DOCSLIB.ORG

Chembiodraw V14 User Guide

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Chembiodraw V14 User Guide ChemBioDraw 14.0 User Guide ChemBioDraw 14.0 Table of Contents Recent Additions vi Chapter 1: Introduction 1 About this Guide 1 Chapter 2: Getting Started 4 About ChemBioDraw Tutorials 4 ChemBioDraw User Interface 4 Toolbars 5 Documents 6 Chapter 3: Page Layout 10 The Drawing Area 10 The Document Type 10 Printing 12 Saving Page Setup Settings 13 35mm Slide Boundary Guides 13 Viewing Drawings 14 Tables 16 Chapter 4: Preferences and Settings 20 Setting Preferences 20 Customizing Toolbars 23 Document and Object Settings 23 Customizing Hotkeys 33 Working with Color 35 Document Settings 38 Chapter 5: Shortcuts and Hotkeys 44 Atom Keys 44 Bond Hotkeys 45 Function Hotkeys 46 © Copyright 1998-2014 CambridgeSoft Corporation, a subsidiary of PerkinElmer, Inc. All rights reserved. i ChemBioDraw 14.0 Shortcuts 47 Nicknames 50 Chapter 6: Basic Drawings 52 Bonds 52 Atoms 57 Captions 58 Drawing Rings 67 Chains 69 Objects 71 Clean Up Structure 88 Checking Structures 89 Chemical Warnings 89 Chapter 7: BioDraw (Ultra feature only) 92 BioDraw Templates 92 Customizable Objects 95 Chapter 8: Drawing Biopolymers 101 Biopolymer Editor 102 Protecting Groups 103 Pasting Sequences 104 Expanding Sequences 106 Contracting Labels 106 Modifying Sequence Residues 107 Merging Sidechains with Residue 107 Hybrid Biopolymers 110 IUPAC Codes 111 Disulfide Bridges 115 Lactam Bridges 116 Chapter 9: Advanced Drawing Techniques 118 Coloring Objects 118 © Copyright 1998-2014 CambridgeSoft Corporation, a subsidiary of PerkinElmer, Inc. All rights reserved. ii ChemBioDraw 14.0 Labels 119 Attachment Points 122 Atom Numbering 124 Structure Perspective 125 Mass Fragmentation 126 Drawing Reactions 127 Stoichiometry Grid 133 Templates 136 Defining Nicknames 138 ChemScript 141 Chapter 10: Struct=Name (Ultra Feature) 143 Struct>Name 143 Name>Struct 147 Chapter 11: Chemistry Features 149 Structure Analysis 149 ChemBioFinder hotlink 150 Stereochemistry 151 Chemical Annotations 154 Chemical Properties 158 3D Viewing 165 TLC 168 ChemNMR (Ultra Feature) 173 Chapter 12: ChemDraw/Excel and CombiChem 180 Setting Up ChemDraw/Excel 180 Importing tables 180 Importing hit lists 181 Exporting tables 181 Synchronizing Tables 182 Adding structures 183 © Copyright 1998-2014 CambridgeSoft Corporation, a subsidiary of PerkinElmer, Inc. All rights reserved. iii ChemBioDraw 14.0 Searching 184 R-Group analysis 185 Working with Structures 186 ChemDraw/Excel Functions 188 Chemical Properties 202 General Preferences 210 CombiChem 212 Chapter 13: ChemScript 220 Why use ChemScript? 220 How ChemScript works 221 Getting Started 221 Editing Scripts 222 Introducing the ChemScript API 223 Tutorials 224 Useful References 227 Chapter 14: Query Structures 228 Search Limitations 228 Generic Labels 228 Atom Properties 231 Bond Properties 239 Element Lists 242 Polymers 243 Link Nodes 247 Alternative Groups 248 Anonymous Alternative Groups 254 Expand Generic Structures 255 Atom-to-Atom Mapping 257 Stereochemical Symbols 260 3D Properties 261 © Copyright 1998-2014 CambridgeSoft Corporation, a subsidiary of PerkinElmer, Inc. All rights reserved. iv ChemBioDraw 14.0 Export Compatibility 262 Chapter 15: Sharing Information 267 The Clipboard 267 Transferring Objects 270 Embedding Objects 271 Exporting 271 Importing 272 Transferring Across Platforms 276 Chapter 16: Chemical Interpretation 277 Database Conventions 277 Chapter 17: Property Calculations 290 Chapter 18: ChemBioDraw Web Resources 293 Registering Online 293 User’s Guide 293 Technical Support 293 Querying SciFinder® with ChemBioDraw (Ultra Feature) 295 Chapter 19: Tutorials 298 Tutorial 1: Drawing a Structure 298 Tutorial 2: Drawing rings 299 Tutorial 