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(NH4)2S CaCl2 BRINGING OUT NaHS CHEMICAL SOLUTIONS NaOH PRODUCTS LIST Aluminium Sulfate Maerl A Ammonium Bifluoride M Magnesium Hydroxide Ammonium Bisulfite Magnesium Chloride Ammonium Sulfide Magnesium Sulfate Heptahydrate Anthracite Magnesium Sulfate Anhydrous Barium Carbonate Granular PDV Salt B Barium Carbonate Free flowing Pigments Barium Chloride dihydrate, anhydrous, liquid P Potassium Alum Barium Hydroxide monohydrate Potassium Carbonate Barium Hydroxide octahydrate Potassium Ferrocyanide Barium Nitrate Potassium Fluoborate Borax Decahydrate Potassium Monopersulfate Boric Acid Granular - Powder - High Purity Potassium Pentaborate Potassium Tetraborate Potassium Hydroxide 90% powder Calcium Chloride liquid (from 31%) Potassium Iodate C Calcium Chloride solid (briquettes, prills, powder) Potassium Sulfite Calcium Formate Calcium Hypochlorite Calcium Nitrate Rubber Mono-concentrates Caustic Potash (Briquettes) R Caustic Potash powder - EUPh/Food Caustic Soda (Briquettes) Salt Tablets - softeners, swimming pool & industrial uses Copper Nitrate Sodium Acetate Copper Sulfate Pentahydrate - Technical/Feed S Sodium Bicarbonate Sodium Bisulfate Sodium Carbonate Decontamination chemicals Sodium Chlorate D Diatomea Sodium Chloride Diphenylamine Sodium Dichloroisocyanurate (56%-60%) - SDIC Sodium Ferrocyanide Food grade - Technical Grade Sodium Formate with or without anticraking agent EDTA Calcium Disodium Salt Granulated Sodium Hydrosulfide NaHS flakes / liquid / paste Sodium Hydroxide solid PRODUCTS LIST PRODUCTS E EDTA Disodium Salt Crystal - Technical/USP/FCC EDTA Ferric Sodium USP Food Sodium Hyposulfite EDTA Salts Sodium Metabisulfite EDTA Tetrasodic Sodium Octaborate Sodium Sulfate anhydrous Sodium Sulfide Na2S flakes / liquid Sodium Tetrasulfide solution F Filtration sand Strontium Carbonate Sweetening catalyst - Refinery Hydrochloric Acid H Trichloroisocyanuric Acid 90% (granular/tablets) - TCCA T Turpentine pure gum Iodine I Isocyanuric Acid Z Zinc Sulfate Heptahydrate / Monohydrate Logistics Warehouses in Europe Own laboratories and worldwide distribution R&D and quality control All products specifications (technical files, safety data sheets, packaging, sieve analysis) are available upon request For any other product please contact our sales department [email protected] - 00334 90 78 70 50 Quadrimex Chemical . 772 chemin du Mitan . 84 300 CAVAILLON . FRANCE.

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United States Patent (19) (11) 4,078,139 Barton Et Al
United States Patent (19) (11) 4,078,139 Barton et al. 45) Mar. 7, 1978 54 PROCESS FOR DEOXYGENATING SECONDARY ALCOHOLS OTHER PUBLICATIONS (75) Inventors: Derek H. R. Barton, London, Perkins, "J. Chem. Soc.,' No. 16, pp. 1574-1585, 1975. England; Stuart W. McCombie, West Hitoshi, et al., "Chem. Abst.," vol. 76, 1972, pp. 127, Orange, N.J. 293x. 73) Assignee: Schering Corporation, Kenilworth, Primary Examiner-Johnnie R. Brown N.J. Attorney, Agent, or Firm-Mary S. King; Stephen B. Coan 21 Appl. No.: 704,703 57 ABSTRACT 22) Filed: Jul. 12, 1976 The process for removing a secondary hydroxyl group from an organic compound having at least one second Related U.S. Application Data ary hydroxyl group and having any amino groups pro (63) Continuation-in-part of Ser. No. 600,704, Jul. 31, 1975, tected, comprises the reaction of a reactive ester of said abandoned. secondary hydroxyl group selected from the group Int, Cl’....................... C07H 15/22; CO7J 31/00 consisting of an O-alkylthioester and an O-alkylseleno U.S. Cl. ................................... 536/17; 260/.397.2; ester with at least one mole of an organotin hydride, 260/.397.4; 260/.397.5; 260/429 R; 260/429.7; preferably tri-n-butylstannane, in an inert, aprotic sol 260/452; 260/455 R; 260/463; 260/596; vent at a temperature of at least about 100° C and under 260/603 R; 260/638 R; 260/666 R; 424/180; an inert atmosphere. 424/181; 424/182; 536/1; 536/4; 536/10; The process is particularly useful in removing second 536/26,536/115; 536/121; 560/106; 548/341 ary alcohols in aminoglycoside antibiotics to produce (58) Field of Search ......................
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Recent Advances in the Synthesis of Five- and Six-Membered Selena
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