Introduction to Semiconductors (Conductivity for Si Depends on Doping, Cu ~ 6E7 -1M-1) Think of a Crystal Matrix of Silicon Atoms (Si Has 4 Valence Electrons)
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Semiconductors: Basics to Applications-1 Dr. Anurag Srivastava Associate Professor, ABV-IIITM, Gwalior Email: [email protected] | [email protected] Web: http://tiiciiitm.com/profanurag/ Office: Room-110, First Floor, E-Block, IIITM Campus Engineering Physics –II Course OBJECTIVES: This course deals with an introduction to semiconductor materials and various applications. SYLLABUS: Semiconductors: Fundamentals of semiconducting materials, Band formation, Bonding, Forces, types of semiconductors, conductivity and resistivity, Intrinsic silicon, extrinsic n and p type silicon, mobility of carriers, carrier transport in semiconductors; p-n junctions diodes and other applications Semiconductor Materials The Semiconductor Industry • Semiconductor devices such as diodes, transistors and integrated circuits can be found everywhere in our daily lives, in televisions, automobiles, washing machines, mobiles, computers etc.. We have come to rely on them and increasingly have come to expect higher performance at lower cost. • Personal computers clearly illustrate this trend. Anyone who wants to replace a three to five year old computer finds that the trade-in value of his (or her) computer is surprising low. On the bright side, one finds that the complexity and performance of the today’s personal computers vastly exceeds that of their old computer and that for about the same purchase price, adjusted for inflation. • While this economic reality reflects the massive growth of the industry, it is hard to even imagine a similar growth in any other industry. For instance, in the automobile industry, no one would even expect a five times faster car with a five times larger capacity at the same price when comparing to what was offered five years ago. Nevertheless, when it comes to personal computers, such expectations are very realistic. • The essential fact which has driven the successful growth of the computer industry is that through industrial skill and technological advances one manages to make smaller and smaller transistors. These devices deliver year after year better performance while consuming less power and because of their smaller size they can also be manufactured at a lower cost per device. Objectives: 1. Understand a semiconductor – no. of electrons in outer shell, location on periodic table, most commonly used ones etc, its importance in current Electronic Industries. 2. Know the crystal structure of elementary semiconductor silicon, bonding, forces, band formation, the cause and result of defects and doping. 3. Properties of semiconductors. 4. Understand type of semiconductors, intrinsic silicon and extrinsic semiconductor behaviour, know how to tailor this behaviour through doping. 5. P-N junction and other applications Conductivity Semiconductor: Definition /Resistivity Semiconductors are materials whose electrical properties lie between Conductors and Insulators. Best known Ex : Silicon and Germanium Difference in conductivity/Resistivity Basic characteristics of semiconductors Something about the history: • 1833 M. Faraday: – For AgS decreasing ρ with increasing T • 1873 W. Smith: – Photoconductivity of Se • 1874 F. Braun: – Rectifying properties of PbS • 1948 Bardeen & Brattain: – Bipolar transistor Semiconductors - Conductivity/Resistivity Definition Metals Semimetals Semiconductors • Semiconductors constitute a large class of substances which have resistivities lying between those of insulators and conductors. • The resistivity of semiconductors varies in wide limits, i.e., 10–4 to 104 Ω-m and is reduced to a very great extent with an increase in temperature Semiconductors As compared to electronic valves, semiconductor devices offer the following advantages: (i) low weight and small size (ii) no power for the filament (iii) Long service life (thousands of hours) (iv) mechanical ruggedness (v) low power losses and (vi) Low supply voltages. Semiconductors At the same time semiconductor devices suffer from a number of disadvantages: – deterioration in performance with time (ageing); higher noise level than in electronic valves – Unsuitability of most transistors for use at frequencies over tens of megahertz; – low input resistance as compared with vacuum triodes; – inability to handle large power – deterioration in performance after exposure to radioactive emissions. Why semiconductors? • SEMICONDUCTORS: They are here, there, and everywhere • Computers, palm pilots, Silicon (Si) MOSFETs, ICs, CMOS laptops, anything “intelligent” • Cell phones, pagers Si ICs, GaAs FETs, BJTs • CD players AlGaAs and InGaP laser diodes, Si photodiodes • TV remotes, mobile terminals Light emitting diodes (LEDs) • Satellite dishes InGaAs MMICs (Monolithic Microwave ICs) • Fiber networks InGaAsP laser diodes, pin photodiodes • Traffic signals, car GaN LEDs (green, blue) taillights InGaAsP LEDs (red, amber) • Air bags Si MEMs, Si ICs • and, they are important, especially to Elec.Eng.