The Metamorphic Facies Concept
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CORDIERITE-GARNET GNEISS and ASSOCIATED MICRO- CLINE-RICH PEGMATITE at STURBRIDGE, I,{ASSA- CHUSETTS and UNION, CONNECTICUTI Fnor B.Cnrbn, [
THE AMERICAN MINERALOGIST, VOL 47, IVLY AUGUST, 1962 CORDIERITE-GARNET GNEISS AND ASSOCIATED MICRO- CLINE-RICH PEGMATITE AT STURBRIDGE, I,{ASSA- CHUSETTS AND UNION, CONNECTICUTI Fnor B.cnrBn, [/. S. GeologicalSurttey, Washington,D. C. Aesrnacr Gneiss of argillaceous composition at Sturbridge, Massachusetts, and at Union, Connecticut, 10 miles to the south, consists of the assemblagebiotite-cordierite-garnet- magnetite-microcline-quartz-plagioclase-sillimanite. The conclusion is made that this assemblagedoes not violate the phase rule. The cordierite contains 32 mole per cent of Fe- end member, the biotite is aluminous and its ratio MgO: (MgOf I'eO) is 0.54, and the gar- net is alm6e5 pyr26.agro2.espe1.2.Lenses of microcline-quartz pegmatite are intimately as- sociated with the gneissl some are concordant, others cut acrossthe foliation and banding of the gneiss. The pegmatites also contain small amounts of biotite, cordierite, garnet, graphite, plagioclase, and sillimanite; each mineral is similar in optical properties to the corresponding one in the gneiss. It is suggestedthat muscovite was a former constituent of the gneiss at a lower grade of metamorphism, and that it decomposedwith increasing metamorphism, and reacted with quartz to form siliimanite in situ and at lerst part of the microcline of the gneiss and pegmatites These rocks are compared with similar rocks of Fennoscandia and Canada. INtnouucrroN Cordierite-garnet-sillimanitegneisses that contain microcline-quartz pegmatiteare found in Sturbridge,Massachusetts, and Union, Connecti- cut. The locality (Fig. 1) at Sturbridgeis on the south sideof the \{assa- chusettsTurnpike at the overpassof the New Boston Road; this is about 1 mile west of the interchangeof Route 15 with the Turnpike. -
Facies and Mafic
Metamorphic Facies and Metamorphosed Mafic Rocks l V.M. Goldschmidt (1911, 1912a), contact Metamorphic Facies and metamorphosed pelitic, calcareous, and Metamorphosed Mafic Rocks psammitic hornfelses in the Oslo region l Relatively simple mineral assemblages Reading: Winter Chapter 25. (< 6 major minerals) in the inner zones of the aureoles around granitoid intrusives l Equilibrium mineral assemblage related to Xbulk Metamorphic Facies Metamorphic Facies l Pentii Eskola (1914, 1915) Orijärvi, S. l Certain mineral pairs (e.g. anorthite + hypersthene) Finland were consistently present in rocks of appropriate l Rocks with K-feldspar + cordierite at Oslo composition, whereas the compositionally contained the compositionally equivalent pair equivalent pair (diopside + andalusite) was not biotite + muscovite at Orijärvi l If two alternative assemblages are X-equivalent, l Eskola: difference must reflect differing we must be able to relate them by a reaction physical conditions l In this case the reaction is simple: l Finnish rocks (more hydrous and lower MgSiO3 + CaAl2Si2O8 = CaMgSi2O6 + Al2SiO5 volume assemblage) equilibrated at lower En An Di Als temperatures and higher pressures than the Norwegian ones Metamorphic Facies Metamorphic Facies Oslo: Ksp + Cord l Eskola (1915) developed the concept of Orijärvi: Bi + Mu metamorphic facies: Reaction: “In any rock or metamorphic formation which has 2 KMg3AlSi 3O10(OH)2 + 6 KAl2AlSi 3O10(OH)2 + 15 SiO2 arrived at a chemical equilibrium through Bt Ms Qtz metamorphism at constant temperature and = -
The Origin of Formation of the Amphibolite- Granulite Transition
The Origin of Formation of the Amphibolite- Granulite Transition Facies by Gregory o. Carpenter Advisor: Dr. M. Barton May 28, 1987 Table of Contents Page ABSTRACT . 1 QUESTION OF THE TRANSITION FACIES ORIGIN • . 