DOCSLIB.ORG

Zinc Cyanide Zcn

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Zinc Cyanide Zcn ZINC CYANIDE ZCN CAUTIONARY RESPONSE INFORMATION 4. FIRE HAZARDS 7. SHIPPING INFORMATION 4.1 Flash Point: 7.1 Grades of Purity: 55% Zn 40% Cn Common Synonyms Solid-powder Greyish white to white Odorless Not flammable 7.2 Storage Temperature: Ambient Cyanide of zinc 4.2 Flammable Limits in Air: Not flammable Zinc dicyanide 7.3 Inert Atmosphere: Currently not available 4.3 Fire Extinguishing Agents: Not pertinent Sinks in water. 7.4 Venting: Currently not available 4.4 Fire Extinguishing Agents Not to Be 7.5 IMO Pollution Category: Currently not available Keep people away. AVOID CONTACT WITH SOLID. Used: Not pertinent Wear goggles, self-contained breathing apparatus, and rubber overclothing (including gloves). 4.5 Special Hazards of Combustion 7.6 Ship Type: Currently not available Notify local health and pollution control agencies. Products: Not pertinent 7.7 Barge Hull Type: Currently not available Protect water intakes. 4.6 Behavior in Fire: Not pertinent Not flammable. 4.7 Auto Ignition Temperature: Not 8. HAZARD CLASSIFICATIONS Fire flammable 8.1 49 CFR Category: Poison 4.8 Electrical Hazards: Currently not available 8.2 49 CFR Class: 6.1 CALL FOR MEDICAL AID. 4.9 Burning Rate: Not flammable 8.3 49 CFR Package Group: I Exposure DUST 8.4 Marine Pollutant: Yes POISONOUS IF INHALED OR IF SKIN IS EXPOSED. 4.10 Adiabatic Flame Temperature: Currently Move to fresh air. not available 8.5 NFPA Hazard Classification: 4.11 Stoichometric Air to Fuel Ratio: Not If breathing has stopped, give artificial respiration. Category Classification If breathing is difficult, give oxygen. pertinent. Health Hazard (Blue).......... 2 4.12 Flame Temperature: Currently not Flammability (Red)............. 0 SOLID available Instability (Yellow)............. 1 POISONOUS IF SWALLOWED OR IF SKIN IS EXPOSED. 4.13 Combustion Molar Ratio (Reactant to Irritating to eyes. Product): Not pertinent. 8.6 EPA Reportable Quantity: 10 pounds Remove contaminated clothing and shoes. Flush affected areas with plenty of water. 4.14 Minimum Oxygen Concentration for 8.7 EPA Pollution Category: A IF IN EYES, hold eyelids open and flush with plenty of water. Combustion (MOCC): Not listed 8.8 RCRA Waste Number: P121 IF SWALLOWED and victim is CONSCIOUS, have victim drink water or milk 8.9 EPA FWPCA List: Yes and have victim induce vomiting. 5. CHEMICAL REACTIVITY IF SWALLOWED and victim is UNCONSCIOUS OR HAVING CONVULSIONS, do nothing except keep victim warm. 5.1 Reactivity with Water: No reaction 9. PHYSICAL & CHEMICAL 5.2 Reactivity with Common Materials: PROPERTIES Water HARMFUL TO AQUATIC LIFE IN VERY LOW CONCENTRATIONS. Contact with acids or acid salts will May be dangerous if it enters water intakes. liberate highly toxic and flammable 9.1 Physical State at 15° C and 1 atm: Solid Notify local health and wildlife officials. Pollution hydrogen cyanide gas. 9.2 Molecular Weight: 117.42 Notify operators of nearby water intakes. 5.3 Stability During Transport: Stable 9.3 Boiling Point at 1 atm: Not pertinent 5.4 Neutralizing Agents for Acids and 9.4 Freezing Point: Decomposes at 800°C Caustics: Hypochlorite solution to destroy the cyanide. 9.5 Critical Temperature: Currently not available 1. CORRECTIVE RESPONSE ACTIONS 2. CHEMICAL DESIGNATIONS 5.5 Polymerization: Will not occur. 9.6 Critical Pressure: Currently not available Stop discharge 2.1 CG Compatibility Group: Not listed. 