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Safety Data Sheet Acid Alcohol 1%

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Safety Data Sheet Acid Alcohol 1% Safety Data Sheet Acid Alcohol 1% SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY 1.1 Product Identifier Trade Name Acid Alcohol 1% Product # 3803650 3803651 SDS # 128 SDS Date August 22, 2013 1.2 Relevant Identified Uses of the Substance or Mixture and Uses Advised Against Product Use: Histology / Cytology and General use reagent, Differentiation Uses Advised Against: All other uses. 1.3 Details of the Supplier of the Substance or Mixture Manufacturer/Preparer: Leica Biosystems Richmond, Inc. Leica Biosystems Canada, Inc. 5205 Route 12 83 Terracon Place Richmond, IL 60071 Winnipeg, Manitoba R2J 4B3 800-225-8867 800-665-7425 1.4 Emergency Telephone Number Emergency Spill Information 1-800- 424-9300 (CHEMTREC) +1-703-527-3887 International calls (call collect) Other Product Information: 1-800-225-8867 SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the Substance or Mixture CLP/GHS Classification (1272/2008): Physical: Health: Environmental Flammable Liquid Category 2 Specific Target Organ Toxicity - Not Hazardous Corrosive to metals Category 1 Single Exposure Category 1 EU Classification (67/548/EEC): F, Xn, R11, R20/21/22, R68/20/21/22 2.2 Label Elements DANGER! Contains methanol and hydrochloric acid. Hazard Phrases H225 Highly flammable liquid and vapour. H370 Causes damage to nervous system and eyes. www.LeicaBiosystems.com #128 Page 1 of 10 Issue Date: 22 August 2013 Rev F H290 May be corrosive to metals Precautionary Phrases P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking P233 Keep container tightly closed. P234 Keep only in original container. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting equipment. P242 Use only non-sparking tools. P243 Take precautionary measure against static discharge. P260 Do not breathe vapors. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves, protective clothing and eye protection. P303 + P361 + IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water. P353 P307 + P311 IF exposed: Call a POISON CENTER or doctor/physician. P370 + P378 In case of fire: use dry chemical, foam or water spray for extinction. P390 Absorb spillage to prevent material damage. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P406 Store in corrosive resistant container with a resistant inner liner. P501 Dispose of container/contents to approved disposal site in accordance with all local and national regulations. 2.3 Other Hazards: None SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substances Chemical Name CAS Number / % EU CLP/GHS Classification EINECS Number / (w/w) Classification (1272/2008) REACH Reg. Number (67/548/EEC) Ethanol 64-17-5 <65 F R11 Flammable Liquid Category 2 (H225) 200-578-6 Isopropanol 67-63-0 <5 F, Xi R11, R36, Flammable Liquid Category 2 (H225) R67 Eye Irritation Category 2A (H319) 200-661-7 Specific Target Organ Toxicity – Single Exposure Category 3 (H336) Methanol 67-56-1 <5 F, T R11, Flammable Liquid Category 2 (H225) R23/24/25, Acute Toxicity Category 3 (H301, 200-659-6 R39/23/24/25 H311, H331) Specific Target Organ Toxicity – Single Exposure Category 1 (H370) Hydrochloric acid 7647-01-0 <1 C, R34, R37 Skin Corrosive Category 1B (H314) Eye Damage Category 1 (H318) 231-595-7 Specific Target Organ Toxicity – Single Exposure Category 3 (H335) Corrosive to metals Category 1 (H290) Aquatic Toxicity Acute Category 3 (H402) www.LeicaBiosystems.com #128 Page 2 of 10 Issue Date: 22 August 2013 Rev F See Section 16 for full text of GHS and EU Classifications. SECTION 4: FIRST AID MEASURES 4.1 Description of First Aid Measures First Aid Eye contact: Immediately flush eye with water for at least 15 minutes while lifting the upper and lower lids. Get immediate medical attention. Skin contact: Wash thoroughly with soap and water. Get medical attention if irritation develops. Remove contaminated clothing and launder before reuse. Inhalation: Remove victim to fresh air. Get medical attention if irritation persists. If breathing is difficult have qualified individual administer oxygen and get immediate medical attention. If breathing stops, give artificial respiration and get immediate medical attention. Ingestion: Do not induce vomiting unless directed to do so by medical personnel. If the victim is conscious and alert, have them rinse their mouth with water. Never give anything by mouth to an unconscious or drowsy person. Get immediate medical attention. See Section 11 for more detailed information on health effects. 