2 DEFINING THE FACIES INVOLVED • • • • • • • • • • 3 Amphibolite Facies • • • • • • • • • • 3 Granulite Facies • • • • • • • • • • • 5 Amphibolite-Granulite Transition Facies 6 CONDITIONS OF FORMATION FOR THE FACIES INVOLVED • • • • • • • • • • • • • • • • • 8 Amphibolite Facies • • • • • • • • 9 Granulite Facies • • • • • • • • • •• 11 Amphibolite-Granulite Transition Facies •• 13 ACTIVITIES OF C02 AND H20 . • • • • • • 1 7 HYPOTHESES OF FORMATION • • • • • • • • •• 19 Deep Crust Model • • • • • • • • • 20 Orogeny Model • • • • • • • • • • • • • 20 The Earth • • • • • • • • • • • • 20 Plate Tectonics ••••••••••• 21 Orogenic Events ••••••••• 22 Continent-Continent Collision •••• 22 Continent-Ocean Collision • • • • 24 CONCLUSION • . • 24 BIBLIOGRAPHY • • . • • • • 26 List of Illustrations Figure 1. Precambrian shields, platform sediments and Phanerozoic fold mountain belts 2. Metamorphic facies placement 3. Temperature and pressure conditions for metamorphic facies 4. Temperature and pressure conditions for metamorphic facies 5. Transformation processes with depth 6. Temperature versus depth of a descending continental plate 7. Cross-section of the earth 8. Cross-section of the earth 9. Collision zones 10. Convection currents Table 1. Metamorphic facies ABSTRACT The origin of formation of the amphibolite granulite transition -
Transition from Staurolite to Sillimanite Zone, Rangeley Quadrangle, Maine
CHARLES V. GUIDOTTI Department of Geology and Geophysics, University of Wisconsin, Madison, Wisconsin 53706 Transition from Staurolite to Sillimanite Zone, Rangeley Quadrangle, Maine ABSTRACT GENERAL GEOLOGICAL SETTING Ordovician and Silurian to Devonian pelitic schist, conglomerate, quartzite, calc-silicate Study of pelitic schists in the Rangeley Figure 1 shows the location of the area granulite, and biotite schist. Post-tectonic, area, Maine, by means of petrographic, and a generalized geologic map of the shallow-dipping, adamellite sheets intrude x-ray, and electron-microprobe techniques southwestern third of the Rangeley quad- the metamorphosed strata. As illustrated in enables definition of the isogradic reaction rangle based upon Moench (1966, 1969, Figure 1, the isograds have a clear spacial relating the staurolite and lower sillimanite 1970a, 1970b, 1971). The rocks in this area relation to the distribution of the adamel- zones. The reaction is a discontinuous one consist of tightly folded, northeast-trending lites; but in a few cases, the adamellite and can be shown on an AFM projection as the tie line change from staurolite + chlorite to sillimanite 4- biotite. This topology change, in conjunction with the min- eralogical data provides the equation: Staur + Mg-Chte + Na-Musc + (Gam?) Sill + Bio + K-richer Muse + Ab + Qtz + H20. This reaction should result in a sharp isograd in the field but in fact is found to be spread out over a zone which is called the transition zone. It is proposed that this zene results from buffering of fH20 by means of the equation above. Buffering of fH.,o by continuous reactions also appears to be taking place in the lower sillimanite zone. -
Geologic Map of the Southern Ivrea-Verbano Zone, Northwestern Italy
•usGsscience for a changing world Geologic Map of the Southern Ivrea-Verbano Zone, Northwestern Italy By James E. Quick,1 Silvano Sinigoi,2 Arthur W. Snoke,3 Thomas J. Kalakay,3 Adriano Mayer,2 and Gabriella Peressini2·4 Pamphlet to accompany Geologic Investigations Series Map I- 2776 1U. S. Geological Survey, Reston, VA 20192- 0002. 2Uni versita di Trieste, via Weiss 8, 341 27 Trieste, ltalia. 3Uni versity of Wyoming, Larami e, WY 8207 1- 3006. 4Max-Planck-lnstitut ft.ir Chemi e, J.J. Becherweg 27, 55 128 Mainz, Germany. 2003 U.S. Department of the Interi or U.S. Geological Survey COVER: View of the Ponte della Gula, an ancient bridge spanning the Torrente Mastellone approximately 2 kilometers north of the village of Varallo. Diorite of Valsesia crops out beneath the bridge. Photograph by ADstudia, Silvana Ferraris, photographer, Pizza Calderini, 3-13019 Varallo Sesia ([email protected]) INTRODUCTION REGIONAL SETTING The intrusion of mantle-derived magma into the deep conti The Ivrea-Verbano Zone (fig. 1) is a tectonically bounded sliver nental crust, a process commonly referred to as magmatic of plutonic and high-temperature, high-pressure metamorphic underplating, is thought to be important in shaping crustal com rocks in the southern Alps of northwestern Italy (Mehnert, position and structure. However, most evidence for this process 1975; Fountain, 1976). To the northwest, it is faulted against is indirect. High P-wave velocities and seismic-reflection profiles the basement of the Austro-Alpine Domain by the lnsubric Line, reveal that much of the deep continental crust is dense and a major suture zone that separates the European and Apulian strongly layered, consistent with the presence of layered mafic plates (Schmid and others, 1987; Nicolas and others, 1990). -
Oregon Geologic Digital Compilation Rules for Lithology Merge Information Entry