5.6 Inhibitor of Polymerization: Not pertinent 9.7 Specific Gravity: 1.85 at room temperature Collection Systems: Dredge 2.2 Formula: Zn(CN)2 9.8 Liquid Surface Tension: Not pertinent 2.3 IMO/UN Designation: 6.1/1713 2.4 DOT ID No.: 1713 6. WATER POLLUTION 9.9 Liquid Water Interfacial Tension: Not pertinent 2.5 CAS Registry No.: 557-21-1 6.1 Aquatic Toxicity: 2.6 NAERG Guide No.: 151 Toxic to fish in range 0.05 to 10 ppm (as 9.10 Vapor (Gas) Specific Gravity: Not pertinent 2.7 Standard Industrial Trade Classification: Cn). Toxicity increases with acidity, 9.11 Ratio of Specific Heats of Vapor (Gas): 52381 temperature, low oxygen tensions Not pertinent and Zn content. 3. HEALTH HAZARDS 9.12 Latent Heat of Vaporization: Not pertinent 6.2 Waterfowl Toxicity: Currently not 9.13 Heat of Combustion: Not pertinent 3.1 Personal Protective Equipment: Approved dust respirator, air or oxygen mask in emergencies, available chemical safety goggles, dry cotton gloves for handling solids and rubber gloves for solutions, hard 9.14 Heat of Decomposition: Currently not 6.3 Biological Oxygen Demand (BOD): 62.4 hat or brimmed felt hat, rubber or leather safety shoes, long sleeved shirt. available mg/l Zn will cause a 50% drop in five day 3.2 Symptoms Following Exposure: EYES: Causes eye burns. SKIN: Irritation. INGESTION OR BOD. 9.15 Heat of Solution: Not pertinent INHALATION: A bitter, acrid burning taste is sometimes noted followed by a feeling of constriction 6.4 Food Chain Concentration Potential: Zn 9.16 Heat of Polymerization: Not pertinent or numbness in the throat. Salivation and nausea are not unusual, but vomiting is rare. Anxiety, may accumulate slightly. confusion, vertigo, giddiness and often a sensation of stiffness in the lower jaw. Hypernea and 9.17 Heat of Fusion: Currently not available dyspnea. Rapid respiration, then slow and irregular. Unconsciousness, convulsions, death from 6.5 GESAMP Hazard Profile: 9.18 Limiting Value: Currently not available respiratory arrest. Bioaccumulation: 0 Damage to living resources: 4 9.19 Reid Vapor Pressure: Currently not 3.3 Treatment of Exposure: Call a physician. INHALATION: Remove to well-ventilated place. Remove available contaminated clothing. Keep patient quiet and warm. Administer by inhalation amyl nitrate for 15 Human Oral hazard: 3 seconds. Repeat about five times at 15-second intervals. Repeat procedure three or four times Human Contact hazard: I at 5-minute intervals. If breathing stops apply artificial respiration. When breathing starts use Reduction of amenities: 0 amyl nitrate. EYES: Flush with plenty of water for 15 minutes. SKIN: Remove clothing. Wash with soap and water. INGESTION: Induce vomiting and give 1% sodium thiosulfate solution. Then NOTES proceed with treatment as described for inhalation. 3.4 TLV-TWA: Not listed. 3.5 TLV-STEL: Not listed. 3.6 TLV-Ceiling: 5 mg/m3 as cyanide. 3.7 Toxicity by Ingestion: Grade 4; LD50 below 50 mg/kg. 3.8 Toxicity by Inhalation: Currently not available. 3.9 Chronic Toxicity: Chronic exposure may cause headache, lack of appetite, weakness and inflammation of the skin with small pimples or blistery spots. 3.10 Vapor (Gas) Irritant Characteristics: Not pertinent 3.11 Liquid or Solid Characteristics: Causes smarting of the skin and first-degree burns on short exposure; may cause second-degree burns on long exposure. 3.12 Odor Threshold: Odorless 3.13 IDLH Value: 25 mg/m3 as cyanide 3.14 OSHA PEL-TWA: 5 mg/m3 as cyanide 3.15 OSHA PEL-STEL: Not listed. 3.16 OSHA PEL-Ceiling: Not listed. 3.17 EPA AEGL: Not listed JUNE 1999 ZINC CYANIDE ZCN 9.20 9.21 9.22 9.23 SATURATED LIQUID DENSITY LIQUID HEAT CAPACITY LIQUID THERMAL CONDUCTIVITY LIQUID VISCOSITY Temperature Pounds per cubic foot Temperature British thermal unit per Temperature British thermal unit inch Temperature Centipoise (degrees F) (degrees F) pound-F (degrees F) per hour-square foot-F (degrees F) N N N N O O O O T T T T P P P P E E E E R R R R T T T T I I I I N N N N E E E E N N N N T T T T 9.24 9.25 9.26 9.27 SOLUBILITY IN WATER SATURATED VAPOR PRESSURE SATURATED VAPOR DENSITY IDEAL GAS HEAT CAPACITY Temperature Pounds per 100 pounds Temperature Pounds per square inch Temperature Pounds per cubic foot Temperature British thermal unit per (degrees F) of water (degrees F) (degrees F) (degrees F) pound-F I N N N N O O O S T T T O L P P P U E E E B R R R L T T T E I I I N N N E E E N N N T T T JUNE 1999.
