DOCSLIB.ORG

Refinement of Substance List. 3043 Materials (2/27/2018)

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Refinement of Substance List. 3043 Materials (2/27/2018) Refinement of Substance list. 3043 materials (2/27/2018) CAS Substance number name 50-00-0 Formaldehyde 50-01-1 guanidinium chloride; guanadine hydrochloride 50-06-6 5-Ethyl-5-phenyl-2,4,6(1H,3H,5H)-pyrimidinetrione; Phenobarbital 50-18-0 *Cyclophosphamide anhydride 50-21-5 *Lactic acid 50-29-3 1,1,1-Trichloro-2,2-bis(4-chlorophenyl)ethane [DDT] 50-31-7 *2,3,6-trichlorobenzoic acid 50-32-8 Benzo[a]pyrene 50-44-2 *6-Mercaptppurine 50-78-2 Aspirin 51-21-8 *5-Fluorouracil 51-28-5 2,4-Dinitrophenol 51-48-9 *Tyroxine 51-52-5 2,3-Dihydro-6-propyl-2-thioxo-4(1H)-pyrimidinone; Propylthiouracil 51-55-8 atropine 51-75-2 Bis(2-chloroethyl)methylamine; Nitrogen mustard 51-79-6 Urethane 52-24-4 *Thiotepa 52-51-7 bronopol (INN); 2-bromo-2-nitropropane-1,3-diol 52-68-6 Dimethyl 2,2,2-trichloro-1-hydroxyethylphosphonate; Trichlorfon; DEP 52-86-8 *Haloperidol 52-90-4 *L-cysteine 53-70-3 Dibenz[a,h]anthracene 54-11-5 Nicotine 54-64-8 thiomersal 54-85-3 *Isoniazid 55-18-5 N-Nitrosodiethylamine 55-38-9 Fenthion 55-56-1 *Chlorhexidine 55-63-0 Nitroglycerin 55-68-5 *Phenylmercury nitrate 55-98-1 *Busulfan 56-04-2 6-Methyl-2-thiouracil; Methylthiouracil 56-18-8 *3,3'-Iminodi(propylamine) 56-23-5 Tetrachloromethane 56-35-9 Distannoxane, hexabutyl- 56-36-0 tributyltin acetate 56-38-2 Parathion 56-53-1 *Diethylstilbestrol 56-55-3 Benz[a]anthracene 56-72-4 coumaphos (ISO); O-3-chloro-4-methylcoumarin-7-yl O,O-diethyl phosphorothioate 56-75-7 2,2-Dichloro-N-[2-hydroxy-1-(hydroxymethyl)-2-(4-nitrophenyl)ethyl]acetamide; Chloramphenicol 56-93-9 *Benzyltrimethylammonium chloride 57-06-7 Allyl isothiocyanate 57-09-0 Hexadecyltrimethylammonium bromide 57-14-7 *1,1-Dimethylhydrazine; Dimethylhydrazine 57-24-9 Strychnine 57-41-0 5,5-Diphenyl-2,4-imidazolidinedione 57-47-6 *Physostigmine 57-57-8 propiolactone 57-74-9 *1,2,4,5,6,7,8,8-Octachloro-2,3,3a,4,7,7a-hexahydro-4,7-methano-1H-indene; Chlordane 58-08-2 caffeine 58-55-9 *Theophylline 58-89-9 1,2,3,4,5,6-Hexachlorocyclohexane [Lindane] 58-90-2 2,3,4,6-tetrachlorophenol 59-50-7 4-Chloro-3-methylphenol 59-88-1 Phenylhydrazinium chloride 59-89-2 N-Nitrosomorpholine 60-00-4 Ethylenediaminetetraacetic acid 60-09-3 *p-Phenylazoaniline 60-11-7 4-dimethylaminoazobenzene 60-12-8 *beta-Phenyl ethylalcohol; Phenethyl alcohol 60-23-1 Cysteamine 1/48 CAS Substance number name 60-24-2 *2-Mercaptoethanol 60-29-7 Ethane, 1,1'-oxybis 60-34-4 methylhydrazine 60-35-5 Acetamide 60-51-5 O,O-Dimethyl S-(N-methylcarbamoyl)methyl phosphorodithioate; Dimethoate 60-57-1 dieldrin 61-68-7 *Mefenamic acid 61-73-4 *Methylene blue 61-82-5 *3-Amino-1H-1,2,4-triazole; Amitrole 62-23-7 p-Nitrobenzoic acid 62-38-4 Phenylmercury acetate 62-44-2 4'-Ethoxyacetanilide; Phenacetin 62-50-0 ethyl methanesulphonate 62-53-3 Aniline 62-55-5 Thioacetamide 62-56-6 Thiourea 62-73-7 *Dimethyl-2,2-dichlorovinyl phosphate; DDVP 62-74-8 sodium