. 0 0.S9J 0. 391 ST ANDARD 4 8C' Ci. C^ 1.-11 1 1 . i 1 ,1 ,1. THNDAFD 5 1 'IC. il. C) ,1 . 2-^6 1 .29o .--1 ^-- --"** 1 i -.. 1 H 1 ..'- 1 •w- .-.-' 1 .--' i y'' ...'"" 1 _..---" ! n.-i .1 1 .^' •.'oy ic C'JHCtfllKHI IliN IjG'l lie SAMf-LE i '",. •„' • !_,' , '•1 ',„-' ,2 0. Cjil7 ,-. ,',,"-, cr Si^il •PL,E ,^- -,.,. --.,. , Cj 005 SAHPLE — -4.;;, '-1. •:,. 0. .- ,i .' 0 . ~ i "' 3y^nr:...E 4. ^6 C' ,; i 0 717 .'-| -7 ' "7 r: .:i-h-il"'ii'-'LE. C> 1,1. V.,1 '!' .iCi;! .-' . -," ' J i",- ,'i 7 :-,---.:-:PLir .- 0 0 Cl ••• •'.'. C.Ci2 SAl-IPLE "' 20 C-.. '-,;.'. 310 0. 310 c-Al-VrLE ,"- 19 0 ••"• C) 29'^ 0.299 SAMPLE -• 0 0 _ ..,i (..'. Ciil2 0. '.)02 BAMPLE i '.' C) .1 ..,.,• .1 il'l2 0. ilci2 SAMPLE 1 I 19 0 Cl Cj 295 0.295 A1 ^ SAMPLE ^3] 16 0 Cl ll . 75il 0.250 <^< ^^^ C,o^\ u- BAriPl^ 14 0. '1 2 j 7 0.217 n ,'^7 'I '^ •:-,^>? SAMP LE 25 21 0.0 0.337 0. 337 SAMP LE 26 0 0.0 0.006 0. 006 SAMP'L E 27 0 Cl. i.i 0. 005 0. 005 SAMP LE 28 1 0. Cl 0. 008 0. (.1(18 SAMP LE 29 1 0. Cl 0. 012 0.012 SAMF'L E 30 19 '1. Cl 0.306 >1. 3>16 SAMP LE 31 1 0. 0 0. Oil9 0. CiO9 SAMP LE 32 1 0. 0 C». 009 Ol. '009 SAMP LE 33 18 C-'. Cl 0.291 Ci. 2 •? 1 SAMP LE 34 19 Ci. 0 0.297 0,297 SAMF •LE 35 0. 0 il. il'-17 0. ilil7 SAMF •LE 36 0. C) 1,1. 013 0,013 SAMP LE 37 0. cn PI > o o to U) Ul ^c^/3c/lsry Tr^y H^UL rtit A^ 1^"- T>'U - C-p UbN)«- R^talt*" «IU- 4^ct- 1 OJ &i^'^^ ^fO z Di-:! • f>^aJ^ ^^o 3 4-^5- ^o /^••r;/,C,J-c_ Tv ." ;c /4^/ ildc 4 l>>c,,L-C-<. >/ Tv -- J li s- yi-6^y^ - It ;--c-i . .^ C' /• ^-. 23 • • ; ZH -„ -; i^^ |26 ' 27 |28 /- 21 • cn PI 1,30. > .,. ,o o 1 to t- 1 CO V ^31. r^ i ^Lft • P» ^<= -t r- OPERATOR N.K.NAMBOODIRI DATE 01-02-88 BATCH NORTHSEA # 12 TRAY # f-y PROGRAM 1 As SAMPLE CONC ••:RSD MEAN READINGS UG\L ABS BLANIC C) 0. 008 0. 0C)8 STANDARD 1 20 (Ii. i.i 0. 293 0. 293 STANDAPE •— 40 il. -0 0.572 Cl. 572 STANDApr "'. 60 0. i."' 0.844 Cl. S44 STAI-JDARI" 4 80 0. 0 1 . 076 1. 076 STANDARt 5 100 0, 0 1.289 1. 2B9 1. mo I 8.see l^ COKCEliTRftTIOH UGM ue SAMPLE O (J . Cl SAMPLE 0 0.0 SAMPLE 50 0. c> SAMPLE 51 0, (1 ^SAMPLE 0 0, (1 ^SAMPLE (1 0, C'ckC •^i?*^ ^^!C \ / -,, ^ z Dic,.^j^ y~ \c ( ^ i- ^ , o / ^ Pi^plf3>0 ^•: 1L-^ /i-/^/>ANL 7 -t2o -43 0 Z^' ^ci- ^<- 6 •+2o -4 30 /^ ^, cy- /^L-•^ 7>ifjt^^ • r^3^^n ^ .il- fc- 1 10 JX^^-^%o ^ (L- t • 11 i2o •U2JO /fo -^ s-^ /^y^^ 12 7^3 4?>^ ^-:ip Mu^^/^ . 13 Pi- -f • ^3>H <(r ^'OA/CL H •Y?o l-i^L, , /^ '^r/' )?ce ir C-4 9^..X^ ^ir (6 ^^•&w4^- -'-t.- 17 ll^^i>>S> z-,c- A4i^ j^4c. {« 2H-4^fe ^~/c ^P0A/C_ 11 -f 2o - i-fM; z-;^ ^'T^/ ^<^ --^ ir* 20 ih^mii. ) /T-./.^ .^^:-..4 . -' ( L~ 21 P-y^ii 2 (• • 22 rjt.-- ^ .4 2 :^.3> y/^'Z-KC.. 23 7.^34 4 0 ^(c^ ^ • /r//>- B<^^^k 9 • 1 - ..-•-' ^• ZH JX^-^li U ^( = 2S Oc..4 4(? ^ ^> • ^ '//r/- K-* «—- 26 r^' •/t)k»«it- ^/c' 27 2>?p-|i»..4^. ^-IC . 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U .M I Jk»v_l««< COft^i^iCr, OThfcCu^M^i 'C/.sn.r-x.siin Sfn.4scr-fcr^«^«^ 3 /-'*<_> Sv'^'fc^T' Fc^l=>C3i---fc OPERATOR N.K.NAMBOODIRI DATE 01-04-88 BATCH NORTHSEA # 12 TRAY # 1 PROGRAM 4 INSTRUMENT MODE ABSORBAtvlCE CALIBRATION MODE CONCENTRATION MEA'SUREMENT MODE PEAK HEIGHT LAMP POSITION 1 LAMP CURRENT (mA) 5 SLIT WIDTH (nm) 0.5 SLIT HEIGHT NORMAL WAVELENGTH (nm) 276.8 SAMPLE INTRODUCTION SAMPLER AUTOMI XING TIME C.DNSTANT 0. Ci5 MEASUREMENT TIME (sec) 1. O REPLICATES 1 BACKGROUND CORRECTION ON FURNACE PARAMETERS •ETEP TEMPERATURE TIME GAS FLOW GAS TYFE READ r..-Ci. (C) i sec ) (L/min) COMMAND -Tcr J / O 5.0 3. 0 NORMAL NG •T .L- 90 2.0 . il NORMAL NO "'. 105 30. 0 -^ (1 NORMAL NO 4 1 —'-' 3C'. i'i T; Ci r-JQRMAL MO cr 4C"-1 5. il ^ Cl NORMAL NO O 4(10 15.0 T; (1 NORMAL NO "••• 400 5. Cl 0 .0 i CiRMAL NO 3 220«>. 1. 1 i". 0 NORMAL I'ES -•• 2200. 2.0 (1 Ci NORMAL YES 1 0 2500 1. 0 T (1 NORMAL NO SAMPLER PARAMETERS VOLUMES (uL) SOLUTION BLANK MODIFIER cn BLANK 2ci PI > STANDARD 18 STANDARD 14 o STANDARD 12 o STANDARD 8 to STANDARD 16 4 to SAMPLE 2ci (") o o RECALIBRATION RATE ^C SAMPLE CONC y.RSD MEAN READING UG/L ABS BLANfC (1 0.030 0,030 STANDAP0 1 1 0 0.0 '1. il92 0.092 STANDARD —: .30 0. 0 0. 313 0.313 STANDARD T 40 0. 0 0.385 0.385 STANDARD 4 60 0. '1 0.568 0. 568 STANDARD BO 0. 0 0. 733 0.733 3.386 H I e i 9,'-'C». ISL_ COHCEriTftfiTiuil UG/L 88 SAMPLE 1 - 1 (1. '0 -0.0O5 -0. iioe SAMPLE -1 0. il -0. Oil5 -0.005 SAMPLE —_ 54 0. 0 0. 509 '1. 509 SAMPLE -a 54 0. 0 0. 51 1 '1.511 SAMPLE CT , 1 0. il-i il. 005 0. il05 SAMPLE c- 1 ll. il 0. 006 il. il(16 SAMPLE " 18 0. 0 0.171 0. I-'l £A!-1FLE 5 19 0. il 0. 180 C'. ISO SAMPLE •V 1 0. 0 0, CiilS '1. 005 SAMPLE 1 C' (1 0. 0 (l.Oill <1. <101 SAMPLE I -1 1.-. 0. 0 0. 156 0. 156 SAI'IPL E 1 -• — Cl 0, 0 -'0. 002 -0.002 tn.,. SAMPLE J --• — il 0, 0 -0.003 -0. '003 p] * SAMPLE i 4 19 0. 0 0. 189 0. 189 SAMPLE 15 1 • 0. 0 il. ciiiy Ci, 006 o SAMPLE It, -il 0. 0 -'0. iiii2 -il. il02 o SAMPLE 17 '0 (1. (1 0. 001 0.001 SAMPLE IS —(1 0. 0 —il. Cl(l(l -0. (I'lO SAMPLE 1 c 18 0. o 0. 174 0. 174 to o I SAMPLE ",", (1 0. 0 il.OOl il. 001 O i SAMPLE 21 1 0. 0 il. 006 Cl. SAMPLE 0.0 0.229 0.229 SAMPLE 26 1 0.0 0. 007 0.007 SAMPLE *;: / 1 0.0 Cl. 0'16 0.006 " SAMPLE 28 —O 0.0 -Cl. (1(11 -0.001 SAMPLE 29 C) 0.0 (1. CiCiCi o.ocio SAMPLE -3(1 20 0.0 0. 192 0.192 SAMPLE 31 19 0.0 0. 182 0. 182 SAMPLE -1 0.0 -0.CI05 -0.005 SAMPLE -Cl 0. 0 -il. C)(12 -CI.002 SAMPLE 34 19 0. 0 0.182 0.182 SAMPLE —il 0.0 -Cl. (Ill] -il. 001 SAMPLE — (1 Cl. il -il. 000 -0.000 SAMPLE —(1 0. 0 -il. CiCil -O.CiOl SAMPLE (1 0. 0 •1. 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NY. 11747 • S16-604-S040 HOLZMACHEK McLENDON Md MURRELL PJC • ENVtRONMENTAL Mid INOUfTIIUL ANALYTICAL SERVICES ICP WVELBESl CAUBRATICN WD sn^nsacs PC5R rmED CURVES. to to 03 1"^ CHAIN OF CUSTODY RECORD ': VriKUIIO. fKOJCCTNAUl I I . 1 1 W#iii>'»l • 1 6)>iyyA l,y. £UB£ 1^1; •TATWII iOCATMM LA(>W(^MI^ct€«i b,^^TiHa. .jd^Ld{ MlIZ. »> .£CJA^,.S\ UUMI^ w Ola.oAsCU J2yxJ^oU^\/ f\evV ^l tt •*-» .» .." .-*« OullTlm* n»(tW«tf kyi Wrti^l MfN<«qu<•^fd kyi /(^Miwfl 0«l« /T)m« flfC«l««4 •^1 «?f'A*e ^ \/jfiy(^^ ^;i^L^ i " V)lM A(lift^ih«4 ky: ft^*MK llM«W«tf \m LjkwtlMv kyi OM« / Tlm« KWMtVli r /d/^tlY-li^ {b\-A'ir\\ ^o"' '- "^^^^WtA^^ ' It.' >f C**f «• C«l»f !>«»»»«<# »4M : •.|"t 1 V I '>r .fe. -ltl^^''^^^^ii'^'^^^'' TZOZ ZOO V3S 11 "^ Fv>\\ CU'' ^ Ceo rtitH LAMOtUTOKT Paoe •SHVAf «t,f "5- LA Cbntirtiijw Qiain of Custodv ^ cc V\<^ date ICK-JV sn ^TtWO f signature cN\«-<^T r No. of bJttlffs reoeived ^ r^.^^-i^c, "To* 3 type sat lab no. 0'>c "^^ \o M^*3c ^>- ^»^,'^^,^ A :^x(g>,3>.M ~lt^=?°vo ^^^ /K\'» * I MUJ*3A ^ P ID, \ A 'Hf f>/.^^f^ k. I ^. \ t. I TTTJ ~><:36r.i S2art3le J**"! •< rt-nii c*ygd jjfjSaaial^ e J^soeived hr Date BSTHO aottle Type ^tea^aoa / 1 V'\<.'. ACt_ •ST...-,^* 1 Ar^JyC,^ k lUJ- 1 [ icKMi-s 1 r<» - / 7'^ I 1 r ^ > o o ------. .-... - to (O o to to -. iiZH lAWMTOKT ™_jy5e2^1 Page 2 CGntirmjiq Chain of Custody Analysis Bv Date Analvst Simatare Date Qstcadian Sianature \Ki Ll. -./^./o IDS W lilzUr:?. - ^/v^ WK ll/ioi^l ?u..J i^t /////A 7 /ai:.M\r. Uct\ M)/fc/&7 A/" (^Tfcw***^^ 7 7^:^.0 ^^W^>^ ;/kA/ /'//^/A-7 I <^ li l^!')(r U^^^^^^^ •fZ?o ih^liluk^^' VMV^ ,^.>^.7,-C<^.~^. •'V/^\- y ^ .^VWit^"- ^ mj jikci<^n ffl/u^JlJi..^^ W -~^- T4S-- A//CV ij^lk^ iM sC ^ • /t/ZW // io(^ i-ty^^-^-^ ^Z _& pcup ///^/rt( 7X m dhjuMy wnM 2^ U-i<,<^ :jrp ^ JMUj^M. TJ ^ /A^ CO Sigegviaoc .-• Regies o QC >fanager fo to o M CJ 01-18-1988 & 11:AC):£0 — 1 Foi-- i-Javeierioth Crt 1 i br-at i ori, S:• Dec:i a 1 or •:C> £< i . .TiCtfCl" ur Er.-.iir 3~. i-C\CL>fv3D r-:\}r\3EH •. i - r •;:• :z:>. L i : Stafidarc r, ^ t;-o!: ut j or. L* pjr; L:L;N"! INUL; ;:^C--'.> !'i'': - '"1:: ; >'r'-Oi.iV..... /i; f-:£;p i a cat 2 c-ri Peak r-'os-. fj ^•caK Off 'eaK i:- ,L f-;;!Grc"it ,--o'- 11 i ori N I.I'll beV i rit ensi t y Pnt IritC'i-s Pnt. c i nt efi': i-i.;: t'L=-ai; : *vi.-' r .1 ~-M l-lo No P»: a k ! iv ..' IH No >-'C-f tiC.;.. iC ii I-. uj Mrc.ciric Lli C^C-. C-•-...: Peak Replicat ic 'YI P'eak P'os. urf Pcv£-.k Off Peak E ] f-iiieri t P'i'Sit ii^.n Number Int ens ity Pnt . i InteriS Pnt. 3 Iritey>£ CD No Peak! i N/fi 394 CD No Peak! £ N/A 2&3 CD No Peak! N/A 387 StatistICS for CD 33S. 50£ AVERAGE 0 01-18-1988 @ 11:48:46 •A R. S. D. 0. OOO Scanri in g Around NI 331.604 Peak Re->pl icat ion P'eak P'OE. Off Peak Off Peak Clement Posit ion Number Iritensity P'r.t. 1 Intens P'rit. ;-; ii'i + N i No Peak! 1 N/A NI No Peak! o N/A '11-.-. NI No Peak! N/A 4t:.4 Statist ics for Ni ,^21, 604 AVERAGE 0 •/. R, 6. 0. - 0. CJCJO Scann inci Around BE SC'i. Sfcl Peak '^r: A ; r c-.-":- i ori P'ef. k Pov-. Off Peak Off Peak. Ci ernent POC=: t lOr; "-1 ;:';b'.>*- !i -it eri-2 11 y Pr,r-. 1 I nt eris Pnt. CL Int^^'-i PE No i-'e f'r! i:. : N..' t^; l.^F No ^•c;.:>v. ; h-i/M BE. No Peak! K/ft Stat ist ics fo-- Bt; £34. 861 AVERAGE •/. R. S. D. = 0.000 Scanni nn Around MN 3^.7.3:0 Peak Fr-.pl •• cat ion P'eak i-'os. Off Peak Off Peak C: i.-j,^er,t. Pi:'S i t i --'f. ;';'.u,iber- Intersity i'-'*'.t. 1 Interi'^ k'nt. 3. I rit ens No Peal-'.' - !•.' / A I-":. • ,;o i-'(=at-' : I''!..' H No i-'era'! J:- :.j.-p Stat ist ics f.:..-- f'C 337. 610 AVERAGE = 0 % R. S. D. = 0-000 Scanriing Around FE C'59. S40 - Peak Replication P'eak Pos. Off pF-ak Off ('e.-.-.k E1 ernent P'DSit lofij' '- Number Irit ensi ty P'n.t. i Intens Pnt . 3 i nt f;-i-i'i FE No Peak^^^^r N/A FE No Peak^^% N/A FE No PecAk-\S- 3 N/A Stat istics for FE £53-940 • AVERAGE Cl % R. S. D. ~ O. 000 Scanrii ng Around CR £67.716 Peak Replication Peak Pos. Off Peak Off Peak cn Element Posit ion Number Intensity P'nt. 1 Intens Pnt. Int eni > CR No Peak! 1 N/A 446 CR No Peak! £ N/ft 445 O CR No Peak! 3 N/A 446 O Stat ist ics for CR £67.716 AVERAGE = 0 O •/ R. S- D. = 0. 000 to Scanning Around MG £79.079 cn Peak Replicat ion Peak Pos. Off Peak Off P'eak Element Posit ion Number Intensity P'nt. 1 Intens P'nt. £ Int ens MG No Peak! 1 N/A AVERKbC 0 •/ R. S. D. 0. OOO Scarinir g Around AL 306.£15 Peak Replicatiori Peak Pos- Off Peak Off Peal'. I f?iiieht Posit ion N 1.1 IP ber Interi'iity r-"'nt. 1 Intens Pr,t AC -0. 007",• X N/A 3 76 AL -0.0079 ^ N/fi 37£ AL -O. OOSc: N/A 375 Stat ist ics for AL 308.215 OVERAGE 0 cn > o to too to 01-18-1988 & 11:57:33 — •X R. S. D. 0. OOO Scanning Around CA 31 /. -333 Peak Replication P'eak P'os Off Peak utt Pf->ak t: 1 erner t P'osi t iori r; umber Intensit I'vit. 1 Intens P'r.t. ;-' Ci'ilens CA IN'O P'eak ! 1 N/A CA No Peai--. '.• w .N/.-:! CA No Peak. ! N / H StatistICS for- Cft 317. '933 AVERAGE - o y- R. S. D. 0. OOO •Scanriing Around CU 3£4.754 Peak f-ierl icat ion Peak Pos Off Peak Of rl i emer t P'Dsi t ion IN I.I m ber Intensi t Pnt. 1 Intens Pr.t. CU No Peak! 1 N/A CCi n.'.r. Peak '. 3 N/A CU No P'eak 1 N/A St at ist i cs- r or 'Cu 3£^. 754 AVERAGE 0 •/. R. S. D. 0. 000 Sc a nr ing Around AG 3£S.068 Peak Rec'l i cat ion Peak Pos Off Peak )f f C 1 emer t pT'Sit ion Nuri.ber Intens i t Prit. 1 Intens 11 . iri i!:i AG No Peak! 1 N.'A AG No Peak• iT- i^J..-A AG No Peak: l-J..' A otatistICS for Mb 3£6. 'Jfc.a AVE .K AGE O y. R. 3. D. = 0.000 'Scanr inp Around BF\ '+55. 403 h'eak ^. f,- Replication P'C?£>k I-•-•'::: e.1 erner t P' •:• s 11 i C'.ti^^ji i^- u rn b e r Intens i t t-'rft. A Iritens i-'r'.t . .' iiitr-i-' bA No Peal^^;?-. i N/A BA No PeaSifffliv.- £ N/'A BA No Peaklir*-^ 3 N/H Statistics for BA 455.403 ' AVERAGE = 0 •/ R. S. D. = O. 000 "^ Scann1r g Around NA 588.995 cn Peak Replication Peak P'os. Off Peak Uff Peak tn Element P''Osit ion Number Interisits Pnt. 1 Intens P'nt. 3 Iritci- > NA -0.0005 1 N/A o NA -0.0005 £ N/A o NA -0.0005 3 N/fi to Statist ics for NA 588.995 AVERfiGE O too * R. S. D = 0. 000 to BLANK RE-CALCULfiTED AT END OF CALIBRATION 00 Enter STftNDftRD NUMBER (1-7) or -1 to EXIT: standard «£ solution aspirating - CONTINUE ? Y Cit-ir.Grit Porri i t i ._'r. .••iMiiibc-v 1 Intens AG 0.00O6 1 ^•3t-H AG O. 0<;i07 £ 40C'3 AG O.0009 5 40 3'. St at i st i cs for AG 3£S. 068 AVERAGE -- i+OOO y.. R. S. D. = O. 387 STANDARD «£ 1* cn tn > o to oto to 01-18-1988 t* 12:07:48 — 4 Element Wavelength Ave Int yi R.S.D. Ref Blank Int Off P'eak Int Net Int AG 3£6. 066 4000 O. 387 O 4000 Enter STANDARD NUMBER •; 1 - 7) or -1 to EX I'l : 3 S t a rid a r d ** 3 s •:• i y t x •:• ri a t p i v .>i t i ri Q i;T INUC Scaririinci Plrc'und AG 3£tj. '-/'6fo PsB^- ffepi icat ion i^'eak P'os. Off Peak Off Peak Element P'osition Number Intensity P'nt. 1 Intei-is Pnt. 3 j-.-it ens AG 'j. 0';>0& 1 18453 AG O. O'OOa £ 1S45£ AG O.';:)i.i07 3 , 18481 'Statistics for AG 3£6. 068 AVERAGE = i846£ % H. 3. D. -• O. 0'9u STANDARD «3 Element Wavelength Ave Int % R.S.D. Ref BlanK Int Off Peak int i'-Jet int AG 3£S. 068 1646£ 0.090 0 aS46£ Enter STANDARD NUMBER (1 - 7) or -1 to EXIT: 4 Standard ^H solution aspiratinD - CONTINUE ? Scanni-ncj Proond AS 133.759 P'eak Rei-pl icat ion P'eak P'os. (.Iff P'eak Off P'<.-,--a- LlemG?rit Pc^sition Number i. nt ens i t'y -V . .;• i i-'t en: AS -O. 0C)31 1 £90 1 _-•-!;•:• 1 '11 1 "* '-t AS -O. 00£8 £ £8':* A. <»' —' 1 3t- AS -0.00£5 3 £36 133 1 33 Stat ist ics-_. for AS 1'33. 