Radium Girls: the Dark Side of Luminous Watches” (KEEP) 3
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Name:__________________________ Campus: CHS Teacher:_______________________ Corsicana Independent School District Chemistry May 4 – May 8 Student Directions 1. Read and study the Nuclear Chemistry Notes (KEEP) 2. Read and study the “Radium Girls: The dark side of luminous watches” (KEEP) 3. Use the information from the notes and article to take the quiz (RETURN) Unstable Nuclei and Radioactive Decay Nuclear Chemistry Radioactivity Chemical reactions involve only •Chapter 4 & electrons, NOT the nucleus. 25 Nuclear Chemistry Protons determine the identity of an atom. Change the protons, it is a different atom!! Unstable Nuclei and Radioactive Decay Nuclear Radioactivity Reactions- - substances reactions spontaneously which involve emit radiation a change in an atom’s nucleus Radioactive atoms Emit radiation because their Radiation- rays and nuclei are unstable. particles emitted by Radioactive decay- a process the radioactive in which unstable radioactive material atoms lose energy by emitting By emitting radiation radiation, atoms of one element can change into atoms of another element. 1 Unstable radioactive atoms 3 Types of Radiation undergo radioactive decay until they form stable 1800’s Scientists directed non radioactive atoms of a radiation between 2 electrically charged plates and different element. found there were 3 different types; some deflected to the negative, some to the positive, and some were not deflected at all. Alpha, Beta, and Gamma Alpha Radiation an alpha particle (we use the symbol α) Alpha radiation - is positive attracted to a beta particle (symbol β) is negative negative plate a gamma ray (symbol γ) is neutral and made of alpha particles and gives off gamma rays. Alpha Radiation Alpha particle Decreases the mass number Alpha Particle- by 4, and the atomic 2 protons, and 2 number by 2. neutrons so it is positive +2 and mass of 4. Equal to a Helium-4 nucleus. 2 Example Radium decays into Radon by nuclear equation -show emitting an alpha particle the atomic number and the mass number Note the equation is balanced Beta Radiation Beta Particles A neutron becomes a proton and an electron. Beta radiaton - attracted to the The electron leaves the atom at high speed. positive plate, made of beta particles and gives off gamma rays. beta particles –made of an electron with a negative charge -1. The new proton stays in the nucleus increasing the atomic number by 1. H becomes He! Beta particle Mass number stays the same. increases the atomic number by one Carbon-14 becomes Nitrogen by emitting a beta particle. 3 Gamma Radiation – made of gamma rays Nuclear Stability Gamma Rays- high-energy radiation that possesses no mass and no charge but releases the most energy. The ratio of neutrons to protons determines an atom’s stability. atoms with too many or too few neutrons are unstable. They go through radioactive decay to form a nucleus with a stable composition of neutrons and protons making a stable nonradioactive atom. Nuclear Chemistry Nuclear Radiation 1895- William Roentgen found that invisible rays were emitted when electrons He took “pictures” of bombarded the surface of his wife’s hand. certain materials. X-rays caused Discovered X-rays. photographic plates to darken In 1901 Röntgen was awarded the very first Nobel Prize in Physics. Henri Becquerel 1896 - studied minerals that emit light after being exposed to Accidentally, he discovered uranium sunlight- called emitted radiation without an external phosphorescence. source of energy such as the sun. He wondered if they Becquerel had discovered radioactivity, the spontaneous emission of radiation by also emitted X-rays. a material. 4 The Curies Later, Becquerel demonstrated that the radiation shared certain characteristics 1898 - Marie with X rays but, unlike X rays, radiation could be deflected by a magnetic field and and Pierre therefore must consist of charged Curie –isolated particles. the elements that were emitting the rays. polonium, and radium Rate of radioactive emission of charged particles from elements could be measured and compared. In addition, she found that there was a decrease in the rate of radioactive emissions over time and that this decrease could be calculated and predicted. But perhaps Marie Curie's greatest and most unique achievement was her realization that radiation is an atomic property of matter. Nobel Prize in Physics 1903 – was shared; Curies and Becquerel for work Types of Radiation in radioactivity Nobel Prize in Chemistry 1911 – Marie Radioisotopes- Curie for her work with the elements isotopes of atoms Polonium and Radium. with unstable nuclei C-14 is a radioisotope of C-12 5 Most common types of radiation are X-Rays alpha, beta, and gamma rays X-rays and gamma rays – high-energy electromagnetic radiation that is extremely penetrating and damaging to living tissue. Blocked by lead and concrete. Transmutation Transmutation – the conversion of an atom of one element to an atom of another element. Can be natural or induced All elements with atomic numbers 93 and greater are transuranium. Transuranium elements – produced in the laboratory by induced transmutation and are radioactive. Made by particle accelerators (synchrotrons) bombarding the nucleus with high-energy alpha, beta, or gamma radiation. 