State of Oregon Department of Geology and Mineral Industries Vicki S. McConnell, State Geologist OREGON GEOLOGIC DIGITAL COMPILATION RULES FOR LITHOLOGY MERGE INFORMATION ENTRY G E O L O G Y F A N O D T N M I E N M E T R R A A L P I E N D D U N S O T G R E I R E S O 1937 2006 Revisions: Feburary 2, 2005 January 1, 2006 NOTICE The Oregon Department of Geology and Mineral Industries is publishing this paper because the infor- mation furthers the mission of the Department. To facilitate timely distribution of the information, this report is published as received from the authors and has not been edited to our usual standards. Oregon Department of Geology and Mineral Industries Oregon Geologic Digital Compilation Published in conformance with ORS 516.030 For copies of this publication or other information about Oregon’s geology and natural resources, contact: Nature of the Northwest Information Center 800 NE Oregon Street #5 Portland, Oregon 97232 (971) 673-1555 http://www.naturenw.org Oregon Department of Geology and Mineral Industries - Oregon Geologic Digital Compilation i RULES FOR LITHOLOGY MERGE INFORMATION ENTRY The lithology merge unit contains 5 parts, separated by periods: Major characteristic.Lithology.Layering.Crystals/Grains.Engineering Lithology Merge Unit label (Lith_Mrg_U field in GIS polygon file): major_characteristic.LITHOLOGY.Layering.Crystals/Grains.Engineering major characteristic - lower case, places the unit into a general category .LITHOLOGY - in upper case, generally the compositional/common chemical lithologic name(s) -
Control of Material Transport and Reaction Mechanisms by Metastable Mineral Assemblages: an Example Involving Kyanite, Sillimanite, Muscovite and Quartz
Fluid-Mineral Interactions: A Tribute to H. P. Eugster © The Geochemical Society, Special Publication No.2, 1990 Editors: R. J. Spencer and I-Ming Chou Control of material transport and reaction mechanisms by metastable mineral assemblages: An example involving kyanite, sillimanite, muscovite and quartz C. T. FOSTER,JR. Geology Department, University ofIowa, Iowa City, Iowa 52242, U.S.A. Abstract-Metastable mineral assemblages strongly influence reaction mechanisms and material transport when a new mineral grows in a metamorphic rock. The effects exerted by the metastable assemblages on the reactions that take place when sillimanite grows in a kyanite-bearing rock are examined using metastable elements of activity diagrams and irreversible thermodynamic principles. The results show that a commonly inferred reaction mechanism, where muscovite assists in the growth of sillimanite at the expense of kyanite, is a consequence of material transport constraints imposed by a metastable mineral assemblage in the matrix that separates growing sillimanite from dissolving kyanite. INTRODucnON pressures and temperatures represented by points I, II, and III (Fig. la) is shown in Fig. lb. ONEOFTHEPRIMARYcontrols on mineral textures Sillimanite nuclei first form in sites in the rock that develop during metamorphism is the distri- with the lowest activation energy for nucleation of bution of minerals in a rock at the time when a sillimanite. Under many metamorphic conditions, new mineral nucleates. The distribution of the new the low energy sites for sillimanite nucleation in mineral is strongly influenced by the abundance pelites appear to be in micas, because this is where and location of other minerals with favorable nu- sillimanite is commonly first observed with in- cleation sites for it. -
A Systematic Nomenclature for Metamorphic Rocks
A systematic nomenclature for metamorphic rocks: 1. HOW TO NAME A METAMORPHIC ROCK Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: Web version 1/4/04. Rolf Schmid1, Douglas Fettes2, Ben Harte3, Eleutheria Davis4, Jacqueline Desmons5, Hans- Joachim Meyer-Marsilius† and Jaakko Siivola6 1 Institut für Mineralogie und Petrographie, ETH-Centre, CH-8092, Zürich, Switzerland, [email protected] 2 British Geological Survey, Murchison House, West Mains Road, Edinburgh, United Kingdom, [email protected] 3 Grant Institute of Geology, Edinburgh, United Kingdom, [email protected] 4 Patission 339A, 11144 Athens, Greece 5 3, rue de Houdemont 54500, Vandoeuvre-lès-Nancy, France, [email protected] 6 Tasakalliontie 12c, 02760 Espoo, Finland ABSTRACT The usage of some common terms in metamorphic petrology has developed differently in