75':- AvERAG^^^%=-'' £9£ Scanriing Around;^ftji;96. 030 Peak?^^p£jlTRepl icat ion P'tai-; Pos. Off >-'eak Off P'eak E1 ernent Posi t i orisS - Number Intensity P'nt. 1 Intens P'nt. 3 Intens SE -O.0006 1 30£ SE -0.0005 2 295 SE -O.OOIO 3 289 •Statistics for SE 196.090 AVERAGE = £95 •/. R. S. D. = £. 347 cn Scanning Around ZN £13.856 > Peak Replication P'eak Pos. Off Peak Off Peak Element P'osition Number Intensity P'nt. 1 Intens P'nt. £ Intend', O O ZN -O.0028 1 4392 137 to ZN -O.0030 2 4393 134 ZN -0.0031 3 4415 139 to Statistics for ZN 213.856 o AVERfiGE = 4400 CJ % R. S. D. = O. 303 o Scanning Around PB £20.353 PB -O. .j.:.:i i P'B -O. 0015 351 Stat i st ics for PB 220.353 AVERAGE 348 y. R. S. D. 1. 954 Scanning Ar'i-und CD £26. 502 Peak Replication P'eak P'OS. Off Peak Off Peak E1ernent Pos i t i on Number Inten'ji-1 ty Pnt. 1 Intens Pnt. £ Intens .§igrr.'5,i':.,. 01-18-1988 & 12:16:15 — 5 CD O. 0<;i£8 1 51 £6 406 CD 0. CtCiES 2 5175 419 CD Cl. O'JEii 3 51 95 407 Stat i-t icfj for CD 226.50£ AVt.l\'iV;-f.-. 5166 •••: R. •.-:. D. 0. 673 Scanning Around Nl £31.604 Peak Replicat ion P'c-ak P'or;. Uff P'eak Uff Peak Elernent P'os i t 1 ori Number Intensi tv Pnt . 1 Int ens it. 3 Intensi NI -O. (.!•;:) i 3 1 333'i 4 65 NI -0. 0'J15 £ 333S 475 Nl -•:>. o.'.^i 5 471 Statist ics for NI 231. 60'+ AVERAGE = 2294 y. R. S. D. 1. 856 Scannin g Around BE 234.661 Peak Replicat ion Peak. P'OS. Off Peal'. Orr P'eak". Element Posit ion Number" Ir. cen'.i 11 y i-'nt. 1 Intens P'nt .3 1 ntens BE 0. 0014 1 5£346 BE 0.0017 c! 52435 BE 0. 'O'J 1 3 3 . 333^3 Stat 1st ici for BE £34.861 AVERAGE 5234 i V. R.S. 0. O. 1»^ 'Sca.nri 1 rit l Piron;-.d hIN £57.610 PeaP; Replicat ion Pt;av.' P'OS. Off Peak Off P'eak Element P'O'.; i t ion Number I fitensi ty k'nt . 1 I ntens k'nt . 3 Inter MN -0. OC>06 1 1750U MN -O.0006 ki 1756'+ MN -0. '30O&'-; 3 i ~ -•> 41' St at i s ti^si f-or MN 257. 3 1 O AVE RAG'^i-'"; '. = 17502 •/. R. s-!^": • = 0-350 Scannin e Arourid ''FE 259.940 Peak Replicat ion Pdak Pos. Off P'eak U-i-f ', Element Pos i t i on Number Intensity P'nt. 1 1 rit ens, P'nt. £ FE -0.0030 1 1487 FE -0.0030 2 1470 FE -0.0031 3 1484 Stat ist ics for FE 259.940 AVERAGE 1480 '/. R. S. D. 0. 602 Scsiririin g Around CR 267.716 Peak Replicat ion P'eak P'OS. Off Peak Off Peak E1ernent P'i'S i t i on Number Intensity Pnt. 1 Intens Pnt. £ CR 0.0025 1 3153 CR 0.0025 2 3171 CR 0.0027 3 3135 Statistics for CR 267.716 AVERfiGE = 3153 EI emer it P'o'.^..'. , --i i Number Pf;t. 1 irrci.-. i- -":. ifiteris> MG -O, 0'.";)-t 1 MG -0. •:)0i:i3 2 MG -O. 0>:>04 3 .8l'ri Stati::t3cs for MG 279.073 AVlLi'i-ioE = 830 •A R. £. D. = 1. 159 Scanning Around fiL 308.215 Peak Replication Peak Pos. Off Peak Off Peak • E1 eriient Pos i t i on Number Intensi ty P'nt. 1 Intens Pnt. 2 Intens ^ffz;T 9c . CO M O O to to O CJ CJ 01-18-1986 e 12; 19 — 6 AL 0. 0010 1 991 386 AL 0. OOl2 2 376 387 AL 0. 0'J03 3 389 390 StatistICS for AC 308.215 Ave RAirL 966 •/. R. S. D. 0.621 Scanriinn1 Arourid CA 317.933 Peak Replicat ion Peak Pos. Off Peak Uff Peak E1 efiient Pos it ion Number Irit en-ii t-y Pnt. 1 Intens (-•nt. £ I rit ens CA -0.0004 1 1551 CA -0. 0i;>03 £ 1555 CA —0. O'JO 1 ..1* i55C st at ist 1 c'3. f c^r CA 317. 333 Fi:^ERi-\33 1554 •/. R. S. 0. — ." ' L: *= Scanning 1 At'ourid CU 324.75H Peak Replication Peak Pos. Off P'eaK Uff P'eak E1ernent Pos-i t i ori Number Interisity Pnt. 1 Intens P .':t . £ 1 rit ens CU -0.0025 1 3615 324 CU -0.0024 2 3651 322 CU -0.0023 3650 32 i Stat ist ics for CU 324.75t AVERAGE 3633 •A R. S. D. = O. -TJ-ZIB Ccannin;.' Around BA Mt-.',:... •'^Cii Peak Kepj icat ion P'eak Pos. Uff Peak 'J f t P'eai-: e 1 ernent P'-r-s i t i on Number irit c-rr-;. ity Pnt . i Intens •."Z m L-: " i rit eris BA -0.004 5 1 8348 BA -0. 0';i4 7 2 8930 BA -0. OO^^ir. bBb3 Stat ist^Hlffo r BA 455. 403 AVERAGi%;;l.^z = 8920 ••'• F.. sm-Dl '-= 0. 373 Scanninc ! AroundSfNfi*''•588 . 995 Peak Replicat ion P^ak P'OS. Of f P'eak Lift P'eaP; E1ernent Posit i'On Number I nterisi ty K'nt. 1 Intens Pnt . £ Int 6 NA -0.0008 1 1275 NA -0. 0006 2 1270 in NA -O. 0008 3 1279 Statistics for NA 588.995 fiVERAGE 1275 v •/ R. S. D. 0. 340 o STANDARD *»4 to E1ernent Wavelength Ave Int •/ R.S.D. Ref Blank Int Off Peak Int Net I ^J BA 455.403 8320 0. 373 0 6^ -CJ BE 234.861 52341 O. 184 0 523 .*- CD 226.502 5166 0. 673 411 47^- CR 267.716 3153 0. 582 464 £689"' CU 324.754 3639 0. 558 322 3317 MN 257.610 17502 C). 350 O 1 T^-.ris- FtL C.'—''l' . 'ziH^.i 14 to •- ^ILV," 1.1 14 so CA 317.933 1554 C:. 165 c> 1554 MG £79.079 830 1. 159 o 830 NA 568.995 1275 0. 340 o 1275 01-18-1388 If" 12:31:45 — 7 SE 196.090 £95 2. 347 O 295 AS 193,759 292 1. 333 139 153 PB 220.353 346 1. 954 O 348 Enter STANDARD NUMBER (1-7) I'r -1 to EXIT; Stancard *5 solution aspirating - Cc^-.ilNUL ? Scani-iinq Around AS 193.759 P'eak Replicatiori P'eaP; Pos. Off Peak Off Peak Elemerit P'osition Number Iritensity P'nt. 1 Intens P'nt. 2 Intens AS -O.0027 1 944 149 140 AS ~0.0027 2 319 1 4 7 • 1 4 O A'S -O. 0027 3 954 143 .1 .-.5 '.•statistics for A'S 1'9.3.75'9 AVERAGE = 339 y. R. S. D. = 1.'902 Scanriirip Around SE 133. OSCj P'eak Replication P'eak Pos. Off Peak. uff Peak Element Position Number Intensity Pnt. 1 Intens Pnt. 2 Int en:; SE -O.OOll 1 383 SE -0.0012 2 343 SE -O. (.>010 3 373 . 'Statistics for SE 1'36. 0'30 A'v'ERAGE = '370 vi R. S. D. = 1. ':''3-^' Scanri: r:(.i Arourid IN £13.856 Peak Replicatic^n keak P'os. '0* f f'eak 'J ft P't-ai-: £ 1 ement P'.i-s it i on Number I rit ens ity P'nt. 1 Intens P'rit. - £ I nt c?' ZN -O. 0026 1 22451 i 78 ZN -0.002^^;^- 2 22331 175 ZN -O. C)0^^^' • 3 224£3 177 Stat isf^S^SiFor ZN 213.856 AVERAG^^- = 22424- % R. S.''Div.= 0. 134 ScanriiriD Around PB 220.353 ' P'eak Replication P'eak Pos. Off Peak Off Peak Element Position Number Intensity Pnt, 1 Intens P'nt. 2 Intei P'B -0.0022 1 1140 cn PB -0.0021 2 1131 tn PB -0.0019 3 1126 > Statistics for P'B 220.353 o AVERfiGE = 1132 o y. R. S. D. = 0.617 to Scanning Around CD 226.502 P'eak Replication P'eak P'os. Off Peak Off Peak o El ernent Position Number Intensity Pnt. 1 Intens Pnt. 2 Inteni CJ Ul CD O.00£3 1 25733 454 I CD O.0024 2 25302 457 ^ CD O.0026 3 25383 444 Statistics for CD ££6.502 Peak Repl 1 cat j Ll, P-tak Pos. OT t 1 -• tl tjiv r'. Off Peak Elemev-, t Posit ion Number Intensity Pnt. 1 intens P'nt. 2 Int en NI -0.0016 1 10112 520 NI -O.0016 wL 9970 525 Nl -0.0017 . 3 . 10091 51 1 i-tat list ics for NI £31. E-'O'-i AVERAGE = 10057 •/ R. S. D. = 0. 76£ m cn > o o to too I CJ I cr> ' V_ 01-16-1988 e 12:41:04 — 8 Scanrii ng Around BE 234.861 Peak Replication P'eak P'OS. Off Peak Off Peak £ 1 emerit P'os i t i ori Number Intensity P'nt. 1 i rit ens Pnt. 2 Intens BE 0. OOll 1 274956 BE 0. 001 1 •1' £75897 BE 0.0011 £76346 Stat istics for BE £34. yt-i AVERAGE £7t..3c'7 % R. S. D- = (.1. .r-t--;.4 Scs^YiYi 1 r 9 Around MN 257.61O Peak Replication Peak Pos. Off P'eak Off Peak E 1 erriprit P'T'Si t ion Number 1 ritensi ty F'r.t. i ir.t ens r-'Yit. 2 Intent !nN -0. '::i'Ji6 1 90575 r^li-J -'."'. 0017 2 9071 1 MN- -0. ('!':ii7 31 18£ Stat i':;t ics for MN 257. b i'J AVERAGE 30£C3 % R. S. D. = 0.33i Scannir 9 Around FE 259.940 Peak Repl icat lori Peak Pos. Off P'eai: Off Peak E 1 ernent Pos i t i on Number Intensity P'nt. 1 J rit ens Pnt. 2 Intens FE -0.0038 1 7107 FE -0.0036 2 7148 FE -0. 0'J35 7143 -5tat i'.:;t i cs for FE £5'3. 3'vO AVERAGE 7 i 35 •A R. S. D. = 0. 333 Scann3 r 9 Piround CR £67.716 Peak Replication l'i.-ak Pos. Off Pi-ai Off Peak Element P'l'S 111 '^'.n.j,.., Nufrtber J ntens ity P'nt. 1 i nx e-ns P'rit. 2 Interis CR 14671 501.) CR i4fa60 4 35 CR 1 46^4 493 Stat ist'fcs>:for CR 267. /16 AVERAGE = 14656 1 •A R. S. D. 0. 092 Scanning Around MG 279. 079 r Peak Replication P'eak P'os. Off Peak Off Peak '• Element P'OS i t i on Number Intensity Pnt. 1 Intens Pnt. 2 Irit&ri cn MG 1 2871 -0.oooe > MG -0.0007 o 2860 MG -0.0008 3 2879 o Stat ist ics for MG 279.079 o to A'v'ERAGE 2870 % R. S. D. = 0.339 to Scannir g ftround fiL 308.215 o Peak Replicat ion P'eak P'os. Off Peak Off Peak CJ Element Posit ion Number Int ens ity Pnt. 1 Int ens P'nt. 2 Inteni. AL 0.0011 1 3378 428 ^ AL 0.0010 2 3362 431 s. D. = Scan,'l l r ig Arourid CA 317.933 Peak Repl icat i cri Peak P'os. Off Peak Off Peak Elemer it P'os it ion Number intensity Pnt. 1 Intens Pnt. 2 Intens CA -0.0007 1 6119 CH -0.0008 I.*' 6079 CA -0.0006 6060 Stat ist ics for Cfi 317.333 AVERfiGE 6066 •A R. D. = O. 500 •C'^^-.S-- •^zmtW-c. • 01-16-1388 e 12:46:59 — 9 Scanning firciund CU 324.754 Peak Repl icat i ori P'eak P'OS. Off Peak Off Peak E1 ement P'OSi t i on Number Intensi ty Pnt. I Intens P'nt- £ Int en CU -O.0034 1 17729 360 CU -O.0032 17672 353 CU —O. Ci';"i3'C> 17716 365 t at i st1cs for CU 3c:--t. 75^ AVERAGE = 177 06 y. R- S. D = CK 1 70 ocanning Around BA 455.403 P'eak Repl icat 1 c-ri P'eak P'C'S. Off •'eak Off P eak Element Posit ion Nurnber i rit ens i t V Pnt. 1nt ens Pnt, 2 I ntens BA -O.0047 1 ^+3784 BA -O.0047 rt3e48 BA -O.0047 4 33l£ Stat ist ics for BA '-t;C AVERAGE 64 S •A R. S. D. = l'-t6 Scarining Around Nfi 588 995 Peak Repl1 cat i on P'eaP; Pc'S. Off i 'eak Off P eak El ernent Posit ion rvJumber I nteriS ity Pnt. 1 Int eriS •nt. 2 I rit erii NA -O.OOO8 NA —C.>. 0008 NPl - >J. 0010 *-'*c..» t atist ics for NA AVERAGE H't33 y. R. 3. D STANDARD «5 Element Wavelength Ave Int K. '3. D. Kef Blank Int Off Pe ak Int Net I nt BA 455. 4034v^., H3848 O. irtt Cl 43BM8 BE --• ---^'•- £34. a&m^:,.,. £75927 '-'. 364 •;; £7'.;. 3 c:'7 CD c.'£.'6. 50^^p^-;..-; • 25473 O. 633 '^52 2502 1 CR £67.7l5^ii^- 14658 '-.'. 03£ H33 1 4 11.2 CU 324.7S4&-'. 17706 0. 170 361 17345 MN 257.610 90823 0.'351 0 90625 NI 231.604 10057 0. 762 513 95 38 ZN 213.856 22424 O. 134 177 AL 306.215 428 29 .i.i»'76 366 , -cn FE 259.940 7135 71 PI ca 317.933 6066 5CIU 0 60 .: > MG 279.079 0 28 '-. ; 2870 333 o NA 588.995 4465 530 0 44 - o SE 196.090 970 954 0 9 - to AS 193.759 939 902 143 7 PB 220.353 O. 617 0 1,1 to 1 132 O Enter STANDARD NUMBER (1 - 7) or -1 to EXIT: CJ standard «6 solution aspirating - CONTINUE ? Scanning Around SE 206.833 --^?JfS SB No Peak! 3 , SB No Peak! 3 O Statistics for SB £06.83:: AVERfiGE = 0 01-18-1988 C« 12:51:56 — 10 •/ R. S. D. = O. OOO STANDARD MS Eiement Wavelength Ave Int y. R.S.D. Ref Blank Int Off Peak Int Net Int •i>B 206. 833 O O.OOO (.1 Entcn- STANDARD NUNBCR (1 7) or -1 to EXIT: Standard #/ solution aspirating - CONTINUE ? Y caririinq Around 'SB £06. 833 P'eak f" STANDARD #1 . t' m e r 11 U a v e i e r i q t n Ave int y. F..3.D. Ke-r b.larik Ir.t Orf PeaK in i'i(.;t F:G 328. 038 38*.> N/A BP-i 455. 403 191 N/A J 3: BE 234.861 N/A CD 226.502 384 N/A CR 267,716 463 N/A 44fc- CU 324.754^5,,,;^. 331 N/A 314 Mr-4 257. 61 <;»&&?> 365 N/A '.'_) M 1 i31.60^^" •*^--'"-^* - 423 N/A 458 2N 213. 8Ei^S;^ 138 N/A l£7 3l^ c'Ot.. 8.i;imv.;« 280 N/A 0 AL 308.215 466 N/f4 374 FE 259.940 167 N/fi O CA 317.933 420 N/A O MG 273.079 323 N/ft O NA 588.995 519 N/A 0 SE 136.030 136 N/A C) AS 193.759 134 N/A 134 PB 220.353 156 N/A O Statistics For Fitted Curve 01-18-1988 I? 12:56:03 — 2 Results For AG 328.06;::! Low Intensity Hip-i Jriterisity Intercept 'iiope Cut'vat ure LUr ve i ' J.-&0 1846£ -O. £1007 0. O-liOSS 'j. 00000 Staridard Intensitv Coficen. Calc. Con. Cori. Error % Error Order 1 3SO (.1. <-•(.)<.» o. ouu O. 000 £ 40';:)0 3. 'JOO £'. 'JOl O. OOl U. 05 3 18462 1 O. O'JO 3. 355 ':>. <:i05 -O. 05 ^1 Not in Staridard b N'Ot in Staridara 6 N'Ot 1 ri 'Staridarcj "•• . Not iri 'Standai'c The RMS Error is O. 05O-^ Results For BA 45' Low 1 rit mvi:^ 1t yi --i;cji"i i riv err.-.-i L V i nt 6 ." Cfc-1j t •:irje L u r V 51 M r Cuf-ve 1 I'l'l 43843 -0. 0'-f3/6 0. '.")0':i£3 -.J. i;)00 'Standard Intensity Concen. Calc. Cori. COYI. Error % Error Order i .ft^:lSf ^ 0. iDOO 0. OCiO O. i-^O'-J c Not in btaiacjva.»?d; •• J) Not in Sta^a^- •4 a§MM-" • C m OiJO £- (:n:)0 •.'. UU>.I -'J. VI c- 43848 10. 'JO 1 • 10.00£ o. <:>';> 1 Ol. O 1 6 Not in Standard 7 Not in Standard ~^ The RMS Error is O. 014vi cn PI ; > ! O Results For BE 234.661 o to Low Iritensity High Intensity Intercept Slope Curvature too Curve 1 ci3ci '275927 -O.01008 O.00004 O. OOOOO Standard Intensity Conc^l*!. Calc. Con. Con. Error A' Error Orde. statistics For Fitted Curve 01-18-1988 & 12:58:19 — 3 <.). UOO O. OOO 0. 0C)0 c' Not in standard -r Not in Staridard A 52341 £. 326 2. 264 0. '064 -2. 76 w' 275927 1i.641 11.378 0. 337 2. 90 6 Not 1 ri Standard 7 Not in Standard The RMS Error is 2.826% Results For CD 226.502 Low Intensity i-;iqn Intensity Intercept Curvat ure Cuvve 1 —6 25021 o. 00246 0.00041 ' o. 0'J•:>•:"::; Standard Intensity Concen. Calc. Con. C-c>n. Err^or "/ Error Ordt r 1 -6 0. 000 0. CK:>O .1. uuu 1 £ Not in Standard 3 Not in Staridard 't 4755 JLXJ 1.351 .'. Vt :f 5 £50£1 .''I'O 10.257 3 Not in Staridard 7 Not in Standard ne RME Error i s...