6 Radioactive Decay Rates Half-Life- time required for For example: Strontium-90 one-half of a radioisotope’s has a half life of 29 years. nuclei to decay into its If you had 10 grams today, then 29 years from now products you would have 5 grams left. The other 5 grams would have transmutated into the stable element. If the half-life of iodine-131 is 8.04 days, how much of a 100 gram sample will Radiochemical Dating remain after 8.04 days?16.08 days? 32.16 days? The half-life of any radioisotope is constant Half life Time in Grams Radiochemical dating – process days of determining the age of an object 0 0 100g by measuring the amount of a 1 8.04 50g certain radioisotope remaining in that object. 2 16.08 25g 3 24.12 12.5g 4 32.16 6.25g The carbon-14 decays with its half- life of 5,700 years, while the amount of carbon-12 remains constant in the sample. By looking at the ratio of carbon-12 to carbon- 14 in the sample and comparing it to the ratio in a living organism, it is possible to determine the age of a formerly living thing fairly precisely. Because the half-life of carbon-14 is 5,700 years, it is only reliable for dating objects up to about 60,000 years old. However 7 Half Percent of Carbon-14 left to Percent Lives of Carbon-12 of a living sample. 0 100% C- 14 1 50% 50% C-12 C-14 2 25% 75% C-12 C-14 3 87.5% C-12 Fission and Fusion of Atomic Nuclei Other useful radioisotopes for radioactive dating include: Uranium -235 (half-life = 704 million yrs) Nuclear Fission- the splitting of a Uranium -238 (half-life = 4.5 billion yrs) nucleus into Thorium-232 (half-life = 14 billion yrs) fragments; Rubidium-87 (half-life = 49 billion yrs). accompanied by a very large release of energy The neutrons released can cause more fissions, which releases more Chain reaction –self- neutrons causing more fissions and sustaining process in which one so on. reaction initiates the next. Critical mass – a sample that is massive enough to sustain a chain reaction. More than a critical mass can generate a nuclear explosion. 8 Nuclear Reactors 4. A coolant, like water is used to 1. Fission is used to generate power in cool & carry off heat caused by nuclear power plants reaction 2. Fuel rods made of enriched Uranium 5. The water generates steam, emit neutrons to sustain a chain reaction which powers turbines, which produce electricity. 3. Control rods absorb the neutrons and sustain the chain reaction while preventing it from racing out of control Concerns Radioactive materials have long half-lives and continue to be damaging for many years. Overexposure can cause cancer or even death. Nuclear Fusion- the combining No good way to dispose of nuclear of atomic nuclei; capable of waste because it can contaminate water, soil, and air releasing large amounts of energy 9 Hydrogen Fusion Four atoms of H fuse to form He Ex: Sun 4 H 1He + ENERGY powered by a series of Each H atom’s mass = 1.0081 amu fusion reactions 4 x 1.0081 = 4.0324 amu high amount of energy is Each He atom’s mass = 4.0039 required to create reaction One Helium atom weighs .0285 amu less than 4 H atoms. Mass of reactants must = mass of products according to the Law of Conservation of Mass, Matter cannot be created or destroyed 4 H 1He + ENERGY 4.0324 4.0039 + .0285 Does mass or matter disappear? The .0285 amu is the matter that So what happened to it? changes to ENERGY which is multiplied trillions of times to give our sun its heat and light. Thermonuclear Fusion occurs reaction- another in stars, name for fusion which derive reaction their energy The heat required for from fusion only occurs in hydrogen an atomic explosion and helium. or in the plasma state. 10 Applications and Effects of Nuclear Fusion is difficult to achieve in a Reactions lab because of the very strong repulsion of nuclei. Ionizing radiation - radiation Controlled fusion is achieved in particle accelerators to produce energetic enough to ionize many synthetic elements. (damage) matter with which it collides. Detected by Geiger counters Uses of Radiation Radiotracer - radioisotope that emits non-ionizing radiation and is used to signal the presence of an element or specific substance. a. analyze reactions b. detect diseases