3: Fischer projections 301 Tutorial 4: Perspective Drawings 304 Tutorial 5: Newman projections 308 Tutorial 6: Stereochemistry 311 Tutorial 7: Templates 314 © Copyright 1998-2014 CambridgeSoft Corporation, a subsidiary of PerkinElmer, Inc. All rights reserved. v ChemBioDraw 14.0 Recent Additions Windows 8.1, Microsoft Office 2013, and Mac OS X 10.9.x. ChemDraw strives to be a vital and preferred tool for illustrating chemical and biological concepts. Compatibility with the latest operating systems and tools is an essential part of that. Having the ChemDraw Active-X control functional with the latest browsers on both Windows and Mac platforms is part of this process, as well. ChemDraw to SciFinder Interface. Send ChemDraw structure and reaction queries directly to SciFinder to find useful information relevant to your com- pound/reaction. For more information, see "Querying SciFinder® with ChemBioDraw (Ultra Feature)" on page 295. Biopolymer Builder Enhancements. Single and multi letter amino acids - Lets you create single letter amino acids and nucleotides either by entering the corresponding IUPAC code, or by using the Biopolymer toolbar. The Biopolymer Editor lets you create three letter, or non-standard amino acids, by entering the residue name. Toggle Amino Acid Style AA1<->AA3 command - Lets you change the amino acid representation from single to multi-letter, and vice versa. For more information, see "Drawing Biopolymers" on page 101. L- and D- amino acids - Lets you create standard L- or D-amino acids by entering the relevant IUPAC code. Toggle L- and D-amino acids -The ‘Toggle Amino Acid Stereo L<->D’ command lets you change the ste- reochemistry of amino acids from L to D and vice versa. Protecting groups - Lets you add protecting groups such as Trt and Fmoc to amino acids containing additional NH 2 or OH groups (Arg, Aad). You can also expand and contract the protected residues. For more information, see "Pro- tecting Groups" on page 103. © Copyright 1998-2014 CambridgeSoft Corporation, a subsidiary of PerkinElmer, Inc. All rights vi reserved. ChemBioDraw 14.0 Cyclic and branched peptides - Lets you create cyclic peptides by bonding together the terminal residues in a pep- tide sequence. A looped bond indicates that the peptide is cyclic. You can create branched peptides using the sequence builder and bond tools. For more information, see "Cyclic, Crosslinked, and Branched Peptides" on page 113. Lactam bridges - Lets you form lactam bridges between residues with available amino and carboxylic acid leaving groups, such as Lys-Asp and Lys-Glu. For more information, see "Lactam Bridges " on page 116. Merging sequences - Lets you merge multiple sequences into one sequence by bonding together their terminal residues. Hybrid biopolymers - Lets you create hybrid (also called 'chimeric') biopolymers containing peptide, nucleotide, and linker residues, using the Biopolymer toolbar. For more information, see "Hybrid Biopolymers" on page 110. Pasting sequences - Lets you paste sequences in the FASTA format. You can also copy a text string describing a biopolymer as a series of single or multi letter residues, with valid separators (space, tab, dash), and paste it as a sequence. The text string can be generated within or outside of ChemBioDraw. See "Pasting Sequences" on page 104. Displaying expanded residues - Expanded residues can appear in either linear mode or zigzag mode. Expanding and contracting labels - Lets you expand the entire sequence, or any part of it. The sequence is auto- matically cleaned following expansion. When you contract a sequence, the Clean Up Biopolymer command cleans and re-arranges the sequence, so that the residues are aligned and wrapped. Numbering residues - Lets you display residue numbers above any residue. For