Why Use a Flame Arrester?
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The Chemistry of Combustion and Arson
CHAPTER 11 The Chemistry of Combustion and Arson 11.1 The Combustion Continuum 11.3 Fires and Flames 11.2 Aspects of Combustion 11.4 Arson and Fire Investigation OVERVIEW AND ORIENTATION The next few chapters will tackle the second most important work area (behind drug analysis and toxicology) in forensic chemistry. We will begin with an exploration of the fundamentals of combustion, a specialized type of oxidation–reduction that spans can- dle flames to powerful and destructive explosions. The important differences between a fire and a bomb are the speed at which the combustion occurs and the degree to which it is confined. As we will see, combustion can be thought of as a continuum. Forensically, combustion is the process at the heart of arson, bombing, and, perhaps less obviously, gunshot residue. In this chapter, we will cover the fundamental principles that underlie these three types of forensic cases and evidence and discuss the physical evidence asso- ciated with fires. In Chapter 12, we will delve into propellants and gunshot residue and complete our discussion in Chapter 13 , where we will explore explosives. 11.1 THE COMBUSTION CONTINUUM Combustion is an oxidative decomposition in which oxygen (the oxidant) oxidizes a fuel. The different manifestations of combustion ( Figure 11.1 ), ranging from a gentle candle flame to a violent military explosive, are part of a continuum that includes the propel- lants used in firearms. The terms we use to describe this decomposition depends on characteristics such as the speed of the reaction. For example, in the detonation of an ex- plosive, the reaction front moves faster than the speed of sound (~ 741 mph, or 331 m/s). -
Iatg 01.40:2015[E]
INTERNATIONAL IATG AMMUNITION TECHNICAL 01.40 GUIDELINE Second edition 2015-02-01 Glossary of terms, definitions and abbreviations IATG 01.40:2015[E] © UN ODA 2015 IATG 01.40:2015(E) 2nd Edition (2015-02-01) Warning The International Ammunition Technical Guidelines (IATG) are subject to regular review and revision. This document is current with effect from the date shown on the cover page. To verify its status, users should consult the UN SaferGuard IATG project through the United Nations Office for Disarmament Affairs (UNODA) website at: www.un.org/disarmament/un-saferguard. Copyright notice This document is an International Ammunition Technical Guideline and is copyright protected by the United Nations. Neither this document, nor any extract from it, may be reproduced, stored or transmitted in any form, or by any means, for any other purpose without prior written permission from UNODA, acting on behalf of the United Nations. This document is not to be sold. United Nations Office for Disarmament Affairs (UNODA) United Nations Headquarters, New York, NY 10017, USA E-mail: [email protected] Tel: +1 917 367 2904 Fax: +1 917 367 1757 UN 2015 – All rights reserved i IATG 01.40:2015(E) 2nd Edition (2015-02-01) Contents Contents .................................................................................................................................................. ii Foreword ............................................................................................................................................... -
Gas Explosion Handbook
Gas Explosion Handbook Authors: Dag Bjerketvedt Jan Roar Bakke Kees van Wingerden Gas Explosion Handbook (1992) Preamble The original Gas Explosion Handbook was written by CMR (later CMR Gexcon) in 1992 and distributed as a set of HTML files. We recently decided to instead distribute a printable pdf version with an updated frontpage and preamble, to make it easier to print and to search within the content. Apart from these changed the content is identical to the HTML version from 1992. Obviously, since the publication of this handbook 25 years ago, more research has been done into the various types of explosion phenomena and some of the previous insights may have changed or have been refined over the years. However, the described main mechanisms and the majority of the content are still equally valid today and the handbook should still be a useful starting point for understanding explosion phenomena today. Dr. Kees van Wingerden Senior Vice President Gexcon AS (previously CMR Gexcon) February 2019, Bergen Norway For information on the various related services and software products Gexcon provides, please visit our website at: www.gexcon.com. Disclaimer: Gexcon AS accepts no legal liability or responsibility whatsoever for the consequences of unqualified use or misuse of this book or any results thereof. © Gexcon AS. The information contained herein is to be used by the recipient solely for the purpose for which it was supplied. It shall not be disclosed in whole or in part, by any other party without the written permission of Gexcon AS. GAS EXPLOSION HANDBOOK Authors: Dag Bjerketvedt Jan Roar Bakke Kees van Wingerden TABLE OF CONTENTS • FOREWORD • 1. -
M E M O R a N D U M
