The Visual and Structural Properties of Quasicrystals
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WHAT IS...A Quasicrystal?, Volume 53, Number 8
?WHAT IS... a Quasicrystal? Marjorie Senechal The long answer is: no one is sure. But the short an- diagrams? The set of vertices of a Penrose tiling does— swer is straightforward: a quasicrystal is a crystal that was known before Shechtman’s discovery. But with forbidden symmetry. Forbidden, that is, by “The what other objects do, and how can we tell? The ques- Crystallographic Restriction”, a theorem that confines tion was wide open at that time, and I thought it un- the rotational symmetries of translation lattices in two- wise to replace one inadequate definition (the lattice) and three-dimensional Euclidean space to orders 2, 3, with another. That the commission still retains this 4, and 6. This bedrock of theoretical solid-state sci- definition today suggests the difficulty of the ques- ence—the impossibility of five-fold symmetry in crys- tion we deliberately but implicitly posed. By now a tals can be traced, in the mineralogical literature, back great many kinds of aperiodic crystals have been to 1801—crumbled in 1984 when Dany Shechtman, a grown in laboratories around the world; most of them materials scientist working at what is now the National are metals, alloys of two or three kinds of atoms—bi- Institute of Standards and Technology, synthesized nary or ternary metallic phases. None of their struc- aluminium-manganese crystals with icosahedral sym- tures has been “solved”. (For a survey of current re- metry. The term “quasicrystal”, hastily coined to label search on real aperiodic crystals see, for example, the such theretofore unthinkable objects, suggests the website of the international conference ICQ9, confusions that Shechtman’s discovery sowed. -
Quasicrystals a New Kind of Symmetry Sandra Nair First, Definitions
Quasicrystals A new kind of symmetry Sandra Nair First, definitions ● A lattice is a poset in which every element has a unique infimum and supremum. For example, the set of natural numbers with the notion of ordering by magnitude (1<2). For our purposes, we can think of an array of atoms/molecules with a clear sense of assignment. ● A Bravais lattice is a discrete infinite array of points generated by linear integer combinations of 3 independent primitive vectors: {n1a1 + n2a2 + n3a3 | n1, n2, n3 ∈ Z}. ● Crystal structures = info of lattice points + info of the basis (primitive) vectors. ● Upto isomorphism of point groups (group of isometries leaving at least 1 fixed point), 14 different Bravais lattice structures possible in 3D. Now, crystals... ● Loosely speaking, crystals are molecular arrangements built out of multiple unit cells of one (or more) Bravais lattice structures. ● Crystallographic restriction theorem: The rotational symmetries of a discrete lattice are limited to 2-, 3-, 4-, and 6-fold. ● This leads us to propose a “functional” definition: A crystal is a material that has a discrete diffraction pattern, displaying rotational symmetries of orders 2, 3, 4 and 6. ● Note: Order 5 is a strictly forbidden symmetry → important for us. Tessellations aka tilings Now that we have diffraction patterns to work with, we consider the question of whether a lattice structure tiles or tessellates the plane. This is where the order of the symmetry plays a role. The crystals are special, as they display translational symmetries. As such, the tiling of their lattice structures (which we could see thanks to diffraction patterns) are periodic- they repeat at regular intervals. -
A Review of Transmission Electron Microscopy of Quasicrystals—How Are Atoms Arranged?