more information, see "Numbering Residues" on page 110. Hide/Show termini and bonds - Lets you hide bonds and termini without affecting the underlying chemistry. Nickname Enhancements. In ChemBioDraw 14.0, many new residues, for example, non-standard amino acids, non-standard nucleotides, linkers have been added to the nickname library. Defining nicknames is much easier and more flexible now.For more inform- ation on nicknames, see "Defining Nicknames" on page 138. Struct>Name Enhancements. Struct>Name in ChemBioDraw 14.0 is enhanced to support many homopolymers, copolymers, and alternating poly- mers, and stoichiometry specified as bracket properties, including fractional stoichiometry. For more information, see "Struct>Name " on page 143. Electron Pushing. ChemBioDraw 14.0 introduces the Electron Pushing tool for illustrating electron transfer. For more information, see "Electron and Radical Pushing" on page 132. © Copyright 1998-2014 CambridgeSoft Corporation, a subsidiary of PerkinElmer, Inc. All rights reserved. vii ChemBioDraw 14.0 Gel Electrophoresis Tool. Gel electrophoresis separates molecules using an electric field applied to a gel matrix. The gel electrophoresis tool in ChemBioDraw 14.0 works much like the TLC tool and lets you easily draw and mark bands based on weight or dis- tance. For more information, see "TLC" on page 168. TLC Plate Enhancements. Lets you copy and drag spots between lanes. For more information, see "TLC" on page 168. Polymer Bead Enhancements. Lets you re-size polymer beads. For more information on polymer beads and other attachment points, see "Attach- ment Points" on page 122. New Toolbars. ChemBioDraw 14.0 introduces several new toolbars, including, Structure, Curves, Windows, and Biopolymer tool- bars. You access these toolbars from the View menu. Color by Element. Lets you color atom labels using colors associated with their atomic symbols, as shown in the example below. For more information, see "Color by Element" on page 36. New Property Predictions. Incorporates new calculations from Molecular Networks for predicting pKa, LogS
Load more

Recommended publications
  • Nextfit ® Ix Car Seat
    Convertible Car Seat User Guide For future use, STORE USER GUIDE in compartment at rear of base. ©2016 Artsana USA, Inc. IS0148.3E www.chiccousa.com If you have any problems with your Chicco Child Restraint, or any questions regarding installation or use, please call: Chicco Customer Service 1-877-424-4226 Please have Model and Serial Number available when you call. These are located on a label on the bottom of the Child Restraint. For future reference, fill in the information below. The information can be found on the label on the bottom of the Child Restraint. Model Number: Serial Number: Manufactured In: TABLE OF CONTENTS Registration and Recall 2 REAR-FACING INSTALLATION Child Guidelines 4 Rear-Facing Setup 38 Safe Use Checklist 6 Install Using LATCH 42 Important Warnings 8 Install Using LAP-SHOULDER BELT 48 Best Practices 14 Install Using LAP BELT ONLY 54 Need Help? 15 FORWARD-FACING INSTALLATION CHILD RESTRAINT OVERVIEW Forward-Facing Setup 60 Child Restraint Components 16 Install Using LATCH 64 LATCH and Tether Components 18 Install Using LAP-SHOULDER BELT 70 LATCH and Tether Storage 20 Install Using LAP BELT ONLY 76 Selecting Rear/Forward Facing Position 22 Adjusting Crotch Strap 26 SECURING YOUR CHILD Newborn Insert 28 Securing Child with Harness 80 Secure Child Checklist 92 VEHICLE INFORMATION Vehicle Seating Positions 30 ADDITIONAL INFORMATION Vehicle Seat Belts 32 Installation on an Aircraft 94 What is LATCH? 34 Cup Holder 96 What is a Tether? 36 Cleaning and Maintenance 98 REGISTRATION AND RECALL Please complete the Registration Card that came with your Child Restraint and mail it promptly.