Load more

Recommended publications
  • Transport of Dangerous Goods
    ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions.
    [Show full text]
  • UNITED STATES PATENT OFFICE 2,668,795 WHITE Brass PLATING Christian J
    Patented Feb. 9, 1954 2,668,795 UNITED STATES PATENT OFFICE 2,668,795 WHITE BRAss PLATING Christian J. Wernlund, Niagara Falls, N. Y., as signor to E. I. du Pont de Nemours and Con pany, Wilmington, Del, a corporation of Dela Wale No Drawing. Application July 28, 1951, Seria No. 239,190 12 Claims. (C. 204-44) 2 This invention relates to the electroplating of The foregoing objects may be attained in ac a White zinc copper alloy from an electrolyte cordance with the present invention by electro containing the cyanides of zinc and copper. plating a white zinc copper alloy from an aque Wernlund U. S. P. 2,181,773 describes the elec ous cyanide-containing electrolyte which con trodeposition of a “white brass' from a cyanide tains a Small amount of a Vanadium compound electrolyte. This white zinc copper alloy elec and preferably also a benzaldehyde-aliphatic trodeposit may be electroplated in accordance ether. Employing both of the above-mentioned With the Wernlund patent to produce a semi addition agents, white brass electrodeposits are bright or bright electrodeposit, which is useful obtained with excellent brightness Over a Wide as undercoating for chromium plating and which, O range of current densities without the addition Without a chromium overdeposit, forms an ex of hydrogen peroxide. For example, by the here cellent, corrosion resistant, decorative finish for in described process I have been able to electro articles made of steel, copper, yellow brass and deposit excellent bright white brass. Within the zinc. As undercoat for chromium plating, the current density range of from 5 to 90 amps.
    [Show full text]
  • Chemical Name Federal P Code CAS Registry Number Acutely
    Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extremely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extremely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extremely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extremely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extremely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extremely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extremely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extremely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extremely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime.
    [Show full text]
  • Acutely / Extremely Hazardous Waste List
    Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extemely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extemely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extemely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extemely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extemely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extemely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extemely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extemely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extemely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extemely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extemely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extemely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extemely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime.
