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Workshop hosted by Sponsors Contents AU S O T T R S A N L A I A UN S IVERSITIE Contents ContentsOverview 2 Programme 4 Committees 8 Invited speakers 10 Talks 20 Posters 52 Contacts 70 Index 74 Notes 76 www.nbi.ansto.gov.au/neutronsandfood Neutrons and Food 1 Overview Scope The application of neutron scattering to food-based systems is still in its infancy but has significant potential to understand the complex relationship between food structure, processing, rheology, nutrition, food quality and security. OverviewThe “Neutrons and Food” workshop seeks to identify the future scientific needs and opportunities in the application of neutron scattering to food science and to foster collaboration and networking between researchers. The outcomes from this workshop will assist neutron scattering facilities to further adapt their infrastructure to the requirements of the wider scientific community and to enable potential users to develop collaborations with neutron scattering researchers. Time Sunday Monday Tuesday Wednesday 31 October 1 September 2 September 3 September 8.00 Registration 8.45 9.00 Opening and Protein and Digestion and welcome complexes metabolic Introduction processes Drinks and beverages 10.30 Morning tea Morning tea Morning tea 11.00 Dairy Protein and Where to from complexes here? 12.30 Lunch Lunch Lunch 13.30 Lipids and fats Glassy states Visit ANSTO 15.00 Afternoon tea Afternoon tea 15.30 Networking Food packaging session and food safety 17.00 Arrival / Poster session Plant materials registration 19.00 Welcome Workshop dinner reception / harbour cruise 2 Neutrons and Food Map OverviewN Bridge St Lang St Jamison St Amora Hotel Jamison Bond St r Margaret St Curtin Pl Wynyard St Carrington Hunter St n Train Station Wy Shelley St yard Ln yard Western Distributo Erskine St Clarence St St George York St Sussex St Kent St tt St tt Lime St Pi Barrack St King St Darling Harbour Pitt St Ma St Pitt Pier 26 ll Pyrmon t Bridge Market St 100m Neutrons and Food 3 Programme Day 1 - Monday, 1 November 9.00 Welcome by Adi Paterson, Chief Executive Officer, ANSTO Elliot Gilbert and Mike Davidson Introduction Chaired by- Mike Davidson 9.15 Neutrons and food: P. Lillford University of York, Programmewhat are the problems? United Kingdom 9.45 Neutron scattering – a natural tool for food E. Gilbert ANSTO Bragg science and technology research Institute, Australia 10.15 Discussion 10.30 Morning tea sponsored by Nestlé Dairy session Chaired by- Hans Tromp and Rex Hjelm 11.00 Quantitative models of casein micelle C. Holt University of structure derived from SAXS and SANS Glasgow, United Kingdom 11.30 Protein–lipid interactions at model I. Koeper Flinders membrane architectures University, Australia 11.50 Co–adsorption of β–casein and calcium T. Nylander Lund University, phosphate nanoclusters (CPN) at hydrophilic Sweden and hydrophobic solid–solution interfaces studied by neutron reflectometry 12.10 Discussion 12.30 Lunch Lipids and fats session Chaired by- Tommy Nylander and Anna Sokolova 13.30 Neutron scattering, hydrogenous materials J. Katsaras National and nutraceuticals Research Council, Canada 14.00 The effect of water on structuring of organic W. Bouwman Delft University of phases by mixtures of β–sitosterol and Technology, γ–oryzanol The Netherlands 14.20 Nanoaggregates of bile salt and cationic J. Mata ANSTO Bragg surfactant Institute, Australia 14.40 Discussion 15.00 Afternoon tea 15.30 Networking session 17.00 Poster session 4 Neutrons and Food Day 2 - Tuesday, 2 November Protein and complexes session I Chaired by- Stephen Holt and Dominique Champion 9.00 Neutron scattering studies of food structure: R. H. Tromp NIZO food gelation, complexation and the effect of high Research, The pressure Netherlands Programme9.30 The sweet taste of neutrons S. Teixeira Keele University, United Kingdom 9.50 Puroindoline binding to lipids and its relation L. A. Clifton ISIS Spallation to wheat endosperm structure Neutron Source, United Kingdom 10.10 Discussion 10.30 Morning tea sponsored by Nestlé Protein and complexes session II Chaired by- Peter Lillford and John Katsaras 11.00 Protein structure (SANS), water and protein C. Loupiac Université de dynamics (elastic and inelastic neutron Bourgogne, scattering), and protein–lipids interface France (neutron reflectivity) 11.30 Folding and dynamics of the digestive D. Dee University of enzyme pepsin Guelph, Canada 11.50 Antioxidant–protein interactions in D. McGillivray University of phospholipid membranes Auckland, New Zealand 12.10 Discussion 12.30 Lunch Glassy states session Chaired by- Katy Wood and Susana Teixeira 13.30 Protein structure and interactions in the solid S. Krueger NIST, USA state 14.00 Mobility in the vicinity of the glass transition: D. Champion Université de thermal and dynamical properties Bourgogne, France 14.20 The temperature and moisture dependence A. Sokolova ANSTO Bragg of protein dynamics in glycinin: Institute, Australia a quasi–elastic neutron scattering study 14.40 Discussion 15.00 Afternoon tea Day 2 Programme continued next page → Neutrons and Food 5 Day 2 - Tuesday, 2 November continued Food packaging and food safety session Chaired by- Susan Krueger and Jitendra Mata 15.30 Need for neutron scattering techniques in R. Lee PTIS, USA packaging 16.00 Potential for neutron scattering in Food M. Davidson University of ProgrammeSafety Tennessee, Knoxville, USA 16.20 Discussion Plant materials session Chaired by- Herma Buttner and Ingrid Appelqvist 16.40 Multi–scale structural characterisations of A.L. Fameau CEA/INRA, fatty acid multilayer tubes with temperature France tunable diameter in bulk and at the air/water interface by coupling SANS and neutron reflectivity 17.00 Discussion 18.00 Depart from hotel to Pier 26, King St Wharf 18.45 Embark for 19.00 departure 6 Neutrons and Food Day 3 - Wednesday, 3 November Digestion and metabolic processes session Chaired by- Duncan McGillivray and Al Paulson 9.00 Bile physiology and physical chemistry in R. Hjelm Los Alamos digestion: National fundamental insights from small–angle Laboratory, USA Programmeneutron scattering 9.30 Starch granules under attack: J. Blazek ANSTO Bragg multidisciplinary investigation of structural Institute, Australia mechanisms governing starch digestion Drinks and beverages session Chaired by- Wim Bouwman and Jaroslav Blazek 9.50 Colloidal interactions involving condensed A. Vernhet Montpellier tannins in diluted systems: SupAgro, France what problems can we solve through SANS? 10.20 Discussion Where to from here? Chaired by- Rob McGreevy, Mike Davidson, Elliot Gilbert and Herma Buttner 10.40 Open forum including morning tea 12.30 Lunch 13.30 Visit ANSTO Neutrons and Food 7 International Scientific Advisory Committee (ISAC) Peter Belton UEA, UK CommitteesArjen Bot Unilever, Netherlands Jörg Fitter Jülich, Germany Rex Hjelm LANSCE, USA Peter Lillford University of York, UK Duncan McGillivray University of Auckland, New Zealand Phil Perkins Bush Brothers, USA V. Prakash CFTRI, India Hans Tromp NIZO, Netherlands Johan Ubbink Nestlé Res. Cent., Lausanne, Switzerland Rickey Yada University of Guelph, AFMNET, Canada 8 Neutrons and Food Organising Committee Joseph Bevitt ANSTO CommitteesJaroslav Blazek ANSTO Herma Buttner ANSTO Elliot Gilbert ANSTO Martin Kelly ANSTO Jitendra Mata ANSTO Anna Sokolova ANSTO Rhiannon Still AINSE Cherylie Thorn ANSTO Michael Zettinig ANSTO Neutrons and Food 9 Invited speakers Neutron scattering - a natural tool for food science and Elliot Gilbert technology research ANSTO, Australia Elliot Gilbert is programme leader for Food Science at the InvitedAustralian Nuclear Science and Technology Organisation spea (ANSTO) in Sydney, Australia and instrument responsible for the small-angle neutron scattering instrument, Quokka. He was born in London, completed a first degree in Chemical Physics at Edinburgh University before moving to Australia to undertake a PhD in polymer physics. This is where he was first exposed to the idea of using neutrons to probe structure and dynamics in materials. After completing a postdoctoral fellowship with a major international company studying the formation of high-internal phase emulsions for explosive application, he subsequently became a fellow at Argonne National Laboratory in the United States where he investigated the structure of polymers in confined geometry. He returned to Australia in late 2001 to lead the project for the design, construction and commissioning of the state-of-the-art small-angle neutron scattering instrument Quokka, at ANSTO. Elliot’s interests lie in soft condensed matter science and has investigated such diverse areas as phase separation in paraffins, the design of biocompatible ferrofluids for medical application and the nanostructure of composite materials for aerospace. He now has an increasing focus on naturally occurring materials. Elliot devised, initiated and now leads a research group in the application of nuclear methods to investigate fundamental and industrial problems of national significance in food materials science. He recently published the first review of neutron scattering as applied to food-based systems in Trends in Food Science and Technology and is chair of the next international small-angle scattering conference in 2012. 10 Neutrons and Food Bile physiology and physical chemistry in digestion: Rex Hjelm fundamental insights from small–angle neutron scattering LANSCE, United States of America Rex Hjelm is a Senior Scientist at Los Alamos National Invited speaLaboratory (LANL); in addition he holds