crystals Review A Review of Transmission Electron Microscopy of Quasicrystals—How Are Atoms Arranged? Ruitao Li 1, Zhong Li 1, Zhili Dong 2,* and Khiam Aik Khor 1,* 1 School of Mechanical & Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore; [email protected] (R.L.); [email protected] (Z.L.) 2 School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore * Correspondence: [email protected] (Z.D.); [email protected] (K.A.K.); Tel.: +65-6790-6727 (Z.D.); +65-6592-1816 (K.A.K.) Academic Editor: Enrique Maciá Barber Received: 30 June 2016; Accepted: 15 August 2016; Published: 26 August 2016 Abstract: Quasicrystals (QCs) possess rotational symmetries forbidden in the conventional crystallography and lack translational symmetries. Their atoms are arranged in an ordered but non-periodic way. Transmission electron microscopy (TEM) was the right tool to discover such exotic materials and has always been a main technique in their studies since then. It provides the morphological and crystallographic information and images of real atomic arrangements of QCs. In this review, we summarized the achievements of the study of QCs using TEM, providing intriguing structural details of QCs unveiled by TEM analyses. The main findings on the symmetry, local atomic arrangement and chemical order of QCs are illustrated. Keywords: quasicrystal; transmission electron microscopy; symmetry; atomic arrangement 1. Introduction The revolutionary discovery of an Al–Mn compound with 5-fold symmetry by Shechtman et al. [1] in 1982 unveiled a new family of materials—quasicrystals (QCs), which exhibit the forbidden rotational symmetries in the conventional crystallography. -
Some Considerations Relating to the Dynamics of Quasicrystals
Some considerations relating to the dynamics of quasicrystals M. Pitk¨anen Email: [email protected]. http://tgdtheory.com/public_html/. November 12, 2012 Contents 1 The dynamics of quasicrystals, the dynamics of K¨ahleraction, symbolic dynamics, and the dynamics of self-organization 1 1.1 The non-determinism for the dynamics of quasicrystals contra non-determinism of K¨ahleraction . .1 1.2 The dynamics of quasicrystals as a model for fundamental dynamics or high level sym- bolic dynamics? . .2 1.3 Could ordered water layers around biomolecules be modelled as quasicrystal like structure?3 2 What could be the variational principle behind self-organization? 4 2.1 Why Negentropy Maximization Principle should favor quasicrystals? . .5 2.2 Maximal capacity to represent information with minimal metabolic energy costs as a basic variational principle? . .5 2.3 A possible realization for 4-D dynamics favoring quasicrystal like structures . .6 2.4 Summary . .7 1 The dynamics of quasicrystals, the dynamics of K¨ahlerac- tion, symbolic dynamics, and the dynamics of self-organization The dynamics of quasicrystals looks to me very interesting because it shares several features of the dynamics of K¨ahleraction defining the basic variational principle of classical TGD and defining the dynamics of space-time surfaces. In the following I will compare the basic features of the dynamics of quasicrystals to the dynamics of preferred extremals of K¨ahleraction [K1]. Magnetic body carrying dark matter is the fundamental intentional agent in TGD inspired quantum biology and the cautious proposal is that magnetic flux sheets could define the grid of 3-planes (or more general 3-surfaces) defining quasi-periodic background fields favoring 4-D quasicrystals or more general structures in TGD Universe. -
A Quasicrystal for Cherry Valley-1
The Visual and Structural Properties of Quasicrystals Key words: Quasicrystal Sculpture, Quasicrystal Architecture, Stability A Quasicrystal for Cherry Valley A visually rich and complex quasicrystal sculpture is quickly assembled with relatively few standard parts of only three types. Quasicrystals fill space with a non-repeating pattern; parts repeat, but not at regular intervals. In two dimensions, the pattern might be a Penrose tessellation, although other similar patterns could also be in this category. In three dimensions, the units are two skewed cubes, and in a lattice structure these can be made with rods and dodecahedral nodes. All the rods are of the same length; all the nodes are the same and in the same orientation; all the faces of the lattice are the same rhomb, and can be filled with identical plates. For the Cherry Valley Sculpture Exhibition of 2012, I made a quasicrystal sphere. It has a triacontahedral hull – a 30 sided figure that derives from the fusion of a regular dodecahedron and a regular icosahedron. Nested inside my hull is a rhombic icosahedron and nested inside that is a rhombic dodecahedron. Even though all the parts are standard, the sculpture has 2-fold symmetry (of squares), 3-fold symmetry (of triangles and hexagons), and 5-fold symmetry (of star pentagons), depending on the location of the viewer. This wonderful complexity of aspect is also apparent in the shadows that the sculpture casts. Structural considerations As an artist, I am primarily concerned with the visual properties of quasicrystals; for a wider application to architecture, however, the structural and rigidity properties of these structures must be understood. -
Quasicrystals