& Computer Sciences Semiconductor Materials • Elemental semiconductors – Si and Ge (column IV of periodic table) –compose of single species of atoms • Compound semiconductors – combinations of atoms of column III and column V and some atoms from column II and VI. (combination of two atoms results in binary compounds) • There are also three-element (ternary) compounds (GaAsP) and four-elements (quaternary) compounds such as InGaAsP. Semiconductor materials Semiconductor Materials • The wide variety of electronic and optical properties of these semiconductors provides the device engineer with great flexibility in the design of electronic and opto-electronic functions. • Ge was widely used in the early days of semiconductor development for transistors and diods. • Si is now used for the majority of rectifiers, transistors and integrated circuits. • Compounds are widely used in high-speed devices and devices requiring the emission or absorption of light. • The electronic and optical properties of semiconductors are strongly affected by impurities, which may be added in precisely controlled amounts (e.g. an impurity concentration of one part per million can change a sample of Si from a poor conductor to a good conductor of electric current). This process called doping. Solid state structures A crystalline solid is distinguished by the fact that atoms making the crystal are arranged in a periodic fashion. That is, there is some basic arrangement of atoms that is repeated throughout the entire solid. Thus the crystal appears exactly the same at one point as it does at a series of other equivalent points, once the basic periodicity is discovered. However, not all solids are crystals (Fig. 2); some have no periodic structure at all (amorphous solids), and other are composed of many small regions of single-crystal material (polycrystalline solids). The periodic arrangement of atoms in crystal is called the lattice; the lattice contains a volume, called a unit cell, which is representative of the entire lattice and is regularly repeated throughout the crystal. Crystal Structure • How do Atoms combine with each other?? • Atomic Structure?? • Structure Changes Property Changes ??? • Artificially tailor the structure ?? Intel Ireland Atomic Structure • Atoms are the building block • Plum and Pudding Model The plum pudding model is one of several scientific models of the atom. First proposed by J. J. Thomson in 1904 soon after the discovery of the electron, but before the discovery of the atomic nucleus, the model represented an attempt to consolidate the known properties of atoms at the time: 1) electrons are negatively-charged particles and 2) atoms are neutrally-charged. Thompson used the word corpuscles Rutherford's gold foil experiment disprove the plum pudding model? • In 1909, Hans Geiger and Ernest Marsden conducted experiments with thin sheets of gold. Their professor, Ernest Rutherford, expected to find results consistent with Thomson's atomic model. It wasn't until 1911 that Rutherford correctly interpreted the experiment's results[4][5] which implied the presence of a very small nucleus of positive charge at the center of gold atoms. This led to the development of the Rutherford model of the atom. Intel Ireland Rutherford's gold foil experiment disprove the plum pudding model? • When Rutherford shot α particles through gold foil, he found that most of the particles went through. Some scattered in various directions, and a few were even deflected back towards the source. • He argued that the plum pudding model was incorrect. The symmetrical distribution of charge would allow all the α particles to pass through with no deflection. • Rutherford proposed that the atom is mostly empty space. The electrons revolve in circular orbits about a massive positive charge at the centre. Solid state structures • Cubic lattices: Unit cells for types of cubic lattice structure. Simple cubic (sc) Body-centered cubic (bcc) Face-centered cubic (fcc) Diamond lattice unit cell, showing the four nearest neighbour structure The basic lattice structure for many important semiconductors is the diamond lattice, which is characteristic of Si and Ge. In many compound semiconductors, atoms are arranged in a basic diamond structure but are different on alternating sites. This is called a zincblende lattice and is typical of the III-V compounds. The diamond lattice can be thought of as an fcc structure with an extra atom placed at a/4+b/4+c/4 from each of the fcc atoms. Solid state structures Each atom in the diamond lattice has a covalent bond with four adjacent atoms, which together form