National Fire Protection Association 1 Batterymarch Park, Quincy, MA 02169-7471 Phone: 617-770-3000 • Fax: 617-770-0700 • www.nfpa.org M E M O R A N D U M TO: NFPA Technical Committee on Explosion Protection Systems FROM: Elena Carroll, Administrator, Technical Projects DATE: September 9, 2011 SUBJECT: NFPA 67 ROP TC Letter Ballot (F2012) ____________________________________________________________ The ROP letter ballot for NFPA 67 is attached. The ballot is for formally voting on whether or not you concur with the committee’s actions on the proposals. Reasons must accompany all negative and abstention ballots. Please do not vote negatively because of editorial errors. However, please bring such errors to my attention for action. Please complete and return your ballot as soon as possible but no later than Friday, September 30, 2011. As noted on the ballot form, please return the ballot to Elena Carroll either via e-mail to [email protected] or via fax to 617-984-7110. You may also mail your ballot to the attention of Elena Carroll at NFPA, 1 Batterymarch Park, Quincy, MA 02169. The return of ballots is required by the Regulations Governing Committee Projects. Attachments: Proposals Letter Ballot Report on Proposals – November 2012 NFPA 67 _______________________________________________________________________________________________ 67-1 Log #CP13 _______________________________________________________________________________________________ Technical Committee on Explosion Protection Systems, The Technical Committee on Explosion Protection Systems is proposing the adoption of a new document, NFPA 67, , as shown at the end of this report. The committee has developed this document to provide the user with criteria for designing piping systems to protect against damage from deflagrations or detonations due to combustion of flammable atmospheres therein. -
Understanding Vented Gas Explosions
rf *t*o 3 V77-T?bry — (trr*. ! Understanding vented gas explosions RECEIVED APR 2 7 1998 O&TI DISTRIBUTION OF THIS DOCUMENT IS UNLIMITED "VTT FORBGN PROHIBITED^. TECHNICAL RESEARCH CENTRE OF FINLAND VTT TIEDOTTEITA - MEDDELANDEN - RESEARCH NOTES 1812 Understanding vented gas explosions Risto Lautkaski VTT Energy ■’Jtt ISBN 951-38-5087-0 ISSN 1235-0605 Copyright © Valtion teknillinen tutkimuskeskus (VTT) 1997 JULKAISUA - UTGIVARE - PUBLISHER Valtion teknillinen tutkimuskeskus (VTT), Vuorimiehentie 5, PL 2000, 02044 VTT puh. vaihde (09) 4561, faksi (09) 456 4374 Statens tekniska forskningscentral (VTT), Bergsmansvagen 5, PB 2000, 02044 VTT tel. vaxel (09) 4561, fax (09) 456 4374 Technical Research Centre of Finland (VTT), Vuorimiehentie 5, P.O.Box 2000, FIN-02044 VTT, Finland phone internal. + 358 9 4561, fax + 358 9 456 4374 VTT Energia, Energiajaijestelmat, Tekniikantie 4C, PL 1606, 02044 VTT puh. vaihde (09) 4561, faksi (09) 456 6538 VTT Energi, Energisystem, Teknikvagen 4C, PB 1606, 02044 VTT tel. vaxel (09) 4561, fax (09) 456 6538 VTT Energy, Energy Systems, Tekniikantie 4C, P.O.Box 1606, FIN-02044 VTT, Finland phone internal. + 358 9 4561, fax + 358 9 456 6538 Technical editing Leena Ukskoski DISCLAIMER Portions of this document may be illegible electronic image products. Images are produced from the best available original document. Lautkaski, Risto. Understanding vented gas explosions. Espoo 1997. Technical Research Centre of Finland, VTT Tiedotteita - Meddelanden - Research Notes 1812. 129 p. UDC 533.27:541.126 Keywords gases, explosions, vented explosions, flammable gases, flammable liquids, industrial plants, dust explosions, designers, combustion, turbulence, blast effects, pressure, vents, models, mathematical models, methods, predictions, liquefied petroleum gases ABSTRACT The report is an introduction to vented gas explosions for nonspecialists, particularly designers of plants for flammable gases and liquids. -
Criteria for Transition from Deflagration to Detonation in H2-Air-Steam Mixtures
CRITERIA FOR TRANSITION FROM DEFLAGRATION TO DETONATION IN H2-AIR-STEAM MIXTURES C.K. Chan, W.A. Dewit and G.W. Koroll AECL Whiteshell Laboratories Pinawa, Manitoba R0E 1L0 CANADA ABSTRACT. Flame acceleration and transition to detonation were examined for various H2-air-steam mixtures in a 28 cm diameter, 6.4 m-long, combustion duct filled with obstacles. The run-up distances for DDT (distance between ignition and onset of detonation) were measured for these mixtures and found to be inversely proportional to the laminar burning velocities of the corresponding mixtures. Based on these results, experimental DDT limits were established. Instead of relying on the detonability limits as the conservative criteria for DDT, the experimental DDT limits offer a set of less restrictive criteria. Results also showed that DDT did not occur if a flame had not accelerated to a speed corresponding to a flame Mach number greater than 1.5. This critical value indicates that for H2-air-steam mixtures, the mechanism for DDT is closely related to the strength of its leading shock. Comparison with other experiments confirms that initiation of detonation by shock focusing caused by the reflection of the leading shock off obstacles is the dominant mechanism for DDT in these insensitive mixtures. INTRODUCTION During postulated loss-of-cooling accidents in nuclear power reactors, hydrogen can be produced as a result of metal-steam reactions. This hydrogen can leak into the containment building to form a combustible mixture. If ignited, the pressure loading on local structures resulting from a hydrogen burn, depends on whether the burn is a deflagration or a detonation.