-gi» 2. 505/4 MiM'3 '^s^^'n: Results For CR £67. 716 Low Intensity High Intensity Intercept Sl>ope Curvature •^ Curve 1 17 14162 -0.01237 0.00073 0.OOOOO cn PI Standard Intensity Concert. Calc. Con. Con. Error A' Error Order > 1 17 0.000 0.000 0.000 1 o 2 Not in Standard to 3 Not in Standard 4 2689 2. 000 -2.79 to 1.944 -O. 056 o 5 14162 10.000 10.292 O. 292 2.92 6 Not in Staridard to 7 Not in Standard statistics For Fitted Curve 01-18-1988 e 12:58:34 — 4 I'he RMS Error is 2. S57y. Results For CU 3£4.754 Low Intensity Piigh Intensity Intercept 'Slope Curvature Cur-ve 1 17 17345 —O.iJltiOt. 0.00059 O. (JO Standard Intensitv C'l'ncen. Calc. Con. Cc^n. Error 'A Error Order .L 17 0. OCi'J 0. 000 lO. 000 1 3 Not i n Standard 3 Not in Standard 4 3317 £. cjiC.)Ci 1. 35£ -0.048 -2. 40 1 CT 17345 10.00£ 10.251 0. 250 2. 50 1 6 Not in Standard 7 Not in Standard RMS E r-ror - is 2.44954 Results Kor MN 337. Low Intensity 1-Uqh intensity I nt ercirpt c^ i '.'De Curvat ure C'.u-ve 1 it,; •:J'J823 ~0.0414H O. OOO 11 iJ.'I'OO'.'O 'c^t a nd ar d I nt ejrrSfiSt'.y. C'l'ncen. Calc. Cori. Cori. Error 'A Error Oroe- -i'365»-, '-.'. '.H.l'-.l O. OCi^ C). OO'. Not in Standard Not in Standard 17502 2. OOO 1. 946 -O. 054 -2. 68 90823 10. 000 10.274 O. 274 2. 74 6 Not in Standard 7 Not in Standard The RMS Error is 2.710% Results For NI 231.604 Low Intensity High Intensity Intercept Slope Curvature Curve 1 -35 9538 C>. 03722 0.00106 0.0C>000 statistics For Fitted Curve 01-16-1988 e 12:58:49 — Standard Intensity Concen. Calc. Con. Con. Error % Error Order 1 -35 O. 000 O. 000 O.000 1 2 Not in Standard 3 Not iri •Standard 4 1817 cl. OOl 1. 969 •0. OE-E -1. 61 1 5 3538 10.007 10.173 O. 172 1. 72 6 Not in Staridard 7 Not iri 'Standard The RMS Error is 1.664% l^esults For- IN' E13. 33C L'I'W Iritensity Higfi Intensity intercept Slope Curvature Curve 1 11 22247 -O.0050G 0. J0046 (.1. OV- )'X. Standard Intensity Concen. Calc. Con. Cori. Error y: Err Urder 1 11 Cl. 'i'cio o. OOO 0. Ci'-.'":- 3 N o t iri Et::-. r i d a r d 3 Not in Standard 4 4263 2. 001 1. 357 —ll. 044 -£. 30 1 5 £££47 10. <:>(.'>6 10.236 0. £29 2. 29 1 6 Not in Standard 7 Not in Standard The RMS. Error i s^Sr'.S'. £45% m& Results For SB 206.833 L •r-w Iritensity H igh Intensity Interce pt Slope Curvature cn Curve 1 280 215.3 84b 2 -0.76923 0.OOOOO p] 0 > Stand ard Intensity Concen. Calc. Con. Con. Error % Error Orde o 1 1 280 0.000 0.000 O.000 1 to I O Not in Standard to «^ Not in Standard o 4 Not in Standard it" 5 Not in Standard 6 O 2.000 215.385 213.365 10669.23 1 . ^r.-.-.'r^^'r^'^^r^J statistics For Fitted Curve 01-18-1988 & 12:59:04 7 267 IO.000 IO. OOO O. OOO O. OO The RMS Error is 7544.285% Results For AL 308.215 Low Intensity High Intensity Intercept SlT'pe Curvat ure Curve 1 112 2943 -0. 41704 0.00377 0. c>c>ooo St arid ard irit erisity Concen. Ca ic. Con. Cc ri. Error % Error Ord 1 1 13 0. C'OO 0. 005 0. 005 1 . £ Not iri ot ariwa'r" d 3 Not in 'Staridard 4 538 2. 000 1.835 -0. 165 -8.24 1 5 2948 10.000 10. 686 0. 686 6. 86 1 £ Not in St andard 7' Not in St andard The RMS Erv-or is '.81% Resul'ts For FE 259.940 Low Iritensity High Intensity Intercept 'Sl'i'pe Curvature Curve 1 7135 -0.24562 0,00147 0.'IiOOCiO • *i5Si¥!-:-':i: St andard Irit ens#i^.X C'l-ncen. Calc. Con. Con. Eirror % Error Order- 1 167 O. 000 O. 001 O. 001 2 Not in Standard 3 \ 3 Not in Standard 4 1460 2. 000 1.937 -O. 063 -3. 15 1 CO ! P] : 5 7135 10-000 10.276 0. 276 2. 76 1 > 6 Not in Standard 7 Not in Standard o. 1 O ' to ; The RMS Error is 2.965% oto : cji : Results For Cft 317.933 i V_ y Low Intensity High Intensity Intercept Slope Curvature statistics For Fitted Curve 01-18-1988 C- 12:59:19 — 7 Curve 1 420 6086 —J. 74112 0.00176 O. OOOC)0 Standard Inten'sity Concen. Calc. Con. C'i'n. Error •.'. Error- Order 1 •i3Ci) 0.000 '.'. •.>0Ci O. OOO 1 i£ Nc't- iri 'ct-arici ard 3 Not in StsvVidard 4 1554 2.000 L:'. 0';:ii 0.001 0.0'^ 1 5 6'ja6 10.000 3.33/ -O. C)03 -0. 03 1 6 Not in Standard 7 Not in Stanriai'c The RMS E.rY-c Results For MG 279.079 L'i'W Iritensity High Intensity Intercept Slope Curvature Curve 1 .i£3 2870 1.2691! O. OO.i9.i O. O'OO00 '3t f;ridar'd 1 riteris11 v .oriceri. c . J c . .•ri. Error '• -r Of-der 1.1. <.>*.>'J '..'. 'J!.>1 cj. 001 . 1 2 Not in 'St .Tindarc 3 Not in Staridard 4 B30 £.'. OOO i . 334 -O. <.i<.)6 -'.I. ^i.> *-* '— ^.t'^' I'j. (JO'.'i I'll. 014 O. (j 1 4 0. 1 -4 6 rJ'Ot in Standard 7 Not in Standard Tne RMS Error i s-." .-O. .i j.5% Results For NA 588.995 L'Ow Intensity High Intensity Intercept Slope Curv-^-t i.ire Curve 1 519 4465 -1-32376 0.00256 '.i. iliOOOC) Standard Intensity Concen. Calc. Con. Con. Error % Error Order 1 519 0. 000 0. 007 O. 007 1 2 Not in Standard 3 Not in Standard 4 1275 £. OOO 1.946 -O.054 -2.70 1 statistics For kitted Curve 01-18-1988 I? 12:53:35 — 8 5 4465 IO.000 10.127 O. 127 1 . £7 6 N'Z't in 'Staridard 7 Not- iri Staridard The RMS Err 3.109% Results Foi- '£-E,:36.090 Low Intensity High Intensity Intercept Slope Curvature Curve 1 970 -1.63995 0. 01 £.' 14 •-.'•. '-.;(.)(.) 1..1U St andard Concen. Cajc. Con. Con. Error ill ror Drdev u. ouo O. 011 o. i:)i 1 2 Not in St ancard 3 Not in St andar-d 4 £95 2. 001 1. 340 -0.061 Jl. 05 5 970 10.006 IO.132 O. 126 l. 33 6 Not jri Stand£ird 7 Not in 'St aricJarc he KMB Er 334% Results For AS 133.759 -m^'^^ Cow 1 nteX'Siii'ty High Intensitv InterceDt Slope I.. ..l ; • - C, 'C I.i , li imr^3- C u r V e 1 ••-^:0& 796 O.09642 O. 01 £•'+4 I.I. i.)'.:><.H.)(;i Staridard Intensity Concen. Calc. Cori. Con. Error % Error- Order V O. OOO (.). C136 O. 096 w Not in Standard 3 Not in Standard 4 153 2. OOO 2. CiOO O. 000 '..1. *.iu 5 796 10.000 10. 000 0. 000 0, cjC) 6 Not iri Standard 7 Not in Standard The RMS Error is 1.27E-11% Results For F'B 220. 353 Statistics For Fitted Curve 01-18-1988 C-> 12:53:49 — 9 Low Iritensity High Intensity Intercept Slope Cur-.-at ur-e Curve 1 156 1132 -1.603C)6 0. 0103':> '1. 'JVOOO S t a r 1 d ard Iri t c- r i •:; 11 y Coricen. Ca.lc. C-^^ri. Con. Error v. Cv • r Order 1 C53 C). CiC.)C.) ij, C)Q2 O. 003 £ TvJot 1 ri 'zZ'X ari'ij^ird 3 Not in Stario-i>rd 4 34 6 2. 002 1. 361 -0.021 -1. 07 1 5 i 132 10.OlO 10. LIS4 0. 044 0. '1'^ ,1 6 Ncit iri &T arid ard 7 N o t 1 ri 31 .-.^ 1 •. vi .n r d The RMS Error is 0.616% .S^teC "'^P0sr cn PI > o to oto it. CD Line ^ Best Fit ^or HC mM 221(4- Cone 8.M 2.58 5.M 7.58 18.88 Press the (Howe) key for POP-UP m\i, FIHEL? mm MM .'^Ar-^c-v..-- • cn PI o to too CD Line Of Best Fit for 611 «S. 52611 Cone 8.88 2.58 7.58 18.88 Press the (Hone) ke«! for up Menu. msmm mmmFINEL Y mm mil •-J© •% .^-;i?''^j;i; Line Of Best Fit for BE 234.B(1 321798 Cone 8.88 2.91 .73 11.64 Presmms mthe (Hone) ken for POP-UP nenu FINELY mmmii ••^i Line Of Best Fit for CS 224.582 29273 Cone 8.88 2.58 Press the {Hone) ken forjoru? nenu. mm FiNEU! mmm ''^m'] cn , o o to oto Ol to Line Of Best Fit for CS 267.7U U512 8.88 2.58 7.58 Press the (How) ke«i for POP-UP nenu. nmi mmun mmmmimmmmh Line Of Best Fit for Oi 324.754 28387 Press the {Hone) key for POP-UP nenu. FINELY mmmii WM>r cn PI > o to o CJI Line Of Best Fit for kH 257.618 186895 n 26524- Cone 8,88 2.58 7.58 Press the (Hone) keu for up Renu. nma mmmk Line Of Best Fit for Nl 231. 11252 n 2813 Cone 8.88 2.58 7.51 16.81 Press the (How) key for up Menu. FiNELi! mmmfi iifiiiiaiii immummhmmmmm cn PI > o to to o Ul cr> Line Of Best Fit for ZN liim Cone 8J 2.58 nv7.5m8 mmm18.8^ 1 Press the (Hone) key for pop-up wnu. mMm ~N cn > o o to o CJI Line Of Best Fit for UL 388.215 3319 S) Cone 8.88 2.58 7.58 18.88 mmmPress the (Honei ) key for mm, FINELY mm mil =p#*t.' Line Of Best fit for FE 259. 833? Cone 8.88 2.58 7.58 18.88 Press the (Howe) kej for nm mm mil mmmi up Menu. mmmmmmm\mh fi^fe/'f*!- wm cn PI > o o to to I cn CD ! Line Of Best Fit for CU 317.933 7385 Cone 8.88 2.58 7.58 18.88 Press the (How) ke«i for up Menu. FIHEV mCHIFyMIH ..1^:<-" Line Of Best fit for KC 279.879 3448 Cone 8.^ 2.58 7.58 18.88 Press the (HoRe) key for pop-up nenu. nm mm mil ••.i%:'-i.- .- ;SiiK$H: cn PI > o to to I Scn ' j/vH liZM LABS, INC. {^^^ l^TlA- ///^/U CUP LAB. NQ- OIL.FAnPR NCTES \ Z fir. RQC * ... 3 (2[(a^to^ gcMlC .f LCS xc\/ ^ ^65A3c^ /Vlui4(S gw rri r^ G. ^y.' 7 :^jf^3.0 ATT, Tn., t^< /i/^n 8 ^ A^^ 1 • - ^ 4^.^^)P 10 V^i^^ U 4-^^^)^ \ / ^^ ^.3^i-^^ vnbyih \^ ^}r;f vnv^Af^ \H A2^ muv^c 6:??p /YlU)^ r6 4dZ Fi^a^p • n 4/ 4i](, Tf2iP IS G(lf.(V H Ci^ r^uc 2/3 c<:v/ 21 ^^^^Ci A'l^vv 21 c^f^b 23 V:» ^i ^s^Hf 't. 2? dpS^JP- > 26 4 -S^^^P 4^ 27 ?^\^^7 nuA^l 28 ) ^t/i^ r ^ • 21 ^^? AitAi.'^r3 \ a •• 30 vJ-^f \' •. 3((,%o?. fi/^^o te6 TGif. • \'- • .CaJ U\^ \ a: hSi^ \ " : li2Ai LABS, INC. {^^^ \Z ^ lA- 07/U CUP LAB. NO- RmiTiT 0iL.FArir>p NCTES I CAc RLlr 1)i(n fiO^ p4^s\$to: gcM^ tcs xc\/ ^6543^ /iMAd ^. r,r^ T/V. GA ALI C^cT^^SO 8 4- ^]N2 h %y\'^^)^ to jju^A^f u +-' 4^)(^ \K 12 ^.3^-^^ nnyi/V \3 4,^(^-muaA^ w jO P^^KC ir 41?iP/V1U}^ (6 MZ Fit^p n 4^ 446 IJLH IS CA^i:^(K H . f)<^ (^M6 20 c<:\/ 21 ^63.-y?0 ft'i^\Yl 22 23 -h ZH Sm 2J c^^F 26 ^ ilir^P vk 27 li^^d mtA).^^ cn 28 si^ pi. 21 ^I Ai^^y? o 30 S^9-f^ o to Ji2^ SiiO to o 6gfe Teif cn CJ 1#Q cn PI o O % v\tfefZ4ir<^ - uviiiAN _ ._X^i^'^'^ ^^ jcer^c ^]6^I;D(-J to 52. _^-P_£_J?i€«^ ?egc:s:,^>T>l f^ fcec - l-ao/ft 1^0 ^3n>L^ 50V^ <^S0 1 fi2M LABS, INC. S7S WtOAOHOUOW ROAO. MELVH.LE. NY. 11747 • Sie-«B4.3O40 HOLZMACHER McLENDON mn Lab I Sk^MX) I.D. t (viu^SC >o< Duplicate Serial Initial Dup. CoDtrol StaJced Aaomt Dilution Element Result Result RPD l.'imtt Result Spitei Reocwery Result Difterenoe Notes I/O _<[0 (^ ^^o a^o O 32) I to O I (v\n (fefio i^)/ l?0(9 1^0 !i3o ^ I N 1^0 ?0 fcic *f 4^0 400 i IC)? cn ,Soo 3ob 0 5oo 3^0 loo p] zY \ W > o '^01, o f-e. 4fc,ooo A^coo ^y, 4^00? (OOO [OO to ± to I O i cn , CJI ;. V 7 li2M LABS, INC* S7SMOAOHOUOW ROAO. MCLVIUE. NY. 11747 • 9ie-aM.3040 HOLZMACHER. McLENDON and MURRELL P.C • CUVIHOWIIEWTAL wid IWOUSTWIAt AtJAtmCAL SERVICEi Labi T(g^S?^ I.D. f_jVLiA\3C ^ O^ td f I Duplicate Senal Initial Dup. CcQtnl spiked taOBt Dilution Ell ement Result Result RPO Liut Result SpiJMd Recxwery Result Difference Notes % '^b -h C^i ^L^b I loo I 'go i a... i_Cy. 46 SO C)\C 3^jia + Qo D m^(^ ISO i 10^ Ma -f • N; so SO 0 30 ^y 2.60 ^ n 3o 0 ^^2(|o idC ^ 30t lioo [OOO ^^ i f£ -^ ISO 140 flr.alyze Sariipies 01-18-19S8 Q' 15:01:36 No ft/S File 'Selected 1:HIGH 3: INTER Z;:NSEAi214 'i : 33 STANDHKD •AEND : ;-'G UT'' to View Mor-e Lirits I'n 10 or 'ESCape' to 3\ r.p ViewINTER INTERELEi^ENT INTERFERENCE STflNDfiRD Begin ftnaivE.IE - Sarnplt? Nurfiber 1 Eiii. Wave- Meari Peak I'leafi P'c;ak Net Peak Sv"i. Jt-riDth Po&itiori 1 r;t e'i'r.i.. 11 v 1 nt fcl:t 1 t V ZN £13.-:>;:i;u. Off Peak Ir.t- 1 C3 O. 0<1'0£.' '^ .:.'ri'-4 CD 333.303 Off Peal^ Int. -'•'. O'OOS w-'.. " -.' J Nl 331 . G.'.i^^ Off ~'t:-rik Int.. —'.'. (JOC>4 l7'::'i BE 3.:.^. 33 1 -O. OOOfc S'+'iii MN i"5;'.t. 1 —j. 0007 * V.. - .- V 1807 V- FE 333. 3'i -0. OOOG l63'S*.i3 CR ^::.7.7it. Off ;:'s=-ci>'iKint-, =• j0^. ~0. OOO / Mb E73.0 7'3^,^^^ -0.0003 T A '".^ -' ' 3B331 ML 303. ^l^t'' Off Peak Int. = t'w -0.0003 17355 17£&B Cfl 317.333 -0.OO07 1701GS 17':ilE.3 CU 32A.754 Off Peak Int J^EO -O. 0015 3747 3Ai'", Calculating Concent rat ic Elern. Wave- - Net P'eak Calculated Interference Net /> 0 ^ Sym. length Intensity Co'nce-nt rat ioci Correction Concentration BE £34.861 54022 0.015 2. 322 I OO CD £26.50£ 5001 2. 052 2. 052 f ^ CR £67.716 2762 2.012 2.012 joO Analyze Samples 01-18-1938 C« 13:06:55-— £ '/. O ^ rwp^atn CU 324.754 34£7 .:;. 017 O. 024 1. 333 I OO MN £57.61 1S077 2. Ol£ £.03 £ ^-Sj NI £31. E3.)--i 1793 1. 344 O. 074 1.87 0 100 ZN £13. 35i-- 4 334 £. 01S O. 050 1. 3ta \oo flL 308. £1L. 17286 64.63c FE £53.34 165309 £44. t ) !•-•> £4 4.418 \oQ CA 317.333 170168 £93.5:H £33.51M MG £73.073 38921 151. 7^'"r 151.743 —' tnter N LI ml •<:.'• Repi icat i orrs/Measurement INlERhLtMENT INTERFERENCE STANDARD fcietiiri i-lr-iti .1 ,'E-i E - Sampjir Ni.uiiber 3 Uave- f'lc-ari Pc?ak Mear. i-'Cik V. RSD Net H'oak iVm. length Position Intevriity I nteris i r v :N £13.856 Off Peak Int. = 14£ 144 143 i'4 1 138 Peak 1 ntMrifei'.t y = 4563 '4558 4540 455£ 4t.'r<7 O. OOOE- •-tbu-.-.' O, 468 H4£0 UD c:£6. 502'''^'r Off Peak Int. 4 57 H£5 451 441 445 P'eak Intensity = 5543 S507 5540 5470 5448 cn PI -0.0007 5502 O. 765 5058 > NI £31.604 Off Peak Int. 496 501 515 507 506 o to Peak Intensity = £280 ££66 £305 ££84 £3£0 ' to O -O. 0012 ££31 O. 934 1786 cn BE £34.861 00 Peak Intensity = 54340 54566 54187 54144 54417 ! -0.O0O9 54295 O. 225 4295 MN P=;-7 Cl --0. O'JIO ; ct^Z. 1 •::> FE £53.94 A ri B 1 y -.• e S a m pie s. 01-1 8-1 38ii I,' • . J. ^- . W<0 Pei»i< inte-iCiity - 166020 166.1.64 166£60 1 ("..G^^M 1 16710.': --'.j.'..lOl 1 lt.6H'33 Cl. £46 166^'j3 £6"/. 716 Off Peak Int. = 478 471 462 471 487 !-"' e i-i K Iritensity = 3 3 -i •- 3 £ 8 3 3 £ 5 4 3 3 3 5 3Eti-3i -'II. 'JO 3 i :-£t:.7 O. 535 £783 MG £7'9. 