    [Show full text]
  • Do's & Don'ts of Bright Zinc Plating Part I: Alkaline Zinc
    Do’s & Don’ts Donald W. Baudrand, Consultant 621 NE Harrison St. Poulsbo, Washington 98370-8453 E-mail: [email protected] Do’s & Don’ts of Bright Zinc Plating Part I: Alkaline Zinc A little history deposit characteristics, the zinc post-plating coating characteristics Zinc plating became popular when in 1933 the automotive industry and the ability to accept post treatments. took on the cadmium bearing. They bought up all but about 40% of the available cadmium. Cadmium plating had been useful for Selection corrosion resistance applications. The result was a shortage of and This is the controversial part of this editorial. I prefer acid zinc- a high price for cadmium. The alternative was to use zinc for cor- nickel where the nickel content is 9.5 - 10%. At this nickel con- rosion protection applications. centration the reception of chromates and other post treatments is Today there are many choices of zinc plating solutions. The good. The neutral salt spray performance ranges from 750 to 1,000 oldest solutions used sodium cyanide to complex the zinc. The hours. It is the most ductile and is suitable for plating cast iron, deposits were very good. The brightening addition agents were malleable and carbonitrided surfaces. capable of producing very bright and attractive zinc coatings. The Zinc-cobalt can also plate onto the above metals. Zinc-iron deposits were relatively easy to chromate. Clear bright chromates deposits are weldable and are the most ductile, but they deteriorate were possible and light and dark yellow chromates provided sig- when exposed to heat. nificant corrosion protection.
    [Show full text]
  • The Use of Alkaline Cyanide-Free Zinc Plating Under Paint And
    INDIANAPOLIS, INDIANA The Use of Alkaline Cyanide-Free Zinc Plating Under Paint and Powder Coatings Rick Holland, Technical Manager & Brett Larick, Sales Manager Columbia Chemical Corporation, Brunswick Ohio The scope of this paper and presentation is to ALKALINE CYANIDE-FREE ZINC address the properties and benefits of the alkaline PLATING OVERVIEW cyanide-free zinc deposit as a base coating for paint and Work on the first alkaline cyanide-free zinc plating powder coating applications. The deposition structure systems began in the early 1960s when waste treatment and process characteristics for alkaline cyanide-free zinc requirements became stringent. This was the beginning of plating will be evaluated and compared to acid chloride the push to eliminate cyanide zinc plating. Many processes zinc plating, zinc phosphating and iron phosphating. Salt were introduced into the market but did not prove to be spray testing and production costs for an alkaline viable plating processes. In the last forty some years, cyanide-free zinc deposit will be compared to other technology has come a long way and alkaline cyanide-free commonly used base coatings. zinc plating has become a very large part of the zinc plating market. There are still some problems with alkaline INTRODUCTION cyanide-free zinc plating, such as the inability to effectively Zinc plating is utilized by many different industries plate heat-treated fasteners and high-carbon steels. for many different reasons. It is a very versatile deposit Alkaline cyanide-free processes can plate these types of primarily used for its functional properties but with recent parts but additional steps in the pretreatment or cleaning advancements in technology, it is beginning to replace stages of processing need to be taken.
    [Show full text]
  • Maine Remedial Action Guidelines (Rags) for Contaminated Sites
    Maine Department of Environmental Protection Remedial Action Guidelines for Contaminated Sites (RAGs) Effective Date: May 1, 2021 Approved by: ___________________________ Date: April 27, 2021 David Burns, Director Bureau of Remediation & Waste Management Executive Summary MAINE DEPARTMENT OF ENVIRONMENTAL PROTECTION 17 State House Station | Augusta, Maine 04333-0017 www.maine.gov/dep Maine Department of Environmental Protection Remedial Action Guidelines for Contaminated Sites Contents 1 Disclaimer ...................................................................................................................... 1 2 Introduction and Purpose ............................................................................................... 1 2.1 Purpose ......................................................................................................................................... 1 2.2 Consistency with Superfund Risk Assessment .............................................................................. 1 2.3 When to Use RAGs and When to Develop a Site-Specific Risk Assessment ................................. 1 3 Applicability ................................................................................................................... 2 3.1 Applicable Programs & DEP Approval Process ............................................................................. 2 3.1.1 Uncontrolled Hazardous Substance Sites ............................................................................. 2 3.1.2 Voluntary Response Action Program
    [Show full text]
  • Interagency Committee on Chemical Management
    DECEMBER 14, 2018 INTERAGENCY COMMITTEE ON CHEMICAL MANAGEMENT EXECUTIVE ORDER NO. 13-17 REPORT TO THE GOVERNOR WALKE, PETER Table of Contents Executive Summary ...................................................................................................................... 2 I. Introduction .......................................................................................................................... 3 II. Recommended Statutory Amendments or Regulatory Changes to Existing Recordkeeping and Reporting Requirements that are Required to Facilitate Assessment of Risks to Human Health and the Environment Posed by Chemical Use in the State ............................................................................................................................ 5 III. Summary of Chemical Use in the State Based on Reported Chemical Inventories....... 8 IV. Summary of Identified Risks to Human Health and the Environment from Reported Chemical Inventories ........................................................................................................... 9 V. Summary of any change under Federal Statute or Rule affecting the Regulation of Chemicals in the State ....................................................................................................... 12 VI. Recommended Legislative or Regulatory Action to Reduce Risks to Human Health and the Environment from Regulated and Unregulated Chemicals of Emerging Concern ..............................................................................................................................
