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7962 N-Tridecane

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7962 N-Tridecane S0285 Material Safety Data Sheet HAZARD WARNINGS RISK PHRASES PROTECTIVE CLOTHING Highly toxic compound, do not ingest or inhale. Avoid all contact with this material. [Inhalation Hazard]. Irritating to skin, eyes, and the respiratory system. Section I. Chemical Product and Company Identification Chemical Name n-Tridecane [Standard Material] Catalog Number S0285 Supplier TCI America 9211 N. Harborgate St. Synonym Not available. Portland OR 1-800-423-8616 Chemical Formula CH3(CH2)11CH3 In case of Chemtrec® CAS Number 629-50-5 Emergency (800) 424-9300 (U.S.) Call (703) 527-3887 (International) Section II. Composition and Information on Ingredients Chemical Name CAS Number Percent (%) TLV/PEL Toxicology Data n-Tridecane 629-50-5 Min. 99.5 Not available. Rat LC50 (inhalation) >41ppm/8H [Standard Material] (GC) Mouse LD50 (intravenous) 1161mg/kg Section III. Hazards Identification Acute Health Effects Toxic if ingested or inhaled. Avoid prolonged contact with this material. Overexposure may result in serious illness or death. Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Chronic Health Effects CARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Section IV. First Aid Measures Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Inhalation If the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not improve. Ingestion INDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Section V. Fire and Explosion Data Flammability May be combustible at high temperature. Auto-Ignition Not available. Flash Points 79°C (174.2°F) Flammable Limits Not available. Combustion Products These products are toxic carbon oxides (CO, CO 2). Fire Hazards Not available. Explosion Hazards Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media SMALL FIRE: Use DRY chemical powder. and Instructions LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet. Consult with local fire authorities before attempting large scale fire-fighting operations. Continued on Next Page Emergency phone number (800) 424-9300 Printed 2/24/2005. S0285 n-Tridecane Page 2 [Standard Material] Section VI. Accidental Release Measures Spill Cleanup Toxic liquid. Irritating liquid. Instructions Stop leak if without risk. DO NOT get water inside container. DO NOT touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all sources of ignition. Consult federal, state, and/or local authorities for assistance on disposal. Finish cleaning the spill by rinsing any contaminated surfaces with copious amounts of water. Consult federal, state, and/or local authorities for assistance on disposal. Section VII. Handling and Storage Handling and Storage TOXIC. IRRITANT. Information Keep locked up. Keep away from heat. Mechanical exhaust required. When not in use, tightly seal the container and store in a dry, cool place. Avoid excessive heat and light. DO NOT ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Treat symptomatically and supportively. Always store away from incompatible compounds such as oxidizing agents. Section VIII. Exposure Controls/Personal Protection Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location. Personal Protection Splash goggles. Lab coat. Vapor respirator. Boots. Gloves. A MSHA/NIOSH approved respirator must be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits Not available. Section IX. Physical and Chemical Properties Physical state @ 20°C Liquid. (Colorless.) Solubility Very soluble in ethyl alcohol, ethyl ether Soluble in carbon tetrachloride Specific Gravity 0.7564 (water=1) Soluble in water 0.0047 mg/L Molecular Weight 184.37 Partition Coefficient Not available. Boiling Point 235.4°C (455.7°F) Vapor Pressure 0.1 kPa (@ 20°C) Melting Point -6°C (21.2°F) Vapor Density 6.4 (Air = 1) Refractive Index 1.4256@20°C Volatility Not available. Critical Temperature Not available. Odor Not available. Viscosity Not available. Taste Not available. Section X. Stability and Reactivity Data Stability This material is stable if stored under proper conditions. (See Section VII for instructions) Conditions of Instability Avoid excessive heat and light. Incompatibilities Reactive with strong oxidizing agents. Section XI. Toxicological Information RTECS Number YD3025000 Routes of Exposure Eye Contact. Ingestion. Inhalation. Toxicity Data Rat LC50 (inhalation) >41ppm/8H Mouse LD50 (intravenous) 1161mg/kg Chronic Toxic Effects CARCINOGENIC EFFECTS : Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS : Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Acute Toxic Effects Toxic if ingested or inhaled. Avoid prolonged contact with this material. Overexposure may result in serious illness or death. Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound. Continued on Next Page Emergency phone number (800) 424-9300 Printed 2/24/2005. S0285 n-Tridecane Page 3 [Standard Material] Section XII. Ecological Information Ecotoxicity Not available. Environmental Fate n-Tridecane's production and use in organic synthesis, jet-fuel research, manufacturing of paraffin products, the rubber industry, the paper processing industry, crude oil, automobile exhaust, and as a solvent and distillation chaser may result in its release to the environment through various waste streams. If released to air, a vapor pressure of 0.056 mm Hg at 25 deg C indicates n-tridecane will exist solely as a vapor in the ambient atmosphere. Vapor-phase n-tridecane will be degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals; the half-life for this reaction in air is estimated to be 24 hours. Based on data for n-hexane and iso-octane, n-tridecane is not expected to absorb UV light in the environmentally significant range of >290 nm. If released to soil, n-tridecane is expected to have essentially no mobility based upon an estimated Koc of 82,000. Volatilization from moist soil surfaces is expected to be an important fate process based upon a Henry's Law constant of 2.31 atm-cu m/mole but may be attenuated by adsorption. Volatilization from dry soil surfaces should not be an important fate process given the vapor pressure of this compound. In a study of soil spiked with JP-4 jet fuel, the concentration of n-tridecane on day 1, 5, 10 and 15 was determined to be 0.099, 0.067, 0.022, and 0.018 ug/l in untreated soil and 0.094, 0.070, 0.043, and 0.029 ug/l in sterile soil. A consortium of Prince William Sound microorganisms was used to degrade Alaskan North Slope crude oil over a 6-month time period; by day 19, 100% n-tridecane was degraded. If released into water, n-tridecane is expected to adsorb to suspended solids and sediment in water based on the estimated Koc. Volatilization from water surfaces is expected to be an important fate process based on its Henry's Law constant. The estimated volatilization half-life from a model river is estimated as approximately 4 hours. The estimated volatilization half-life from a model lake is estimated as approximately 5 days. However, the estimated Koc of 82,000
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