    [Show full text]
  • Solving the Schrödinger Equation for Helium Atom and Its Isoelectronic
    THE JOURNAL OF CHEMICAL PHYSICS 127, 224104 ͑2007͒ Solving the Schrödinger equation for helium atom and its isoelectronic ions with the free iterative complement interaction „ICI… method ͒ Hiroyuki Nakashima and Hiroshi Nakatsujia Quantum Chemistry Research Institute, Kyodai Katsura Venture Plaza 106, Goryo Oohara 1-36, Nishikyo-ku, Kyoto 615-8245, Japan and Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan ͑Received 31 July 2007; accepted 2 October 2007; published online 11 December 2007͒ The Schrödinger equation was solved very accurately for helium atom and its isoelectronic ions ͑Z=1–10͒ with the free iterative complement interaction ͑ICI͒ method followed by the variational principle. We obtained highly accurate wave functions and energies of helium atom and its isoelectronic ions. For helium, the calculated energy was −2.903 724 377 034 119 598 311 159 245 194 404 446 696 905 37 a.u., correct over 40 digit accuracy, and for H−,itwas−0.527 751 016 544 377 196 590 814 566 747 511 383 045 02 a.u. These results prove numerically that with the free ICI method, we can calculate the solutions of the Schrödinger equation as accurately as one desires. We examined several types of scaling function g ␺ and initial function 0 of the free ICI method. The performance was good when logarithm functions were used in the initial function because the logarithm function is physically essential for three-particle collision area. The best performance was obtained when we introduce a new logarithm function containing not only r1 and r2 but also r12 in the same logarithm function.
    [Show full text]
  • Many-Electron System I – Helium Atom and Pauli Exclusion Principle
    Lecture 17 Many-electron System I { Helium Atom and Pauli Exclusion Principle Study Goal of This Lecture • Helium atom - many electron wavefunctions • Helium atom - variational ground state (screening) • Eigenstates of a two-spin system 17.1 Helium Atom Helium atom includes two electrons moving around a fixed nucleus with charge Z = 2, we can write down the Hamiltonian as: 2 2 2 2 ^ ~ 2 2 1 Ze Ze e H = − (r1 + r2) − ( + − ) 2me 4π0 r1 r2 r12 2 2 2 2 2 ~ 2 1 Ze ~ 2 1 Ze e = − r1 − − − r2 − + 2me 4π0 r1 2me 4π0 r2 4π0r12 (17.1) | {z } | {z } | {z } H^1 H^2 H^12 = H^1 + H^2 + H^12: 1 If H^12 = 0(or neglected) then the problem is exactly solved. Recall that for a total system composes of independent sub-systems H^T = H^1 + H^2 + ··· ; (17.2) and we can firstly solve all ^ n n n Hnφm = Emφm; (17.3) then the solution of H^T is the product states Y n = φ : (17.4) n If consider as many-electrons, i.e. H^n for the n-th electron. Then the product solu- tion is a natural "independent electron" solution. Even when the electron-electron interactions are non-zero, we will see the independent electorn approximation is a good starting point. Let's consider the Helium atom, we know: H^1φ1 = E1φ1; (17.5) H^2φ2 = E2φ2; and total E = E1 + E2. φ1; φ2 are Helium hydrogen-like atomic orbitals. We know the two ground states (neglect spin for a moment.) H^1φ1s(1) = E1sφ1s(1); (17.6) H^2φ1s(2) = E1sφ1s(2); number 1 and 2 denotes electorn 1 and electron 2 respectively.
