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Phibrochem+Zinc+Cyanide+SDS.Pdf Conforms to HazCom 2012/United States Date : 05/15/2014 Version : 1 Safety Data Sheet Zinc Cyanide Section 1. Identification GHS product identifier : Zinc Cyanide Chemical name : Zinc cyanide Other means of : Zinc(II) Cyanide identification MSDS ID Number : 2208‐200‐US‐E Relevant identified uses of the substance or mixture and uses advised against Not available. Supplier's details : Phibrochem Glenpointe Centre East, 3rd Fl 300 Frank W. Burr Blvd., Ste 21 Teaneck, NJ 07666-671265 Tel: (201) 329-7300 Toll free: (888) 475-7355 Fax: (201) 329-7070 e-mail address of person : [email protected] responsible for this MSDS Emergency telephone : CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887 number (with hours of (CCN17221) operation) Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : ACUTE TOXICITY (oral) - Category 2 substance or mixture ACUTE TOXICITY (dermal) - Category 1 ACUTE TOXICITY (inhalation) - Category 2 GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Fatal if swallowed, in contact with skin or if inhaled. Precautionary statements General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Prevention : Wear protective gloves. Wear respiratory protection. Use only outdoors or in a well- ventilated area. Do not get in eyes, on skin, or on clothing. Do not breathe dust. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. 1/12 Zinc Cyanide Section 2. Hazards identification Response : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. IF ON SKIN: Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. Immediately call a POISON CENTER or physician. Wash contaminated clothing before reuse. Storage : Store locked up. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise : None known. classified Section 3. Composition/information on ingredients Substance/mixture : Substance Chemical name : Zinc cyanide Other means of : Zinc(II) Cyanide identification CAS number/other identifiers CAS number : 557-21-1 Product code : Not available. Ingredient name % CAS number Zinc cyanide 60 - 100 557-21-1 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention. Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Break an amyl nitrite pearl in a cloth and hold lightly under nose for 15 seconds. Repeat 5 times at about 15 second intervals. Repeat as necessary using a fresh amyl nitrate pearl every 3 minutes until 3 or 4 pearls have been given. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing give artificial respiration using mechanical devices. Do not administer mouth to mouth respiration! If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact : Get medical attention immediately. Call a poison center or physician. Gently wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Wash clothing before reuse. Clean shoes thoroughly before reuse. 2/12 Zinc Cyanide Section 4. First aid measures Ingestion : Administer antidote kit if available following supplied instructions. Administer oxygen and amyl nitrate inhalant as for inhalation treatment as required and seek immediate medical attention. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : No known significant effects or critical hazards. Inhalation : Fatal if inhaled. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Skin contact : Fatal in contact with skin. Ingestion : Fatal if swallowed. Over-exposure signs/symptoms Eye contact : No known significant effects or critical hazards. Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards. Ingestion : No known significant effects or critical hazards. Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use dry chemical powder. media Unsuitable extinguishing : Do not use water jet or water-based fire extinguishers. Do not use carbon dioxide or media other acidic extinguishers. Cyanides and strong acids can release poisonous and flammable HCN gas. Specific hazards arising : Fire water contaminated with this material must be contained and prevented from being from the chemical discharged to any waterway, sewer or drain. 3/12 Zinc Cyanide Section 5. Fire-fighting measures Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Special protective actions : No special measures are required. for fire-fighters Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. Keep personnel unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Methods and materials for containment and cleaning up Small spill : Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a
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