Volume 106, Number 6, November–December 2001 Journal of Research of the National Institute of Standards and Technology [J. Res. Natl. Inst. Stand. Technol. 106, 975–982 (2001)] Quasicrystals Volume 106 Number 6 November–December 2001 John W. Cahn The discretely diffracting aperiodic crystals Key words: aperiodic crystals; new termed quasicrystals, discovered at NBS branch of crystallography; quasicrystals. National Institute of Standards and in the early 1980s, have led to much inter- Technology, disciplinary activity involving mainly Gaithersburg, MD 20899-8555 materials science, physics, mathematics, and crystallography. It led to a new un- Accepted: August 22, 2001 derstanding of how atoms can arrange [email protected] themselves, the role of periodicity in na- ture, and has created a new branch of crys- tallography. Available online: http://www.nist.gov/jres 1. Introduction The discovery of quasicrystals at NBS in the early Crystal periodicity has been an enormously important 1980s was a surprise [1]. By rapid solidification we had concept in the development of crystallography. Hau¨y’s made a solid that was discretely diffracting like a peri- hypothesis that crystals were periodic structures led to odic crystal, but with icosahedral symmetry. It had long great advances in mathematical and experimental crys- been known that icosahedral symmetry is not allowed tallography in the 19th century. The foundation of crys- for a periodic object [2]. tallography in the early nineteenth century was based on Periodic solids give discrete diffraction, but we did the restrictions that periodicity imposes. Periodic struc- not know then that certain kinds of aperiodic objects can tures in two or three dimensions can only have 1,2,3,4, also give discrete diffraction; these objects conform to a and 6 fold symmetry axes. -
Conformal Quasicrystals and Holography
Conformal Quasicrystals and Holography Latham Boyle1, Madeline Dickens2 and Felix Flicker2;3 1Perimeter Institute for Theoretical Physics, Waterloo, Ontario N2L 2Y5, Canada, N2L 2Y5 2Department of Physics, University of California, Berkeley, California 94720, USA 3Rudolf Peierls Centre for Theoretical Physics, University of Oxford, Department of Physics, Clarendon Laboratory, Parks Road, Oxford, OX1 3PU, United Kingdom Recent studies of holographic tensor network models defined on regular tessellations of hyperbolic space have not yet addressed the underlying discrete geometry of the boundary. We show that the boundary degrees of freedom naturally live on a novel structure, a conformal quasicrystal, that pro- vides a discrete model of conformal geometry. We introduce and construct a class of one-dimensional conformal quasicrystals, and discuss a higher-dimensional example (related to the Penrose tiling). Our construction permits discretizations of conformal field theories that preserve an infinite discrete subgroup of the global conformal group at the cost of lattice periodicity. I. INTRODUCTION dom [12{24]. Meanwhile, quantum information theory provides a unifying language for these studies in terms of entanglement, quantum circuits, and quantum error A central topic in theoretical physics over the past two correction [25]. decades has been holography: the idea that a quantum These investigations have gradually clarified our un- theory in a bulk space may be precisely dual to another derstanding of the discrete geometry in the bulk. There living on the boundary of that space. The most concrete has been a common expectation, based on an analogy and widely-studied realization of this idea has been the with AdS/CFT [1{3], that TNs living on discretizations AdS/CFT correspondence [1{3], in which a gravitational of a hyperbolic space define a lattice state of a critical theory living in a (d + 1)-dimensional negatively-curved system on the boundary and vice-versa. -
2007 136Th Annual Meeting & Exhibition Linking Science and Technology for Global Solutions
2007 136th Annual Meeting & Exhibition Linking Science and Technology for Global Solutions Technical Program Program-at-a-Glance ..............................................................2 Session Listing .......................................................................8 Monday AM ...........................................................................16 Monday PM ............................................................................63 Tuesday AM .........................................................................117 Tuesday PM .........................................................................164 Wednesday AM ...................................................................223 Wednesday PM ...................................................................274 Thursday AM .......................................................................327 General Posters ..................................................................359 Index ....................................................................................363 2007 136th Annual Meeting & Exhibition Monday Tuesday Wednesday Thursday ROOM AM PM AM PM AM PM AM Materials Materials Intellectual Intellectual Materials Materials Materials Processing under Processing under Property in Property in Processing under Processing under Processing under the Influence of the Influence of Materials Materials the Influence of the Influence of the Influence of External Fields: External Fields: Science: Patents, Science: Patents, External Fields: External Fields: -