The Jurassic Meteorite Flux: a Record from Extraterrestrial Chrome-Spinels
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THE JURASSIC METEORITE FLUX: A RECORD FROM EXTRATERRESTRIAL CHROME-SPINELS A DISSERTATION SUBMITTED TO THE GRADUATE DIVISION OF THE UNIVERSITY OF HAWAI‘I AT MĀNOA IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY IN EARTH & PLANETARY SCIENCE December 2020 By Caroline E. Caplan Dissertation Committee: Gary R. Huss, Chairperson Kazu Nagashima Hope A. Ishii Greg Ravizza Schelte J. Bus Keywords: chrome-spinel, chromite, Jurassic, meteorites, oxygen isotopes To my ten-year-old self who wanted this for so long, you did it! ii ACKNOWLEDGMENTS Graduate school will forever be one of my favorite times in life. Through its ups and downs I have become more knowledgeable, confident, and have found true joy in science. I am especially thankful to my advisor, Gary Huss, without whom none of this work would have been possible. He has guided me through graduate school to grow as researcher, including giving me the opportunities to explore new avenues of my work. I would also like to thank my committee members: Kazu Nagashima for always answering my questions with patience, Hope Ishii for work and life guidance, Greg Ravizza for his excitement and new perspectives, and Bobby Bus for help with statistics and his endless curiosity. Thanks to Birger Schmitz who allowed me to work on such a special project and for the incredible opportunity to travel to Sweden, Russia, and Italy to obtain a better understanding of my samples and the area of work. I would also like to thank the HIGP and ERTH (GG) departments for fostering a productive and friendly environment. The faculty truly helped me learn and improve as a researcher and person, including Linda Martel, Julia Hammer, Eric Hellebrand, Ryan Ogliore, Jeff Taylor, Paul Lucey, Jeff Gillis-Davis, Patty Fryer, John Bradley, and Kenta Ohtaki. Graduate school was so enjoyable due to the friendships of other students (past and present), including Myriam Telus, Christine Jilly, Sarah Crites, Katie Robinson, Myriam Lemelin, Estelle Bonny, Erin Fitch, Elizabeth Shields, Laura Corley, Melissa Adams, Macey Sandford, Lingzhi Sun, Chiara Ferrari- Wong, Abbey Flom, Emily Costello, Colin Ferguson, Warren McKenzie, and Hannah Shelton. Special thanks to the graduate students who helped with defense and dissertation prep: Diamond Tachera, Brytne Okuhata, and Trista McKenzie. Finally, I would like to thank my family. Thank you to my parents, for letting me live my dreams and for giving me every opportunity to succeed. Thank you to my grandparents for their support, and especially my grandfather, Calhoun Howard, for being a scientific inspiration throughout my life. Thanks to my sister, Anna, for always being my biggest supporter and reminding me that I am intelligent and worthy of great things. And thank you to my husband, Andrew, for always being by my side throughout the hardest and happiest parts of graduate school. iii ABSTRACT This dissertation focuses on the classification of extraterrestrial chrome-spinels to determine meteorite types and fluxes during the Jurassic time period and the techniques needed to achieve such classifications. We know the relative abundances of meteorite types falling on Earth today, but we do not know what fell in the distant past. Abundances of the past are unknown because meteorites tend to only survive on Earth’s surface for a few tens of thousands of years due to the weathering environment of the Earth. Fortunately, chrome-spinels from disaggregated meteorites and micrometeorites can be preserved in limestone and retain their characteristic compositions. In many instances, the parent meteorite type of each grain can be determined by comparing their chemical compositions and oxygen isotope abundances to those of chrome-spinels from modern day meteorites. The goal of this dissertation is to classify chrome-spinel grains from the Jurassic period, determine the relative abundances of parent meteorite types, and compare these abundances to those of other time periods. This was achieved by ensuring we had a well-characterized database of chrome-spinel compositions from modern meteorites in order to reliably classify each remnant chrome-spinel. We also had to confirm that our chemistry and oxygen-isotope measurements of the Jurassic chrome-spinels were reliable. This was determined, in part, by taking new measurements of chrome-spinels from modern meteorites using the same electron and ion microprobes used for the remnant grains. It was also necessary to understand instrumental artifacts that may affect oxygen isotope abundances during ion probe measurements, such as the crystal orientation of chrome-spinel. We confidently classified the remnant chrome-spinels of the Jurassic using the compiled database, and compared the meteorite abundances to other time periods. However, it was difficult to determine the subgroup for a few of the ordinary-chondrite-like grains using chemistry and isotopes alone. In this event, (scanning) transmission electron microscope techniques were implemented to study the silicate inclusions within these chrome-spinels to help determine their parent meteorite type. Overall, this work supports the use of chemistry, oxygen isotopes, and inclusions to classify remnant chrome-spinels and demonstrates that meteorite populations from the past are different than today. iv TABLE OF CONTENTS ACKNOWLEDGMENTS ........................................................................................................... iii ABSTRACT .................................................................................................................................. iv LIST OF TABLES ...................................................................................................................... vii LIST OF FIGURES ..................................................................................................................... ix CHAPTER1. INTRODUCTION ................................................................................................. 1 1.1 Background ................................................................................................................................................... 2 1.2 Jurassic Grains ............................................................................................................................................. 3 1.3 Classifications ............................................................................................................................................... 4 1.4 Technical Advancements ......................................................................................................................... 6 1.5 Dissertation Outline ................................................................................................................................... 7 CHAPTER 2. REMNANT EXTRATERRESTRIAL CHROME-SPINELS REVEAL METEORITE ABUNDANCES OF THE JURASSIC............................................................... 8 2.1 Abstract........................................................................................................................................................... 8 2.2 Introduction .................................................................................................................................................. 9 2.3 Methods ....................................................................................................................................................... 10 2.3.1 Collection and Preparation ............................................................................................................................ 10 2.3.2 Analysis .................................................................................................................................................................. 12 2.3.3 Classification Schemes ..................................................................................................................................... 24 2.4 Results .......................................................................................................................................................... 29 2.4.1 Chemical Compositions ................................................................................................................................... 29 2.4.2 Oxygen Isotopic Compositions..................................................................................................................... 31 2.4.3 Classification ........................................................................................................................................................ 34 2.5 Discussion ................................................................................................................................................... 41 2.5.1 Classification Limitations ............................................................................................................................... 41 2.5.2 Jurassic Grains ..................................................................................................................................................... 50 2.5.3 Time period comparisons .............................................................................................................................. 51 2.5.4 Jurassic Relative Abundances....................................................................................................................... 62 2.6 Conclusions ...............................................................................................................................................