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2036 Date: November 2000 Revision: January 2010 DOT Number: UN 1514 Right to Know Hazardous Substance Fact Sheet Common Name: ZINC NITRATE Synonyms: Zinc Dinitrate CAS Number: 7779-88-6 Chemical Name: Nitric Acid, Zinc Salt RTK Substance Number: 2036 Date: November 2000 Revision: January 2010 DOT Number: UN 1514 Description and Use EMERGENCY RESPONDERS >>>> SEE LAST PAGE Zinc Nitrate is a colorless or white, odorless, crystalline (sand- Hazard Summary like) solid or flake. It is used as a catalyst and a mordant for Hazard Rating NJDOH NFPA dyes, and in liquid fertilizer. HEALTH 2 - FLAMMABILITY 0 - REACTIVITY 0 - OXIDIZER POISONOUS GASES ARE PRODUCED IN FIRE Reasons for Citation f Zinc Nitrate is on the Right to Know Hazardous Substance Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious; 4=severe List because it is cited by DOT, DEP and EPA. f Zinc Nitrate can affect you when inhaled. f Contact can irritate and burn the skin and eyes. f Inhaling Zinc Nitrate can irritate the nose and throat. f Exposure to Zinc Nitrate can cause headache, dizziness, nausea and vomiting. f High levels of this substance may reduce the blood’s ability to transport Oxygen, causing headache, fatigue, dizziness, SEE GLOSSARY ON PAGE 5. and a blue color to the skin and lips (methemoglobinemia). f Zinc Nitrate is not combustible, but it is a STRONG FIRST AID OXIDIZER that enhances the combustion of other substances. Eye Contact f Immediately flush with large amounts of water for at least 15 minutes, lifting upper and lower lids. Remove contact lenses, if worn, while flushing. Seek medical attention. Workplace Exposure Limits Skin Contact No occupational exposure limits have been established for f Quickly remove contaminated clothing. Immediately wash Zinc Nitrate. However, it may pose a health risk. Always contaminated skin with large amounts of water. Seek follow safe work practices. medical attention. Inhalation f Remove the person from exposure. f Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped. f Transfer promptly to a medical facility. EMERGENCY NUMBERS Poison Control: 1-800-222-1222 CHEMTREC: 1-800-424-9300 NJDEP Hotline: 1-877-927-6337 National Response Center: 1-800-424-8802 ZINC NITRATE Page 2 of 6 Determining Your Exposure Reproductive Hazard f According to the information presently available to the New f Read the product manufacturer’s Material Safety Data Jersey Department of Health, Zinc Nitrate has not been Sheet (MSDS) and the label to determine product tested for its ability to affect reproduction. ingredients and important safety and health information about the product mixture. Other Effects f Zinc Nitrate has not been tested for other chronic (long- f For each individual hazardous ingredient, read the New term) health effects. Jersey Department of Health Hazardous Substance Fact Sheet, available on the RTK website (www.nj.gov/health/eoh/rtkweb) or in your facility’s RTK Medical Central File or Hazard Communication Standard file. Medical Testing f You have a right to this information under the New Jersey If symptoms develop or overexposure is suspected, the Worker and Community Right to Know Act and the Public following is recommended: Employees Occupational Safety and Health (PEOSH) Act if you are a public worker in New Jersey, and under the f Blood methemoglobin level federal Occupational Safety and Health Act (OSHA) if you are a private worker. Any evaluation should include a careful history of past and present symptoms with an exam. Medical tests that look for f The New Jersey Right to Know Act requires most damage already done are not a substitute for controlling employers to label chemicals in the workplace and exposure. requires public employers to provide their employees with information concerning chemical hazards and controls. Request copies of your medical testing. You have a legal right The federal OSHA Hazard Communication Standard (29 to this information under the OSHA Access to Employee Exposure and Medical Records Standard (29 CFR 1910.1020). CFR 1910.1200) and the PEOSH Hazard Communication Standard (N.J.A.C. 12:100-7) require employers to provide similar information and training to their employees. This Fact Sheet is a summary of available information regarding the health hazards that may result from exposure. Duration of exposure, concentration of the substance and other factors will affect your susceptibility to any of the potential effects described below. Health Hazard Information Acute Health Effects The following acute (short-term) health effects may occur immediately or shortly after exposure to Zinc Nitrate: f Contact can irritate and burn the skin and eyes causing a skin rash and redness. f Inhaling Zinc Nitrate can irritate the nose and throat causing coughing and wheezing. f Exposure to Zinc Nitrate can cause headache, dizziness, nausea and vomiting. f High levels of this substance may reduce the blood’s ability to transport Oxygen, causing headache, fatigue, dizziness, and a blue color to the skin and lips (methemoglobinemia). Exposure to very high levels