    [Show full text]
  • Cisco Unified IP Phone Services Application Development Notes Supporting XML Applications
    Cisco Unified IP Phone Services Application Development Notes Supporting XML Applications Release 8.5(1) Americas Headquarters Cisco Systems, Inc. 170 West Tasman Drive San Jose, CA 95134-1706 USA http://www.cisco.com Tel: 408 526-4000 800 553-NETS (6387) Fax: 408 527-0883 Text Part Number: OL-22505-01 THE SPECIFICATIONS AND INFORMATION REGARDING THE PRODUCTS IN THIS MANUAL ARE SUBJECT TO CHANGE WITHOUT NOTICE. ALL STATEMENTS, INFORMATION, AND RECOMMENDATIONS IN THIS MANUAL ARE BELIEVED TO BE ACCURATE BUT ARE PRESENTED WITHOUT WARRANTY OF ANY KIND, EXPRESS OR IMPLIED. USERS MUST TAKE FULL RESPONSIBILITY FOR THEIR APPLICATION OF ANY PRODUCTS. THE SOFTWARE LICENSE AND LIMITED WARRANTY FOR THE ACCOMPANYING PRODUCT ARE SET FORTH IN THE INFORMATION PACKET THAT SHIPPED WITH THE PRODUCT AND ARE INCORPORATED HEREIN BY THIS REFERENCE. IF YOU ARE UNABLE TO LOCATE THE SOFTWARE LICENSE OR LIMITED WARRANTY, CONTACT YOUR CISCO REPRESENTATIVE FOR A COPY. The Cisco implementation of TCP header compression is an adaptation of a program developed by the University of California, Berkeley (UCB) as part of UCB’s public domain version of the UNIX operating system. All rights reserved. Copyright © 1981, Regents of the University of California. NOTWITHSTANDING ANY OTHER WARRANTY HEREIN, ALL DOCUMENT FILES AND SOFTWARE OF THESE SUPPLIERS ARE PROVIDED “AS IS” WITH ALL FAULTS. CISCO AND THE ABOVE-NAMED SUPPLIERS DISCLAIM ALL WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, WITHOUT LIMITATION, THOSE OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE AND NONINFRINGEMENT OR ARISING FROM A COURSE OF DEALING, USAGE, OR TRADE PRACTICE. IN NO EVENT SHALL CISCO OR ITS SUPPLIERS BE LIABLE FOR ANY INDIRECT, SPECIAL, CONSEQUENTIAL, OR INCIDENTAL DAMAGES, INCLUDING, WITHOUT LIMITATION, LOST PROFITS OR LOSS OR DAMAGE TO DATA ARISING OUT OF THE USE OR INABILITY TO USE THIS MANUAL, EVEN IF CISCO OR ITS SUPPLIERS HAVE BEEN ADVISED OF THE POSSIBILITY OF SUCH DAMAGES.
    [Show full text]
  • Helium Atom, Approximate Methods
    Helium Atom, Approximate Methods 22nd April 2008 I. The Helium Atom and Variational Principle: Approximation Methods for Complex Atomic Systems The hydrogen atom wavefunctions and energies, we have seen, are deter- mined as a combination of the various quantum "dynamical" analogues of classical motions (translation, vibration, rotation) and a central-force inter- action (i.e, the Coulomb interaction between an electron and a nucleus). Now, we consider the Helium atom and will see that due to the attendant 3-body problem for which we cannot determine a close-for, first-principles analytic solution, we will have to find recourse in approximate methods. The Helium atom has 2 electrons with coordinates r1 and r2 as well as a single nucleus with coordinate R. The nuclues carries a Z = +2e charge. The Schrodinger equation is: 2 2 2 h¯ 2 h¯ 2 h¯ 2 1 2 (R; r1; r2) + −2M r − 2me r − 2me r ! 2e2 2e2 e2 + (R; r ; r ) = E (R; r ; r ) −4π R r − 4π R r 4π r r 1 2 1 2 o j − 1j o j − 2j o j 1 − 2j! where the symbol "nabla", when squared, is given by: @2 @2 @2 2 = + + r @x2 @y2 @z2 Keep in mind that the R, r, and r represent the Cartesian coordinates of each paticle. This is a 3-body problem and such problems are not solved exactly. Thus, the problem will be reformulated in terms of 2 variables. The first approximations: Mme , fix the nucleous at the origin (R) = 0. Thus, the Schrodinger equation in relative variables is: 1 2 2 2 h¯ 2 2 2e 1 1 e 1 2 (r1; r2) + + (r1; r2) = E (r1; r2) 2me −∇ − r −4πo r1 r2 4πo r2 r1 j − j Recall that the 2, representing the kinetic energy operator, in spherical r polar coordinates is: 1 @ @ 1 @ @ 1 @2 r2 + sinθ + 2 @r 1 @r 2 @θ 1 @θ 2 2 2 r1 1 1 r1sinθ1 1 1 r1sin θ1 @φ1 The Independent Electron Approximation to Solving the Helium Atom Schrodinger Equation If we neglect electron-electron repulsion in the Helium atom problem, we can simplify and solve the effective 2-body problem.