073 P'eak i nt ens i t v = 3881 a 38434 38876 367£5 38744 -O.OOIO 38730 0.374 38730 AL 308.£15 Off Peak Int = 66£ 673 668 668 663 Peak Int: ensity = 18081 18044 .180:3 18030 : 7303 -n. 00i07 .80 lb O. 356 i 7 34y i'eak 1 ri"i eriti t y - i'7i'.i8-M l6'3£6£ l7'-Jil£ 171515 1734 43 -O.'JOll , 170884 0.734 170884 LU 3£'*. 754 Off Pea:fe^5^. 330 3£8 3£3 3£; j:.. / Peak Inmnsity = 37-''*7 37.35 3"'4 3 373': •''-" ' -'j. 0015 3/437 (j. £68 341£ Calcuiat i nq Conceritrat i ons fo f Sample N'.imbe'r £ cn Eleni. Wave- Net Peak Calc ulated I rit erf erence Net PI > Syrn. length Intensity Concent rat ion Correct ion Conceritrat lo •' \rCxSMSO o BE £34.661 54295 2. 349 0. 015 £. 334 o CD ££6.50£ 505S £. 075 2. 075 to CR £67.716 £783 £. 017 2.017 to CU 3£4.754 34 1£ £. CMlig 0. 025 1. 984 o cr> MN £57.61 18£i9 £. 0£8 2. 028 m NI £31.604 1786 1.936 O. 074 1.862 ZN £13.856 44£0 2. 030 0. 050 1. 980 AL 308.215 17348 64.922 64.922 FE Pf'.q. QA 1 tCAE-.Q o/. =: OOO '-•- -.-." IN-(th en m > o to to o o Analyze Samples 01-18-1988 I? 13:24:31 — 4 1:HIGH :: INTER 3:NSEA1£14 4: SB STANDARD .r_;'-i.V.i: ' P'G UP" to View nrn- Lir.es Fn 1 (J Or- 'fc';.>Lape' to Stop ViewNSEAl MET. •.^•- i-.'i-iHiber o-r Rep 1 icat i ori-=/i':v;,,._ i.^r-en-ie'rit 1 H.i'il e;'- Result File Name i IJIS.-; i inuni 8 cf^iaracters ) NSEAl£14 i-::riter 'Bampie Number 1 CAl. .1 }.•( RAT I ON BLANK begiri Analysis — Sample t'iuiiiber 1 tie. Wave— f)eBrt P'eaK Mean P'eak Net Peak '3ym. length Posit i'l'n intensity I ritensi ty ZN £13.856 Off Peak Int. = i31 No i-"*^ai: : .45 IH CD ££6.50£ Off Peak Int. = 335 No Pea; 33£ NI £31.604 Off Peak-i,*I:nt. = 478 S^^hio Peak" 452 -£6 BE £34.8(^1^^^4.0 Peak' £38 £38 MN £57. 6ll^&i&c. P'eak.' 382 38£ FE £59.94*^F':No Peak! 1.81 181 CR £67.716 Off Peak Int. = 460 No P'eak: 463 CU 324.754 cn Off Peak Int. = 321 PI No Peak: 31 AG 328.068 No P'eak! 384 364 Calculating Concentrations for Sarnple Number 1 10 O Elem. Wave— Net Peak Calculated Interference Net <1 Sym. length Intensity Cc OG 328.068 384 O. O02 O. OOO 0.010 BE 234.861 236 O. OOO O. OOC) n r\r>'=^. Analyze Sampler 13-18-1388 IJ- 13:30:37 — CR £G7 ,' 1 l;.. Cj . <.> 1 '.I C:LI .•-•iZ'i VI. :'.•''/. t>-,r; .-jS 7 3\ ' 1. ' I,- • ; il.: l:'i--.'.^ Ill' .H >-INh. :.' I- 11 1 i-: • 1 r. S i .-ll- ••ii-- t-r.L- :. •*. CD ££'T.. ^:.0£ Off Pc-oP ii-.i. l'(- ..i 1- :. I." - • •' • .* ** -; - I-- ;. h .-.••. .-•. z i-:..- •--* •' • CU. .?..•.•*. 7-5'4f-;. .-: ;wi 1.:,^^ ,rit. ^^^^s;^';. • r,-i... 1 •,- .. I Ml.- ,;.. :--.. rfiSV- - f-j.-. I'l-.-^y La .1 c i.i 1 at 1 t'li r,-. orit 1 .^t 1 .:'ri', tor baiiic.JK- NumPe. E 1^.-1.1. ^J.•^•.•l. I-.'. •. i-'«..-..•.'.- •. •> 1 c '.11 ."•'. trd J rit e-f 1 t:-i f?ric<-^ I'-iet cn Sym. ieriijtf'i J ii\ •;-r.' ity i.'.'I ict-i'it I r't. 1 •'.•fl Cc-r r t-c t J'L.^ri i. CTII c-rit r at I'l.ri PI > AG 328.068 362 0. '.i>.'l u. (."li 1 O. Dl'.l BE £34.861 ££3 O. O'j'.i 0. ' I'.i'.i < ll). ^.«.l^. 8 1 C:D £26. 50£ 1 1 0.''.i07 0. CH.17 CR £67.716 8 -0.007 ( Cl. Ol'j CU 3£4.754 £7 0. CK;>6 0. o«><;i < 0. 025 to 1 MN £57.61 381 0.002 ( C'. 0£«:> NI £31.604 11 0. 049 0. 000 0. 049 ZN £13. 856 15 0. 002 0. 000 < 0. 02C1 \ FE 259.94 172 0. 008 < 0. 020 Analyze Samples 01-18-1988 C" 13:34:20 — 6 METHOD BLANK FILTERED 1^ e p i fl Pi ri a 1 y s 1 s — Sample N i.\ in be r Wavtr- Mean Peak Mean i- Net P Lj .--..- leriLjth P'tl'Sitlori Iritc-rr. 1 nt erir. 11 v :C-i £13.856 Off Peak int. No 3r. ,,*-: ' CD 333.5u£ Oft Peak iv.t. '.i'.i i •••••:. I-: '. 33B NI £31.tM:"4 Off Peai^ int. tuE No t'eakl '-t f. / — J. r" BE £34.861 No Peak! £38 £36 MN £57.61 No Peak! 330 390 FE £53.34 N'O Peak! 1 70 1 70 CR £67.71b Of f i 'e&^^ i I'lt. '= r-N;.. - -r-r,!.'. ' LU 3£4.754 Uff Peak Jr,T. : 1 c. I--I'3 P'e-aK ' J..H3 AG .3£a. 068 No r.'.:i.,H : Cal cul at ii'iQ Conceritrat i oris for 'Sample t-jumber ^• -jsm:^^ •• NefeP.'ee.k'. Laicu ilated •f erencfr Net tl f-r'm. Wave- , ^-.#Sl-:.^: Int er Sym. leriDth Irite.nt^ri-tv C'r'ncer 'tr at I'i'ri C'l. rr ect 1 ori C...-.r icent-rat i -r.^n '^c :• " 1 AG 33a.066 371 -O.005 0. O'0<:> < 0. O 1 C) BE £34.861 £38 0. |-.»0C> 0. 000 ( 0. '-)0S. CD ££6.50£ 3 0, OCjE >'.'. '.'06 CR £67.7i6 -3 -0.013 < 0. 'ji C' CU 3£4.754 33 0. 009 0. CiCn'j •; 0. 033 cn : PI I MN £57.61 330 0. 003 < 0. 03''.i >• \ NI £31.604 -19 0, 017 0. o<;>o < 0. 040 ZN £13.856 9 -0.001 tl>. C)OC) ( 0. 0£0 Oo ' FE £59.94 170 O. 005. < 0. o£(:> to ' ICV too Begin Analysis - Sarnple Number 4 CJ Ele. Wave— Mean Peak. Mean Peak Net Peak Analyze Samples 01-18-1988 (s> 13:39: £8 — 7 Sym. length Position intensity Intensi t y ZN £13.856 ijff P'eak Int. = i4-3 -O.0013 S37£ CD ££6.50£ Off Peak Int. = A3Q -O. 'J0£ / 3'j£8 ::i--00 |--ii L31 . 604 lift Peak int. = 3i3 —'Jl. ':."'.'£.'•^ t-'.3'.-^'i 7fi73 1^.. >r;3':*. 361 ~'!>. '..:'J-.::V , "677 ;-i;-- i.'5<-.6l -O. <.Z>033 £3663 £366 FE £53.34 -0.0':i£l i'^6£6 1 4'c.;.: L ;'-: £67. 7 1 6 •..:ft i'eak 11'lt. =• 488 -O. •::iO£:^ 3570 30S£ CU 3£4.754 Off Peak Int. = 342 -O. 0'..'£7 6333 yc.t:-1 MG 3£8.OGa -0-0035 3811 381 l' Co 1 r. 1.11 ,-'\-1 riD Loncent rat 1 orii.-. f.:-.- :<-'.inpi6:' NurriDer 4 fLi<--iYi. ^Jc LCS cn p] Begin Analysis - Sample Number 5 > o Ele. Wave- Mean P'eak Mean P'eak Net Peak o Sym. length P'osition Intensity Interisi t V to ZN 213.856 oto Off Peak Int. 152 Sl -O.0011 9049 8897 CD 226.502 Analyze Samples 01-18-1988 C" 13:-»3:18 — 8 Off P'eak Int. 4£H --0. 00£6 £336 £57 £ NI £31.604 Urf P'e-ak 1 nt . = 51 3 -0. 0':li30 t'--ti4 7363 BE £3^^. 86: -o. 003£ £3680 £368':' MN £57.Gl -0. 00 3 £ £3 £83 £3£e3 FE £53,34 —Cj. 00£7 iH'Ji'lG 3 4516 CR £G7 . '.' 1 6 3fi P'OAJ: Int. = b'-.'ir: -•:;>. 00£7 3'.:'L;.G 3.:-'6 LU 3£4.754 Orf Peak Int. -- .;•'+ 3 —0. 'I'O 3.1 8H.--'o tiG 338. 'JfcS -o. 0'J37 3 7'30 Lalculatirig Conceritrat ioris for 'Sample Number- 5 Elem. WJave- rviet Peak Calculated I nt erf erericcr Net / iCe^ 'Sym. length Intensity C'i'nc erit rat i ori Correc t i ori C'-jncent rat i cri rtG 3£8. (J68 3790 i. a.-:- -.. BE £34. 861 £3680 1 •0 2 'H 1. '-:' 1« LL' ££G. 503 £57£ 1 '!>57 I. ':;t- 7 104, CR £67. 716 3064 L £17 II o LU 3£4. '/'34 858L L' 06.' 5. OLi- iO i MN £57. 61 £9283 .i £84 3. £8-4 I/O a NI £31. 60M 7963 5 1 0 '.>. '.I'-.l I 8. 503 ZN £13. 856 889/ '-, ill 30 o. ^:>'-:i5 4. 085 FE £53. 34 J-345'16 £1 161 ;1. 161 7 634 30 MWAB ^:; Begin Analysis - Sarnple Number 6 Ele. Wave- Mean Peak Mean Peak f'iet P'eak Sym. length P'osition Iritensity Intensitv ZN £13.856 Off Peak Int. = 130 -O. OC>12 c:56 126 CD ££6.50£ Off Peak Int. = 4 10 No Peak! 41 1 NI 231.604 Off Peak Int. = 517 No Peak! 485 -3i: BE 234.861 No Peak! 250 250 Analyze Samples 01-18-1988 (? l.;::-48:07 — 9 MN 3'3. '•' - 1:^3 -0.0035 £i=:£"ri cicl.i'i* FE £t.'':-l. '•i 'I -Ij. 00£'3 IG-'HG i 64 3 CR £ G 7. ;- .i Vi. 0 f T !- • :- c\'' irit. 4 6 7 No Peak! MG 1--' 7 '•'• -o. 0':>30 108::' io8':i AL 30i::.. .-_' J '.:• Of-t 1 >-•., V-: irit. = 331 No Peak! 5 1 7 3 L'fc CA 3 3 /' . 33.:: ~0.0037 ..'•'i^':'':' 3 3'30 CU ..I:..-'M . .- *J.' -"-r L'-; -- 'r- • - fl ••: : nt. -O. OOiZE •_'-");:.. AG EEZ^.- . • ''.-. •'.-: No Pti-Jii- ! -:-"-^i La ic'-i 1 at iriD Lcricj-rit rat ions for- Sample (vii.imDe; c-.- Elem. Wave— ;t:-t Peak Calculated 1 iitevf erence Net Sym. ienpt r: it r rii... 11 v C'l-ricent rat ion '.:o-i r-tr-c i I'l'ri C'I'nee rit r at i .I'ri i-ili Eciti. '.'t-tj t»H U. '.li.li '.n.i'.) '->. •_; 3' Bt £34. tn... i-'l. '-.I'.' ; i'.. Cl- >'- i;u .::.?6. ::..(:>.: '.I. 'j.).-. i.:R 3< z/. ,•• \ G •:'. CY.-:zz L. U 3i;: 4 . I L'I Cj. 133 '.1. Ici-r riN LL/.u:-- '-.*. E ^ ^ 0. £ 1 £• Nl ^'31 . L'..i4 o. 0':>3 •Ol ':i. t:>4'j ZN £13. 8Lt.. . l.z.'ii.. 'D. <:i53. o. 053 AL 308.315 O. 058 O. 15':; FE £59.34 , £. 177 £. 1 7 7 CA 317.933 6. £"ri'^ fc. iz'ri'r' MG £73.073 ilM>80- £. 377 3. '=!•"•• 763430 DUP' MW4L' Begin Analysis > a m p i e Number 7 Eie. Wave— Mean P'eak Mean P'eak Net P'eak Sym. length P'osition Intensity Intensi tv cn PI 1 > ZN £13.856 Off Peak Int. = 13£ 00 2 -O.0O17 £06 74 CD ££6.50£ Off Peak Int. = 40O to No Peak! 395 o NI £31.604 -0 cr> , Analyze Samples 01-18-1968 C" 13:51 .1 — 10 Off l-'ij.r-.k Int. = 457 No Peak! 1£ BE £3'i..:itl No Peak! £38 MN £57. •:-:. -O. 0::'37 : FE £5'-3. 3-1 -Zi. ':'0i3O j CR £67. 7.:G Off P'c-ak. int. - -4 4'3 r-J.:. P'eak ! MG £73.':i7-ri -Ci. 003£ 10 1 '-I 1 O 1 H AL 3(:>8. 3 y.:: Off .'•-«-.. I .'it . = 383 No ^'eak! 51 i lEH Cft 3l7.•:^^.^ -O. 00£7 26'.!'..; 36'-.'5 CU 3£^:. 754 Off Peak int. = -0.0'Ui3 14G- AG 3£8.068 No Peak! w. 7 ''-i 374 Ccilcui at ing Ci:'ncentr-at i c-ns f'nr Sampie" Number -' Eiem. Wave- Net l-"eak Calculated i r,\..-3rft=:rtsrirkr 'Sym. ienpth irit. triE-: i ty C'r'ricentrat ion 'C •.:••-r-ec' :ior C'r'ricer-t .-• at : '.-i AG 3c:6. ';:)68 C'it *:>.i: ' •:.;..• *; C:. i.: ) '.; BE £34. 861 £3-8 0. •:'':•'':.-• O. ':".>'.• CD ££6. 50£ •*'.:_• CR £67. 716 64 'j. '.' w. " O. 03^ CU 3£4. 754 146 0. 0 7G >. OOC 0. 076 MN £57. 61 , ,,|j£S»S3 •:•'. 13£ '..I. 13£ NI £31. 604 0. ':)5':' 1..'. •.".) i '.:'. 043 ZN £13. 856 •^fcl 0. OiE':^ •:>. ':>'>';' 0. :..i£3 AL 308. £ 1 5 -'^^|i-^8 ri. 065 (. 0. lU'.: FE £53. 34 ^|5^7£ 1..3 £5 1. 3£5 CH 317. '333 3605 w'. 6£0 5. 6£0 MG £73. 079 1014 £. 71 7 £. 7 1 / 763430 t- MW4B cn Begin Analysis - Sample Number 8 PI > Ele. Wave- Mean Peak Mean Peak Tvlet P'eak O Sym. length P'ositicin Iriterisity Int ens i t v o to ZN £13.856 to Off Peak Int. 130 o -O. 0013 647 517 CD 226.502 Analyze Samples 01-18-1988 C" 13: :.5 — 1 1 Off Peak Int. = :37 -O. 00£; 1£4 Ni £31.604 uti t'-'t-ak int. - M L / —Ol. OlO3 1 .'..f.t- bi 33-i. 3G1 -0. ':)•::)35 1333 m-i £57.Gl -'.1. '.i'-i36 3-'ol 4 F 3 £53. 3'-, — OL (Zi03 1 31 5 1 £ 3 8 1 CR £6'/. / 1 6 Off Peak. 1 rit. —.:i. .-...'.>z--'.' c:4 1 I'-,'.- --.;• .'.':. r -. .-.-.-.'. -0. ':i'.!.-..:: 3ZzS 7 ££67 AL 3'-Ki. 3:. :'• 'Ofi .-'co-ai: i nt. No Pean: 30E. lc:l CA 31 7.':>33 •-•J- •J'-ic"i' 654 £ CU 3£4.754 Off Peak I nt. 3£l -0.0023 855 fi3 3£8.068 -o, >-:)'::w::i 5M 1 541 . lating C'r-ncerit r at i crit f.:.>-- 'SairiPle Number ;-i '-,.•<-/e- ;--i'.-?t l-'eal-:. L.--'i r: I.GL ,-11?':; 1 nt err f?-i-er ice riti 1 er: uz n 1 rrc erit, 11 y Z:c'ric-e:'.t r at i .z.r. L'l'rr-ect i 'I'ri C.onc eritr t't i .ZYI AG ..ILH. '.»G8 54 1 '.I. '.I':.!'.' '.I. viyj BE 3.3 4. 861 1 333 'j. OOO 0. 0)50 CD ££G. 5>.i£ ...J-^"* •:K 053 CP. £67. 716 :^^2.4-i- 0. 163 OL 163 CLI 3£4. 754 " 'i^^3a 0'. 305 O. 3':) 5 ,- • •. «- w ^^•4 1 • ••. «". CJ r.N £t;.7. 61 .- • ^- ^*\..- \ • . ... w.' 1..- Ni £31. 604 •^^p86 O. 448 O. o-'Oi 1 <:>. 447 ZN £13. e.56 '"'•-•'517 O. OOl AL 303. £ 1 5 1£1 O. 03'3 0. 150 FE £53. 34 £ 1 81 £. 371 £. 371 CA 317. 333 654£ 10.80£ 10.80£ MG £79. 079 ££87 7. 7££ 7. 7££ 763430 FILTERED MW4B cn PI > Begin P^nalysis — Sample Nutnber 9 O O Eie. Wave— Mean P'eak Mean Peak Net Peak to Sym. length Position Intensity Intensity to O ZN 213.856 •V] • 03 Analyze Samples 01-18-3 368 & 14:00:16 — 12 Off Peak Int. 131 -O. 00££ £78 147 CD ££6.50£ Off P'eak Int. = 391 No Peak' 333 Nl £31.604 Orf Peak Int. No Peak' 463 BE £34. 861 N'l' O'eak ' C:E'3 ££3 l>i!--l £57. 6l - -Z. .nj'. i 1 873 1873 !-L £5'3. '34 -.j. .jOC-j.. £4G LR £6'7. 7 i £-• Off P'eaO. i ri\ . No ;-'£.aif.- I'lL? TiL 30)8. 3\3 Off Peak Int. o . <" r No I'eak : .^•cr^i i-itj -.^83 . •-• .tJ E •_ >-i 1 ci.i 1 at-i i'lU C'lJ'riCt^-rit 1'at-1'r-rii": t'l'r -oatiip'lt.- !^Ji.lil^bt='r- 3 Liem. Wave- Net P'eak La i ci 1 at ed J rit er rereri..::c- Pvlet Sym. ieripth Intensity Concent rat i'.ri L'i'rrect i'^'ri L'l'ncerit r at i'I'r: '^4-, A I- - H'o 3£y. Ot-a 0). o><:> 1 0'. CjC_-\j < Cj, Cj 1 >:> BE £34.661 o>. ooo> 0. O'jO < 0. 0':i5 STs^^ _• CD ££6. 50)£ 'OL O'O'J. <• Cj, 005 CR £6-/. 7'16 -o. >:»i6 •; 0. 010 Cu 3£4.754 O. 'J17 0. 000 i. <:>. 0£5 MN £57.61 1879 O. 172 0. 17£ Nl £31.604 6 Cl. ':>44 '.-). OOO 0. i;>44 ZN. £13. 856 147 O. 063 0. C)00 0. 063 ^ AL 308.215 16 -O.357 < 0. 150 0. 117 cn FE £53.34 £46 Ol. 117 p] CA 317.933 3538 5. 502 _'. 50£ > MG £79.079 976 £. 568 2. 568 o 763430 FILTERED DUP MW4& Begin Analysis - Sample Number 10 to O •o Ele. Wave- Mean Peak Mean Peak Net Peak ID Syrn. length Position Intensity Int ens ity Analyze Samples 01-18-1988 C- 14:03:58 ZN £13.856 Off Peak int. = 1£7 —0). OiOi,:;3. £3.9 1 1£ GD ££6.50£ Off Peak Int. - • 337 No )--fc/^>k' 388 Nl £31.604 iJff P'eak Im.. - .H6'3. No Peak' ^7':> £3-4.8t-i. 1 -r-.o i-'feak' ££7 MN £•5-7.61 -0). 0)'::i-u 1 18'/£ 187£ FF. £53. 34 —O. ':i(:>33 £35 CH £67. '716 Off P'eak Irit. = 46/ No Peak! 467 i.t Mb £73.079 -0.0034 991 991 AL 308.£15 Off Peak Int. = 379 No Peak! 387 8 CA 317.333 -'::>. 0>O30> 34'38 3'+38 LU 3£4.754 Off P'ee-t:. 1 nt . == -3:5 AG 3£8. iJE.a No La j c I.I 1 at i rig Coricent r-fit i'I'rit. ' .yr ';.-•;.rr.pi e Number- 3'.) Lierii. Wa-ze- Net,-„Pje«k. Ga ic-^.i 1 ated r,tf?-r t o-.-•l^- i AG 3£8. 038 ^»"375 —01. i.i'.ij, 0'. '.''..)0> O'. ':• 3 01 BE £34.861 (.>. O0)Ci, OL 0>0i'..) ; o. 'J015 CD ££6. 