4.2 Most Important symptoms and effects, both acute and delayed: Causes severe eye and skin irritation; and burns. May cause respiratory irritation. Inhalation of vapors may cause abdominal pain and nervous system effects including dizziness, drowsiness, nausea, vomiting, visual disturbances and unconsciousness. Harmful or fatal if swallowed. 4.3 Indication of any immediate medical attention and special treatment needed: Immediate medical treatment is required for ingestion, and eye contact. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing Media: Use dry chemical, alcohol-resistant foam, carbon dioxide (CO2), or water spray. 5.2 Special Hazards Arising from the Substance or Mixture Unusual Fire and Explosion Hazards: Highly flammable liquid and vapor. Vapors are heavier than air and will travel along surfaces to remove ignition sources and flash back. Vapors will collect in low areas. Vapors may be ignited by static sparks. Flames may be invisible in daylight. Combustion Products: Oxides of carbon, smoke, hydrogen chloride, chlorine. 5.3 Advice for Fire-Fighters: Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool. SECTION 6: ACCIDENTAL RELEASE MEASURES www.LeicaBiosystems.com #128 Page 3 of 10 Issue Date: 22 August 2013 Rev F 6.1 Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate protective equipment. Eliminate all ignition sources and ventilate the area with explosion-proof equipment. Prevent entry into basements or confined areas. 6.2 Environmental Precautions: Prevent entry in storm sewers and waterways. Report spill as required by local and federal regulations. 6.3 Methods and Material for Containment and Cleaning Up: Stop spill at the source if it is safe to do so. Absorb with an inert material. Use non-sparking tools and equipment. Collect into a suitable container for disposal. 6.4 Reference to Other Sections: Refer to Section 8 for personal protective equipment, and Section 13 for disposal information. SECTION 7: HANDLING and STORAGE 7.1 Precautions for Safe Handling: Prevent contact with eyes, skin and clothing. Avoid breathing vapors. Use only with adequate ventilation. Wash thoroughly after handling. Remove contaminated clothing and launder before re-use. Keep product away from heat, sparks and all other sources of ignition. Electrically bond and ground transfer equipment, Use appropriately rated electrical equipment in areas where this material is handled and stored. Keep containers closed when not in use. 7.2 Conditions for Safe Storage, Including any Incompatibilities: Keep product away from heat, sparks and all other sources of ignition. Electrically bond and ground transfer equipment, Use appropriately rated electrical equipment in areas where this material is handled and stored. Protect containers from physical damage. Store in a cool area. Keep away from excessive heat and open flames. Keep containers closed when not in use. Store away from oxidizers. Empty containers retain product residues. Do not cut, weld, braze, etc. on or near empty containers. Follow all SDS precautions in handling empty containers 7.3 Specific end use(s): Industrial uses: None identified Professional uses: Histology / Cytology and General use reagent, Differentiation SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control Parameters: Chemical Name US OEL EU IOEL UK OEL Germany OEL Ethanol 1000 ppm TWA OSHA PEL None Established 1000 ppm TWA 500 ppm TWA 1000 ppm STEL ACGIH TLV 1000 ppm STEL Isopropanol 400 ppm TWA OSHA PEL None Established 400 ppm TWA, 200 ppm TWA, 200 ppm TWA, 400 ppm STEL 500 ppm STEL 400 ppm STEL ACGIH TLV Methanol 200 ppm TWA OSHA PEL 200 ppm TWA 200 ppm TWA, 200 ppm TWA, 200 ppm TWA, 250 ppm STEL skin 250 ppm STEL 800 ppm STEL skin ACGIH TLV www.LeicaBiosystems.com #128 Page 4 of 10 Issue Date: 22 August 2013 Rev F Hydrochloric 5 ppm Ceiling OSHA PEL 5 ppm TWA, 1 ppm TWA, 2 ppm Ceiling acid 2 ppm Ceiling ACGIH TLV 10 ppm STEL 5 ppm STEL Refer to local or national authority for exposure limits not listed above. Chemical Name Biological Limit Value Ethanol None Established Isopropanol Acetone in urine 40 mg/L, end of shift at end of workweek (ACGIH) Methanol Methanol in urine 15 mg/L, end of shift (ACGIH) Hydrochloric None Established acid 8.2 Exposure Controls: Recommended Monitoring Procedures: Collection on charcoal tubes with analysis by gas chromatography. Appropriate Engineering Controls: Use with adequate local exhaust ventilation to maintain exposure levels below the occupational exposure limits. Use explosion-proof equipment where required. Personal Protective Measures Eye/face Protection: Wear chemical goggles. Skin Protection: Impervious clothing as needed to prevent skin
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