fluoroacetate 62-75-9 dimethylnitrosoamine 62-76-0 Ethandioic acid, disodium salt 63-25-2 Carbaryl 63-92-3 Phenoxybenzamine hydrochloride 64-02-8 *Tetrasodium ethylenediaminetetraacetate 64-04-0 *beta-Phenylethylamine; Phenethylamine 64-17-5 Ethanol 64-18-6 Formic acid 64-19-7 Acetic acid 64-67-5 Diethyl sulfate 64-69-7 iodoacetic acid 65-30-5 nicotine sulphate 65-45-2 *Salicylamide 65-85-0 Benzoic acid 65-86-1 *Orotic acid 66-25-1 *Hexanal 66-27-3 methyl methanesulphonate 66-32-0 strychnidin-10-one mononitrate 66-76-2 *4,4'-Dihydroxy-3,3'-methylenedi-2H-chromen-2-one 66-81-9 cicloheximide 67-56-1 Methanol 67-63-0 Isopropyl alcohol 67-64-1 Acetone 67-66-3 Chloroform 67-72-1 Ethane, hexachloro- 67-97-0 colecalciferol; Vitamin D3 68-11-1 Mercaptoacetic acid 68-12-2 N,N-Dimethylformamide 69-72-7 *Salicylic acid 70-25-7 N-Methyl-N'-nitro-N-nitrosoguanidine 70-30-4 2,2'-methylenebis-(3,4,6-trichlorophenol); hexachlorophene 70-34-8 *1-Fluoro-2,4-dinitrobenzene 71-23-8 *n-Propyl alcohol 71-36-3 1-Butanol 71-41-0 *1-Pentanol 71-43-2 Benzene 71-48-7 Cobalt(II) acetate 71-55-6 Ethane, 1,1,1-trichloro- 72-20-8 endrin 72-43-5 Methoxychlor tetrasodium 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7- 72-57-1 disulphonate] 74-11-3 *p-Chlorobenzoic acid 74-31-7 *N,N'-Diphenyl-1,4-phenylenediamine 74-82-8 Methane 74-83-9 *Methyl bromide 74-84-0 Ethane 74-85-1 Ethylene 74-86-2 Ethyne 2/48 CAS Substance number name 74-87-3 Chloromethane; Methyl chloride 74-88-4 iodomethane 74-89-5 Methanamine 74-90-8 Hydrogen cyanide 74-93-1 Methanethiol 74-95-3 dibromomethane 74-96-4 Ethane, bromo- 74-97-5 Methane, bromochloro- 74-98-6 Propane 74-99-7 1-Propyne 75-00-3 Chloroethane 75-01-4 *Vinyl chloride 75-02-5 Ethene, fluoro- 75-04-7 Ethanamine 75-05-8 Acetonitrile 75-07-0 Acetaldehyde 75-08-1 Ethanethiol 75-09-2 Dichloromethane; Methylene dichloride 75-10-5 *Difluoromethane 75-11-6 Methylene iodide 75-12-7 Formamide 75-15-0 Carbon disulfide 75-18-3 Dimethyl sulfide 75-19-4 *Cyclopropane 75-20-7 Calcium acetylide 75-21-8 Ethylene oxide 75-25-2 Tribromomethane; Bromoform 75-26-3 2-bromopropane 75-27-4 bromodichloromethane 75-28-5 *2-Methylpropane 75-29-6 2-chloropropane 75-31-0 2-Propanamine 75-34-3 Ethane, 1,1-dichloro- 75-35-4 1,1-Dichloroethylene [Vinylydene dichloride] 75-36-5 acetyl chloride 75-37-6 *1,1-Difluoroethane 75-38-7 Vinylidene dibromide 75-43-4 dichlorofluoromethane 75-44-5 Phosgene 75-45-6 Methane, chlorodifluoro- 75-46-7 *Trifluoromethane 75-47-8 iodoform 75-50-3 Trimethylamine 75-52-5 Methane, nitro- 75-54-7 *Dichloromethylsilane 75-55-8 2-methylaziridine 75-56-9 *propylene oxide; 1,2-Epoxypropane 75-59-2 *Tetramethylammonium hydroxide 75-61-6 dibromodifluoromethane 75-63-8 Methane, bromotrifluoro- 75-64-9 *t-Butylamine 75-65-0 tert-Butanol 75-68-3 1-Chloro-1,1-difluoroethane; HCFC-142b 75-69-4 Methane, trichlorofluoro- 75-71-8 Dichlorodifluoromethane 75-72-9 Chlorotrifluoromethane; CFC-13 75-73-0 *Tetrafluoromethane 75-74-1 Tetramethyllead 75-75-2 methanesulphonic acid 75-76-3 *Tetramethylsilane 