50)£ " -3 -O.Ooi O. 0-)0i5 CR £67,716 O -O.012 ; 01. 0110) LU 3£4.754 69 O. 031 01. i.l'.'O o. ':)3i MrJ £57. 61 1872 O, 171 O. 17 1 Nl £31.604 1 0. 038 o. (:i'::i':> <:>. <:>H0I ZN £13.856 1 12 O. 046 OL CjOO O. 046 AL 308.215 8 -0.387 O. 150 FE £59.94 235 O. 101 0. 101 cn CA 317.933 3498 5. 431 5. 431 PI > MG £79.079 991 £'. 6£-7 £. 6£7 o 763430 FILTERED SPIKE MW4B o to Begin Analysis - Sample Number 11 too CP o Analyze Samples 01-18-1986 t? 14:08:09 — 14 tie. Wave— Mean Peak Mean Peak Net Peak Sym.' length P'II-E:.it i OT. Intensity I ritensi ty ZN £13.856 CJff P'eak int, ISE 67: }4 1 L;D E33. 50£' L'ff Peak int. 401/ ic:7 !-;l L31 , 604 Gfr P'eak i rit, •-I "-I / 87 3 4£6 33 £3''-!. 361 - :.:. .-' .''JZ'J 1 3801 1380 r':N -57,61 -•Z . •.r..^3 3£57 3£57 FE £59.34 —Cj. '.'•:.'..{.V 883 888 CR £67,716 Off Peak 1 nt. ^6£ -OL oii.'3£ 604 142 MG £79.079 -0. O0i35 ££14 2£14 AL 308.£15 Off P'eak i rit. i.t^l No '•(:•;• i: : 3'::<6 1 5 G1---I 3 17. 3;::3 -0;. -.-. : : G3 36 36 •_ L; 3k::4. /U-iH Off P'pak i i-'t. .18 JC>E'^- 730 G/£ Au 3£8. 0)68 548 i'4e La 1 C'.i 3 ax 1 riD Concent;r;a;>.. iT.-r.;:. for Scimple Number- ii •:0f^S'»Siv0: Lieiii. Wa-v'G - G •-•i 1 cu 1 at ed Interference Net '3\Th. i«'riiitG .:c-ncerit rat i 'i-ri Cc-rrect i '^'ri C ':• ricerit >" at i or: AG .i£8. 0168 "'•" 548 O. 093 OL OH.iO' 0). O>9J BE £.i.4. 861 1 380 0. 050 0. CjCjCj o>. 0150 CD ££6. 50)£ 3 £7 O. 055 0). 055 CR £67. 716 1 4 3 O. 091 O. 091 CU 3£4. 754 4 7£ O. 269 O, iJOO O. 269 MN £57. 61 -;••". t: 7 OL 3£e O. 328 NI 231. 604 4£6 O. 490 O. OCjO O. 490 ZN 213. 856 , 541 0. 244 o. OOO) 0. 244 AL 308. 215 15 -O.361 0. 150 FE £59. 94 888 1. 064 O 1. 064 O CA 317. 933 6336 10.439 10.439 to MG £79. 079 2214 7.435 7. 435 Is) I O 763434 MW4A Cb Analyze Samples 01-18-1988 V 14:12:14 — 15 Begin Analysis — 'Sample Number 12 Ele. Wave— Mean P'.-e-it: Mean Peak Net Peak Gyni. length P'o;; i v i'.'ri iritensity .1 ntensi ty ;•: N lu' 13. 85c. Off P'eak int. 1.^-E. —OL Ol' i3i:. 348 3D £££.. 5(:)£ Off P'eak int. No '•( ,. •- : '1 IH Ni £31. 601A Off P'eak int. r-.;.:- t .-.^:-- ' 1 J:- B E £34.861 r-J';' ;••:-.- B : -• ' ._'G£ NN £57. 61 --0'. -.'0..>b -fi5£4 85£4 FL £53. 34 -'.L .".•--•£ 3 7671 7671 CR £67.716 Off P'eak Irit. = No .'E-ai-: ^iG £73. 0073 -Ol. 0:0)3^: AL 3 08.£15 Off P'eak irit. fc.'.il'-t L Pi 31 ,'. '-533 -•:'. OZCr • \-:flE CU 3£4. 75-1 O'fr P'eai'. irit.. - —OL ':I^' 1 3 3 5 3.i A(7 3£8. Oi66 No P'eak ! ; "7 6 .76 .5-T.i*:E.r. Lal cul at iriD C'r'nee.riti-tjat i'Z-ris t- '-•aiiipic- f^iutnber l£ ">i'a.w..-.., : Eiem. Wave- N'e.tfep'e'ak Calculated , Interf erenc. Net 'Syin. lerigth Intensity Loncentrat iori Lorrecti'.'n .:<:!'.''icerit- r-at i c^ri AG 3£&. Ot68 376 —0'. OiO'E' 0). •.••JJ> Oi, '.' 101 BE £34. 661 £62 OL OiOl O. Ol'JL 0). '.'0>5 CD £26. 502 5 OL 010)5 O, 010)5 r > CR £67. 716 59 Ol. 0)31 CL '031 cn CU 324. 754 93 0). 0)45 OL 0)0) J O. 04£ PI MN 257, 61 8524 O. 327 O. 9£7 > NI 231. 604 13 Cj. 0)51 01. 0>08 O. 043 o ZN 213. 856 £15 OL 034 O. O0i5 O. 089 o AL 308. 215 60 1 4 ££.£34 to FE 259. 94 17671 £5.814 25.814 M CA 317. 933 1S12 £. 633 2. 633 O MG 279. 079 1422 4, 3£1 4. 321 CD to Analyze Samples 01-18-1988 & 14:18:28 — 16 763434 FILTERED MW4A Ber^iri Analysis - Sample Number 13 Eie, Wave- Mt-rrrr i't-ak Meari P'eak Net P'Erak '3ym. length P'<-.''= ri t i'.'ri Intensity I ntericv ity ZN £13.856 Off Peak 1--, 131 187 CD ££6.50£ Uf f 1 'eak. .; ri 336 I 'fe-at: .i37 N i £3-3 . b:.i'+ Ufr P'eak iri No 0•t;.^^: • •4 (.: / c> BE £34.861 No P'eak' ££6 ££6 MN £57.61 -'-:L '_'01'-!•'•-» •J 14 314 FE £53.94 -01. o)'::)3£ £14 £14 CR £67.716 Off P'eak Int. = HC-.-1 Z'-io ! 'fc'ak ; •HGO:. I'-i-i i_;73. 0)73 -'.:. .".I.- ,- 715 Gf f P'eak i rrt . - 38'0i rvJ.:' i-'c-.:- r. ' 336 It. L^-i Jil7. 333 -'... '.;'::-.-.: lt;.0£ 1 t.oi£ G-U 3£4. 754 Off Peak Int. - 316 No Peak! 368 AG 338.'Z.)EiW^ff.-yf^o Peak' Wi:''-'- aiculatirig Conciferis^rat i'Zins fc-r Eainple Number 1. Eiem. Wave- Net P'eak Laicuiated Interference Net bym. leriqth intensity G'-Ticerit rit i on Cc-rrect i ori C'l-ricent rat i on AG 3£8.068 -•J, o>04 Ol. Ol'OO) < Cj. 01 O BE £34.861 £26 0). OlC)0) 0), otO)C) < 0. 005 CO CD ££6. 5<:i£ 1 0), 0)0)3 < C), C)C)5 PJ CR £67.716 -5 -0). 016 < O, OK) > CU 3£4.754 52 O. 021 0). 0)00 < C), C>£5 MN £57,61 914 O, 062 C). 06£ oO Nl £31,604 6 0). 044 0. OOC) 0. C)44 IO ZN £13,856 56 O, 021 c>. c»oo 0.021 AL 308,215 16 -O,357 < 0.150 olo FE 259,94 £14 O. 070 C). C>7C) CD CA 317.933 1602 2.086 2. 086 CJ Analyze Samples 01-18-1988 C" 14:23; 17 MG 279.079 715 1. 542 1. 542 763438 MW4C B&v, 3 n A-fia J yi::i i aiiip j L- ."-i'.a.iber 1 H Lie. Wave- t-lc-.ir- i'tiak Meari -P'eak Net P'eak 'G-yriJ. ieriDth \^oi.. x y ori intensitv i rit ens i t v ZN £13.856 Off Peak Int. -'.:. 0-GL'G ^•':i CD 226.50£ Uff Peak int. No -'eak' • rtt. NI £31.604 Off P'eak Int. = A A3 No P'eak! 465 16 BE £34.861 No Pi^ak ! £32 MN £57. 61 -0). O.J'->c. 868 P'E £53.'34 -0'. •:''..'3.:. 3 £74 CR £67.716 Off i'eak Int. •- No .•e:V^:• MG £73.073 -0'. •;".•;-;•: lO'-^';- AL 30)8. £l5 G f f Peak J r. T. 80& CP-i 317.'333 -0.0'JH'j 41 40) 1 13 37: Calculating C'l-ncentrat j ons for Sample Number 14 Eiem. Wave- Net Peak Calculated Intetference fvlfct Sym. length Intensity Conceritrat i'i FE 259.94 1£74 1. 633 1.633 CA 317.333 4 140 6. 564 6. 564 d tr t- MG 273.073 10)43 C.. Ow«.J i_ . O ..J w.' 763438 FILTEPEI.' MW4G Begin Arialysis ~ 'Sample N'.imber 15 Ele. Wa-v'c-- Mean P'eak Mean P'ectk Niz-t P'eak 'Sym. li-~rigti"i Pc-siti-r-rr Triten-rity Int ens i t y ZN £ J. 3 . Gt.-c. Off -'tak int. = - •:). O'O'ci 3 0'i5 Cu EclC. G'.:i£ Off Pe-aK int. = 403 No Peak! 334 -15 Nl £31.6'0H Off Peak Int. 448 N'l- P'eak ! •st-t. 18 BE £34.aGl N'l' Poav; ! ££6 3 £6 ?\N 3.zZ/ . 3: -O. 0\JA7 57 £ if' 7 £ . -;. .^ 'I 3.3.4 •T t -i.i' int. - to'. No P'eak MG : ..'-•» •-'.'. '3' .'^: y.5t. AL ur 1 K 1 nt. i&£ _^il N'O Peak ! 'i 3 ,' LA 3 3 -' . 333^^^0..-0o4l i.5l0 Ofi iZ'eci^^^t. = •3 'r- '^^No Peak! f80i 61 AG 33a. 'j3§'^-'*'''' No Peak I 376 i76 cn Cai coi 1 at iric. G'i'ncent rat ions for Sample Number 15 PI > Elem. Wave- Net P'eak Calculated 1 riter"^r erence Net o Sym. length Interisity Concentr at ic-n Correction Concentration o to AG 328.068 376 -C). C)02 0, C)C)C) < 0). 0) 10) BE £34.861 £26 C). OCK) 0, OOC) < Cl. 0C)5 CD £26.50£ -15 -0. 0C)4 < 0. 005 CR 267.716 7 -O. 007 < 0. OIC) CU 324.754 61 C>. 026 0. 0C>0 0. 026 MN 257.61 572 O. 024 0. 024 NI 231.604 18 0.056 O. 000 0. 056 Analyze Samples 01-18-1986 tf 14:32:15 — 19 ZN 213.856 1 08 C). C)45 0). 0)0)0) O. 045 AL 3C)8. £l5 -O.£85 O. 150 FE £59.94 £34 C). C)99 0). 0)33 CA 317,333 3510 5. 45£ 5. 4'o£ MG 3/3. '.'73 858 £. 104 •76344£ FiLLD BLANK Begin Piriai \-'J= i "i- - '-L^IIIDIP N'-imber 3 6 Ele. I'lean P'eak t'leari P'ea-: Net P'eak Gym. I t;- 1 ''i-i 11 1 on i rirei-r'.:. 11 y 1nt ens11 ZN £ 3 .:.. f.'.-'t- UT f P't'c-. t'. : rit . = rvio P'eak ! iG.;; CD ££G.50G Off PeaK int. = • o»i No Peak! 394 Ni ."'31. K^'JA Uff P'eak int. = r-J.:. k'eak : 3E 3 3-i. G3 : i'io Pecvi- • MN GG7. t.., Nr.. Peal-. ' FL j.;:,G. ': •• ;••:•:. i-:.y..\-. '' CF. 33/. 7 3 L Off r-'rzr.r. Int. = •4t.'H I'io Pean: 'i'_,.-J - / MG .:;73. 017-j N-.- Pea!-:! 3£ 1 •£l u-rf Pei^»^|.-,. = ••- 386 ^^^^^o Peak! 383 CA 3.-• 1 7.'M^^^mr^O/. ^:iss:mmi^''-' P'eak: A '•-: 'H CU Off Peak?'^Int. :.l 7 No Peak! ..^t.t. 43 AG 3£8. 0)68 N-D P'eak! 3 .'-^: *• i83 cn PI Calculatirig Cc.ricent rat i oris for Sample r.Jumber- i6 > Elem. Wave- Net P'eak Calculated Interference Net o Sym. length intensity Concentration Correction Concentration o to AG 3£S.068 383 C). 0)C)2 CL C)0C) < 0. 0)10 to , BE £34.861 226 O. OOC) C). 0C)0 < O. OC)5 CD £26. 5C)2 -7 C). OOC) < O. C)C)5 01 ' CR 267.716 -7 -O.017 < O. C)10 CU 324.754 49 O. 019 o. oc»o < O. 025 Analyze Samples 01-18-1988 I? 14:36:40) — 2C) MN 257.61 378 0), 0)0) 1 0). O£o) NI 231,60^ 7 O. 045 01. 0C)0 o. 0'H5 ZN 213,856 31 0"). o-)03 O. 0)0)0 0). Cj3'j AL 308,215 -0.4£& 0). 1 '30 FE £53, 3'+ 3G8 o. o)':)£ 1.1. Cj3Cj CA 317,33.:. 4 53 C). 7S3446 TRIP BLANK Begin Ariai y.-j r: - '.Sample Number 17 Eie. Wa-vt..-- Mean P'eak Meari >-•£•:i:c>i r^iet i--«fti Sym. ier.|.;ii-. r'.:.r; 111 or, iriterisity int 6 r..-- 1 t y ZN £13. 85t.> Off P'eak irit. = 133 No Peak! 145 1,:; CD ££6.50£ OfT ^'eak int. = 388 N-o P'eak! Nl L3 1 . {yj't Off P'ec-iJ-- 1 rit. = *t7t. l^o h'-Z'a K : BE .3'3^4. 8G1 ;'•;•;• P's-s;-- MN £57. 61 NO Pt-ak FE £53, 3'+ No Peak IE .65 CR £67.716 Ofr P'eak. int. = 456 A5£ MG £79,.Ci;;^»Mo, Peak! AL 308, £^^^^p|G - Off Pe^^p^l'l; = 38 7 ^^^ll^lc; Peak ! CA 317, 33#%^No Peak! 4 3:3 4£3 CU 3£4,754 Uff Peak Int, = 3l6 No P'eak! 354 J.-a AG 3£8. 0)68 r>lo P'eak! 374 3 74 cn p] Calculating Concent reit ions for Sample Number 17 o o Elem, Wave- Net P'eak Calculated Interference Net IO Sym, length Intensity Concentration Correction Concentration IO o 03 AG 328.068 374 -O.003 < 0. 010 BE £34.861 228 C). C)C)C) 0. 000 < 0. 005 CD 226.502 7 0. 005 0. 005 Analyze Samples 01-18-1988 tf 14:^4£:4£ — £1 CR £67.716 -4 -O,015 O. OlO' CU 3£4. 754 38 O, 01 £ 01. '.10)0) 0. Oi£t:. MN £57.61 372 O. 001 '..'). O£'0> Nl £31. 6>:.>4 -20 O. oil 6 01. 0'4 0 ZN £13,85G 12 C>, 0)0)0' 0:. CjE'j AL 308.£15 -O,4£5 FE £53.34 165 -C). 0':)£ CA 317,333 423 C). 00)5 O. cZO:. MG £73,073 —C). '-)'-)."•. •j. £'.". CAi. I3HPr!G ON G. 1-1OQ 1 ri Aria i ••.-•:-.- : ^ 111 pie ;-;uir. b(-;. Ele. Mean P'eai-; Mean P'eai: rJet Peak oyiii. 1 (.";-! I. C I I P •:• s i 11 o n Interisi t v Intensi t v ZN £13. 856 Off Peak Int. = 130 No Peak! 1 -4 0) CD ££t.. 50£ Ufr P-eak int. = No Peak' l-Ji c.-.:- .. . r.'JH Uf-r P'Pf.i: Int. = A's-i'- No P'eal-. ' BE £.^4. iryc.l No Peak ' MN £57.G3 No Peak! .l, ,• 1 37 i FE £5'5. -"H No i-'eak ! IbM 164 CR £6/. /16c. -~ Off Peak#lrit^.. - 46" •i5Mp%No Peak. ! CU 3c:4.75¥»&f J- 3 0) ^^'^---No Peak! 356 AS AG 3£8.068 No Peak! 3"73 Calculating C'r-ncentratic-ns for Sample Number 36 cn PI Eiem. Wave- Net P'eak Calculated Interference Net > Sym. length Intensity Concentration Correction Conceritrat ion o P^G 3£8. 068 J73 -C). 004 O . C) 1 o to BE £34.861 O. C)C)C) O. OC)C» O. C)05 -4 C). 001 O. 0C)5 to CD £26.502 o CR 267.716 -12 -0.021 0.010 03 CU 324.754 46 0.017 O. OOO O. 025 OO MN 257.61 371 0.001 O. 02O An.;iiy = e Samples L - l.'i-3'H3B 1." i4:4f c:3i . t-.oiM .;. ',13.;. »>, .,)^*,> IO .::i 3. 85L I. 0)0>O t.». '.ic!',' 1 L . 1 t--4 . 3H .'. 0' IA • 1. ''iv--' 1 ..- •• ... 'i: G( 3N\'. •'. t'.riri 3 ys 1 E - Si^nic-' tie. Wave- I'U.-:-,-- • •/ir, I'e^-il' '. -|-*ri I- Svni. 1 f-riij'. r-. i--.:-'.. -I-', f.M-li- 11 v ri' .! -1. s- 't .-. I: . r. Ufr PfccG ivit. j-B . il £31 . GO)^ ^: I : P'i.:-a.-- j ••i\ . . Gl P'c.-i' ifC. .-,;(••• J i't 1 1-1II I .-..r'lgle^-ri'lir at i • Gi-iinplf- Nitiot't t.ji?iii. Wave- Net P'oaK i. a i i.. •. 3 .^t e<.i Inter 1 ef-|>r.i .- Net 'ovM, length Intensity (...nc erit'• at i •:.-ri Lorr i. .;.!.( (--r AG .3£8. 0)68 o>. o)0).3 11, '. ' '. ' 1 j '.' BE £34.861 0. OC.iCj .•|_ y;. ,. '.'. .'jZC. cn PI LD EEC. 5i.)£ 'j. 'J0 7 •j. «.)• '7 CR £67.716 - i c •0. C)£l < 0. 010 '• ':• '.). 1 H.'O) •; C). 0)£5 CU 3£4.754 '.'. '.114 o Mr-J £57. 61 376 0). 'CiOl < Cl. 0)£O to NI £31.604 -5 01. 03£ Cj. CjijO < 0). 0)40) ZN £13. 856 16 0). 0)O£ 0. 0)010) < C). 0£C) to FE £59. 34 168 0). 00)£ < 0. 0£0 o 00 OO CCV ccv Analyze Samples 01-18-1988 & 14:48:£4 — Begin Analysis - 'Gample Number £C) Ele. Wave- f-'it-an P'eak Mean P'eal; Net Peak Svm. ic-fii;tii I • 'i' -r ^ t 1 o n 1 n tens 11 v I ntensi t-y iN £13. 8Gh. Off P'eak 1 rii . 153 -'). cxjEZi -£^33^3 CD Off P€^;>l: .1 ••rt . - 4; 34 -...' . 0" j3'7 3.01O 1 t'G/ Ni £.::,3 . v..-.."i Uri r-i'.: ;• i 111 . ^ii 'js -) 1 .1 e0£6 BG t-.i.A. 3L.' .L :>3b c--tij: •-..:• £4£4 3 MN £5V . fc.:, -•: :L ..j. :i4 1 £3'-tj i £9411 Ft £53. 3-1 .'. 0".. ) .1' .' 1457G 14576 CR £67.716 Off Peak I rit . = 503 £357 GU 3£M. /5M Ufr i-'eaP; i r:i. . Ji-t -.), ...)'.ii+ j, 8 7 7 •> ••.'. I.:'.)4'3 38 i 'i .' £1 i C -.! 1 Cl X. 1 r 1D L. O YI C. O Y, X. C i-.- I L.iHWDl G- N'.linll'er- Liein. PMve- i'-i e t- 1-' t:- a k Lai c; i.i i a tec 1 n t e 1" -r t.- r e r. Net . / e^. '.--•yin. lerigth 1 rit eris i t y C-;:"nc erit r at i .Z'ri Corri?ct j •;• G'r.ricent r- ii,t : on nG 3£8. 0)68 .38 3 4 1. 898 '.). O'.L 1 . 83^. Be- £34. 861 3AyA Jl 3. •:)A3 OL 0)'i; 3 . O'MG lOM- CD ££6. 50)£ £567 1. 055 1 . 055 CR £67.716 £357 £. 133 £. 133 109- CU 3£4.754 8778 5.13.^ 0). 0)Olc: 5, 161 MN £57.61 £34 1 1 3. £9'3 3, £33 NI £31.604 S'OEL. 8. 571 0), 0)t.) / 8. 564 10? ZN £13.856 8333 4. 135 0. 0)0)5 4, 1 30) FE £59.94 1 4 5 "7 6 £1.3A3 £1.£43 'OS 763590 MW3C Begin Analysis - Sample Number £1 Ele. Wave- Mean Peak Mean Peak Net Peak Sym. length Position Intensity Intensity ZN 213.856 Analyze Samples 01-18-1988 L" 14 ^1 — £4 Off Peak Int. 141 -0. O0)£7 8£G 685 CD ££6. 3>0^z Off Pe-ak i rit. 334 No Peak! '14 3 Nl £31. GO'4 Off Peak 1 r,t . 