    [Show full text]
  • MOS 2016 Study Guide for Microsoft Powerpoint
    MOS 2016 Study Guide for Microsoft PowerPoint Joan E. Lambert Microsoft Office Specialist Exam 77-729 MOS 2016 Study Guide for Microsoft PowerPoint Editor-in-Chief Greg Wiegand Published with the authorization of Microsoft Corporation by: Pearson Education, Inc. Senior Acquisitions Editor Laura Norman Copyright © 2017 by Pearson Education, Inc. Senior Production Editor All rights reserved. Printed in the United States of America. This publication is pro- Tracey Croom tected by copyright, and permission must be obtained from the publisher prior to any prohibited reproduction, storage in a retrieval system, or transmission in any Editorial Production form or by any means, electronic, mechanical, photocopying, recording, or like- Online Training Solutions, Inc. wise. For information regarding permissions, request forms, and the appropriate (OTSI) contacts within the Pearson Education Global Rights & Permissions Department, please visit http://www.pearsoned.com/permissions. No patent liability is assumed Series Project Editor with respect to the use of the information contained herein. Although every pre- Kathy Krause (OTSI) caution has been taken in the preparation of this book, the publisher and author assume no responsibility for errors or omissions. Nor is any liability assumed for Compositor/Indexer damages resulting from the use of the information contained herein. Susie Carr (OTSI) ISBN-13: 978-0-7356-9940-3 Copy Editor/Proofreader ISBN-10: 0-7356-9940-2 Jaime Odell (OTSI) Library of Congress Control Number: 2016953078 Editorial Assistant Cindy J. Teeters First Printing October 2016 Interior Designer/Compositor Microsoft and the trademarks listed at http://www.microsoft.com on the Joan Lambert (OTSI) “Trademarks” webpage are trademarks of the Microsoft group of companies.
    [Show full text]
  • Annex XV Report
    Annex XV report PROPOSAL FOR IDENTIFICATION OF A SUBSTANCE OF VERY HIGH CONCERN ON THE BASIS OF THE CRITERIA SET OUT IN REACH ARTICLE 57 Substance Name(s): 1,6,7,8,9,14,15,16,17,17,18,18- Dodecachloropentacyclo[12.2.1.16,9.02,13.05,10]octadeca-7,15-diene (“Dechlorane Plus”TM) [covering any of its individual anti- and syn-isomers or any combination thereof] EC Number(s): 236-948-9; -; - CAS Number(s): 13560-89-9; 135821-74-8; 135821-03-3 Submitted by: United Kingdom Date: 29 August 2017 ANNEX XV – IDENTIFICATION OF DECHLORANE PLUS AS SVHC CONTENTS PROPOSAL FOR IDENTIFICATION OF A SUBSTANCE OF VERY HIGH CONCERN ON THE BASIS OF THE CRITERIA SET OUT IN REACH ARTICLE 57..........................................................................................IV PART I ...............................................................................................................................................1 JUSTIFICATION ..................................................................................................................................1 1. IDENTITY OF THE SUBSTANCE AND PHYSICAL AND CHEMICAL PROPERTIES ...................................2 1.1 Name and other identifiers of the substance................................................................................2 1.2 Composition of the substance ........................................................................................................2 1.3 Identity and composition of degradation products/metabolites relevant for the SVHC assessment ....................................................................................................................................3
    [Show full text]
  • Cycloalkanes, Cycloalkenes, and Cycloalkynes
    CYCLOALKANES, CYCLOALKENES, AND CYCLOALKYNES any important hydrocarbons, known as cycloalkanes, contain rings of carbon atoms linked together by single bonds. The simple cycloalkanes of formula (CH,), make up a particularly important homologous series in which the chemical properties change in a much more dramatic way with increasing n than do those of the acyclic hydrocarbons CH,(CH,),,-,H. The cyclo- alkanes with small rings (n = 3-6) are of special interest in exhibiting chemical properties intermediate between those of alkanes and alkenes. In this chapter we will show how this behavior can be explained in terms of angle strain and steric hindrance, concepts that have been introduced previously and will be used with increasing frequency as we proceed further. We also discuss the conformations of cycloalkanes, especially cyclo- hexane, in detail because of their importance to the chemistry of many kinds of naturally occurring organic compounds. Some attention also will be paid to polycyclic compounds, substances with more than one ring, and to cyclo- alkenes and cycloalkynes. 12-1 NOMENCLATURE AND PHYSICAL PROPERTIES OF CYCLOALKANES The IUPAC system for naming cycloalkanes and cycloalkenes was presented in some detail in Sections 3-2 and 3-3, and you may wish to review that ma- terial before proceeding further. Additional procedures are required for naming 446 12 Cycloalkanes, Cycloalkenes, and Cycloalkynes Table 12-1 Physical Properties of Alkanes and Cycloalkanes Density, Compounds Bp, "C Mp, "C diO,g ml-' propane cyclopropane butane cyclobutane pentane cyclopentane hexane cyclohexane heptane cycloheptane octane cyclooctane nonane cyclononane "At -40". bUnder pressure. polycyclic compounds, which have rings with common carbons, and these will be discussed later in this chapter.