75-77-4 *Chlorotrimethylsilane 75-78-5 *Dichloro(dimethyl)silane 75-79-6 *Trichloro(methyl)silane 75-85-4 *2-Methyl-2-butanol 75-86-5 Propanenitrile, 2-hydroxy-2-methyl- 75-87-6 Trichloroacetaldehyde 75-88-7 *2-Chloro-1,1,1-trifluoroethane 3/48 CAS Substance number name 75-89-8 Trifluoroethanol 75-91-2 tert-Butyl hydroperoxide 75-94-5 *Trichloro(vinyl)silane 75-97-8 *3,3-Dimethyl-2-butanone 75-98-9 *2,2-Dimethylpropanoic acid 75-99-0 2,2-Dichloropropionic acid 76-01-7 Pentachloroethane 76-03-9 Trichloroacetic acid 76-05-1 *Trifluoroacetic acid 76-06-2 Trichloronitromethane; Chloropicrin 76-12-0 tetrachloro-1,2-difluoroethane 76-13-1 Ethane, 1,1,2-trichloro-1,2,2-trifluoro- 76-14-2 Ethane, 1,2-dichlorotetrafluoro- 76-15-3 Ethane, chloropentafluoro- 76-16-4 *Hexafluoroethane 76-19-7 *Octafluoropropane 76-20-0 2,2-bis(ethylsulphonyl)butane 76-22-2 bornan-2-one 76-44-8 heptachlor 76-87-9 Fentin hydroxide 76-93-7 *Benzilic acid 77-09-8 3,3-Bis(4-hydroxyphenyl)isobenzofuran-1(3H)-one 77-47-4 Hexachlorocyclopentadiene 77-58-7 *Dibutyltin dilaurate 77-73-6 Dicyclopentadiene 77-77-0 *Divinyl sulfone 77-78-1 Dimethyl sulfate 78-00-2 Lead, tetraethyl- 78-04-6 Dibutyltin maleate 78-10-4 Silicic acid, (H4SiO4), tetraethyl ester 78-11-5 Pentaerythrite tetranitrate 78-30-8 Tris(o-cresyl) phosphate 78-32-0 tricresyl phosphate; tritolyl phosphate 78-34-2 dioxathion 78-40-0 *Triethyl phosphate 78-42-2 Tris(2-ethylhexyl) phosphate 78-48-8 S,S,S-tributylphosphorotrithioate 78-57-9 menazon 78-59-1 2-Cyclohexen-1-one, 3,5,5-trimethyl- 78-62-6 *Diethoxydimethylsilane 78-63-7 2,5-Dimethyl-2,5-bis(tert-butylperoxy)hexane 78-67-1 2,2'-Azobisisobutyronitrile 78-69-3 *3,7-Dimethyloctan-3-ol; Tetrahydrolinalool 78-70-6 *Linalool 78-76-2 *2-Bromobutane 78-77-3 *Isobutyl bromide 78-78-4 Butane, 2-methyl- 78-79-5 Isoprene 78-81-9 *Isobutylamine 78-82-0 Propanenitrile, 2-methyl- 78-83-1 1-Propanol, 2-methyl- 78-84-2 Isobutyraldehyde 78-85-3 *2-Methyl-2-propenal 78-87-5 1,2-Dichloropropane 78-88-6 *2,3-Dichloropropene 78-89-7 2-Chloro-1-propanol 78-90-0 *1,2-Propanediamine 78-92-2 Butan-2-ol 78-93-3 2-Butanone 78-94-4 butenone 78-95-5 2-Propanone, 1-chloro- 78-96-6 1-aminopropan-2-ol; isopropanolamine 78-97-7 *Lactonitrile; Acetaldehyde cyanohydrin 79-00-5 1,1,2-Trichloroethane 79-01-6 Trichloroethylene 79-03-8 *Propanoyl chloride 79-04-9 Chloroacetyl chloride 4/48 CAS Substance number name 79-06-1 Acrylamide 79-07-2 *Chloroacetamide 79-08-3 *Bromoacetic acid 79-09-4 Propionic acid 79-10-7 Acrylic acid 79-11-8 Chloroacetic acid 79-14-1 *Hydroxyacetic acid 79-16-3 *N-Methylacetamide 79-19-6 thiosemicarbazide 79-20-9 Methyl acetate 79-21-0 Peroxyacetic acid 79-22-1 methyl chloroformate 79-24-3 Ethane, nitro- 79-27-6 1,1,2,2-tetrabromoethane 79-31-2 *2-Methylpropionic acid 79-33-4 L-Lactic acid 79-34-5 *1,1,2,2-Tetrachloroethane; sym-Tetrachloroethane 79-36-7 dichloroacetyl chloride 79-38-9 *Chlorotrifluoroethylene 79-39-0 *Methacrylamide 79-41-4 Methacrylic acid 79-43-6 dichloroacetic acid 79-44-7 Dimethyl carbamyl chloride 79-46-9 Propane, 2-nitro- 79-74-3 *2,5-Di-tert-amylhydroquinone? 