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Tailore Assembly of Chemically Modifed Carbon Nanomaterials For Energy & Fuels Preprints Presented at the 246th ACS National Meeting & Exhibition 2013 Division of Energy & Fuels, American Chemical Society Energy & Fuels Preprints Volume 58 Number 2 Indianapolis, Indiana, USA 8-12 September 2013 Editors: Hong Cui ISBN: 978-1-62748-843-3 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 Some format issues inherent in the e-media version may also appear in this print version. Copyright© (2013) by American Chemical Society Division of Energy and Fuels All rights reserved. Printed by Curran Associates, Inc. (2013) For permission requests, please contact American Chemical Society Division of Energy and Fuels at the address below. American Chemical Society Division of Energy and Fuels c/o Dr. Elise B. Fox Savannah River National Lab Materials Science and Technology Aiken SC 29809 Phone: (803) 507-8560 [email protected] Additional copies of this publication are available from: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 USA Phone: 845-758-0400 Fax: 845-758-2634 Email: [email protected] Web: www.proceedings.com 2nd International Symposium on Graphene for Energy and Fuels Tailored Assembly of Chemically Modifed Carbon Nanomaterials for Advanced 1 Optoelectronics and Energy Applications Sang Ouk Kim Chemically modifying graphene for surface functionality 3 Paul Sheehan, Rory Stine, Jeremy Robinson, Sandra Hernández, Keith Whitener, Scott Walton Hybrid graphene and single-walled carbon nanotubes material in supercapacitors, 4 field emitters and microsupercapacitors James Tour Graphene-Based Membrane and Porous Materials for Gas Separation 5 De-en Jiang Electrodes for dye-sensitized solar cells: a case of graphene-based materials 6 Ladislav Kavan, Jun-Ho Yum, Michael Graetzel From Graphitization to Graphenization 7 Weijie Lu Tailoring and integrating graphene into device architectures via chemical 8 modification Mark Hersam Graphene derived nanocarbon architectures for energy storage 9 Quan-Hong Yang Rational design of graphene-based nanomaterials and their application in energy 10 Storage devices Bin Luo, Bin Wang, Linjie Zhi Ambient Fabrication of Large-area Graphene Films via a Synchronous Reduction 12 and Assembly Strategy Xiaodong Chen Graphitic Carbon Nanomaterials as Metal-Free Catalysts for Energy Conversion 13 Liming Dai Modifications of Few-layered Graphene Flakes 14 Liangbing Hu Graphene Aerogels for High-Performance Electrical Energy Storage 15 Peter Pauzauskie, Zach Rousslang, Jennifer Hanson Three Dimensional Graphene for Dye-sensitized Solar Cells 16 Yun Hu, Hui Wang Porous Materials for Energy Conversion and Storage SuperhydrophobicMesoporous Materials with Catalytically Active Sites as Efficient 17 Catalyst for Biomass Conversion Feng-Shou Xiao Metal Organic Frameworks catalysts in the conversion of CO2 to cyclic carbonates 18 Moises Carreon Porous metal-organic frameworks: Mechanical stabilities and methane storage 19 applications Wei Zhou Capacitance Dependence on the Pore Size in Electric Double Layer Capacitors 20 De-en Jiang Electrically-Regenerated Metal-Organic Frameworks 21 Carlos Fernandez, B. McGrail, Praveen Thallapally Revisiting the Charge Storage Mechanism of Nano-Structured Li4Ti5O12 23 Zonghai Chen, Yan Qin, Yang Ren, Chengjun Sun, Steve Heald, Ira Bloom Energy Storage by Conjugated Microporous Polymers 24 Donglin Jiang, Fei Xu, Atsushi Nagai Understaning nanoporous NiO in p-type dye-sensitized solar cells 25 Yiying Wu Microporous Cu-CHA materials for the selective catalytic reduction of NOx with 26 NH3: Catalyst structure/function and mechanistic studies Feng Gao, Eric Walter, Nancy Washton, Janos Szanyi, Charles Peden Energy-Efficient Dehumidification over Mesoporous Metal Carboxylates with 27 Hydrothermal Stability Jong-San Chang, Ji Woong Yoon, You-Kyong Seo, Young Kyu Hwang, U-Hwang Lee, Dong Won Hwang Methane Storage in Metal–Organic Frameworks and Nanoporous Carbons: Current 29 Records, Surprise Findings, and Challenges Taner Yildirim, Yang Peng, Vaiva Krungleviciute, Ibrahim Eryazici, Joseph Hupp, Omar Farha Surface investigation of ZIF thin films 30 Lauren Benz, Andres Gomez, Amber Mosier Synthesis-driven structural variation in redox-active mixed-metal MOFs 32 Karen Mulfort, Shenshen Li, Yu-sheng Chen Selective gas uptake and storage in porous organic framework 33 Ali Kemal Sekizkardes, Mohammad Gulam Rabbani, Zafer Kahveci, Hani El-Kaderi Porphyrinic Metal-Organic Frameworks: Materials design and applications 34 Wonyoung Choe Tailoring mesoporous carbons and related materials for energy applications 35 Sheng Dai Microalgal biodiesel production via a two-step process with biochar-based acidic 36 catalyst Tao Dong, Difeng Gao, Chao Miao, Shulin Chen Novel Hierarchically