476 No Peak' BE £3^.861 —O. 0)':)3b 3'r*'T^ 333 MN £57.cl -0. '-.'0'33 14555 14555 FE £53. 3^+ -^1. v.,J:.:: w. 3 3;v7,':i. 31GL3 CR £67.73G Off Poj,): j nt. 'H'74 r.j.-. 1 (. ,,,,•• f. i: MG £73- '.: 7'- ••-...••. • '••: :-;-- 5 £'•-..-.• HE 30)8. ^•..•..• Off P'e-ai<: 1 rit. = 713 -- --'. '.:'0i3.'.) 187'-.1.1. 17'330 CA 317.333 --'-:'. 0)0'40) 18638 186£8 CU 3£4, 754 Off. Pr-ai-: 1 rit-. - 3£4 - '.'. -.lO'M 1 y..".' AG 3£3. OK-.G Nc- P'fi-. - •' 38 'i ,38 1 . cu 1 at- i rip G'Z'rici-i IT- r ' T. .; o YI '- T •:• I i. a Til L.' i e f'J 1.1 :u D t- L- i L-sro. Wa-/i.- — Nii-v P'e,-:(k 1 -1^\.. c: '-1J a "c »^ .'J r>t r=-r I r-r tsviCB Net 3yuT. length i r, i Cr 11;-; 11V G'i'nc erit rat i 'i.ri 3ori- v/at i';:.ri C'l'-ricent i"at i'i.r. 0-;G 3£ti. 068 381 0'. '.10'i '. '.I'.'5 '.). 0) 1'.' BE £34.861 333 0. 0)0)7 1. O'-.i:;. '-:'. '-:)0)5 GD ££6.50£ 43 O. 0£3 Cj. 0o33 L-R £67. 716 41 0. 0) 1 7 0). C)3 7 LU 3£4,754 476 0.2 72 i.i. 0>i.)5 0. £67 MN £57,61 14555 1. 61 £ 1. 6 3 £ rJl £31. 6C)^ 35 O. 0)74 '..).. O 3 H 0. OE-iJ ZN £13.856 665 C). 31 Cl 0). 00)3 0. 30 3 AL 30)8. £15 1 7330 6 7. 340) 67.340 GE £53.34 31££3 45.733 45.733 cn CA 317,933 18628 slt\Z^ m 1 4Z. / 3£.1£7 PI MG £79,079 5202 13. 163 13. 183 > O 763590 DUP MW3C o to Begin Analysis - Sample Number ££ too Ele. Wave- Mean Peak Mean Peak Net Peak 00 Sym. length Position Intensity Intensity Analyze Samples 01-18-1988 (£• 14:56:58 — 25 ZN £13. 85G Oft i'eak 1 nt. = 143 -'i j. 00£3 ^' 1 L 66' CD clEc.. '-••j3 Uff P'e^rik -int. = 4£4 No Peak! 44 6 NI £31 . GO-4 Off i-'ea k i nt. = 478 No Peak! 517 EEI vE .-Z3'i. 8fc,l - .1. Oi':."4& 3 S 3 386 NN £5-7. G 1 - :L 0'0>4£ 1 4 3G'G 14365 FE £5'-. GM 7- :). '.i':)33 3076 7 3';i767 LP. £6"/ . 7 3 L Dff t-'eeit-: 3 rit. = •^67 No Peak ! 515 4ti NG £73.073 — :i. 0036 5137 .'37 AL 306.£15 Off Peak I nt. = 70)4 - .'. 00£7 16584 1 7880 GH 317.333 -':. . 0)0)37 1^485 18-4 85 u U 3£'^. 75-+ Off Leak 3 nt. 1 1 i. • -• >' 14 ."\ 'Z.' > • •,' t . A\:i '.^li't. Oils i'.jr. •.•i'lCC Tit rat i .^.-ns- -r.i'-r- bairip 'N. i Til;..-;-1• Llein. i/^avt;- I'-iet »-'eak Lc. 1 cul a tea i nt e." fccrf^riCb! •'•- f. •- 'Svin. length 1 ritensi ty Cc'ncentraT- i.r.n G-.^'-r^ r-ect L C'r iC F-r ": : at 1 'r- 1.': 0} _• £ .y. 01 CS 385 O. 0)03 OL *.'' 5 BE £ w- 4. 661 386 0. 007 'j. 0)0)3 0, C)Ci5 CD e:£6. 502 ££ O. 01 1 0.011 CR £67, 7i6 48 C). C)£3 C), C)23 CU 3£4. 754 48£ 0. £75 O. 005 0. £70 NN £5 7. 61 14365 1. 590 1, 590 Nl £31. tiO'^-i 39 0. 073 0. 014 0. 065 cn ZN c:l3. 856 663 0). 3C)3 O. 00)3 O. £94 PJ AL 30 8. £15 17880 66.9£5 66.9£5 > FE £53. 94 30767 45.1£6 45. 1£6 o CA 317. 933 18485 31.875 31.875 o MG 279. 079 5197 19.163 13.163 to 763590 SPIKE MW3C o10 10 to Begin Analysis — Sample Number 23 Analyze Samples 01-18-1388 (£• 15:011 :i:i: — £6 Eie. Wave- Mean P'eak Mean P'eak Net Peak Gym. 3 ength P'.;.si t i .:.ri I riterisi ty Intensit v i'. i 'i £3 3. 856 C'--."f P'ef,k. I nt-. 137 —0). ':ii:>£3 3 £47 3 3 3':' LU GLG.50£ Uff Peak Int. - 4 0'+ -0. oi':i-'4£ 5'..G '.-. 3 G.^3 . G'-i4 ZCf Peak Ini-. -tZ..r -Ol. OZj'33 •7-7 ". Cr. G.i-'i. Go 3 -Cj. >_rjr:.H- -'.:.- • 3 rZ'i LG7. tr.-l -Ol. •;:•;:4'.' 3 t'.'t- / i-G 3o--j. 3H -'•j. 'jiiCrZ ,: 3 a J. .^ .1-1 G£3 GG L c-.. 7 ."736 Uf-f Peak 1 nt. 473 -0. 0035 675 ifG £73.073 —OL 0)036 6473 GM73 HL 3'.'8. £15 Off P'eak Int. 7- 3 0) —'-:i. ' ''-'.r.'tS 3y33£ 3 ti-E^c: '. !-' r. 1 / . .t^. '• ..:• --:-. 0..'33 c 3 ::• .:• '.. rl 1 t- -• 1 C I: .'..-•'-:. / 5 A ..G - s'oak T ri-r . .'.c _• -'.;. 'j03'j i'.>L.'.: A-3 3£3.0G8 — 0). ::;0i-. 3 'Z: .'•,_' La 1 c i.i 3 ar- i ntj Goncerit -rat i .:- i or -oaint-irr r-JiiriiDe'r- £3 Eie!i-i. i-javt.:- Net.- Peaw La icui c-it ed i rit er-f erence i'-it?t Svm. leriqtn Intensity C .;.ri'j-erit <"at i'r.n C.:'r--ec.-t i on Cc-''ic%:'-nt rat i'l-n AG ££8. 066 535 O.08fc. '.). 0>0)5 O. 081 BE £34. 861 1571 O. 058 0). O0>3 O. 055 CD ££6. 30c 15£ O. 065 Cj. '.:)65 CR £67. 7 16 £o)£ 0. 135 O. 135 CU 3£4. 7 5'4 741 . O.4£8 0). 010)5 0. 4£3 MN £57. 61 1606''- 1. 783 1. 763 cn NI £31. 604 ^37 0). 50£ 0, 014 O. 488 PI ZN £13. 856 1110 C). 506 C), 0)0)3 0. 497 > AL 308. £15 ia£££ 68.£14 68.£14 o FE £53. 34 3 1 8£3 46.63£ 46.692 o CA 31 7. 333 £1631 37.426 37.426 to MG £73. 073 6473 £4. £C)3 24. 2C>3 (o ; o 763590 FILTERED MW3C U) i CJ ; Analyze Samples 01-18-1388 t" 15:05:10 — 27 Begin Pina lysis — Sample Number 24 Lie. Ga-.e— Mean Peak Meari P'eak Net Peal-: Syiii. .lei'icth P'-Z'S i t I'l'n I ri\ o ••: ^'• r ••/ Inttrr.uii. ; V 7N £3 3. 656 Off ii'eak Irit. = -O. '.)0'£^ 33 .i,:;''.:-. 503' oGt P'eak Int. No P-ec-;i- • -•ii ,:i.:- -. . G':)4 urr ;'taP;. Irit. = No ''c-a.):.' GL ci.i-'i. :-Gi No P-ea- : L ..-..Vj PiN .r'G 7. tl 1 -O. OlO'Hl 3 M30 3 4:v:i FE G5'3. 34 -O. 003.C, CR 337. 7 16 Ciff P'eak Irit. = r^l.:. Peak ' -••I t.'-.i MG ,:;7'i.'.G"3 -':i. 0)0)33 ML Er:ci. cll'r.. No Pf.'-.. CU .^.£4. 754 Of* P'eak. Int. = -O.O0i£; i-'-'G 3£'8. 0'68 No Peak: Ca i Cl i at 1 riQ G-'i-ncent rat ions f.:.r -c.atnp j t.- Number £4 Elem. Wave— Net P'eak Calciiatec interference Net Sym. length iritensity Concentration Correction Conceritrat i .i-; AG 3£8. 0't,8 381 Cj. 0)01 C). C)OC) 0). '.) 3 01 BE £34. 861 236 C). 0)oiO) C). C)OC) 'j. 0)05 CD ££6. 50)£ -8 -0. 0'-:ii 0. 005 CR £67. 736 4 -0). C)C>9 0. 0) 1 Ol cn CU 324. 754 85 O. 040 0. 000 0. 04'J PI MN 257. 61 1430 O. 121 C). 3£1 > NI 251. 604 15 C). C)53 C). C)C)0) 0. 053 o ZN 213. 656 70 0). 0)£7 O. C)0)O 0. 0)£-7 o AL 30)8. 215 71 -O. 150) 0. 150 to FE 259. 94 271 0. 154 0. 154 CA 317. 933 2900 4. 376 4. 376 oto MG 279. 079 698 1. 475 1. 475 oD Analyze Samples 01-18-1388 t' 3 5:10:37 — £8 763530 DUP- FILTERED MW3C Begiri i Vri a .G.--r; i s; — Sample Number £5 ;:: 7 l-J .-• : .-.. tiUfc. . f i i-'c--a k 1 rit. = -0'. 0)0)£0) - ;.. .:.-.:.... G':)£ ;.-:' •• r 'I- a k j r,t. -•• •rH.. , ••.: c-.: : <.• •• ^ i-eai-: i rit. -• r-4o Peak : GG G:^.'-i.Gi-i PJo Peak' t'lOJ 3'3-7. 61 -O. 'JOi-H 1 1 40)t. GG y3'zi.3A -O. 0)C)3£ £&£ G r, - 3 /. . 3 G L* : P'eak Int. = No i-'eak ; :•-;(." -7 z-r •_. .-3 -':L O'i'GG No i'eak : i7G ::-l7. 333 —0'. '.'0)4'..' £::)£'4 GU .;-£'+. 754 G: : !-'i:-ak Int. -0. 0)0)13 G-t AG 3£8.':i68' No Peak: Ca 1 CU 1 at J riL; Lii.ncentrat i C'ns f'.-.r 'Samp.iCj Number- £5 Elem. Wave- Net P'eak Calculated interference Net Sym. lengtTi interisity C'^ricerit r c"-. i i. ••i L.i.rrect i on CC'ricent r at i ori AG 3£8.068 383 '.1. '.".'.:: C). 0)0') C) < O. 0)1 *-i BE £3-4. 861 £31 0). O'oi':i 0. 0)0)01 < O. 0)05 CD ££6. 50 £ -1 01. Oioi£ < O. (.105 o CR £67. 716 -5 -O.016 < 01. 0 3 0 o to CU 3£4. 754 94 O. 046 0. 0)0)0 0. 0A6 MN £57. 6i O. 1 18 0. 1 18 1406 to NI £31. 604 16 0. 054 0. 000 O. 054 o ZN £13. 856 0.0£7 0. C)00 0. 0£7 oD 69 Ul AL 308. £15 87 -O. 089 < C). 15C) FE £53. 34 £62 O. 141 0. 141 CA 317.333 2924 4. 418 4.418 Analyze Sample; 01-18-1988 C" 15:14:£3 — 29 MG £79.073 688 1 . H3I 3. •'4 36 763530 SPiKE FILTERED MW3C Bo q X YI i-vn:-. '5 a rii p 1 e N '.i / n b e r Eie. Meari P'eak iY..t:.;.r. P'eak Nei i-'c-ai- '3yiii. ienqth P'-Z'Si t iiz-ri i-r.^.iry 3 rit tz-r,-^:. : •• ZN 3:3 3... a'56 G" f i'eak Irit. = -O. ':)0)££ Ll) -i£o. 50£ '...Iff Peak Int. -'j. OiO)£8 N3 £31. 6'.:)4 . u-;-1 P'eak int. = -0. 0C)35 BE £34.861 -O. 0C)37 :-61 J. w-t. 3 Ml'i £57. 61 -0-'. OiOi40' FE £53. '34 -0). ':>03£ '.-)-.-> ci CR £6 7. 716 Off P'eak Int. = -01. •..)'.l3 3 ML:. .3 73.-:i7-3 -01.010)38 AL GVU'.. £11:' O-t'f i-'C"-ak iri-r, =: No Peak! 8t> LA .3 3 7. '533 -'.L '.)0)4O • Oic; G7o)£ C3 3£4.754 Off P'eak. Int. = -0. 0C)4i &14 436 AG 3LG.'.)68- -O. OO)H3 G '* 3 54 3 Calculating Cc'ncentrat ions for Sample Number £6 Elem. Wave- Net Peak Calcoiiated Interference Net Sym. length Intensity Concent rat ic^ri Ccirrect i'Z'n Concent rat i'I'ri in PI AG 3£8.068 543 0). ':)'3o' 0). C)0o) 0, O30i > BE £34.661 1361 0, 0)4 3 Ol. 0)0)0) 0, 0)43 o CD ££6.50£ 115 C). 050. 0). e)5o) o CR £67,716 133 OL 08^ C). C)84 to CU 324,754 436 01. £83 O. 010)01 O. £83 to MN 257,61 2800 O. £77 O, £77 o NI 231,604 362 O. 4££ C), 00)0) O. 4££ ZN 213,856 533 O. £40 C). C)C)C) O. £4C) AL 308.215 88 -O.086 0. 150 Analyze Samples 01-18-1988 C* 15:18:55 — 30 FE £59,94 94£ 1 . 144 1. 144 CA 317.933 57 0£ 3. 3£0 9. 32C) MG £79.079 1931 6. 3£3 6, 323 763534 MW3A Begiri Analysis - Sample Number £7 Ele. Wave— Mear, P'eak Mea.-'i P'eak ;Je-t P'c-ak Sym. length P'C'Si t i'i.'ri Iriterisity i riT ensi t y .: i-i fc-Ufc. uf- 'tak int l.i.6 CD £c:6. GOL Uff Peak Irit. No P'eak : M 3 / Ni £31. 6':)4 Off Peak Int. 475 No Peak' Gi:: £3-'4. ftbi N.:. >-'eai-' I 3^E £4£ MN £57.63 -'.1. OiO'45 30 •.-4 3 3:0)'S'3 3-7. rZ'.-Cz). ''="•: •-•7. 'i-.03w b-3Gi.i 3.3F.O Lt?!. ^^ 1 r:T . -- <:->.o 7--c-aK ' -t':iC> 17 Mi.3 ;. :'73 -•:>. 0033 I. i33M AL Uff Pea k I nt. = A 3 4 ~0. 0)0)31 ^. :.) 1 5 3 t'.i 3 GG 317. •3.33," -G.'.:)036 3':":i7 30":77 CU 3£-4. 754. • Off Peak I-nt. = 3£0 -0), 0C)£5 ^8£ 16£ AG 3£8,068 No Peak! . 375 Ca 1 Cu i at 1 rig C'l'ricent rat ions for Sample r>luiiiber '37 cn p] Elejii. Wave- Net Peak Calculated I nt er f ererice Net > Syrn. length Intensity Conceritrat 1 on Correction Concentration o o AG 328.068 375 -O. 0C)3 0. 001 < 0. 010 10 BE 234.861 £4£ C). C)C)0 C), C)C)1 < 0). 00)5 CD ££6.50£ 3£ C). 016 0, 01 6 too CR £67. 716 17 C). C)00 < 0. 010 OD CU 334.754 162 O. 086 0.001 0. 085 MN 257.61 3C)99 O. 311 0. 311 NI 231.604 7 O. 045 0. 004 0. 0)41 Analyze Samples 01-18-1988 I? 15:24:13 — 31 ZN 213.856 1 03 O. 0)45 0). 0)0). <.). 04£ AL 306.215 1601 5. 61 3 5. 61 3 FE £59.94 8350 13.953 13.353 CA 317.933 30)0)7 4. 565 4. 565 MG £ 7'3. 0)7':^ 3 334 3. '575 3. 575 763534 FILTERED MW3A Begin Plrialynie; — 'Gatiipie Niirrb.?-r" £8 Ele. T'ltari t-'eaK Meafi i-'ear- Ntt P'eak Sym. r'-::.c.i\ I'i.ri I rG eriii i t >/ .; Y:Z erii; 11 v ZN Gj 3. 8Gi: vif:' P'r-,. i: ir.t. -• 13A -OL ':>0£j 1 'riG CD ££6. 50)£ Off P'eak Int. = 3'38 N.I' Peak ' 386 -1£ Nl £3i . '3'.)4 Off Peak Int. = 450 I'J.r. P'eak ' IS B;- L.--'4 . Gl-. 1 N.r. i-'iva;^ • 3-£G L G fc MN L7'':.7.G3 --I. '..'..'M'... 3 . j..3-ii FE GG3. 3-4 -':;. 0C,33 CF 337. 7 3 G Of-; P'eak Int. = 4':..3 No I-'eak' 4 53 -A MG £7'3. '-.)7'3 -rCj. Oi'::)38 375 375 AL 3i:)8. 3lti Off P'eak i-nt. = 381 No Peak' 14 CA 317.333 -0.0)0)35 £664 :G64 CU 334.754 Off Peak Int. = 3l8 —0. 00)04 336 78 AG 3£8. ':)G8 No Peak ! 3/5 cn \ Calculating' Gc.ricerit rat I'i.ns f'l.r Sample Number L'8 pi ^ 3^ , Elem. Wave- Net P'eak. Calculated Interference Net Sym. length Intensity Concentration Cc.rrection Concentration Oo 10 AG 3£8. 0)68 375 -C), OC)^ 0, 0)00 < 0. 010 BE £34.861 226 O- C)C»0 0, OOO < 0. 005 lO ^ CD £26.502 -12 -O.0O2 < 0. 005 CP CR 267.716 -4 -0.015 < 0. 010 CU 324.754 78 C). 036 0. C)OC) 0. 036 Analyze Samples 01-18-1988 (? 15:28:41 — 32 MN 257.61 1 338 O. Ill O, 1 1 1 NI 231,604 X kl> O, 051 •-L 0^.10) O. 0)51 ZN 213,856 61 O, C)£3 Ol. OiO'O) C). C)£3 AL 308.215 -O. 364 O. 1501 FE 253.34 O. £75 0). £7'5 CA 317.333 c:<:::0'-i 3. 353 3. 353 MG £79.073 '3 7 ;:• £. 56'-i £. 564 763598 MW3B Begin Analysis - tM:iii-ip3e NumPe-r-- £'3 Ele. w a -•-.• (.i - !'-'(::^ari i-'e.5i Meari P'eak Net P'eaK S y m. 3 eriC't T'C'i. 11 1 ir-ri I rit erisi t v 1 nt eri 5-11 • ZN £13.G5G Off .Ueak int. = 130 -O.0025 43 j; CD 226.502 Off Peak irit. = 333 •No Peak' ^ 3 J:. 14 N 1 t J 3 . GO'H Off Peak irit. = 4^-3 N-o P'eai: : bOit BE £3'4. 3G1 No yr^i^]-:' MN £57. 61 -0). 00)46 .r.'7'.il 7 FE £5'9. •r'4 -O.0":)33 : '-i-^G4 CF. £67.716 Off Peak Int. = 467 No Peak! 488 MG £73. '.-)79. -O. 0037 4 335 ii.:L.--JZ. AL 308.315^ Off Peak Int. No Peak! ,4 51 7 3 CA 317.933 -O.0034 £4^:. 1'..' L'4310 CU 334.754 Off P'eak int. = 3l8 -C). O)0£5 476 .. t_'0 AG 3£8.068 No Peak' 384 384 cn PI Calculating Cc-ncentrat icms for Sample Number £3 > o Elem. Wave— Net Peak Calculated Interf ererice Net o Sym. length Intensity Concentration Correction Concent rat i ori to to AG 328.068 384 0). C)C)2 0. C)03 < 0. 010 o BE 234.861 243 0. 000 C). 002 < 0. 0C)5 OD OO CD 226.502 14 O. 008 0. 008 Analyze Samples 01-18-1988 & 15:3: ;>£ — 33 CR £67.716 i-' 1 C). C)03 O. 0)10' CU 3£4. 754 i 5G C). 083 iio)^; o. 08^:' MN £57.61 £70)17 3. 0£7 3. 0L7 NI £31. 604 3 s C). 104 i:09 0). 0-33 ZN £13. 85G 3G3 0. 16£ lOG O. 15G AL 308.£15 "i-' 3 -O.14£ 0. 15':' FE £53.34 3 -iriiEA £9.136 23.136 CA 317.333 £4310 42.153 42.153 MG £79.073 4 335 16.01 O 16. O 3 '0 763538 f-li-TERED r'u-JGB Begin Arialysis - G-.-^iiii. i .-"r Number 30) Eie. Wave- 'ir-fiYi t-'eal-; Mean P'ecik Net P'eak Sym. length :1 t I'Dn Intensity Intensi ty ZN 213.856 Off Peak Int. = 129 -01. 0)0i£3 •:EA CD ££6.S0£ Off Peal-:, irit. = .^.33* NI:- P'£-ak! I'^i i .7.3 3 . fc,:.:-! L'f f f 'tyal- J "t. Vv'.- .'fvak! 6 BE GG'i. G .3 •''.:• 3-z^i- ' £33 MN £57. Gl -^.>. -.)Ci45 ct.ur.. 1 £6£5 3 F£ 3:53. •'dA -0. 0)0i3£ l7 5'-ii 17538 CR £67.716 Uff P'eak 3 nt. No Peal-: ' -IS MG £7'3. 079 -O. •:)03'+ 4337 AL 308.315 Off Peak Int. 381 No P'eak : 333 18 CA 317,'333 -':•'. ..:)0)34 £3537 23537 CU 3£4.754 Off P'eak Int. = :. 