may cause trouble breathing, collapse and even death. Chronic Health Effects The following chronic (long-term) health effects can occur at some time after exposure to Zinc Nitrate and can last for months or years: Cancer Hazard f While Zinc Nitrate has been tested, it is not classifiable as to its potential to cause cancer. ZINC NITRATE Page 3 of 6 Workplace Controls and Practices Eye Protection Very toxic chemicals, or those that are reproductive hazards or f Wear eye protection with side shields or goggles. sensitizers, require expert advice on control measures if a less f Wear a face shield along with goggles when working with toxic chemical cannot be substituted. Control measures corrosive, highly irritating or toxic substances. include: (1) enclosing chemical processes for severely irritating and corrosive chemicals, (2) using local exhaust Respiratory Protection ventilation for chemicals that may be harmful with a single Improper use of respirators is dangerous. Respirators exposure, and (3) using general ventilation to control should only be used if the employer has implemented a written exposures to skin and eye irritants. For further information on program that takes into account workplace conditions, workplace controls, consult the NIOSH document on Control requirements for worker training, respirator fit testing, and Banding at www.cdc.gov/niosh/topics/ctrlbanding/. medical exams, as described in the OSHA Respiratory The following work practices are also recommended: Protection Standard (29 CFR 1910.134). f Label process containers. f At any detectable concentration, use a NIOSH approved f Provide employees with hazard information and training. negative pressure, air-purifying, particulate filter respirator f Monitor airborne chemical concentrations. with an N, R or P95 filter. More protection is provided by a f Use engineering controls if concentrations exceed full facepiece respirator than by a half-mask respirator, and recommended exposure levels. even greater protection is provided by a powered-air f Provide eye wash fountains and emergency showers. purifying respirator. f Wash or shower if skin comes in contact with a hazardous f Leave the area immediately if (1) while wearing a filter or material. cartridge respirator you can smell, taste, or otherwise detect f Always wash at the end of the workshift. Zinc Nitrate, (2) while wearing particulate filters abnormal f Change into clean clothing if clothing becomes resistance to breathing is experienced, or (3) eye irritation contaminated. occurs while wearing a full facepiece respirator. Check to f Do not take contaminated clothing home. make sure the respirator-to-face seal is still good. If it is, f Get special training to wash contaminated clothing. replace the filter or cartridge. If the seal is no longer good, f Do not eat, smoke, or drink in areas where chemicals are you may need a new respirator. being handled, processed or stored. f Consider all potential sources of exposure in your workplace. f Wash hands carefully before eating, smoking, drinking, You may need a combination of filters, prefilters or cartridges applying cosmetics or using the toilet. to protect against different forms of a chemical (such as vapor and mist) or against a mixture of chemicals. In addition, the following may be useful or required: f Where the potential for high exposure exists, use a NIOSH approved supplied-air respirator with a full facepiece operated in a pressure-demand or other positive-pressure f Use a vacuum or a wet method to reduce dust during clean- mode. For increased protection use in combination with an up. DO NOT DRY SWEEP. auxiliary self-contained breathing apparatus or an emergency escape air cylinder. Personal Protective Equipment The OSHA Personal Protective Equipment Standard (29 CFR Fire Hazards 1910.132) requires employers to determine the appropriate If employees are expected to fight fires, they must be trained personal protective equipment for each hazard and to train and equipped as stated in the OSHA Fire Brigades Standard (29 CFR 1910.156). employees on how and when to use protective equipment. f Zinc Nitrate is not combustible, but it is a STRONG The following recommendations are only guidelines and may OXIDIZER that enhances the combustion of other not apply to every situation. substances. f Use water only. DO NOT USE CHEMICAL or CO2 as Gloves and Clothing extinguishing agents. f Avoid skin contact with Zinc Nitrate. Wear personal f POISONOUS GASES ARE PRODUCED IN FIRE, including protective equipment made from material which can not be Nitrogen Oxides and Zinc Oxide fumes. permeated or degraded by this substance. Safety f Use water spray to keep fire-exposed containers cool. equipment suppliers and manufacturers can provide f Zinc Nitrate may ignite combustibles (wood, paper and oil). recommendations on the most protective glove and clothing material for your operation. f Safety equipment manufacturers recommend Nitrile and Natural Rubber for gloves, and Tyvek®, or the equivalent, as a protective clothing material.
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