79-77-6 *Ionone 79-92-5 *0 79-94-7 Tetrabromobisphenol A 80-05-7 Bisphenol A 80-08-0 dapsone; 4,4'-diamino diphenyl sulfone 80-10-4 *Dichloro(diphenyl)silane 80-15-9 2-Hydroperoxy-2-phenylpropane 80-38-6 4-chlorophenyl benzenesulphonate; fenson 80-43-3 2-Phenyl-2-[(2-phenylpropan-2-yl)peroxy]propane 80-48-8 *Methyl p-toluenesulfonate 80-51-3 *4,4'-Oxybisbenzenesulfonylhydrazide 80-54-6 *p-tert-Butyl-α-methylhydrocinnamic aldehyde 80-56-8 *2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene; alpha-Pinene 80-62-6 Methyl methacrylate 81-14-1 3,5-Dinitro-2,6-dimethyl-4-tert-butylacetophenone;
Load more

Recommended publications
  • Chemical Threat Agents Call Poison Control 24/7 for Treatment Information 1.800.222.1222 Blood Nerve Blister Pulmonary Metals Toxins
    CHEMICAL THREAT AGENTS CALL POISON CONTROL 24/7 FOR TREATMENT INFORMATION 1.800.222.1222 BLOOD NERVE BLISTER PULMONARY METALS TOXINS SYMPTOMS SYMPTOMS SYMPTOMS SYMPTOMS SYMPTOMS SYMPTOMS • Vertigo • Diarrhea, diaphoresis • Itching • Upper respiratory tract • Cough • Shock • Tachycardia • Urination • Erythema irritation • Metallic taste • Organ failure • Tachypnea • Miosis • Yellowish blisters • Rhinitis • CNS effects • Cyanosis • Bradycardia, bronchospasm • Flu-like symptoms • Coughing • Shortness of breath • Flu-like symptoms • Emesis • Delayed eye irritation • Choking • Flu-like symptoms • Nonspecific neurological • Lacrimation • Delayed pulmonary edema • Visual disturbances symptoms • Salivation, sweating INDICATIVE LAB TESTS INDICATIVE LAB TESTS INDICATIVE LAB TEST INDICATIVE LAB TESTS INDICATIVE LAB TESTS INDICATIVE LAB TESTS • Increased anion gap • Decreased cholinesterase • Thiodiglycol present in urine • Decreased pO2 • Proteinuria None Available • Metabolic acidosis • Increased anion gap • Decreased pCO2 • Renal assessment • Narrow pO2 difference • Metabolic acidosis • Arterial blood gas between arterial and venous • Chest radiography samples DEFINITIVE TEST DEFINITIVE TEST DEFINITIVE TEST DEFINITIVE TESTS DEFINITIVE TESTS • Blood cyanide levels • Urine nerve agent • Urine blister agent No definitive tests available • Blood metals panel • Urine ricinine metabolites metabolites • Urine metals panel • Urine abrine POTENTIAL AGENTS POTENTIAL AGENTS POTENTIAL AGENTS POTENTIAL AGENTS POTENTIAL AGENTS POTENTIAL AGENTS • Hydrogen Cyanide
    [Show full text]
  • Theoretical Studies of Phenylmercury Carboxylates
    TA Theoretical studies of Phenylmercury 2750 carboxylates 2010 This page is intentionally left blank Theoretical studies of Phenylmercury carboxylates Complexation Constants and Gas Phase Photo- Oxidation of Phenylmercurycarboxylates. Yizhen Tang and Claus Jørgen Nielsen CTCC, Department of Chemistry, University of Oslo This page is intentionally left blank Table of Contents Executive Summary ................................................................................................................ 