    [Show full text]
  • Hazardous Waste Management Document - EC-001 |9
    Hazardous Waste Management Document - EC-001 |9 Appendix B: List of Acutely Hazardous Chemicals and Waste Codes Chemical Name Federal CAS Registry P Code Number Acetaldehyde, chloro- P023 107-20-0 Acetamide, N-(aminothioxomethyl)- P002 591-08-2 Acetamide, 2-fluoro- P057 640-19-7 Acetic acid, fluoro-, sodium salt P058 62-74-8 1-Acetyl-2-thiourea P002 591-08-2 Acrolein P003 107-02-8 Aldicarb P070 116-06-3 Aldicarb sulfone P203 1646-88-4 Aldrin P004 309-00-2 Allyl alcohol P005 107-18-6 Aluminum phosphide P006 20859-73-8 5-(Aminomethyl)-3-isoxazolol P007 2763-96-4 4-Aminopyridine P008 504-24-5 Ammonium picrate P009 131-74-8 Ammonium vanadate P119 7803-55-6 Argentate(1-), bis(cyano-C)-,potassium P099 506-61-6 Arsenic acid P010 7778-39-4 Arsenic oxide P012 1327-53-3 Arsenic oxide P011 1303-28-2 Arsenic pentoxide P011 1303-28-2 Arsenic trioxide P012 1327-53-3 Arsine, diethyl P038 692-42-2 ehs.utk.edu | 974-5084 Hazardous Waste Management Document - EC-001 |10 Chemical Name Federal CAS Registry P Code Number Arsonous dichloride, phenyl- P036 696-28-6 Aziridine P054 151-56-4 Aziridine, 2-methyl- P067 75-55-8 Barium cyanide P013 542-62-1 Benzenamine, 4-chloro- P024 106-47-8 Benzenamine, 4-nitro- P077 100-01-6 Benzene, (chloromethyl)- P028 100-44-7 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Benzeneethanamine, alpha,alpha- dimethyl- P046 122-09-8 Benzenethiol P014 108-98-5 7-Benzofuranol, 2,3-dihydro-2,2-dimethyl-, methylcarbamate.