different countries and a range of specialised rock names have been applied locally. The Subcommission on the Systematics of Metamorphic Rocks (SCMR) aims to provide systematic schemes for terminology and rock definitions that are widely acceptable and suitable for international use. This first paper explains the basic classification scheme for common metamorphic rocks proposed by the SCMR, and lays out the general principles which were used by the SCMR when defining terms for metamorphic rocks, their features, conditions of formation and processes. Subsequent papers discuss and present more detailed terminology for particular metamorphic rock groups and processes. The SCMR recognises the very wide usage of some rock names (for example, amphibolite, marble, hornfels) and the existence of many name sets related to specific types of metamorphism (for example, high P/T rocks, migmatites, impactites). -
What We Know About Subduction Zones from the Metamorphic Rock Record
What we know about subduction zones from the metamorphic rock record Sarah Penniston-Dorland University of Maryland Subduction zones are complex We can learn a lot about processes occurring within active subduction zones by analysis of metamorphic rocks exhumed from ancient subduction zones Accreonary prism • Rocks are exhumed from a wide range of different parts of subduction zones. • Exhumed rocks from fossil subduction zones tell us about materials, conditions and processes within subduction zones • They provide complementary information to observations from active subduction systems Tatsumi, 2005 The subduction interface is more complex than we usually draw Mélange (Bebout, and Penniston-Dorland, 2015) Information from exhumed metamorphic rocks 1. Thermal structure The minerals in exhumed rocks of the subducted slab provide information about the thermal structure of subduction zones. 2. Fluids Metamorphism generates fluids. Fossil subduction zones preserve records of fluid-related processes. 3. Rheology and deformation Rocks from fossil subduction zones record deformation histories and provide information about the nature of the interface and the physical properties of rocks at the interface. 4. Geochemical cycling Metamorphism of the subducting slab plays a key role in the cycling of various elements through subduction zones. Thermal structure Equilibrium Thermodynamics provides the basis for estimating P-T conditions using mineral assemblages and compositions Systems act to minimize Gibbs Free Energy (chemical potential energy) Metamorphic facies and tectonic environment SubduconSubducon zone metamorphism zone metamorphism Regional metamorphism during collision Mid-ocean ridge metamorphism Contact metamorphism around plutons Determining P-T conditions from metamorphic rocks Assumption of chemical equilibrium Classic thermobarometry Based on equilibrium reactions for minerals in rocks, uses the compositions of those minerals and their thermodynamic properties e.g. -
Metamorphic Facies Metamorphic Grade Metamorphic Zones
Metamorphic Grade • Controlled by the temperature of Metamorphic Facies metamorphism • Low-grade rocks contain hydrated and Best, Chapter 10 carbonated phases • High-grade rocks are dehydrated and decarbonized Metamorphic Zones • Mappable metamorphic units of similar grade in a rock of distinct composition • Isograds are lines marking the first appearance of key minerals • Zones of Barrow – Biotite, garnet, staurolite, kyanite, sillimanite Metamorphic Reactions Metamorphic Facies • Formation of talc in a siliceous dolomite Dol + Qtz + H20 = Tlc + Cal + C02 • The set of mineral assemblages occurring in • Controlled by the ratio of H 0/ C0 2 2 rocks of diverse composition • Facies develop under restricted P,T conditions • Mineral assemblages may be plotted on ACF diagrams Main Facies Review of Facies • Zeolite • Prehnite- • Mineral assemblages in metamorphosed pumpellyite mafic rocks •Blueschist • Greenschist • Correlation of Barrow’s zones with facies • Amphibolite from different protoliths • Granulite • P, T diagram for various facies • Eclogite P,T Relations Review of Phase Diagrams Jadeite + Quartz = Albite • Solid-solid reactions • Governed by Clapeyron equation – dP/dT = 10 ∆H/T ∆V = ∆S/∆V – ∆H is the heat of reaction – ∆S is the change in entropy – ∆V is the change in volume • The slope of the stability is dP/dT Open System Models - H2O Open System Models - CO2 • Dehydration curves • Dehydration curves • Example of the general • Example of the general case case • Specific minerals • Specific minerals – Breakdown of chlorite, – Breakdown of calcite, muscovite, biotite, etc dolomite, etc Univariant Curves • Curves that define reactions with one degree of freedom • In P-T space this means that if T is changed, than P must also change to maintain equilibrium • Many important metamorphic reactions are defined by these curves P-T Examples Stability of Iron Oxides • PO2 vs. -