1 1. Quantum chemistry studies on phenylmercurycarboxylates ..................................... 3 2. Results from quantum chemistry ................................................................................... 3 2.1 Structure of phenylmercury(II) carboxylates .............................................................. 4 2.2 Energies of complexation/dissociation ....................................................................... 9 2.3 Vertical excitation energies......................................................................................... 10 2.4 Vertical ionization energies ......................................................................................... 11 2.5 Summary of results from quantum chemistry calculations .................................... 11 3. Atmospheric fate and lifetimes of phenylmercurycarboxylates ............................... 12 3.1 Literature data............................................................................................................... 12 3.2 Estimation of the
    [Show full text]
  • Routine Multipesticide Analysis Orbitrap
    Routine Multi-Pesticide Residue Analysis by Orbitrap MS Technology Osama Abu-Nimreh CMD Sales Support Specialist MECEC , Dubai The world leader in serving science Challenges of Pesticide-Residues Analysis • Sample variability (matrix) • Different compound characteristics • Large number of samples • Hundreds of analytes monitored • Low levels controlled • Baby food (MRL for all pesticides = 0.01 mg/kg) • Fast response required 2 Former Pesticide Multi-Residue Method Setup . Extraction Acetonitrile, Ethyl Mostly replaced acetate, Methanol... by QuEChERS today . Clean-up GPC, SPE, LLE, LC . Determination GC, LC, GC-MS, LC-MS, Thermo Scientific™ QuEChERS™ GC-MS/MS, LC-MS/MS... method 3 Simplified Extraction Procedure Applied 10 g of sample is weighed into Quechers extraction tube + 20 mL of water + 10 mL of ACN shaking 10 min Centrifugation 5 min @ 5000 rpm Injection to LC-HRAM 4 Consumables Used Consumables/Chemicals Part Number Acetonitrile A/0638/17 QuEChERS extraction tube, 50 mL, 250 pack 60105-216 QuEChERS pouches, 50 pack 60105-344 Apparatus/Columns Part Number Horizontal shaker 1069-3391 Horizontal shaker plate 1053-0102 Thermo Scientific™ Barnstead™ EASYpure™II water 3125753 Thermo Scientific™ Heraeus™ Fresco™ 17 micro centrifuge 3208590 Thermo Scientific™ Accucore™ aQ column 100x2.1, 2.6 µm 17326-102130 5 Improving QuEChERS Extraction Tips & Tricks: • Dry food (cereals/dried food, < 25 % water content): • Addition of water to enable adequate partitioning and reducing interaction of pesticides with matrix • Food containing fat/wax (avocado/oil): • After extraction step add a freezing out step and transfer supernatant to clean-up tube • More clean-up might be needed of raw extract (PSA+C18) • Food containing complex matrix (tea/spices) • Additional clean-up with GCB might be necessary (potential loss of planar structure pesticides like thiabendazole) • Acidic food (citrus): • Adjust pH (5-5.5) to increase recovery (e.g.