    [Show full text]
  • Presentation Advice
    Advice for Quality Presentations Resource: 1. North Carolina State Library Toolkit: http://www.lib.ncsu.edu/toolkits/presentations/good_speaking.html 2. The Kaneb Center for Teaching and Learning, University of Notre Dame Strive for Five C's of Presentation Excellence: Look & sound: • Confident, • Credible, • Competent, • Convincing, and • Comfortable. The Basics Be conservative. Be simple. Be conventional. Plan for at least 1 minute per slide. 1 ½ minutes is better. Have slides read from left to right; from top to bottom. People see graphics first, then text. A logical flow of information is essential. If a long presentation, then summary slides are appropriate. Additional Design tips: Remember goal involves improving retention. 1. Use sufficient white space. 2. Use contrast (dark-on-light or light-on-dark) 3. Design from top left to bottom right 4. Use large font size (minimum 18/24 points) 5. Limit use of bold, italics or underlining 6. Do not write in all UPPERCASE 7. No more than two fonts on a screen (preferably one) 8. Be concise with text 9. One main concept per slide 10. Background patterns make slides harder to read 11. When creating original images, use high quality equipment 12. Edit files to reasonable size Principles of Good Speaking and PowerPoint: In most cases, the PowerPoint show is there to enhance your presentation – and not to substitute for it. Despite the presence of the media, principles of good speaking also apply to presentations that incorporate PowerPoint. Focus on the Content: As the saying goes, “The main thing is to keep the main thing the main thing.” Don’t let use of the media hinder you in addressing your topic.
    [Show full text]
  • Quantum Physics (UCSD Physics 130)
    Quantum Physics (UCSD Physics 130) April 2, 2003 2 Contents 1 Course Summary 17 1.1 Problems with Classical Physics . .... 17 1.2 ThoughtExperimentsonDiffraction . ..... 17 1.3 Probability Amplitudes . 17 1.4 WavePacketsandUncertainty . ..... 18 1.5 Operators........................................ .. 19 1.6 ExpectationValues .................................. .. 19 1.7 Commutators ...................................... 20 1.8 TheSchr¨odingerEquation .. .. .. .. .. .. .. .. .. .. .. .. .... 20 1.9 Eigenfunctions, Eigenvalues and Vector Spaces . ......... 20 1.10 AParticleinaBox .................................... 22 1.11 Piecewise Constant Potentials in One Dimension . ...... 22 1.12 The Harmonic Oscillator in One Dimension . ... 24 1.13 Delta Function Potentials in One Dimension . .... 24 1.14 Harmonic Oscillator Solution with Operators . ...... 25 1.15 MoreFunwithOperators. .. .. .. .. .. .. .. .. .. .. .. .. .... 26 1.16 Two Particles in 3 Dimensions . .. 27 1.17 IdenticalParticles ................................. .... 28 1.18 Some 3D Problems Separable in Cartesian Coordinates . ........ 28 1.19 AngularMomentum.................................. .. 29 1.20 Solutions to the Radial Equation for Constant Potentials . .......... 30 1.21 Hydrogen........................................ .. 30 1.22 Solution of the 3D HO Problem in Spherical Coordinates . ....... 31 1.23 Matrix Representation of Operators and States . ........... 31 1.24 A Study of ℓ =1OperatorsandEigenfunctions . 32 1.25 Spin1/2andother2StateSystems . ...... 33 1.26 Quantum
    [Show full text]