16 O. 0o>0)6 385 t.3 cn AG 3£8. 0)68 No Peak! 376 376 PI > Calculatirig Conceritrat ic'ns for Sample Number 3C) O O to Elem. Wave- Net Peak Calculated Interference Net Sym. length Intensity Conceritrat ion Correction Conceritrat ion to O AG 328.068 376 -O.002 O.003 < O. OIC) O Analyze Samples 11^- 3 388 C" 3 5:37:37 BE £34.861 £39 0). 0)0)0) 0). 0>'.)c 0). 0)0)5 CD ££6. 5o)£ £1 o. Cn 1 ':i. Ol 1 o:.R £67. 716 -18 -O.0£5 •j . Cj \ .'j GU 3£4.754 63 O. 0)31 o. o Z]N 337 . Gl £6£51 £. 340) Ni £31.604 6 O. 0)44 ZN £3 3.856 35 O. 0)3'3 ..I. '.'.u--* AL 308. Gi5 18 -O. 3^4 3 :.:. 3 ':•:.' >--£ £53. 34 17538 £5.70G EFi 3 3 7. 3:r.3 ^:':r.537 4'..'. 8'd5 4 - :. 7;.';^; < :-:G £73. ':i7'5 'Gi-.tO'cJ FIEL::' G ; .^ e g i r. i -i ri a 3 y s i i . m p Lie. w£.i-..'t'- Mean -"I ear: -'ea^-: 1 e ri Q t h k' lO s 1 t 1 o r, .1 r11 a r I'ji 1 'c y i y ZN £3 3. 856 uff 'P't-ak 1 rit-. - I'.i'l. r 'h a r-; G7» Lc:t.. 3.jE •..-r -,- I '£-, •••r. 1 riV . - No Peak' .••3 c: f-l i Cl- 1 . >-..-• j'l :..irf Ptai' If-G.. No Peat-: • B fc. £. •: 4 . 8 fc-1 f'J.:- h' e a k. : t'lN £57.63 Nc. P'eak' .-•tit- PG £",:.'3. 'J4 rvl.;. i-'c-a!-. : 1 y-Z LR c67G 7lG Off P'eak Int. - r.4o P'eak ! MG £73. 07'ii No P'eak ' AL 3u8. £3 5 Off P'eak Int. No Peak: 384 CA 317.'333 N-:. Peak' 457 cn CU 3£4.754 p] Off Peak Int. = 314 > No Peak' 351 J- I o AG 3£8. C)68 No Peak ! 375 .:. 75 o to I Calculatirig Concent rat ions for Sample Number 31 to O Elem. Wave- Net P'eak. Calculated Interference Net Sym. length Intensity Conceritrat ion Correction Concentration Analyze Samples Gl-18-1388 (° 15:43:56 -- AG 338.068 ...n'.) BG £34.861 '.105 CD £3-G. 50i3: OiMG I.i-: fc u-- 7 . 7 3 i.- -.' . -+ I I -1 . - GG 3r'i. 73A 0) L)l£ 'NN 337. Gi :''-)£ |-J J £31. fc-':'4 :)30i Z.N ,:Zl r,. ^^' ••:• j03 P-IL .v'-'G. cZ^ -.. !- i. .r.---y -JH 1 /^ Li- 3:. '••. G3.:.. -(57 ^u.i .zz-z.oy-j -..7G' ';:. i Kl P' Bl..Af-JK i.-'e o 1 ri 1-4 ri a J y::;-1 'j: Ele. Wave— Merri Leal-., Net P'eak Svrn. leri.lf h i •-::.;; .. . i..;.ri 3 -rrf. er;t 11 -,- LN c:ir,. c'-33 LLt,. E.'JrZ Ufr P'eak i ra. L:r i i-'oat: 3 i.i . ] ':' EF £.3'4. 8fc,]. I'-i.:- -'..:-=iK ' NN LG?. Gi !--J... i'c-r,;: • GF 1..G3. 3M - !-:•;• f-'i^ai-: ' IG'-:' CR Lfc.7. 7 16 Off P'eak Int. = rJo P'eak ! 450 ML c'73. 073 r-J.:. Peak ! AG 308.315 Lift Peak int. = cn No Peal:.! PJ LA 317.333 No P'eak! > CU 3£4.754 o Uff t'eak Int. o No Peak' 354 S3 to AG 3£8. 068 No t-'eal.'! 370 370 IO oI— Ca i cul at ing C':'ricent rat i .:'ns f'l'r Sample Number to urialyze Sample-: il-3 8-r588 li- i; 36 J em. Wave- (a ic 1.1 j at ecj y. Net .••iii. 3 tr-i'in t i"i . .::.riceriv ra' j -:-<•• fc'.r.rn.-erit i-at '".M cn LG T ; 'fc.. .-. 1'.' •f.'oO lil-. -ifc.b. 'jEa 'e.-.i I • o o IO G ..13 c '.1 j a'. . r.i) Lone fc-rit r-at ions fc'r Sample Numbet' '3s (O o Lic'di. Wave- Net Peak Calculated I nter f ererice Net CJ 'Gym. leriQth Interisity Cc-nc erit rat ion Cc AG 3£8. oifc-;^ GL fc34 . OL. 1 1. 01' " ' GG G£i;.i". i'-i r-J E'.^-/ I-. 1 PG .:-.M ZN .•:i.i. G' .1 FE £53 '34 1.1 3 G! G'! 1.-. l.L .^.:••. . 7G'4 iif f i-'eal: 1 r.t . 'ri' • y 'Y tii'. AG .G3.':). '.11.;..':;- I-P-.. i^T-.'il- cn PI > Ca 3 c '.I 3 a t 1 r.ii t. ...•I'll, t.-ri I. I c.'. i.i.rit- 1i;.r '.-i.ainj. i i • '.MI.II.I- o Elem. Wavr- N,:-! Ge.4k Laicuiated G .t t:-r I ererice r- to Ml.:. s3ii. cn^^. .:./G •'.). 0)'.)fc. Ol. i.i'.iOi < 0'. 0)1'. 1 BE £34.861 £7-4 0). O)0oi OL 00)0) < 0. 0)05 o CD ££6.50£ 1 1 0). 00)7 0. 0)0)7 CR £67.716 -7 -0.017 < 0.010 CU 334.754 A3 0.015 0. 000 < 0. 025 MN £57.61 . 378 0. 001 ( C). 020 Analyze 'Sampler 38 NI £31.604 O. Oil O. 0)4 0) ZN £13.856 0). OlO)*:) OL '::).3'.:' GE £53.34 OL 0H)£' 0). ci£':) Li.-. Geuiri Arieiiysis - 3z-^iiro:^e f-iurnL-ei Ele. Wave- r-'.o-.ir: P-e.:ik T'lea.'-i i'eat- Net Peak Sym. 1 engt t - P'.i'S i r -.. on 1 nt ens its- 1 ritensi ty Off Peai: ; r-',. . 144 -.'j. '.:':i£3 yGiG L.G ££i_;.. GOu.J Uf f P'eaf: ^ r.t . 4l8 -•'j. •jCjs.7 £86£ £444 .Ni £31. 604 Off P'eak int. .Jl ^ -Cj. OiOi3£' 638^ 7863 BE w33 4.86 3 -':>. 0)'O35 £3758 :3758 r-iN £5-7. t'l -•.:i.'OOL-.fc. L"3'..it..-.- ;-3'.'C.3 PG £53-34 -';i.'.>':i£3 I45i 3 CR GG'7. 7 ifc Gf-r r-'(-ai-: ; ri-:-. - 'I 8 j - OL ::":'.:• I LU Sri'l . 7G4 (jr f (-'e^-ik .- ri-. . —'::L -. 370)4 Ai- 338. 038 -'j. '. 3G',3 G, Ll i ax 1 riD L'i'nceriT r at 1 ori; '_ a UK- J '.-:• Elem. Wave- Net k'eak Calculated I nt er f er-erice Net / /^J^C^ Syn;. lerigth Intensity Concent rat i'l.ri Cor" > ec t 1'i.ri G'i'ricerit rat i "Zit.- Alj 3£8. 068 384 3 1.914 '.I. OOE 1.31 L BE £34.861 £3758 1. 0££ Cj. OZjl 1 . 02 3 402- CD ££6. 5C)£ £444 1. O0'4 1. o)':i4 CR £67.716 £336 £, 168 £'. 166 CU 3£4.754 870)4 5, 139 01. OIOIL' 5. 137 MN £57.61 £3063 3, £59 3. £53 NI £31.604 7863 3, 404 8. 337 ZN 213.856 8818 4.054 Ol. Oii'iG 4. 043 \0(y FE 259.94 1451 1 £1.154 £1. 154 NSEA1214 1:HIGH 2:INTER 3:NSEAl£l4 4: SB STANDARD Analyze Samples 01-18-1988 C" 15:53:13 — 40 . ^?- ZN £13,856 4 316 1. 38£ I.!. 0)50) 1. 33£ AL 308.£15 17 £58 64.583 64.58 3 •-E £53.34 3G7310 £47.363 L4 7. 363 lOC L:A - 17.333 :. "7 j Oi34 3':)1.3 48 3.':).: . 3 4 0- r-'.U £73. 0 7'., .3;_•.'... /-'P.. 150.333 1 GOi. 3GG cn PI > o to w i o cn I Analyze Samples 01-18-1368 C" 15:55:05 39 •/-END: P'G UP" t'l. View W'i.re Line' Fn ICj err 'E'GCapc.-' t .:• '.-.'t.r'p '•7ni-w3NlER IN-( EKGLGMGio'; 3 Ni GRGEf Ben J ri Ari.:i 1 y:: i i — •."=.arnp i (- r.i'.imDo. fc^e. Wc..-/c- — '•"lear. P'eak Piean -'--a i-iet P'eaP P'T'ti t i.i'-n I :•.:: ar -.: \ t i rit e 11'- 1 ' 7!-J .^ i .;.. yUfc GT 1 I 'eak i nt. = -O. ';)C)£3 • -tSl I--. 33 ££6. 50)£ Uff Peak Int, = -CL C)0)36 50)4 L Ni £3 3 . 60)4 fciff Peak Int. 4 34 -0). 0)030' . fc:. 4 j'. G 3 . -'!-. O'-.-GL PG £G'3. 34 --:'.0''7:;7 Gr-; .-z33/. 716 •'eak int. = -0. '.iO)£8 f'lG L7':^.0)73 -0. 0)0'.ifc -r'.'Z /E- CF, 30ie.£i5 Off PeaG^ Int. —0>. Oi'iiG.: "t.t.-. i -• szii::- GA fc J 7 . i433 -•;'. '.)i.)fc:. :-'3'-. 3 .- 1 '.)'H4 CU 3£4.754 Off P'eak Int. = —':). 0)0)38 :.756 Calculatinn C'lincentrat i>i'ns for- 'Sample rJumber .i:6 cn PI > E lem. Wave- Net Peak Calci 1 ated Interf erence Net / \C fY\Ofi)r\ ym. length Intensity Concent rat I'^i.ri C.i.rr-ect i'Z'ri C.Dncent rat i.i.n/_£ 1 sy -J O ~ O to BE £34.861 5498£ £. 373 0). '..) 1 5 £, fc;64 /Q I CD ££6.50£ 50-)4£ £. 0G3 £.063 10 0 to CR £67,716 £760 3 . 336 1.336 ^^ CU 324,754 34 3£ £. Ci£'-:> 0). 0)£5 1,935 \00 o MN £57,61 18024 £, 0)0)6 2, 006 ^<7 sJ NI 231,604 1843 1, 997 O. 075 1. 922 103 Tat 5-^ ^A^ILL Alo /> i/^ ^^^? "^ k£X. :2/- 9/ r^-*-^ 7~t^>-/, ^<^^ jg)^;>^<^ y^ 1^ 3 t/^F?^ ^/^ IX ?^^''*- 8 i:2£_ <^^^ g^p^<^ ^^t- :?, V»^ J":^^ i^li^/? 10 fi*"5''7£> 9-7 ^7^ n« U • i*f^r yi^ 1±. J,'i.t.^7*^ ^9^4 \Z !r^¥ ^ ^c y IFPMC y*^t^y* Xh Jyr^*/ ^/, w ^^or^*^ 71 yiVir rt. \S cM/^^ ^1 /^Z: (6 ^ ^^ AV4^ ^ 17 ^f^ ^1 <^^^ ^!^FPH <- ^'^ U' >.^ le J^ ff? ^^^ w tise. rn- 2X Zo I^h. ^ i>^> 9.Pl> Mc f^'^/J i/^ 21 /^2- ^: i,a ^ 2Z Jl ^ir ^/'Z.- !£. fr-u ^ ^ 23 ii»/ ^ /^ ^IPPJ//:^ •r-j^rf. }J^Jr ZH r/^o A^J ^ <^^ 2S lU- ?z- l2^:2k^,/• ^ Z6 cJjfU ^. I e> Zl JiAIUc ^L l> O 21 ^^^ ZfP/f^ y^ W S ^ -fl/tfir^cL ^/^ 30 TzTT^ r^ i'' cn p) f > o f o t— O OD -* * Pj)^^— IMic //7£V?? 7r«y Ai. L Test £L Cwp UeN3«. lUwVt"" }\ 7/15-^^ ^^^ 7 /^PDAJ^ Myfi^ 1^ A'li-^*^*J ' IZ J up r^^ ^^^ • 1 33 ^z- ^•L'/^tc ^_ y\ i*^/*-/"f ^ ri ^.'•^r-f*./ : /S" rty A L^ y pPTiAlf yuii^j^ ^rZ-h^^^J ^ J^ rf4f ^^^ ?7 H»0 n ¥ 6^ 6 ^V^y e^ 78 cJl/^ ^^^ >^ -^.) ;/w^ ^/^ *fO ^-fg- ^^^' y^ppMc^ y^ t^ 1^ ^/ fK^^/ W\ J^r^^ ^/^ 7 4^ 9^ ^JVZ. r**^^ H3 L^S 9/ 9/'/: r-cc- 7-i^ = / ^ ^ *H c^l/^^ ^^^ 45- J.^J/^ ^i:*^/? y ^ ^ <^ li 2t> ^ 42*^ 24 ai r^; ^ • ^ 1 ^ • • 1 - ; ri to to • I- , 1 ^ 1 • I . ^(i I t \ < '^ Si t^ ± sk. i~k S|=>^c:-br^<^^ 3 O / •<* O ' l=» cz> r^ -t OPERATOR WILLIAM -ITTERER DATE 01 -19-88 BATCH NORTHSEA #14 TRAY #1 PROGRAM 5 Sb SAMPLE CONC •/.RSD MEAN READINGS UG/L ABS BLANK 0 0.014 0.014 STANDARD 1 20 0. 0 0, 123 0. 123 STANDARD ^ 40 0. 0 0.227 0.227 STANDARD •2* 80 0.0 0.471 0.471 STANDARD 4 120 C). C) 0.678 0.678 STANDARD 5 160 0.0 0.786 0.786 8.3b5 COiiCEHTRATION UC/L SAMPLE 1 1 0.0 0. 008 0.008 SAMPLE 2 0 0.0 0.001 0.001 ^ SAMPLE 91 C). <;> 0.532 0.532 cn SAMPLE 4 99 0). c> 0.574 0.574 PI SAMPLE 5 —/ r 0), 0 0). (:)42 0.042 > _'n SAMPLE 6 0,0 -0.010 -0.010 o SAMPLE •7 9-3 0). 0 0.544 0.544 o SAMPLE a -1 0, 0 -0.006 -0.006 to SAMPLE 9 Ci o>. 0 0. 001 0,001 SAMPLE 10 87 0. 0 0.510 0.510 SAMPLE 11 89 0!, 0 0.522 0, 522 SAMPLE 12 -1 0. 0 -C). <:)04 -0. C)0)4 SAMPLE 1 -3 -1 0. 0 -0,005 —0, 0)0)5 SAMPLE 14 76 0.0) 0,445 0,445 SAMPLE CONC 7.RSD MEAN READINGS UG/L ABS SAMPLE 15 0 0.0 C). C>02 C). ox:) 2 SAMPLE 16 -1 0. 0 -0,008 -C), 008 SAMPLE 17 -1 0,0 -0,007 -0.007 SAMPLE 18 -1 0. C) -0.005 -0,005 SAMPLE 19 79 0. 0 0. 468 0.468 SAMPLE 20 6 0.0 0.038 0.038 SAMPLE 21 •jl C), 0 0.017 0.017 SAMPLE T^T* 95 0.0 0.554 0. 554 SAMPLE 23 -1 0.. 0 -0.005 -0.005 SAMPLE 24 -1 0.0 -0.008 -0.008 SAMPLE 25 92 0.0 0.539 0.539 SAMPLE 26 0 0. 0 0.000 0.000 SAMPLE 27 -0 0.0) -0.003 -C). C)C)3 SAMPLE 28 -1 0.0 -0.006 -0.006 SAMPLE 29 —C) 0. 0 -0.003 -0.003 SAMPLE 30 52 0.0 0.298 0.298 SAMPLE 31 -0 0. Cl -0.002 -0.(:)02 SAMPLE 32 -1 0. 0 -0.004 -0.004 SAMPLE 33 52 0.0 0.299 0.299 SAMPLE 34 51 0.0 0.293 0.293 SAMPLE 35 —0) 0, 0 -0.003 -0.003 SAMPLE 36 0 0'. 0) 0.000 C). OOC) SAMPLE 37 64 0. 0 0.373 0, 373 SAMPLE 38 -1 0. 0 -0.005 -0,005 SAMPLE 39 -0) 0). 0 -0.001 —C». 0)C)1 SAMPLE 40 -1 0.0 -0.005 -0.005 SAMPLE 41 -0 0. 0 -0.002 -0.002 SAMPLE 42 96 0.0 0.561 0.561 SAMPLE 43 91 0. 0 0.528 0.528 SAMPLE 44 1 0.0 0.004 0.004 SAMPLE 45 C) 0. 0 0.001 0. C)01 cn P: > o o to to P|*-c_ /^^. i. rc^ Jl. << Cwp Ub »0o. Rew\t -lU ^ct fl^C. ijorfhsea^ I coJ,lg(M/ <{0 /its 5d i MhT 3^ 8 530 MW 5 0 12. n n_ fOT^ j:t: \z_ __5ao MM 36 13 W 1^ < (o r NH SO 16 I I T" ^9- (^UcjO^d • « IL hJhJ 5A 21 } 23 b/n»c MH in- ft 2V 26_ il 21 (KM 3B i6 cn >PI gOVorr^^ o 30 o to <10 to < 10 I— ^ lo to a C^ / . A m ^ t I ^^-» - - SF> f=f' •fc I - .^ r^-^ ~ ''!> /" -a <_> S v.^ ^ -t ^ rr» F;.- tS' P:>. <-> r~ -fc OPERATOR MONI tOA DARRON DATE 01-16- 38 BATCH NORTHS — f-l 14 TRAV # 2 PROGRtH M 4 Tl •?A)-ip!. E CONC ::P3r' .'•lEAri REA.niNGS UG/L AB'o B!. ANL t:i 0. ':.'2.3 0. 023 'Sr^cWiAFD 1 ] 0 0. 0 0"', 0'^'5 Ol. CjQ^i r-TAND7-iR'D 3 -30 0. '-' 0 .302 0. 302 ""^ANDAPD 3 40 Ol. Oi 0. 4 23 0.423 STANDARD ^ 60 'Zj. 0' 0.31^ 0.614 ST-NDARD 5 SO 1'. '' 0.87 3 0.871 I I ft i B I c I ' i COHCENTRflTlON UG/l 8b SAMPLE 1 -(.) 0. Oi -0. 0)0 c> —0), o)Or:i SAMPLE •-n o» 0. 0 0.003 0.003 SAMPLE -T_ 49 0. 0 0.511 0.51 1 SAMPLE 4 53 0. 0 0.525 0-525 SAMPLE 5 -0 0. 0 -0.0)02 -0. C)02 cn SAMPLE 6 —O 0. 0 -0.004 -0.004 PI SAMPLE 7 17 C). 0) 0. 160 0. 160 SAMPLE e 1 0.0 0.008 0.008 o SAMPLE p —r:) C). 0 -0.003 ~0. 0)0.3 o to SAMPLE 10 17 0, '•) 0. 167 0.167 SAMPLE 11 16 0, 0 0. 159 0. 1 59 to SAMPLE 12 -1 0. 0 -0.006 -0. C)C»6 SAMPLE 13 -0 0,0 -0.002 -C), C)02 SAMPLE 14 14 0.0 0. 132 0. 132 SAnr-'i F; CONC .P3I7 f-'-y.[- RFA.OJfji-^f !JG.'I SAMPLE :r. o 0) '.>'>i 0, 001 SAMPI. E 3 to —C) i:.i ' *'-)2 -0. C»C)2 SAMPLE ]7 13 Ol 12^^ 0. 126 SAMPL E IS 16 3 50) 0. 150 SAMPLE ] *^' -C> o')0) 3 -0, C)01 SAMPLE 20 ] (.1 0)07 C). C>C)7 SAMPLE 2 5 1 C) CiCif-i ' 0), C)C)8 SAMPLE 22 —<:) -C). 0)0)2 SAMF-'l.F 2-'- 34 0. 3 36 SAMPLf: 2'^ —0> -0. 002 SAMPI r 2'- — 0' -0'. OlO"2 c,'ir.ic:-i r ••., 1 A 01. 1.7:3 SAMF-LE : - — Cl -o.C":)] SAMPLE 2:- -0) -0.002 5AMPI..F 2'-- J -^ I 1 ?' 0. 115 •zi'-iF.p-i. E "-••' 1 OL i:)05 SA!-ir-i„F' ~' -3 -0. '1>07 3zy--i f. ~ z -'•:L 001.2 r-.-^Z'r'l iZ ''• ~ -3 -O". C}Cj7 SANFi. E ~ •'- 1 2 0. 13 3 ",A!-;F'i ,.E Z'-'^' — (I -'.•). <:)':) 3 zZyrFL F -/•- Cj <:). C)o)o) SAMPLE 3-" 2'Zi o 1<^'4 0.394 SAMPI, E 38 -1 Cj OOS -0. o)<:)8 SAMP'L.E 3'-- -(-) o O'O'l -0'). (:)04 SAMPLE a.'- 19 0) 0. 186 SAMP!. E ^ ; — Cj 0) -0. 002 SAMPLE -2 Cj ('W 11 0. C'Oi] SAMPLE -•• 45 J7a '-'. A"C Ul PI o to to u\ Ka *-• '^ Tr4y N4.^J=. Test r*— Cwp UbfO«. Re^ult*"^ 1 0 0 .10 '•- - 1— •- M 7 1 cn , Tr.y ^. 3 Text 5^ J*"* 3>^ '/ ffi<^^ u A^y» X/'/^/y: e.f rfU Act. «i»t. A/Scc^^/U. ^» Hos9o /f /CofAA- A WcV . Af7fZ*/»^VuJ»-C, Jl 7t3t5^o ^r 33 tXy,^9x> ^^ K^bUC 3i -tio S90 fl ftof/C4^ t FS- C^hL^L ^>- ?^ Jx^-U^ ^5r u 37 r^3S^£f 4r 38 />upS9^ 4r ftPJ>*f<- u ?*1 •f/o.S9^ fl noiroK. 4o 7(>2>S9<6 ^5 • HI A^5"f€r ^5" kfONC- v!/ ^2 •//o-5fg M no'f'YLA^ <^3 ^0U.^^a.L. ^i- HH % -^.4 ^fT iL 11 20 - ^ L4 21 22 u 23 ZH L4 2? .,> •", 26 U 27 28 14 21 {^ ^ 30 1 cn i - (Tl — > i 8 L to to ^ 1 •- • V* . ..-.;,. ---'. 'A.^^* ,_, .r.?V'.«L^.:-*»- •••^ '".. '•'^WC. fa--...T-;-f, v,/ .=n r- i .SU m S i=> ^ <= -fc r- ^ «==» 3 O / -^ O S v s -fc e? m F=;: «= p> c=> r^ -fc OPERATOR N.NAMBOODIRI DATE 01-10-88 BATCH NORTHSEA # 14 TRAY # 1 PROGRAM 2 Se INSTRUMENT MODE ABSORBANCE CALIBRATION MODE CONCENTRATION MEASUREMENT MODE PEAK HEIGHT LAMP POSITION 1 LAMP CURRENT (mA) 5 SLIT lAJIDTH (nm) 1.0 SLIT HEIGHT NORMAL WAVELENGTH (nm) 196.0 SAMPLE INTRODUCTION SAMPLER AUTOMI XING TIME CONSTANT 0. C)5 MEASUREMENT TIME (sec) 1.0 REPLICATES 1 BACKGROUND CORRECTION ON FURNACE PARAMETERS STEP TEMPERATURE TIME GAS FLOW GAS TYPE READ NO. (C) (sec) (L/min) COMMAND 1 75 5.0 3.0 NORMAL NO ^ 90 2. 