    [Show full text]
  • COMBINED LIST of Particularly Hazardous Substances
    COMBINED LIST of Particularly Hazardous Substances revised 2/4/2021 IARC list 1 are Carcinogenic to humans list compiled by Hector Acuna, UCSB IARC list Group 2A Probably carcinogenic to humans IARC list Group 2B Possibly carcinogenic to humans If any of the chemicals listed below are used in your research then complete a Standard Operating Procedure (SOP) for the product as described in the Chemical Hygiene Plan. Prop 65 known to cause cancer or reproductive toxicity Material(s) not on the list does not preclude one from completing an SOP. Other extremely toxic chemicals KNOWN Carcinogens from National Toxicology Program (NTP) or other high hazards will require the development of an SOP. Red= added in 2020 or status change Reasonably Anticipated NTP EPA Haz list COMBINED LIST of Particularly Hazardous Substances CAS Source from where the material is listed. 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide Acutely Toxic Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- Acutely Toxic 1-(2-Chloroethyl)-3-(4-methylcyclohexyl)-1-nitrosourea (Methyl-CCNU) Prop 65 KNOWN Carcinogens NTP 1-(2-Chloroethyl)-3-cyclohexyl-1-nitrosourea (CCNU) IARC list Group 2A Reasonably Anticipated NTP 1-(2-Chloroethyl)-3-cyclohexyl-1-nitrosourea (CCNU) (Lomustine) Prop 65 1-(o-Chlorophenyl)thiourea Acutely Toxic 1,1,1,2-Tetrachloroethane IARC list Group 2B 1,1,2,2-Tetrachloroethane Prop 65 IARC list Group 2B 1,1-Dichloro-2,2-bis(p -chloropheny)ethylene (DDE) Prop 65 1,1-Dichloroethane
    [Show full text]
  • Historical Perspectives on Apple Production: Fruit Tree Pest Management, Regulation and New Insecticidal Chemistries
    Historical Perspectives on Apple Production: Fruit Tree Pest Management, Regulation and New Insecticidal Chemistries. Peter Jentsch Extension Associate Department of Entomology Cornell University's Hudson Valley Lab 3357 Rt. 9W; PO box 727 Highland, NY 12528 email: [email protected] Phone 845-691-7151 Mobile: 845-417-7465 http://www.nysaes.cornell.edu/ent/faculty/jentsch/ 2 Historical Perspectives on Fruit Production: Fruit Tree Pest Management, Regulation and New Chemistries. by Peter Jentsch I. Historical Use of Pesticides in Apple Production Overview of Apple Production and Pest Management Prior to 1940 Synthetic Pesticide Development and Use II. Influences Changing the Pest Management Profile in Apple Production Chemical Residues in Early Insect Management Historical Chemical Regulation Recent Regulation Developments Changing Pest Management Food Quality Protection Act of 1996 The Science Behind The Methodology Pesticide Revisions – Requirements For New Registrations III. Resistance of Insect Pests to Insecticides Resistance Pest Management Strategies IV. Reduced Risk Chemistries: New Modes of Action and the Insecticide Treadmill Fermentation Microbial Products Bt’s, Abamectins, Spinosads Juvenile Hormone Analogs Formamidines, Juvenile Hormone Analogs And Mimics Insect Growth Regulators Azadirachtin, Thiadiazine Neonicotinyls Major Reduced Risk Materials: Carboxamides, Carboxylic Acid Esters, Granulosis Viruses, Diphenyloxazolines, Insecticidal Soaps, Benzoyl Urea Growth Regulators, Tetronic Acids, Oxadiazenes , Particle Films, Phenoxypyrazoles, Pyridazinones, Spinosads, Tetrazines , Organotins, Quinolines. 3 I Historical Use of Pesticides in Apple Production Overview of Apple Production and Pest Management Prior to 1940 The apple has a rather ominous origin. Its inception is framed in the biblical text regarding the genesis of mankind. The backdrop appears to be the turbulent setting of what many scholars believe to be present day Iraq.
    [Show full text]
  • The Calcium Arsenates
    Station RuIletin 131. June, 1918 Oregon Agricultural College Experiment Station AGRICULTURAL CHEMISTRY DEPARTMENT The Calcium Arsenates By R. H. ROBINSON Acting Chemist, Oregon Agricultural Experiment Station. CORVALLIS, OREGON The regular huIlejne of the Station are sent free to the residents of Oregon who request them. THE CALCIUM ARSENATES By R. H. ROBINSON Acting Chemist, Oregon Agricultural Experiment Station INTRODUCTION Chemical investigations on the calcium arsenates relative to their economfic value and practicability as insecticides have been carried on by the department of Agricultural Chemistry of this Station during the past two years.The results obtained from these investigations are presented in this bulletin.The work was supported by the annual funds provided by the Adams Act of the United States Government.. Commercial calcium arsenate is an arsenical now being produced by reliable manufacturers of spray material and offered for sale as a sub- stitute for the arsenates of lead.The value of the latter as a stomachic insecticide has been demonstrated, and itis now used extensively for the successful controlof the codling moth, the destructionof the cotton boll worm., the tobacco worm, and the Colorado potato beetle. Previous inveatigations on the toxic values and killing power of calcium arsenate and lead arsenate indicate equal efficiency. A consideration of a few figures will show the economic advantages which might be gained if calcium arsenate could be substituted for lead arsenate.A conservative estimate of the quantity of lead arsenate used annually in the United States, as stated by one of the largest manufac- turers of spray materials, is probably more than 30,000,000 pounds.