  • Proposal to Encode Four Latin Letters for Janalif — 2009-03-16 Page 1 of 8 in 1928 Jaalif Was Finally Reformed and Was in Active Usage for 12 Years (See Fig
    Universal Multiple-Octet Coded Character Set SC2/WG2 N3581 International Organization for Standardization Organisation Internationale de Normalisation Международная организация по стандартизации Doc Type: Working Group Document Title: Proposal to encode four Latin letters for Jaalif Source: Karl Pentzlin, Ilya Yevlampiev (Илья Евлампиев) Status: Individual Contribution Action: For consideration by JTC1/SC2/WG2 and UTC Date: 2008-11-03, revised 2009-03-16 Revision history: The revision of 2009-03-16 takes into account the code points (U+A790/U+A791) devised by UTC #117 for the n with descender. Moreover, it takes into account the name "Latin capital/small letter yeru" for the letter initially proposed as "Latin capital i with right bowl / Latin small letter dotless i with right bowl", as proposed by Michael Everson and continued by the German comments to PDAM7. Also, some sorting considerations were added for the Latin yeru, and fig. 6 was updated. Additions for Janalif U+A790 LATIN CAPITAL LETTER N WITH DESCENDER → 04A2 cyrillic capital letter n with descender U+A791 LATIN SMALL LETTER N WITH DESCENDER U+A792 LATIN CAPITAL LETTER YERU → 042B cyrillic capital letter yeru → 042C cyrillic capital letter soft sign → 0184 latin capital letter tone six U+A793 LATIN SMALL LETTER YERU → 0131 latin small letter dotless i Properties: A790;LATIN CAPITAL LETTER N WITH DESCENDER;Lu;0;L;;;;;N;;;;A791; A791;LATIN SMALL LETTER N WITH DESCENDER;Ll;0;L;;;;;N;;;A790;;A790 A792;LATIN CAPITAL LETTER YERU;Lu;0;L;;;;;N;;;;A793; A793;LATIN SMALL LETTER YERU;Ll;0;L;;;;;N;;;A792;;A792 1. The Jaalif alphabet (fig.
    [Show full text]
  • Estimation of Thermophysical Properties of Athabasca Vacuum Residue Using a Single Molecule Representation 7 1.3
    TABLE OF CONTENTS Page 1. INTRODUCTION 1 1.1. Motivation 1 1.2. Background 2 1.2.1. Athabasca Vacuum Residue and its molecular structure 3 1.2.2. Estimation of thermophysical properties of Athabasca Vacuum Residue using a single molecule representation 7 1.3. Research Objectives 8 2. LITERATURE REVIEW 9 2.1. Phase Equilibrium 10 2.1.1. Basic equations of phase equilibrium 12 2.2. Cubic Equations of State (EOS) 13 2.2.1. Peng-Robinson Equation of State 14 2.3. Group Contribution Concept 15 2.4. Group Contribution Based Equations of State 16 2.4.1. Characteristics of the GC Method 17 2.4.2. Estimation of parameter b 19 2.4.3. Estimation of temperature dependent parameter a 19 2.4.4. Estimation of the shape parameter m 20 2.4.5. Estimation of the parameter a at the boiling point temperature a(Tb) 23 2.4.6. Estimation of the temperature dependent parameter c 24 2.4.7. Estimation of boiling point temperature using the group contribution concept 26 2.4.8. Performance and limitations of the GC Method 29 2.4.9. Simplification of the GC method applicable to mixtures (Crampon et al., 2003) 30 2.5. Application of the GC Method to mixtures 33 2.6. Phase Equilibrium Calculations 35 2.6.1. Equilibrium calculations for single compounds 35 1 2.6.2. Stability Criteria 37 2.6.3. The Tangent Plane Criterion 38 2.6.4. Numerical Solutions in Equilibrium Calculations 40 3. METHODOLOGY 48 3.1. Scope of Project 48 3.2.
    [Show full text]