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Safety Data Sheet According to 1907/2006/EC, Article 31 Printing Date: 06.03.2018 Version Number 3 Revision:______23.02.2017

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Safety Data Sheet According to 1907/2006/EC, Article 31 Printing Date: 06.03.2018 Version Number 3 Revision:______23.02.2017 Page 1/13 Safety data sheet according to 1907/2006/EC, Article 31 Printing date: 06.03.2018 Version number 3 Revision:__________ 23.02.2017 * SECTION 1: Identification of the substance/mixture and of the company/undertaking · 1.1 Product identifier · Trade name: Replenisher part 1 for White bronze bath Ergänzer Teil 1 für Weissbronzebad · Article number: 81010621, 81011751 · 1.2 Relevant identified uses of the substance or mixture and uses advised against Not approved for private consumers. · Application of the substance / the mixture Electroplating auxiliary · 1.3 Details of the supplier of the safety data sheet · Manufacturer/Supplier: Heimerle + Meule GmbH Dennigstrasse 16 D-75179 Pforzheim Telefon +49 (0) 7231 940-0 Telefax +49 (0) 7231 940-2199 www.heimerle-meule.com . · Further information obtainable from: . Abteilung BASU - Bau/Arbeitssicherheit/Umwelt [email protected] IATA - 24h Emergency Contact - (Gefahrgut-Notrufnummer) +49 172 739 6970 . · 1.4 Emergency telephone number: Vergiftungs-Informations-Zentrale Freiburg, ++49 761 19240 (24 h) . * SECTION 2: Hazards identification · 2.1 Classification of the substance or mixture · Classification according to Regulation (EC) No 1272/2008 GHS06 skull and crossbones Acute Tox. 2 H300 Fatal if swallowed. Acute Tox. 1 H310 Fatal in contact with skin. Acute Tox. 2 H330 Fatal if inhaled. (Contd. on page 2) GB 46.0.11 Page 2/13 Safety data sheet according to 1907/2006/EC, Article 31 Printing date: 06.03.2018 Version number 3 Revision:__________ 23.02.2017 Trade name: Replenisher part 1 for White bronze bath Ergänzer Teil 1 für Weissbronzebad (Contd. of page 1) GHS05 corrosion Skin Corr. 1A H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. GHS09 environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. · 2.2 Label elements · Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. · Hazard pictograms GHS05 GHS06 GHS09 · Signal word Danger · Hazard-determining components of labelling: Potassium cyanide potassium hydroxide copper cyanide zinc cyanide · Hazard statements H300+H310+H330 Fatal if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H410 Very toxic to aquatic life with long lasting effects. · Precautionary statements P273 Avoid release to the environment. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Additional information: EUH032 Contact with acids liberates very toxic gas. (Contd. on page 3) GB 46.0.11 Page 3/13 Safety data sheet according to 1907/2006/EC, Article 31 Printing date: 06.03.2018 Version number 3 Revision:__________ 23.02.2017 Trade name: Replenisher part 1 for White bronze bath Ergänzer Teil 1 für Weissbronzebad (Contd. of page 2) · Labelling of packages where the contents do not exceed 125 ml · Hazard pictograms GHS05 GHS06 GHS09 · Signal word Danger · Hazard-determining components of labelling: Potassium cyanide potassium hydroxide copper cyanide zinc cyanide · Hazard statements H300+H310+H330 Fatal if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. · Precautionary statements P260 Do not breathe dusts or mists. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · 2.3 Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. SECTION 3: Composition/information on ingredients · 3.2 Chemical characterisation: Mixtures · Description: Mixture of substances listed below with nonhazardous additions. · Dangerous components / Information on ingredients: CAS: 151-50-8 Potassium cyanide 10-20% EINECS: 205-792-3 Acute Tox. 2, H300; Acute Tox. 1, H310; Acute Tox. 2, H330 Index number: 006-007-00-5 Aquatic Acute 1, H400; Aquatic Chronic 1, H410 RTECS: TS 8760000 CAS: 544-92-3 copper cyanide 10-15% EINECS: 208-883-6 Acute Tox. 2, H300; Acute Tox. 1, H310; Acute Tox. 2, H330 Index number: 006-007-00-5 Aquatic Acute 1, H400; Aquatic Chronic 1, H410 RTECS: GL 7150000 CAS: 1310-58-3 potassium hydroxide 5-10% EINECS: 215-181-3 Skin Corr. 1A, H314 Index number: 019-002-00-8 Acute Tox. 4, H302 RTECS: TT 2102000 (Contd. on page 4) GB 46.0.11 Page 4/13 Safety data sheet according to 1907/2006/EC, Article 31 Printing date: 06.03.2018 Version number 3 Revision:__________ 23.02.2017 Trade name: Replenisher part 1 for White bronze bath Ergänzer Teil 1 für Weissbronzebad (Contd. of page 3) CAS: 557-21-1 zinc cyanide <1% EINECS: 209-162-9 Acute Tox. 2, H300; Acute Tox. 1, H310; Acute Tox. 2, H330 Index number: 006-007-00-5 Aquatic Acute 1, H400; Aquatic Chronic 1, H410 · Additional information: For the wording of the listed hazard phrases refer to section 16. SECTION 4: First aid measures · 4.1 Description of first aid measures · General information: Personal protection for the First Aider. Immediately remove any clothing soiled by the product. Remove breathing equipment only after contaminated clothing have been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration. · After inhalation: Supply fresh air or oxygen; call for doctor. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Seek immediate medical advice. Immediately wash with water and soap and rinse thoroughly. · After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Drink plenty of water and provide fresh air. Call for a doctor immediately. Rinse out mouth and then drink plenty of water. · 4.2 Most important symptoms and effects, both acute and delayed Cyanides poisoning Cyanosis · Information for doctor: Cyanides poisoning · Hazards Danger of pulmonary oedema. · 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures · 5.1 Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · For safety reasons unsuitable extinguishing agents: Water with full jet · 5.2 Special hazards arising from the substance or mixture Formation of very toxic gases is possible during heating or in case of fire. Hydrogen cyanide (HCN) · 5.3 Advice for firefighters · Protective equipment: Mount respiratory protective device. Wear self-contained respiratory protective device. · Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. GB (Contd. on page 5) 46.0.11 Page 5/13 Safety data sheet according to 1907/2006/EC, Article 31 Printing date: 06.03.2018 Version number 3 Revision:__________ 23.02.2017 Trade name: Replenisher part 1 for White bronze bath Ergänzer Teil 1 für Weissbronzebad (Contd. of page 4) SECTION 6: Accidental release measures · 6.1 Personal precautions, protective equipment and emergency procedures Mount respiratory protective device. Wear protective equipment. Keep unprotected persons away. Use respiratory protective device against the effects of fumes/dust/aerosol. · 6.2 Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. · 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. · 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. * SECTION 7: Handling and storage · 7.1 Precautions for safe handling Keep receptacles tightly sealed. Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. he usual precautionary measures are to be adhered to when handling chemicals. Wear suitable respiratory protective device when decanting larger quantities without extractor facilities. Do not dry clean dust covered objects and floors. Wash thoroughly with plenty of water. · Information about fire - and explosion protection: Keep respiratory protective device available. · 7.2 Conditions for safe storage, including any incompatibilities · Storage: · Requirements to be met by storerooms and receptacles: Observe official regulations on storing packagings . Prevent any seepage into the ground. Observe official regulations on storing packagings . · Information about storage in one common storage facility: Do not store together with
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