Salt Effect on Vapor-Liquid Equilibria for Acetone-Water System'
SALT EFFECT ON VAPOR-LIQUID EQUILIBRIA FOR ACETONE-WATER SYSTEM' E1ZO SADA, TOSHIO OHNO** AND SHIGEHARU KITO Department of Chemical Engineering, Nagoya University, Nagoya, Japan Vapor-liquid equilibrium data of acetone-water system saturated with sodium chloride, potassium chloride, sodium nitrate, and calcium chloride dihydrate are determined under atmospheric pressure. These vapor-liquid equilibrium data are correlated by a method which gives approximately the behavior of salt in the liquid. The standard deviation of correlated results is 2.32%. To carry out this correlation, the vapor pressures of aqueous solutions saturated with salts are also determined. Investigations concerned with the effect of salt the portion between Cx and Hj is brought to the addition on the vapor-liquid equilibria of binary- vapor pressure of sample solution. Whenthe system systems are of theoretical and industrial importance, attains equilibrium (about one hour is needed), and not a little knowledge of vapor-liquid equilibrium the heights of Hl5 H2, and H3 aremeasured, and the data in this field is already available2}. However, vapor pressure is calculated from the following most investigations are limited to presentation of equation. P '---(Hi-H,W+(Hg-H,W experimental data with no attempt to develop a cor- LO -% r relation. Among these, only a few correlations />*" (1) are proposed, for example, by Johnson and Furter5), As the density of sample solution is usually an order and Hashitani and Hirata3). In this paper, the vapor-liquid equilibrium data of magnitude lower than for mercury, it does not decrease the accuracy of measurementto use the for the acetone-water system saturated with each density of pure water at measuring temperature in of four kinds of salt, i.e.
[Show full text]