    [Show full text]
  • Chemistry 234 Chapter 16 Problem Set Electrophilic Aromatic
    Chemistry 234 Chapter 16 Problem Set Electrophilic Aromatic Substitution 1) Predict the product and draw the mechanism for electrophile generation for each of the following reactions. Cl (a) 2 FeCl3 HNO3 (b) H2SO4 SO (c) 3 H2SO4 2) Explain why reaction of benzene with Br2/FeBr3 results in the product bromobenzne instead of 5,6-dibromo-1,3-cyclohexadiene. 3) Predict the product and draw the active electrophile for each reaction shown below. Cl (a) AlCl3 Cl (b) AlCl3 Cl O (c) AlCl3 Page 1 of 13 Chem. 234 – Chapter 16 Problem Set 4) Explain why each of the following substrates do not undergo Freidel-Crafts reactions. NH2 NO2 N(CH3)3 NH 5) Arrange the following benzene substituents in order of reactivity in electrophilic aromatic substitution reactions. O Cl Ph Ph N Ph Ph H O N H S Ph N Ph Ph Ph O O 6) Predict the maJor products when the following benzene derivatives are treated to nitration conditions (HNO3/H2SO4). a. O Br b. NH2 Br c. NO2 Cl 7) Write the full electron pushing mechanism for the nitration of toluene. Page 2 of 13 Chem. 234 – Chapter 16 Problem Set 8) Predict the product(s) when each of the following benzene derivatives is treated to chloroethane and AlCl3. a. Br b. NH2 Cl c. OH Br d. OH Cl Cl e. NO2 Cl Cl f. Br Br g. SO3H Page 3 of 13 Chem. 234 – Chapter 16 Problem Set 9) Predict the product(s) when the following benzene derivatives are subjected to electrophilic chlorination conditions (Cl2, FeCl3).
    [Show full text]
  • Chemical Hygiene Plan Manual
    CHEMICAL HYGIENE PLAN AND HAZARDOUS MATERIALS SAFETY MANUAL FOR LABORATORIES This is the Chemical Hygiene Plan specific to the following areas: Laboratory name or room number(s): ___________________________________ Building: __________________________________________________________ Supervisor: _______________________________________________________ Department: _______________________________________________________ Telephone numbers 911 for Emergency and urgent consultation 48221 Police business line 46919 Fire Dept business line 46371 Radiological and Environmental Management Revisied on: Enter a revision date here. All laboratory chemical use areas must maintain a work-area specific Chemical Hygiene Plan which conforms to the requirements of the OSHA Laboraotry Standard 29 CFR 19190.1450. Purdue University laboratories may use this document as a starting point for creating their work area specific CHP. Minimally this cover page is to be edited for work area specificity (non-West Lafayette laboratories are to place their own emergency, fire, and police telephone numbers in the space above) AND appendix K must be completed. This instruction and information box should remain. This model CHP is version 2010A; updates are to be found at www.purdue.edu/rem This page intentionally blank. PURDUE CHEMICAL HYGIENE PLAN AWARENESS CERTIFICATION For CHP of: ______________________________ Professor, building, rooms The Occupational Safety and Health Administration (OSHA) requires that laboratory employees be made aware of the Chemical Hygiene Plan at their place of employment (29 CFR 1910.1450). The Purdue University Chemical Hygiene Plan and Hazardous Materials Safety Manual serves as the written Chemical Hygiene Plan (CHP) for laboratories using chemicals at Purdue University. The CHP is a regular, continuing effort, not a standby or short term activity. Departments, divisions, sections, or other work units engaged in laboratory work whose hazards are not sufficiently covered in this written manual must customize it by adding their own sections as appropriate (e.g.
    [Show full text]
  • Safety Data Sheet Acc
    Product Distributed by Rio Grande SDS access on web: www.riogrande.com Page 1 of 13 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 03/20/2015 Reviewed on 03/20/2015 1 Identification · Product identifier · Trade name: Midas® 24K Gold Cyanide-Based Concentrate Plating Solution · Article number: 335-082 · Recommended use and restriction on use · Recommended use: Electroplating material · Restrictions on use: No further relevant information available. · Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: RIO GRANDE 7500 Bluewater Rd. NW Alburquerque NM 87121-1962 1-800-545-6566 [email protected] · Emergency telephone number: ChemTel Inc. (800)255-3924, +1 (813)248-0585 2 Hazard(s) identification · Classification of the substance or mixture GHS06 Skull and crossbones Acute Tox. 2 H300 Fatal if swallowed. Acute Tox. 2 H310 Fatal in contact with skin. Acute Tox. 3 H331 Toxic if inhaled. GHS07 Skin Sens. 1 H317 May cause an allergic skin reaction. · Additional information: There are no other hazards not otherwise classified that have been identified. 0 percent of the mixture consists of ingredient(s) of unknown toxicity. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS06 · Signal word Danger · Hazard-determining components of labeling: potassium cyanide (Contd. on page 2) 40.1.3 Page 2 of 13 Safety Data Sheet acc. to OSHA HCS (29 CFR 1910.1200) Printing date 03/20/2015 Reviewed on 03/20/2015 Trade name: Midas® 24K Gold Cyanide-Based Concentrate Plating Solution (Contd.