    [Show full text]
  • Characteristics of a Non-Cyanide Alkaline Zinc Plating Bath
    Characteristics of a Non-Cyanide Alkaline Zinc Plating Bath By R.M. Krishnan, S. R. Natarajan, V.S. Muralidharan and Gurdeep Singh Zinc coatings are widely applied for corrosion protec- subsequently plotted vs. the applied current density for solution tion of iron and steel. The protection offered is not temperatures of 30 and 40 ‘C. The slope of the polarization because of envelope effect alone, but is largely a result curve (dE/dt) was calculated for each solution. of zinc’s anodic behavior in any electrochemical reaction. The authors describe experimental investiga- Conductivity of Solutions tions of nitrilotriacetic acid (NTA) solutions and com- The conductivity of each of the different solutions was deter- pare their deposition characteristics with others com- mined by a digital conductivity meter.’ Generally, a plating bath monly used. having high conductivity is associated with less energy con- sumption and greater throwing power. he cyanide process for electrodeposition of zinc is increasingly being replaced by chloride and non- Throwing Power cyanide processes. The chloride baths have found Throwing power was measured in each case by use of a Haring T practical applications over the past few years. With a and Blum Cell. The assembly consisted of a rectangular cell proper combination of brightener additives, these baths produce with two sheet metal cathodes measuring 9 x 5 x 0.1 cm, filling bright, leveled deposits that readily accept a chromate finish.’ the entire cross-section at both ends, and a perforated anode These baths have certain disadvantages, however, such as of the same size. The anode was placed between the cathodes high corrosivity, lower throwing power than cyanide, and so that its distance from one of the cathodes was one-fifth of its susceptibility to iron contamination, which causes difficulty in distance from the other.
    [Show full text]
  • Material Safety Data Sheet
    Page 1/7 Material Safety Data Sheet According to OSHA and ANSI Printing date 06/04/2011 Reviewed on 02/02/2010 1 Identification of the substance/mixture and of the company/undertaking Product identifier Product name: Zinc cyanide Stock number: L15836 CAS Number: 557-21-1 EINECS Number: 209-162-9 Index number: 006-007-00-5 Relevant identified uses of the substance or mixture and uses advised against. Sector of Use SU24 Scientific research and development Details of the supplier of the safety data sheet Manufacturer/Supplier: Alfa Aesar, A Johnson Matthey Company Johnson Matthey Catalog Company, Inc. 30 Bond Street Ward Hill, MA 01835-8099 Tel: 800-343-0660 Fax: 800-322-4757 Email: [email protected] www.alfa.com Information Department: Health, Safety and Environmental Department Emergency telephone number: During normal hours the Health, Safety and Environmental Department at (800) 343-0660. After normal hours call Carechem 24 at (866) 928-0789. 2 Hazards identification Classification of the substance or mixture GHS06 Skull and crossbones H300 Fatal if swallowed. H310 Fatal in contact with skin. H330 Fatal if inhaled. GHS09 Environment H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Classification according to Directive 67/548/EEC or Directive 1999/45/EC T+; Very toxic R26/27/28: Very toxic by inhalation, in contact with skin and if swallowed. N; Dangerous for the environment R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R32: Contact with acids liberates very toxic gas.
    [Show full text]
  • 3.2.2 Table B: List of Dangerous Goods in Alphabetical Order the Following
    Copyright © United Nations, 2008 3.2.2 Table B: List of dangerous goods in alphabetical order The following Table B is an alphabetical list of the substances and articles which are listed in the UN numerical order in Table A of 3.2.1. It does not form an integral part of ADN. It has been prepared, with all necessary care by the Secretariat of the United Nations Economic Commission for Europe, in order to facilitate the consultation of Annexes A and B, but it cannot be relied upon as a substitute for the careful study and observance of the actual provisions of those annexed Regulations which, in case of conflict, are deemed to be authoritative. NOTE 1: For the purpose of determining the alphabetical order the following information has been ignored, even when it forms part of the proper shipping name: numbers; Greek letters; the abbreviations "sec" and "tert"; and the letters "N" (nitrogen), "n" (normal), "o" (ortho) "m" (meta), "p" (para) and "N.O.S." (not otherwise specified). NOTE 2: The name of a substance or article in block capital letters indicates a proper shipping name (see 3.1.2). NOTE 3: The name of a substance or article in block capital letters followed by the word "see" indicates an alternative proper shipping name or part of a proper shipping name (except for PCBs) (see 3.1.2.1). NOTE 4: An entry in lower case letters followed by the word "see" indicates that the entry is not a proper shipping name; it is a synonym. NOTE 5: Where an entry is partly in block capital letters and partly in lower case letters, the latter part is considered not to be part of the proper shipping name (see 3.1.2.1).
    [Show full text]