0 3. 0 NORMAL NO TT 105 30. 0 3.0 NORMAL NO 4 120 30. 0 3.0 NORMAL NO cr- 700 5.0 3.0 NORMAL NO 6 700 ! 5. 0 3.0 NORMAL NO 7 700 5.0 0.0 NORMAL NO 3 2400 1. 1 0.0 NORMAL YES 9 2400 .. 2.0 0.0 NORMAL YES 10 2400 1,0 3.0 NORMAL NO SAMPLER PARAMETERS VOLUMES (uL) SOLUTION BLANK MODIFIER cn 10 t*i BLANK 20 > STANDARD 4 16 10 STANDARD 8 12 10 o STANDARD 12 8 10 o STANDARD 16 4 10 to I STANDARD 20 0 10 to SAMPLE 20 0 10 03 RECALIBRATION RATE 0 RESLOPE RATE 45 SAMPLE COt-JC RSD MEAN 'READING UG/L ABS Bt ANK 0 0.012 0.012 STANDARD 1 20 0. 0 0. 291 0. 291 STANDARD o 40 0,0 C'. 650) 0. 650) STANDARD -T 60 0,0 0.'=24 0,924 STANDARD 4 80 0, 0 1 . 154 1.154 STANDARD 5 100 0, (.-) 1 . 342 1 , 342 ^r? r e I « 338 Li: I^UNitHlftHllOH UG/L u« SAMPLE o» 0. 0 0. i:)i:'7 0. OCj7 Si'iMPLE 0 0. o Oi. ooi.s 0. 00)6 SAMPLE 5] 0.). 0 i:). 808 0. SOS SAMPLE 0.0 0.811 0.811 SAMPLE 0) 0. 0 O. CjCj.': 'j. O0)6 SAMPLE O 0.0 0.004 0. ox:) 4 SAMPLE 7 11 0.0 0.165 0. 165 SAMPLE fi 11 0.0 0. 168 0. 168 SAMPLE Q 1 0.0 0.013 0.013 SAMPL..E 10 o 0.0 0). C)05 0.005 SAMPLE 11 11 0.0 0. 160) 0. 160 SAMPLE 12 0 o.o 0.006 0. C)C)6 SAMPLE 13 0 0. 0 0. 0C)6 C), 006 SAMPLE 14 11 C), C) 0. 164 0, 164 SAMPLE 15 1 0,0 0. OOP C). 'I) (I) 9 SAMPLE 16 0.0 0.005 0.005 SAMPLE 0) 17 0 0.0 0.004 0. 004 SAMPLE 18 0.0 0.004 0.004 SAMPLE 0 IP 11 0.0 0. 161 0. 161 SAMPLE 20 0.0 0.009 0.009 SAMPLE 1 21 C) 0. (.') 0.005 0.005 cn SAMPLE 11 0.0 0. 166 0. 166 PI SAMPLE Cj 0.0 0.005 C». C)05 SAMPLE 24 0 0.0 0.006 0.006 o o K) to I— OO SAMPLE CONC 7.RSD MEAN READINGS UG/L ABS SAMPLE 25 11 0. 0 0, 170 0. i7<:) SAMPLE 26 •0 0.0 0,004 0.004 SAMPLE 27 0 0.0 0.007 0. 0)07 SAMPLE 28 1 0. 0 0.009 0.009 SAMPLE 29 0 0. 0 0.006 0. CX»6 SAMPLE 30 10 0.0 0.152 0. 152 SAMPLE 31 11 0.0 0. 176 0. 176 SAMPLE 32 1 0.0 0.012 0,012 SAMPLE 33 0 0.0 0.005 0.005 SAMPLE 34 11 0.0 0.163 0.163 SAMPLE 35 1 0. 0 0. 008 0. <:)<:) 8 SAMPLE 36 1 0.0 0. 010 C). 01C) SAMPLE 37 0) 0.0 0.006 C). 0)06 SAMPLE 38 1 0.0 0.008 0. o)<:)8 SAMPLE 39 11 0.0 0. 162 0. 162 SAMPLE 40 0 0.0 0.005 C). (:)(:)5 SAMPLE 41 Cj 0. 0 0. C')C)6 0. 0C)6 SAMPLE 42 11 0.0 0. 160 0, 160 SAMPLE 43 0") 0. 0 0. (r)C)7 0. 0)r.-)7 SAMPLE 44 0) 0), 0 0.006 0, 006 SAMPLE 45 '^6 0, <:) 0.729 0. 729 cn PI > o to to too Tr*Y H*. 'y' £^ Cwp 'Ub rOo- fUtult 4U 4«ct- •k>«. Mfflit^il. CALSiAtnL .^£. oi6,6c/^< A£. CCS 52- TY^^O 104 %eac ^^^/XS 53 iY:. Cwp UbfOo. fUtaVt*"^ 31 :7(.35^5? /^ C? % £/^ rhLL> ii-^g VL tZo6^^ 14- =^o %e6c V/ 33 ^H6«)Z ^^ \ SZ) 9/^(lfi Fieib AiftNJk. ^ ^oz. ^,0 / • 3r -rZO ^02^ za ii^%e6c I ^ ^z, 5^,06, ^5" \ o. ^ T(t\P ClAlOi^ 37 bob ^^ ; «r 1 3>8 -rTo^dh 2t io5%e6C. ^f- 5*^ (AL6tAtJt- ^^ 40 biei5u¥Ji^ . ^5- m ^?te^'a^4 I30t< Ira J3 \ %2M "^p.^jiM N^i^n m/iS^/g 42 ^ //O /v IO // / > 1 43 w ^4 24 \ZO Vobc \ .^ c-^ ••• ^ 4S tcs ^ 2^ •-:. 26 27 26 r : in 21 PI . 30 r-•' 1 § ^- 1 • 1 H 1 1 ^ \ ^ 1 . •• * kiri-4 iEffu^'.ri -st.r-' 1. st.1 '<=. -fc 1-^*=%*=% 3-.0 / -^O •t^mi Ft ^ f=> o r-'-fc OPERATOR PATTY PATAK DATE 01-14-88 BATCH NORTH SEA 14 TRAY # 1 PROGRAM Pb INSTRUMENT MODE ABSORBANCE CALIBRATION MODE CONCENTRATION MEASUREMENT MODE PEAK HEIGHT LAMP POSITION 1 LAMP CURRENT (mA) 5 SLIT WIDTH (nm) 0.5 SLIT HEIGHT NORMAL WAVELENGTH (nm) SAMPLE INTRODUCTION SAMPLER AUTOMIXING TIME CONSTANT 0. <:)5 MEASUREMENT TIME (sec) 1.0 REPLICATES 1 BACKGROUND CORRECTION ON FURNACE PARAMETERS STEP TEMPERATURE TIME GAS FLOW GAS TYPE READ NO. (C) (sec) (L/min) COMMAND 1 75 5.0 3.0 NORMAL NO '7 90 2.0 3.0 NORMAL NO -T 105 20.0 3.0 NORMAL NO 4 120 20.0 3.0 NORMAL NO 5 400 5.0 3.0 NORMAL NO 6 400 15.0 3.0 NORMAL NO 7 400 2.0 0.0 NORMAL ,N0 8 2000 1.0 0.0 NORMAL YES 9 2000 2.0 0.0 NORMAL YES 10 2500 1.0 3.0 NORMAL NO SAMPLER PARAMETERS VOLUMES (uL) SOLUTION BLANK MODIFIER BLANK — 10 STANDARD 1 1 9 STANDARD '^ 3 7 STANDARD ^ 4 6 STANDARD 4 6 4 2 STANDARD 5 8 2 SAMPLE 10 0 RECALIBRATION RATE 0 RESLOPE RATE 11 '•'^ <=^ r-- i .s* n -fc r-- <^ ^ 3.0 / -^ O ;v >m ^ *=> C3 r- -fc OPERATOR PATTY PATAK DATE 01 -14-88 BATCH NORTH SEA 14 TRAY # 1 PROGRAM 3 Pb SAMPLE CONC 7.RSD MEAN READINGS UG/L ABS BLANK Cj 0). C)2<:) 0, 020 STANDARD 1 10 <:>. 0) 0. 096 0,096 STANDARD 'Tl 30 0. <:) 0. 246 0. 246 STANDARD T; 40 0. C) 0.311 0,311 STANDARD 4 60 C), 0") 0.451 0,451 STANDARD 5 SO '.:). C) 0.595 0.595 CClNCEHTRftTIOK UG/L Kb SAMPLE 1 0. 0 0. 006 0. 0)0)6 SAMPLE O 0. 0 0.001 0.001 SAMPLE 0, 0 0, 395 0.395 SAMPLE 0, C) 0.402 0.402 cn ; SAMPLE OVER 0, 0 0.664 0.664 SAMPLE OVER 0. 0 0.652 0.652 \ SAMPLE OVER 0, 0 0. 739 0.739 O 1 : O ', ! SAMPLE 8 87- 0. 0 0.643 0.643 to ', I SAMPLE 9 88 C), SAMPLE 13 1 0. C) Oil 0.011 SAMPLE 14 17 0.0 160 O, 160 SAMPLE 15 1 0.0 010 r:). 0) 1C) SAMPLE 16 1 0.0 012 0.012 SAMPLE 17 17 0. 0 160 0. 160 SAMPLE 18 21 0.0 186 0. 186 SAMPLE 19 C) o. o 002 0. 002 llgibiEit yvi^axJy^jOjM^ (jiMP^-^ uxyyK OMJIW^^ CTA- SAMFLr2 24 O. . Cl 0. ^> I 7 0. 0 1 7 SAMPLE 25 1 0. 0 0.011 0 . C) 1 1 SAMPLE 26 17 0. 0 0. 174 0. 174 SAMPLE 27 6 0.0 0. 063 0. 063 SAMPLE 28 5 0. <:) 0. 054 0,054 SAMPLE 24 0. 0 0.231 0,231 SAMPLE ZO (:i 0. <:) 'j. 0)0)2 <.'). 0)0)2 SAMPLE 31 -0 0). 0 -<:». 0)03 -0.003 SAMPLE 14 0. 0 0. 144 0. 144 SAMPLE A 0. Cj 0.044 0. 044 BLANK 0 -0.006 -C). C)06 RESLOPE 30' 0, 0 0.214 0,214 SAMPLE 7 0. 0 0.053 0, 053 SAMPLE 0. 0 0. 194 0, 194 SAMPLE *.6 0, 0 0.019 0.019 SAMPLE 37 0, 0 0.024 0.024 SAMPLE 38 24 0. 0 0. 177 0. 177 SAMPLE 39 — 0) (.-). 0 -0. o«:»o —0. <:)0<:) SAMPLE 40 0. 0 0.013 0.013 SAMPLE 41 13 0. 0 0. 106 0. 106 SAMPLE 42 11 0. (.') 0.088 0. 088 SAMPLE 43 37 <:). 0 0.254 0.254 SAMPLE 44 55 0). 0 0. 353 0.35t5 BLANK Cj 0. 004 0.004 RESLOPE 2-0 0. 0 0.222 0. 222 SAMPLE 45 54 0. 0 0..3.64 0.364 A cn PI > o o to to to cn P^... 1^ / / ^fu ^ 7c/t Pb J.iU wwp ^^^^J^f^tS&oJffflffi/^"k I »c6t/iAJ^ i£ CX^^t/toiK ^35%? j^ A/6^/4r) to to 1 V-' .^. I— i c^ f-» ; p> ^ cr -fc r- «=^ «^ 3 <_> / -a t-> v •m • !=> cz> r^ -fc ^z It OPERATOR MONIKA DARRON DATE 01-14-88 BATCH NORTHSEA 16 (+44 i'. 14) TRAY PROGRAM 3 Pb SAMPLE CONC y.RSD MEAN READINGS UG/L ABS BLANK 0 0. 028 O. 028 STANDARD 1 10 0.0 0. 1 09 O. 109 STANDARD •-» 30 0. 0 0. 254 0.254 STANDARD "T 40 0. 0 0. 334 0.334 STANDARD 4 60 O. 0. 0. 4 7:- 0. 4 72 STAMDARD 5 - SO Ol ^ .'. 0. 589 '•).5S9 •.> ^ ' r. r— ! s ; E c I I / .? {-88 kl. iONCENISfiTION UG/L 88 SAMPLE 3 -0 0.0 —0 . OlOiO) -0. 0)00 SAMPLE r* —0 0. 7' -OL 170)01 • .1, '.lOiO) "T cn SAMPLE 48 0. •:• 0. 391 0'.391 PI SAMPLE 4 46 0. <:) 0. 380 0,380 SAMPLE 5 6 0. 0' 0. lift ] 0.O6J o SAMPLE 6 T' Oi. 1' ''. ':)26 0. 026 o SAMPLE -7 4 li. • ' 0;. 1 '45 11, Ol4 5 to C; Q SAMPI F, ' •'. ' ' 0). ] 0)0i SAMPLE C.- 1 H '. -'. -' . . ; ---. • .. .1 7S K) SAMPL E 1 '-' 28 0. '•' 1). 244 0. 244 to 03 SAMPLE 1 1 36 0.'' i'j. 303- O. 30)3 BLANi: 0) 0. 0)06 0). C)06 RF.SI riF'E —ri ,-. .-. ••' -.-r^ —- SAMPLE CONC •'.RSD MEAN READINGf S UG/L ABS SAMPLE 13 12 0.0 0.117 0.117 SAMPLE 14 34 0.0 0. 256 0.256 SAMPLE 15 34 o.p 0.255 0.255 SAMPLE 16 1 0.0 0.012 0.012 SAMPLE 17 -1 0.0 -0.OO6 -0. o<:>6 SAMPLE 18 0 0.0 0.002 0.002 SAMPLE 19 (•) 0.0 O.C'OS 0.005 SAMPLE 20 J 8 0). 0 0. 158 o. 158 S^MPl E 21 "i 0), 0 0,010 0.0)10' SAMPLE '>'? C) •:>. 0) 0, 0>O4 0. O0i4 FEFiNt- '•' -0.008 -0, O'OS RESLOPE .30) 0). S.^MP' E .T i'' 2.3 ' • . .'.'• 0, 198 0. 193 SAMPLE 31 • OVER ':-. 0 1. 3S5 1 . 385 'T CAJ<\+ onr\' ^o^ e*^ SAMPI._E -T'n 1 0. 0 0.011 0.01 1 SAMPLE •?"T 11 0). 0 0. 106 0. 10»6 BLANK •:.) 0.003 0. Oo)3 RE5L OPE 30) '0. 0 0.258 0.258 •-.%i-iF-; fc- 34 '-Z- 0'. o 0, I'OO 0. 1 Ol'j SAMI-'L f: -? cr ^.-. 0-. ij 0.276 0. 2~.t. '-.AMF'LE 36 21 0. Cj 0. 197 0. 197 ~T^ 4 cr Cl . i"-, SAMPLE 1 . • 0. 152 0. : 52 q,:.,riPL.F -.;- -' • Cj '-.'. '1 0.322 A. 322 ' 1. ' ' •SAMPLE ^. •-*' "^^ 0). 0)3-.f' 0. 0)3>:> '2MMLL£ --) 0 "•^ '.,.', 1 C).031 0. OZl •SAMPLE Al ]'=^' '.). 'j 0. l&S 0. ISti 'l^iAMFI F 42 ..:i 0. 0 0. C)05 0.0)05 SAMPLE 4 3 i J Oi. ''.1 0.001 0). O'O)1 ::;,-iLL-!.F 44 cr-y o'i. 0 0.435 0.435 BL-^f-ll Cl 0.014 <:).'.) 14 RESLOPE 3'."' o. 0 0.247 0.24 7 2Mrir'L.-P 4^1 —-r.'Ot'T— —0. •:• 1 f cn PI > o to to to OO ^hf^'^ V r/jrt Tr*y Ut X Test ^ 3^*^ TD-tc r ^^ /if&^it/i^ — Cwp 9^\t*^ il'J ^ct- [ /^-y^^iuUL ^\o z Z>^-ALJ, ^\a ' i 1 kcs. -7i/>tfT> 1 3 4f fr/vecc 4 tfflc-i ^9 1f/'flCC fi/'-i-ro 1 6" y^zs^D CJ 1 I J 1 V^na^r^x^n Sf=> -fc r-~*=**=* 30/-^0 !-v"^-t€=m R."^i=> OPERATOR N.NAMBOODIRI DATE 01-09-88 BATCH NORTHSEA # 14 TRAY # PROGRAM 1 As INSTRUMENT. MODE ABSORBANCE CALIBRATION MODE CONCENTRATION MEASUREMENT MODE PEAK HEIGHT LAMP POSITION 1 LAMP CURRENT (mA) SLIT WIDTH (nm) '.). D SLIT HEIGHT WAVELENGTH (nm) NORMAL '5AMPL F INTRODUCT ION ALITOMIXING TJME COrJSTANT SAMPLER MEASUREMENT TIME (sec) REPLI GATES BACLRRGUND CORRECTION ON FURNACE PARAMETERS STEP TEMPERATURE TIME GAS FLOW GAS TYPE READ NO. 1 -TCT 5. 0 3. 0 NORMAL NO ,2 90_! 2. Oi "T; C) NORMAL NO ~T; 105 3o). 0 "7 C' NORMAL NO A 1 20 .30. 0 — . 0 NORMAL NO cr 8o)0 5.0 -r Ol NORMAL. NO 6 Si-.)':.) 1 5. 0 "T; . 0 NORMAL rjn •^ S0)o:) 5. 0 0 l") NORMAL NO s 2500) 1. 1 0) Oi NORMAL YES 9 2500 :, 2. 0) 0 Cj NORMAL YES 10) 2500 1. 0' .;. " - . 0 NORMAL NO SAMPLER PARAMETERS VOLUMES (uL) SOLUTION BLANK MODIFIER cn BLANK — 20 p] STANDARD 4 16 > STANDARD 8 12 STANDARD 12 8 o STANDARD 16 4 to STANDARD 20 C) SAMPLE 20 C) to CJ to RECALIBRATION RATE 0 RESLOFE RATE 4 _C'. SAMC'LE CONC XRSD MEAf-j REAP I L:?? UG\L ABS BLAWt 0 0'). o'oiS 0. 'jiyE- STANDARD 1 20 0). '•' 0' .Tit 0.316 STANDARD •-> 40 0. '--' 0. 6'~'3 0.693 ^-TANDARD — 60 O. '•' 1 .'-:'22 1 . 022 STANDARD 4 8':.) Ol. •-' i • 3-7''' 1 . 33'.:' STANDARD 5 lOiOl '-' • ' ' 1 . 586. 1 . 5S6 ,-^ ^ I U ! 'J ti(*? kiL: ':OHC£HT'"WI!0>I '-.'V L .•^iAMf-|_E J SAt-IF'l. F 2 SAMP'L.E 3 Si%MPLF -i S,':,MF-i .F '^- '~-0'M'^-;.E -.- •:-.f^MR! F - •:AMF; f- -^ •:^.AMF L F •= -.^.MPLF I" BAMF'LF 1 : •-'..iMF-i F. ; 2 SAMPLE :3 SAt-lPLF ! -^ SAMPLE If: SAMP!. E 1 t- 5AMPLF 17 •SAMPL F SAMF'LF S»:,MPI F SAMPL E S,-,MPO E iAMPLF '-AHFl F SAMPLE CONC y.RSD MEAN REAP I .'-JGS UG\L ABS '-%er SAMPLE 2r. -'. _•. -_i 0. 375 SAMPLE 26 1 0 . Oi 0. Ol 1 5 0.015 SAMPLE r^T 1 0' '-) .013 0). 01 3 SAMPLE 28 '"• ."t . 0 0.025 '0. 0)25 SAMPLE 2 cn PI > o to to rg^- 3Ji«LC Test /fjS. ^ / 7(^ga Ai>,iy,t ^'/<^y,. << Cwp Ub ro«- R*io\t *kt. /i/'^c^^/4. •hgHs .. 3 LC&. 4ri ^2-//gfr 'T 7b3>^o 6 />t^ g-?o -^ / C7C> UPPKJC^ 7 t2.a'S^O /09-/.fL6t. 8_-^>2t?-S-9o <^ y^3Sr9o 10 A^.g-^o <^/PO y /o /WliKfic •2.0 cn PI o to to CJ cn V<=«i r- i ann S|=> e?ci-fc r^<^^ -30/-^O •!yi Ft ^ f=> CD ^^ -fc OPERATOR N.NAMBOODIRI DATE 01-09-88 BATCH NORTHSEA # 14 TRAY # 2 PROGRAM 1 As INSTRUMENT MODE ABSORBANCE CALIBRATION MODE CONCENTRATION MEASUREMENT MODE PEAK HEIGHT LAMP POSITION 1 LAMP CURRENT (mA) 5 SLIT WIDTH (nm) 0.5 SLIT HEIGHT NORMAL WAVELENGTH ';nm) 193. 7 SAMPLE INTRODUCTION SAMPLER AUTOMIXING TIME CONSTANT 0.05 MEASUREMENT TIME (sec) 3. 1 REPLICATES 1 BACKGROUND CORRECTION ON FURNACE PARAMETERS "EP TEMPERATURE TIME GAS FLOW1 GAS TYPE READ (C) (sec) (L/min) COMMAND 75 5.0 3. 0) NORMAL NO 90 2. 0 3. 0 NORMAL NO 105 3C). 0) 3.0 NORMAL NO 120 3C). 0 3. C) NORMAL NO 800 5.0 3. 0 NORMAL NO 8C)C) 15.0 3.0 NORMAL NO 800 5.0 0. 0 NORMAL NO 2500 1. 1 0. C) NORMAL YES 2500 2. o> C). C) NORMAL YES 10 2500 1.0 3.0 NORMAL NO SAMPLER PARAMETERS VOLUMES (uL) SOLUTION BLANK MODIFIER BLANK 20 10 STANDARD 4 16 10 cn PI STANDARD 8 12 10 > STANDARD 12 8 10 STANDARD ,4 10 o 16 o STANDARD 20 Cj 10 to SAMPLE 20 r\ 10 to CJ RECALIBRATION RATE 0 cn RESLOPE RATE 45 SAMPLE CONC •/.RSD MEAN READINGS UG\L ABS BLANK C) 0.011 0.011 STANDARD 1 20 0.0 0.262 O. 262 STANDARD *-^ 40 0. 0 0.656 0. 656 STANDARD *T 60 0.0 0.970 0.970 STANDARD 4 80 0. 0 1.244 1.244 STANDARD 5 100 0. 0 1. 509 1, 509 . oeo I I I ft .-I n .^ P. t'rc COHCENTRAIION UGvL lie SAMPLE 1 Cj i'j , 0 0. 000 0). OiOO) SAMPLE -y —0 C), C) -0.002 -0). 0)02 SAMPLE •^ 51 0, 0 0. 828 0.828 SAMPLE 4 51 0. 0 0.834 0.834 SAMPLE e; 1 0.0 0.014 0.014 SAMPLE 6 1 0. 0 0.017 0. 01 7 SAMPLE 7 21 0. 0 0.280 0. 280 SAMPLE 8 20 0.0 0.261 0.261 4 SAMPLE ,o .1 C), 0 0. 015 0. 015 SAMPLE 10 -0 0.0 -0.001 -0. 0)0)1 SAMPLE 11 20 0.0 0.260 0. 260 SAMPLE 12 Cj 0.0 0.001 0. o')C)l SAMPLE 13 —0 0. 0 -0.001 -0.001 SAMPLE 14 24 C). 0') 0.332 0.332 cn PI SAMPLE 15 -0 0. 0 -0.001 -0.001 > SAMPLE 16 -0 0. 0 -0.002 —C). C)C)2 SAMPLE 17 —0) 0,0 -0.001 -0. C»01 o SAMPLE 18 (;i 0.0 0. 000 0. 000 to SAMPLE 19 19 0.0 0. 250 0, 250 SAMPLE 20 -0 0, 0 -0.003 -0,003 K SAMPLE 21 -0 0, 0 -0.002 -0.002 L SAMPLE r^*? '-^T 0,0 0.314 0.314 SAMPLE 23 18 0.0 0.243 0.243 SAMPLE 24 -0 0.0 -0.002 -0.002 ^v^r^i n^ li,U ,JUllM^ hM^\f^t JL^ksaksssk*' ^ Cwp UbN)« Retu\t' ilU- 4;ct- «^fi- hgHs Bt-^NK ©•2 * ^- ^^3 fo /O'OSk. 2>-3^^ *• o »* a-f!^^ ^- f *^ ^• A- o * ^- /^2. 2. • i>» / • o J» O-Ottb 8 ^•3 0-i^^ to CJ 03 ! ^- '•^tid-bi'n'.i: \H '/'v H.\ 1C m/tlH^fVC l kvX: >r( ir :^'. C'---- S (6 •o. cu^--^ ^9 17 M ^10^