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According to Regulation (EU) No. 1907/2006 (REACH), Annex II (COMMISSION REGULATION (EU) No 453/2010)

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According to Regulation (EU) No. 1907/2006 (REACH), Annex II (COMMISSION REGULATION (EU) No 453/2010) According to Regulation (EU) No. 1907/2006 (REACH), Annex II (COMMISSION REGULATION (EU) No 453/2010) Version: 1.0/EN Revision date: 28/05/2012 Product name: Mono bromobenzene SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name: Mono bromobenzene Synonyms: Bromobenzene; Phenyl bromide; Bromobenzol REACH Reg. No.: No registration number is given. CAS No.: 108-86-1 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: Use as an intermediate in the Pharmaceutical and other fine chemical industries. Uses advised against: No information available. 1.3 Details of the supplier of the SDS 1.4 Emergency telephone number SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008[CLP] Flammable liquids, Category 3; H226 Skin irritation, Category 2; H315 Chronic aquatic toxicity, Category 2, H411 Classification according to Directive 67/548/EEC[DSD] or Directive 1999/45/EC[DPD] R10 -- Page 1 / 11 -- According to Regulation (EU) No. 1907/2006 (REACH), Annex II (COMMISSION REGULATION (EU) No 453/2010) Version: 1.0/EN Revision date: 28/05/2012 Product name: Mono bromobenzene Xi; R38 N; R51-53 Additional information Full text of R-phrase(s)/H-statement(s): see SECTION 16. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008[CLP] Hazard pictogram(s): Signal word: Warning Hazard statement(s): H226: Flammable liquid and vapour. H315: Causes skin irritation. H411: Toxic to aquatic life with long lasting effects. Precautionary statement(s): Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370 + P378: In case of fire: Use water spray, carbon dioxide (CO2), dry chemical alcohol-resistant foam for extinction. Disposal: P501: Dispose of contents/container in accordance with local/regional/national/international regulations. Supplemental Hazard information (EUH): No information available. Special rules for supplemental label elements for certain mixtures: No information available. 2.3 Other hazards No information available. SECTION 3: Composition/information on ingredients 3.1 Substance/Preparation information Substance name: Mono Bromobenzene Index number: 602-060-00-9 -- Page 2 / 11 -- According to Regulation (EU) No. 1907/2006 (REACH), Annex II (COMMISSION REGULATION (EU) No 453/2010) Version: 1.0/EN Revision date: 28/05/2012 Product name: Mono bromobenzene CAS No.: 108-86-1 EC No.: 203-623-8 Purity: 99.0 % min. The rest unspecified ingredients are impurities which do not contribute to the classification of the substance. SECTION 4: First aid measures 4.1 Description of first aid measures General notes: In all cases of doubt, or when symptoms persist, seek medical attention. Following inhalation: Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Immediate medical attention is required. Following skin contact: Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes immediate medical attention is required. Following eye contact: Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Following ingestion: Never give anything by mouth to an unconscious person. Drink plenty of water. Get medical attention. If possible drink milk afterwards. 4.2 Most important symptoms and effects, both acute and delayed Acute: Irritation to the skin and eyes, probably also the respiratory tract, narcotic effects and effects on the liver at high exposure. Chronic: No information available for humans, toxic effects on the liver and kidneys found in animal experiments. 4.3 Indication of the immediate medical attention and special treatment needed No information available. SECTION 5: Fire-fighting measures 5.1 Extinguishing media -- Page 3 / 11 -- According to Regulation (EU) No. 1907/2006 (REACH), Annex II (COMMISSION REGULATION (EU) No 453/2010) Version: 1.0/EN Revision date: 28/05/2012 Product name: Mono bromobenzene Suitable extinguishing media: Water spray. Carbon dioxide (CO2). Dry chemical alcohol-resistant foam. Use water spray to cool unopened containers. Unsuitable extinguishing media: No information available. 5.2 Special hazards arising from the substance or mixture Flammable/Explosive properties. Vapors may travel to source of ignition and flash back. Containers may explode when heated. 5.3 Advice for fire-fighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Prevent fire extinguishing water from contaminating surface water or the ground water system. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Refer to SECTION 8 for personal protective equipment. Prevention of skin and eye contact. Ensure adequate ventilation. Remove all sources of ignition Take precautionary measures against static discharges. 6.2 Environmental precautions Do not discharge into drains/surface waters/groundwater. 6.3 Methods and material for containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable and closed containers for disposal. Remove all sources of ignition. Use spark proof tools and explosion-proof equipment. Do not let this chemical enter the environment 6.4 Reference to other SECTIONs See SECTION 7 for information on safe handling. See SECTION 8 for information on personal protection equipment. See SECTION 13 for information on disposal. SECTION 7: Handling and storage 7.1 Precautions for safe handling Handle in accordance with good industrial hygiene and safety practice. Use personal protective equipment as required. Use only under a chemical fume hood. Wear personal protective equipment. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Use explosion-proof equipment. Take precautionary measures against static discharges. 7.2 Conditions for safe storage, including any incompatibilities -- Page 4 / 11 -- According to Regulation (EU) No. 1907/2006 (REACH), Annex II (COMMISSION REGULATION (EU) No 453/2010) Version: 1.0/EN Revision date: 28/05/2012 Product name: Mono bromobenzene Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. 7.3 Specific end use(s) Apart from the uses mentioned in SECTION 1.2 no other specific uses are stipulated. SECTION 8 : Exposure controls/personal protection 8.1 Control parameters Occupational exposure limit values: Not established. DNEL (Derived No Effect Level) for workers and the general population: Not available. PNEC (Predicted No Effect Concentration) values: Not available. 8.2 Exposure controls Appropriate engineering controls: Provide local exhaust or process enclosure ventilation system. Personal protective equipment: Eye and face protection: Wear protective eye/face protection. Skin protection: Wear protective gloves/clothing to prevent contact. Respiratory protection: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Environmental exposure controls: Do not empty into drains. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Clear liquid Odour: aromatic pH: No information available. -- Page 5 / 11 -- According to Regulation (EU) No. 1907/2006 (REACH), Annex II (COMMISSION REGULATION (EU) No 453/2010) Version: 1.0/EN Revision date: 28/05/2012 Product name: Mono bromobenzene Melting point: -31°C / -23.8°F Boiling point: 156°C / 312.8°F Flash point: 51°C / 123.8°F(Closed cup) Evaporation rate: No information available. Flammability (solid, gas): Flammable. Upper/lower flammability or explosive limits: Lower: 0.5% Upper: 2.5% Vapour pressure: 13 hPa at 40°C 4 hPa at 20°C Density: 1.490 g/cm3 Solubility(ies): Practically insoluble Partition coefficient: n-octanol/water: Log Pow=2.99 Auto-ignition temperature: 565 °C Decomposition temperature: No information available. Viscosity: No information available. Explosive properties: No information available. Oxidising properties: No information available. 9.2 Other information No data available. SECTION 10: Stability and reactivity 10.1 Reactivity Vapour/air-mixtures are explosive at intense warming. 10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature). 10.3 Possibility of hazardous reactions The substance can react dangerously with: Oxidizing agents, alkali/alkaline earth metals, peroxy compounds. 10.4 Conditions to avoid Keep away from open flames, hot surfaces and sources of ignition, Excess heat, and Incompatible products. 10.5 Incompatible materials Strong oxidizing agents. Alkali/alkaline earth metals. Peroxy compounds. 10.6 Hazardous decomposition products -- Page 6 / 11 -- According
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