Metamorphic Rocks
Metamorphic Rocks Geology 200 Geology for Environmental Scientists Regionally metamorphosed rocks shot through with migmatite dikes. Black Canyon of the Gunnison, Colorado Metamorphic rocks from Greenland, 3.8 Ga (billion years old) Major Concepts • Metamorphic rocks can be formed from any rock type: igneous, sedimentary, or existing metamorphic rocks. • Involves recrystallization in the solid state, often with little change in overall chemical composition. • Driving forces are changes in temperature, pressure, and pore fluids. • New minerals and new textures are formed. Major Concepts • During metamorphism platy minerals grow in the direction of least stress producing foliation. • Rocks with only one, non-platy, mineral produce nonfoliated rocks such as quartzite or marble. • Two types of metamorphism: contact and regional. Metamorphism of a Granite to a Gneiss Asbestos, a metamorphic amphibole mineral. The fibrous crystals grow parallel to least stress. Two major types of metamorphism -- contact and regional Major Concepts • Foliated rocks - slate, phyllite, schist, gneiss, mylonite • Non-foliated rocks - quartzite, marble, hornfels, greenstone, granulite • Mineral zones are used to recognize metamorphic facies produced by systematic pressure and temperature changes. Origin of Metamorphic Rocks • Below 200oC rocks remain unchanged. • As temperature rises, crystal lattices are broken down and reformed with different combinations of atoms. New minerals are formed. • The mineral composition of a rock provides a key to the temperature of formation (Fig. 6.5) Fig. 6.5. Different minerals of the same composition, Al2SiO5, are stable at different temperatures and pressures. Where does the heat come from? • Hot magma ranges from 700-12000C. Causes contact metamorphism. • Deep burial - temperature increases 15-300C for every kilometer of depth in the crust. -
Stratigraphy of Ontario Ridge Metasediments
Pseudo-stratigraphic Column of Ontario Ridge Metasediments Member 10: Upper portion leucocratic migmatite with minor melanocratic gneiss and locally containing small pods of hornblende rock derived from marble; melanocratic gneiss in lower portion; large swath of marble in lower portion with basal calc-silicate and calc-silicate east of Bighorn Peak, sparse quartzite outcrops. Also includes quartzite layer near Shortcut Ridge with several feet of biotite-hornblende-quartz gneiss near center. *Migmatite: light gray, medium to ne-grained; vague irregular compositional layering, layers locally intrude one another; ptygmatically folded; thin irregular aplite bodies common; average composition about 55% feldspar, 35% quartz and 10% hornblende; biotite locally present; scattered euhedra of sphene usually visible in hand specimen. *Melanocratic gneiss: conspicuously banded with dark gray layers a fraction of an inch to several inches thick alternating with whitish gray layers mostly less 10 than two inches thick; layers irregularly to semiregularly folded with wavelengths of a few inches; fold axes subparallel; dark layers ne-grained, foliated, compositionally variable but typically about 60% hornblende and/or biotite, 30% plagioclase and 10% quartz; light layers ne- to medium-grained; aplitic in appearance, lenticular with irregular shapes, composed of quartz and feldspar. *Quartzite: light gray, granoblastic, ne- to medium-grained; very thin poorly-dened bedding; tightly folded in most outcrops with fold amplitudes of a few inches to a few feet, sheared folds locally simulate crossbedding; average quartz content about 80%, biotite most common accessory. 210 meter thickness Member 9: Gneisses and migmatites dominant; migmatite extensively developed along south side of Icehouse Canyon; roughly 50 feet of dolomite marble and minor calc-silicate rocks 250 feet below top of member; minor marble and calc-silicate rocks interbedded near base; graphite-rich schists locally present.