Porous Beta-MCFs Materials and HDS Performance of DBT 37 Xiaofeng Zhou, Huadong Wu, Aijun Duan, Zhen Zhao, Guiyuan Jiang, Jian Liu Proton-conducting phosphonated frameworks 38 Jennifer Wegener, Anke Kaltbeitzel, Gunnar Glaßer, Robert Graf, Markus Klapper, Klaus Müllen Nanopore-governed heterogeneous catalysis: designing selective reaction cavities 39 on metal surfaces Chia-Kuang Tsung In-situ FT-IR Investigation of the Decomposition of Nano Zn4O(C8H4O4)3 Metal- 40 Organic Framework Peifu Cheng, Yun Hu Solar Energy Conversion and Utilization Earth-abundant cobalt pyrite (CoS2) thin film on glass as a robust, 41 high-performance counter electrode for quantum dot-sensitized solar cells Matthew Faber, Kwangsuk Park, Miguel Cabán-Acevedo, Pralay Santra, Song Jin Biohybrid electrodes based on Photosystem I for solar energy conversion 48 Gabriel LeBlanc, Evan Gizzie, G. Kane Jennings, David Cliffel Emergence of Quantum Dot Solar Cells as Next Generation Photovoltaics 51 Prashant Kamat Programmed Nanomaterials for Solar Driven Water Splitting 52 Xiaodong Chen Novel porphyrin dyes with enhanced light absorption and binding strength for 53 dye-sensitized solar cells Hongshan He, Liping Si, Zhixin Zhao, Wenhui Li Solar wastewater purification via photocatalytic black Ti3+ self-doped TiO2 55 oxidized from TiH2 Lauren Grabstanowicz, Tao Xu Semiconductors, Electrocatalysts, and Interfaces in Solar Water Splitting 57 Shannon Boettcher Multicomponent Quantum Confined Semiconductor Nanorods: From Charge 59 Separation Dynamics to Solar-to-Fuel Conversion Tianquan Lian, Haiming Zhu, Kaifeng Wu Interfacial chemistry of III-V semiconductors for photoelectrochemical water 61 splitting Brandon Wood, Eric Schwegler, Woon Ih Choi, Tadashi Ogitsu Enable Pyrite as a High Performance Solar Material Using Photoelectrochemical 64 and Transport Studies of Pyrite Single Crystals and Nanostructures Song Jin GATR-FTIR characterization of cobaloxime modified p-type gallium phosphide 65 cathodes Gary Moore, Alexandra Krawicz Cyclometalated ruthenium sensitizers for p-type dye-sensitized solar cells and 67 solar fuels Yiying Wu Engineering novel cyclometallated dyes for efficient DSSCs: paradigm shift from 68 organic solvents to H2O suraj soman Catalytic Water Splitting by Metal Complexes Based on Tris(2- 69 pyridylmethyl)amine Derivatives Manohar Vennampalli, Chailu Que, Teera Baine, Min Zhang, John Bollinger, Charles Webster, Xuan Zhao Water-oxidation catalysis for solar fuel production 70 Gary Brudvig, Robert Crabtree, Victor Batista, Charles Schmuttenmaer Bismuth Vanadate Photoanodes for Use in Solar Energy Conversion 71 Yiseul Park, Donghyeon Kang, Jason Seabold, Kenneth McDonald, Kyoung-Shin Choi Enabling Si for Solar Energy Harvesting and Fuel Conversion 73 Ke Sun, Deli Wang Metal oxide nanostructured electrodes for solar hydrogen generation 74 Yat Li Metal oxides as effective counter electrodes for dye-sensitized solar cells 77 Hui Wang, Wei Wei, Yun Hu Efficient ZrN-based counter electrodes for dye-sensitized solar cells 78 Wei Wei, Hui Wang, Yun Hu Synthesis and Characterization of Bi2Ti2O7 with Fe addition: Examining the 79 effects of Fe on photo driven hydrogen Production Bradley Allured, Steven DelaCruz, Muhammad Huda, Vaidyanathan (Ravi) Subramanian Advances in Batteries, Capacitors, and Other Energy Storage Devices Graphene-based composites as electrochemical supercapacitors 83 Zhefei Li, Jian Xie Applications of carbide-derived carbon as electrodes for rechargeable lithium-ion 84 batteries Sun-Hwa Yeon, Kyu-Nam Jung, Sukeun Yoon, Kyoung-Hee Shin, Jae-Deok Jeon Thermal-induced decomposition roadmap of charged cathode material Li1.2- 85 xNi0.15Co0.1Mn0.55O2 studied by Synchrotron X-ray Techniques Chi-Kai Lin, Zonghai Chen, Ira Bloom, Yang Ren Semiconductor Nanowire-arrayed Electrodes for Supercapacitors 86 Yat Li An Enhanced Lithium Ion Battery Via Biological Engeneering 89 Scott Riley High voltage electrolyte based on fluorinated compounds for 5V Li-ion chemistry 90 Zhengcheng Zhang, Libo Hu, Huiming Wu, Khalil Amine Toward fully plastic batteries: Electroactive polymer-carbon composite electrode 91 as cathode materıal for rechargeable batteries Burak Esat, Muhammed Aydin Li intercalation capacity of Fe-Phthalocyanine 94 Ramos-Sanchez Guadalupe, Perla Balbuena Pseudocapacitive energy storage in 2D Nb2O5-graphene nanocomposites 96 Bruce Dunn, Guillaume Muller, Hyungseok Kim, Xavier Petrissans, Veronica Augustyn Capturing the interface in Li-ion cells with heavy alkali dopants: Raman and X-ray 98 techniques Christopher Patridge, Corey Love, David Ramaker Phosphate and diphosphate bimetallic cathode materials 99 Esther Takeuchi, Amy Marschilok, Kenneth Takeuchi Electrodeposition of metal-air battery cathodes: Fabrication, characterization
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