    [Show full text]
  • United States Patent Office Patented Feb
    3,794,643 United States Patent Office Patented Feb. 26, 1974 1. 2 3,794,643 aZolinedione derivatives are produced by reacting the QUINAZOLINEDONE DERIVATIVES compounds having the following general formula: Takahiro Yabuuchi, Takarazuka, and Hajime Fujimura, Akira Nakagawa, and Ryuichi Kimura, Kyoto, Japan, assignors to Hisamitsu Pharmaceutical Co., Inc., Tosu, Saga Prefecture, Japan No Drawing. Filed Apr. 20, 1971, Ser. No. 135,693 int, C. C07, 51/48 U.S. C. 260-260 8 Claims ABSTRACT OF THE DISCLOSURE O The present invention relates to novel quinazolinedione R3 R2 derivatives possessing excellent anti-inflammatory action and analgesic action, and process for the production (wherein R2 and/or Rs have the same meaning as men thereof by reacting the compounds having the following 5 tioned above) with the general formula, RX or RSO, general formula, (wherein R represents the same substances as mentioned O above), R represents lower alkyl radical, and X repre C Sents halogen atom). Consequently, the reaction of the present invention can be understood as being alkylation. 20 The abovementioned compounds used as starting reac tion materials in the present invention can be obtained in good yield by reacting N-phenylanthranilic acid or N substituted phenylanthranilic acid with urea. The quinazolinedione derivatives used as the afore Rs R 25 said starting reaction materials include 1-phenyl-2,4- (1H,3H)-quinazolinedione or 1-substituted phenyl-2,4- (1H,3H)-quinazolinedione, for example, (wherein R and/or R3 represent hydrogen atom, CFs, 1-(3'-triuuoromethylphenyl-2,4(1H,3H)-
    [Show full text]
  • FENIX OUTDOOR Chemical Guideline and Restricted Substances
    Management Guideline Number: SU-POL-FE-01-V04-2018-EN Version: 2.1 Pages: 1 of 82 Valid from: 2018-08-08 Chemical Guideline and Restricted Created by: var. au. /AB Substances List Approved by: Aiko Bode/Swerea FENIX OUTDOOR Chemical Guideline and Restricted Substances List (RSL) 1 Number: SU-POL-FE-01-V04-2018-EN Management Version: 2.1 Guideline Page: 2 of 82 Content 1. General Considerations ......................................................................................................... 4 2. Purpose ................................................................................................................................... 4 3. Scope of Application .............................................................................................................. 5 4. Additional Valid Instructions and Reference Documents ................................................... 5 5. Definition of Terms ................................................................................................................. 5 6. Duties and Responsibilities ................................................................................................... 7 7. Content – The Chemicals List ............................................................................................... 8 7.1 Process and Packaging-related Chemicals 8 7.1.1 Alkylphenol ethoxylates (APEO) and derivatives .......................................................................................... 8 7.1.2 Aliphatic organic solvents .............................................................................................................................
    [Show full text]
  • Safety Data Sheet
    SAFETY DATA SHEET 1. Identification Product identifier Jump Start® Starting Fluid Other means of identification Product Code No. 05671 (Item# 1003843) Recommended use Starting fluid Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Physical hazards Flammable aerosols Category 1 Gases under pressure Compressed gas Health hazards Skin corrosion/irritation Category 2 Carcinogenicity Category 2 Specific target organ toxicity, single exposure Category 3 narcotic effects Aspiration hazard Category 1 Environmental hazards Hazardous to the aquatic environment, acute Category 2 hazard Hazardous to the aquatic environment, Category 3 long-term hazard OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Material name: Jump Start® Starting Fluid SDS US No. 05671 (Item# 1003843) Version #: 01 Issue date: 08-29-2017 1 / 10 Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source.
    [Show full text]